PRODUCT INFORMATION SHEET

Transcription

1 PRODUCT INFORMATION SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number Synonyms SDS number Product code Issue date Version number Revision date Supersedes date Product use Shock Absorber BWI - None May November November-2015 Industrial use 1.2. Relevant identified uses of the substance or mixture and uses advised against Damper Identified uses Uses advised against None known Details of the supplier of the safety data sheet Company name Address Telephone Contact person 1.4. Emergency telephone number Jaguar Land Rover Limited Abbey Road, Whitley, Coventry CV3 4LF UK +44 (0) (Mo-Thu 08:00-17:00 GMT/Fri 08:00-14:00 GMT) sds-info@msds.landrover.com HSE@rle.de (Worldwide English language number) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 as amended In accordance with the REACH Regulation (EC) No. 1907/ 2006 the manufactured item should be considered as an article and therefore not to be classified according CLP Regulation (EC) No. 1272/ 2008 as amended Label elements Label according to Regulation (EC) No. 1272/2008 as amended In accordance with the REACH Regulation (EC) No. 1907/ 2006 the manufactured item should be considered as a product and therefore not to be labelled according CLP Regulation (EC) No. 1272/ 2008 as amended Other hazards None known. SECTION 3: Composition/information on ingredients 3.2. Mixtures The components are not hazardous or are below required disclosure limits. Fluid under gas pressure within article Composition comments SECTION 4: First aid measures General information 4.1. Description of first aid measures Inhalation Skin contact Eye contact In accordance with the REACH Regulation (EC) No. 1907/2006 the manufactured item (damper) should not be considered as product itself. The manufactured item does not contain substances of very high concern (SVHC) with amounts higher than 0.1%. The mono tube absorbers contain up to 0.5 l compressed gas (nitrogen) at a pressure of 5-30 bar This product causes no risk or danger to persons and the environment if used as intended. 1 / 8

2 Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Specific methods SECTION 6: Accidental release measures The fluid may burn,when heated to high temperatures. The flash point of the oil in the damper fluid is >140 C (>284 F) Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Pressurised container may explode when exposed to heat or flame. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Containers should be cooled with water to prevent vapor pressure build up. In the event of fire, cool tanks with water spray. Move container from fire area if it can be done without risk. Self-contained breathing apparatus and full protective clothing must be worn in case of fire Personal precautions, protective equipment and emergency procedures For non-emergency Keep unnecessary personnel away. Do not touch damaged containers or spilled material unless personnel wearing appropriate protective clothing. For personal protection, see section 8. For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS. If fluid is released: Avoid discharge into drains, water courses or onto the ground. Prevent further leakage or spillage if safe to do so. Stop the flow of material, if this is without risk. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). For personal protection, see section 8. For waste disposal, see section 13 of the SDS. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. The shock absorber as product unit: Obtain special instructions before use. Avoid heat, sparks, open flames and other ignition sources. Pressurised container: Do not pierce or burn, even after use. Pressurised container may explode when exposed to heat or flame Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) If fluid is released: Avoid contact with skin and eyes. Avoid contact with clothing. Avoid heat, sparks, open flames and other ignition sources. Avoid prolonged exposure. Avoid exposure - obtain special instructions before use. Observe good industrial hygiene practices. Store in a dry place. Keep away from heat and sources of ignition. Use care in handling/storage. Beware product of physical damage! Always proof if product has been damaged before storage. Damper SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). 2 / 8

3 Recommended monitoring procedures Derived no-effect level (DNEL) Predicted no effect concentrations (PNECs) Follow standard monitoring procedures Exposure controls Appropriate engineering controls Ensure compliance with applicable exposure limits. Individual protection measures, such as personal protective equipment General information Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Use personal protective equipment as required. Eye/face protection Skin protection - Hand protection - Other Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls Wear safety glasses with side shields (or goggles). Not normally needed. Protective gloves are recommended. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Use personal protective equipment as required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Odour Physical state Form Colour Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Not normally needed. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental manager must be informed of all major releases. Solid. Solid. Fluid under gas pressure within article Colourless. Odourless. Not available > C (> F) Open cup (for the oil in damper fluid) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure Vapour density Relative density Solubility(ies) Solubility (water) Solubility (other) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Not available Not available Insoluble Not flammable 3 / 8

