Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 1 0 Health Hazard Fire Hazard 2 0 See Section 15. Section 1. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym -Pentanone SPECTRUM CHEMICAL MFG. CORP S. SAN PEDRO STREET GARDENA, CA DEK Diethyl ketone Diethylcetone (French) Dimethylacetone Metacetone Methacetone Pentanone- Propione Catalog Number(s). CAS# RTECS CI# P SA TSCA T S C A 8 ( b ) i n v e n t o r y : -Pentanone Not applicable. Page Number: 1 IN CASE OF EMERGENCY CHEMTREC (24hr) Chemical Name Chemical Family Chemical Formula Supplier -Pentanone Solvent. C5H10O SPECTRUM CHEMICAL MFG. CORP S. SAN PEDRO STREET GARDENA, CA CALL (10) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m ) STEL (mg/m ) CEIL (mg/m ) % by Weight 1) {-}Pentanone Toxicological Data on Ingredients -Pentanone: ORAL (LD50): DERMAL (LD50): VAPOR (LC50): Acute: 2140 mg/kg [Rat]. 200 mg/kg [Mouse]. Acute: mg/kg [Rabbit] mg/kg [Rat]. Acute: 28.5 mg/l 4 hours [Rat].

2 -Pentanone Page Number: 2 Section. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Hazardous in case of eye contact (irritant), of inhalation (lung irritant). Slightly hazardous in case of skin contact (irritant, permeator). CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance may be toxic to lungs, the nervous system, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage. Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Inhalation Serious Inhalation Ingestion Serious Ingestion If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Flammable C ( F) CLOSED CUP: 7 C (44.6 F). OPEN CUP: 1 C (55.4 F). LOWER: 1.6% UPPER: 6.4% These products are carbon oxides (CO, CO2). Highly flammable in presence of open flames and sparks, of heat. Slightly flammable to flammable in presence of oxidizing materials. Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Slightly explosive in presence of oxidizing materials. Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Fire Hazards Explosion Hazards When heated to decomposition it emits acrid smoke and irritating fumes. Reacts with hydrogen peroxide and nitric acid to form a shock-and heat-sensitive explosive peroxide. Violent reaction with oxidizers, causing fire and explosion hazard

3 -Pentanone Page Number: Section 6. Accidental Release Measures Small Spill Large Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids, alkalis. Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves (impervious). Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. TWA: 705 (mg/m ) from OSHA (PEL) [United States] (vacated PELs) TWA: 200 (ppm) from OSHA (PEL) [United States] (vacated PELs) TWA: 200 from NIOSH [United States] TWA: 705 (mg/m ) from NIOSH [United States] TWA: 705 STEL: 881 (mg/m ) [Canada] TWA: 200 STEL: 00 (ppm) [United Kingdom (UK)] TWA: 716 STEL: 895 (mg/m ) [United Kingdom (UK)] TWA: 200 STEL: 250 (ppm) [United Kingdom (UK)] TWA: 200 STEL: 00 (ppm) from ACGIH (TLV) [United States] Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Acetone like Molecular Weight ph (1% soln/water) 86.1 g/mole Taste Color Colorless. Boiling Point C ( F) Melting Point -9 C (-8.2 F) Critical Temperature Specific Gravity (Water = 1) Vapor Pressure.8 kpa (@ 20 C) Vapor Density (Air = 1) Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) The product is more soluble in oil; log(oil/water) =

4 -Pentanone Page Number: 4 Dispersion Properties Solubility See solubility in water. Soluble in cold water. Solubility in Water: deg. C Miscible with ethanol, ether. Soluble in carbon tetrachloride. Section 10. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Heat, ignition sources, incompatible materials Highly reactive with oxidizing agents. Reactive with acids, alkalis. Corrosivity Polymerization Will not occur. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 2140 mg/kg [Rat]. Acute dermal toxicity (LD50): 2100 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 28.5 mg/l 4 hours [Rat]. May cause damage to the following organs: lungs, the nervous system, upper respiratory tract, skin, eyes. Hazardous in case of inhalation (lung irritant). Slightly hazardous in case of skin contact (irritant, permeator). LD50 [Rabbit] - Route: dermal; Dose: 20 ml/kg May affect genetic material (mutagenic) Acute Potential Health Effects: Skin: May cause skin irritation: Mild irritant. It may be absorbed through the skin. Eyes: Causes moderate eye irritation. Inhalation: Causes respiratory tract irritation. Symptoms include coughing, wheezing, shortness of breath. Exposure to high contrations may cause headache, nausea, vomiting, dizziness, lightheadness and fainting. Exposure to higer levels may cause coma. Ingestion: May cause digestive tract irritation. May affect behavior/central nervous system (ataxia). Chronic Potential Health Effects: Skin: It may cause defatting, dryness and cracking of the skin. Section 12. Ecological Information Ecotoxicity BOD5 and COD Ecotoxicity in water (LC50): >500 mg/l 72 hours [Algae (Desmodesmus subspicatus)]. [Daphnia (daphnia)] mg/l 96 hours [Fish (Pimephales promelas)]. >500 mg/l 48 hours Products of Biodegradation Toxicity of the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.

5 -Pentanone Page Number: 5 the Products of Biodegradation Section 1. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information DOT Classification CLASS : Flammable liquid. Identification UNNA: 1156 : Diethylketone PG: II Special Provisions for Transport DOT Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations Pennsylvania RTK: -Pentanone Minnesota: -Pentanone Massachusetts RTK: -Pentanone New Jersey: -Pentanone California Director's List of Hazardous Substances: -Pentanone TSCA 8(b) inventory: -Pentanone TSCA 8(a) PAIR: -Pentanone TSCA 8(d) H and S data reporting: -Pentanone: Effective date: 9/29/2006; Sunset date: 11/28/2006 California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) CLASS B-2: Flammable liquid with a flash point lower than 7.8 C (100 F). DSCL (EEC) R11- Highly flammable. R7- Irritating to respiratory system. S9- Keep container in a well-ventilated place. S16- Keep away from sources of ignition - No smoking. S25- Avoid contact with eyes. S- Take precautionary measures against static discharges. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 2 0 j National Fire Protection Association (U.S.A.) Health 1 0 Flammability Specific hazard

6 -Pentanone Page Number: 6 WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 16. Other Information MSDS Code References Other Special Considerations P228 Major Uses: in organic synthesis; solvent for paints Validated by Sonia Owen on 6/28/2012. Verified by Sonia Owen. Printed 6/28/2012. CALL (10) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.