4 Explosive properties Oxidising properties 9.2. Other information Not explosive No relevant additional information available. SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Material is stable under normal conditions. Hazardous polymerisation does not occur. Avoid high temperatures. Strong oxidising agents. Carbon monoxide, carbon dioxide and other hydrocarbon fragments. Nitrogen oxides (NOx). SECTION 11: Toxicological information General information Information on likely routes of exposure Inhalation Skin contact Eye contact Ingestion Symptoms Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Mixture versus substance information Other information No information available. SECTION 12: Ecological information Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol /water (log Kow) Bioconcentration factor (BCF) Mobility in soil Results of PBT and vpvb assessment No data is available on the degradability of this product. No data available Other adverse effects The product contains no substance that fulfils the criteria of PBT- or vpvb substance. 4 / 8

5 SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Dispose of in accordance with local regulations. Avoid discharge into water courses or onto the ground. Empty containers should be taken to an approved waste handling site for recycling or disposal. Pressurized units have to be degassed before disposal. The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal methods/information Special precautions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. Dispose in accordance with all applicable regulations. SECTION 14: Transport information ADR UN number UN UN proper shipping ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC (containing non-flammable gas) name Transport hazard class(es) Class 2 Subsidiary risk - Label(s) 2.2 Hazard No. (ADR) Tunnel restriction code E Packing group Environmental hazards No Special precautions Read safety instructions, SDS and emergency procedures before handling. for user Special provisions 283,371,594 Classification code 6A IATA UN number UN UN proper shipping Articles, pressurized, pneumatic or hydraulic (containing non-flammable gas) name Transport hazard class(es) Class 2.2 Subsidiary risk - Label(s) Packing group Packaging instructions Environmental hazards No. ERG Code 2L Special precautions Read safety instructions, SDS and emergency procedures before handling. for user Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. Maximum net quantity No limit. packaging - Passenger and cargo aircraft Maximum net quantity No limit. packaging cargo only Maximum net quantity Forbidden. packaging - Limited quantity Special provisions A48,A114,A195 IMDG UN number UN UN proper shipping ARTICLES, PRESSURIZED, PNEUMATIC or HYDRAULIC (containing non-flammable gas) name 5 / 8

6 14.3. Transport hazard class(es) Class 2.2 Subsidiary risk Packing group Environmental hazards Marine pollutant No. EmS F-C, S-V Special precautions Read safety instructions, SDS and emergency procedures before handling. for user Special provisions 283,371 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Restrictions on use Other regulations Pregnant women should not work with the product, if there is the least risk of exposure. Directive 2012/18/EU on major accident hazards involving dangerous substances National regulations Chemical safety assessment SECTION 16: Other information List of abbreviations Young people under 18 years old are not allowed to work with this product according to EU Directive 94/33/EC on the protection of young people at work. Follow national regulation for work with chemical agents. No Chemical Safety Assessment has been carried out. A48: Special Provision A48 Packaging tests are not considered necessary. A114: Special Provision A114 Articles, containing gas intended to function as shock absorbers, including impact energy absorbing devices or pneumatic springs are not subject to these Regulations provided: a) each article has a gas space capacity not exceeding 1.6 L and a charge pressure not exceeding 280 bar where the product of the capacity (litres) and charge pressure (bars) does not exceed 80 (i.e. 0.5 L gas space and 160 bar change pressure, 1 L gas space and 80 bar charge pressure, 1.6 L gas space and 50 bar charge pressure, 0.28 L gas space and 280 bar charge pressure); b) each article has a minimum burst pressure of 4 times the charge pressure at 20 C for products not exceeding 0.5 L gas space capacity and 5 times charge pressure for products greater than 0.5 L gas space capacity; c) each article is manufactured from material which will not fragment upon rupture; d) each article is manufactured in accordance with a quality assurance standard acceptable to the appropriate national authority; and e) the design type has been subjected to a fire test demonstrating that pressure in the article is relieved by means of a fire-degradable seal or other pressure-relief device such that the article will not fragment and the article does not rocket. A195: Special Provision A This entry also applies to articles, containing a small pressure receptacle with a release device. Such articles must comply with the following requirements: a) the water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C; b) the minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C; 6 / 8

7 c) each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. This may be fulfilled by an additional locking device linked to the activator; d) each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; e) each pressure receptacle must be manufactured from material which will not fragment upon rupture; f) the design type of the article must be subjected to a fire test. For this test, the provisions of paragraphs except letter g, to , (b) and of the UN Manual of Tests and Criteria must be applied. It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 metres; g) the design type of the article must be subjected to the following test. A stimulating mechanism must be used to initiate one article in the middle of the packaging. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. 2. The manufacturer must produce technical documentation of the design type, manufacture as well as the tests and their results. The manufacturer must apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in 1). The manufacturer must provide such information to the appropriate national authority on request. 283: Special Provision 283 Articles, containing gas,intended to function as shock absorbers, including impact energy-absorbing devices; or pneumatic springs are not subject to the requirements of ADR provided: a) each article has a gas space capacity not exceeding 1.6 L and a charge pressure not exceeding 280 bar where the product of the capacity (litres) and charge pressure (bars) does not exceed 80 (i.e. 0.5 L gas space and 160 bar change pressure, 1 L gas space and 80 bar charge pressure, 1.6 L gas space and 50 bar charge pressure, 0.28 L gas space and 280 bar charge pressure); (i.e. 0.5 litres gas space and 160 bar charge pressure, 1 litre gas space and 80 bar charge pressure, 1.6 litres gas space and 50 bar charge pressure, 0.28 litres gas space and 280 bar charge pressure) b) each article has a minimum burst pressure of 4 times the charge pressure at 20 C for products not exceeding 0.5 L gas space capacity and 5 times charge pressure for products greater than 0.5 L gas space capacity; c) each article is manufactured from material which will not fragment upon rupture; d) each article is manufactured in accordance with a quality assurance standard acceptable to the appropriate national authority; and e) the design type has been subjected to a fire test demonstrating that pressure in the article is relieved by means of a fire-degradable seal or other pressure-relief device such that the article will not fragment and the article does not rocket. See also (d) for equipment used for the operation of the vehicle 371: Special Provision This entry also applies to articles, containing a small pressure receptacle with a release device. Such articles must comply with the following requirements: a) the water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C; b) the minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C; 7 / 8

8 c) each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. This may be fulfilled by an additional locking device linked to the activator; d) each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; e) the design type has been subjected to a fire test demonstrating that pressure in the article is relieved by means of a fire-degradable seal or other pressure-relief device such that the article will not fragment and the article does not rocket. f) the design type of the article must be subjected to a fire test. For this test, the provisions of paragraphs except letter g, to , (b) and of the UN Manual of Tests and Criteria must be applied. It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 metres; g) the design type of the article must be subjected to the following test. A stimulating mechanism must be used to initiate one article in the middle of the packaging. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. 2. The manufacturer must produce technical documentation of the design type, manufacture as well as the tests and their results. The manufacturer must apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in 1). The manufacturer must provide such information to the appropriate national authority on request. 594: Special Provision 594 The following articles, manufactured and filled according to the regulations of the manufacturing State and packaged in strong outer packagings, are not subject to the requirements of ADR. UN No fire extinguishers provided with protection against inadvertent discharge; UN No References Information on evaluation method leading to the classification of mixture Full text of any H-statements not written out in full under Sections 2 to 15 Revision information Training information Disclaimer articles, pressurized pneumatic or hydraulic, designed to withstand stresses greater than internal gas pressure by virtue of transmission of force, intrinsic strength or construction. The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. None. This document has undergone significant changes and should be reviewed in its entirety. Follow training instructions when handling this material. The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. 8 / 8

9 Attachment to the Safety Data Sheet Involved Products: LR Part Number Container size LR Part Number Container size 1 LR Part 2 LR Part 3 LR Part 4 LR Part 5 LR Part 6 LR Part 7 LR Part 8 LR Part 9 LR Part 10 LR Part 11 LR Part 12 LR Part 13 LR Part 14 LR Part 15 LR Part 16 LR Part 17 LR Part 18 LR Part 19 LR Part 20 LR Part 21 LR Part 22 LR Part 23 LR Part 24 LR Part 25 LR Part 26 LR Part 27 LR Part 28 LR Part 29 LR Part 30 LR Part 31 LR Part 32 LR Part 33 LR Part 34 LR Part 35 LR Part 36 LR Part 37 LR Part 38 LR Part 39 LR Part 40 LR Part 41 LR Part 42 LR Part 43 LR Part 44 LR Part 45 LR Part 46 LR Part 47 LR Part 48 RNB Part 49 RNB Part 50 RNB Part 51 RNB Part 52 RNB Part 53 RNB Part 54 RNB Part 55 RNB Part 56 RNB Part 57 RNB Part 58 RNB Part 59 RNB Part 60 RNB Part 61 RPD Part 62 RPD Part 63 RPD Part 64 RPD Part 65 RPD Part 66 RPD Part 67 RPD Part 68 RPD Part 69 RPM Part 70 RPM Part 71 RPM Part 72 RPM Part 73 RSC Part 74 RSC Part 75 RSC Part 76 RSC Part 77 RSC Part 78 RSC Part 79 RSC Part 80 RSC Part 81 RSC Part Shock Absorber BWI 1 / 1