Risalah Data Keselamatan Safety data sheet

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1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/17 1. Pengenalan bahan kimia dan pembekal Cegesoft PS 6 Nama bahan kimia: Triglyceride Kegunaan: kandungan kosmetik, Lipid layer enhancer Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Tidak memerlukan pengelasan menurut kriteria GHS untuk produk ini. Unsur label dan pernyataan berjaga-jaga: Produk tidak memerlukan label amaran bahaya menurut kriteria GHS. Bahaya lain yang tidak menyebabkan pengelasan: Tiada bahaya khusus yang diketahui jika peraturan/nota tentang penyimpanan dan pengendalian diberikan perhatian.

2 Mukasurat (Page): 2/17 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Vegetable oil Nombor CAS: Langkah-Langkah Pertolongan Cemas Nasihat am: Jika kesan-kesan kesihatan yang buruk berkembang dapatkan rawatan perubatan. Jika tersedut: tidak berkenaan. Apabila terkena kulit: Jika terkena kulit, segera basuh dengan air yang banyak. Apabila terkena mata: Jika terkena mata, segera basuh selama sekurang-kurangnya 15 minit dengan air yang banyak. Dapatkan perhatian perubatan jika perlu. Apabila tertelan: Segera basuh mulut dan kemudian minum ml air. Nota kepada doktor: Gejala: Tiada gejala yang ketara dijangka oleh kerana pengelasan tidak diperlukan untuk produk ini. Nota kepada doktor: Bahaya: Tiada bahaya dijangka dengan penggunaan yang disyorkan dan pengendalian yang sesuai. Rawatan: Rawat mengukit gejala. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: semburan air, karbon dioksida, serbuk kering, busa Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap. Maklumat lanjut: Lupuskan sisa kebakaran dan air pemadam api yang tercemar menurut peraturan rasmi.

3 Mukasurat (Page): 3/17 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Gunakan pakaian pelindung diri. Langkah berjaga-jaga untuk alam sekitar: Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah kecil: Kutip dengan bahap penyerap yang sesuai. Bagi sejumlah besar: Bina benteng tumpahan. Pam produk. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Perlindungan terhadap kebakaran dan letupan: Ambil langkah berjaga-jaga terhadap luahan statik. Jauhkan dari semua sumber pencucuhan: haba, percikan api, nyalaan terbuka. Penyimpanan Asingkan daripada pengoksida. Bahan yang sesuai untuk bekas: kaca, salutan zink, keluli karbon (besi) Maklumat lanjut tentang keadaan penyimpanan: Pastikan bekas tertutup rapat dan kering; simpan di tempat yang dingin. Kestabilan penyimpanan: Suhu penyimpanan: <= 30 C 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja vegetable oils, ; Nilai TWA 10 mg/m3 (OEL (Peraturan USECHH Malaysia)), Kabut Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan tidak diperlukan.

4 Mukasurat (Page): 4/17 Perlindungan tangan: Sarung tangan pelindung yang sesuai dengan spesifikasi berikut. Cadangan tersebut adalah sah untuk keadaan makmal, keadaan tempat kerja yang khusus perlu diambil kira secara berasingan Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374): getah nitril (NBR) mm ketebalan salutan Perlindungan mata: Kaca mata keselamatan dengan pelindung sisi (gogal berbingkai) (contohnya EN 166) Perlindungan badan: Perlindungan badan mesti dipilih bergantung kepada aktiviti dan pendedahan, contohnya apron, kasut perlindungan, pakaian perlindungan bahan kimia (Berdasarkan DIN-EN 465) Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Jangan makan, minum, merokok atau menggunakan tembakau di tempat kerja. Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: nilai ph: cecair kekuningan hampir tiada bau Tidak boleh digunakan Tidak boleh digunakan julat lebur: 2-10 C takat didih: tidak ditentukan Takat kilat: > 200 C Tahap penyejatan: Nilai boleh dianggarkan berdasarkan Pemalar Hukum Henry atau tekanan wap. Kemudahbakaran (pepejal/gas): tidak mencucuh Had letupan bawah: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Had letupan atas: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Suhu pencucuhan: tidak ditentukan

5 Mukasurat (Page): 5/17 Penguraian terma: pencucuhan sendiri: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Tidak boleh digunakan Bahaya letupan: tidak mudah meletup Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: < 0.01 mbar (200 C) Kepekatan: g/cm3 (25 C) Ketumpatan wap relatif (udara): Tidak boleh digunakan Keterlarutan dalam air: tidak terlarut Keterlarutan (kualitatif) pelarut: air suling tidak terlarut Pekali petakan n-oktanol/air (log Pow): tidak ditentukan Kelikatan, dinamik: Kelikatan, kinematik: mpa*s (25 C) mpa*s (50 C) tidak ditentukan Maklumat lain: Jika perlu, maklumat tentang parameter fizikal and kimia ada dinyatakan didalam bahagian ini. Tiada maklumat lain didapati. 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Lihat MSDS bahagian 7 - Pengendalian dan Penyimpanan. Penguraian terma: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Bahan yang perlu dielakkan: agen pengoksida Tindak balas berbahaya: Tiada jika digunakan untuk tujuan yang dimaksudkan. Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan.

6 Mukasurat (Page): 6/ Maklumat Toksikologi Ketoksikan akut Penilaian ketoksikan akut: Tidak toksik selepas sekali ditelan. Data eksperimen/dikira: LD50 tikus (melalui mulut): > 2,000 mg/kg Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kerengsaan Penilaian kesan merengsa: Tidak merengsakan mata. Tidak merengsakan kulit. Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: merengsa sedikit Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kerosakkan/kerengsaan mata yang serius arnab: tidak merengsa Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Pemekaan pernafasan/kulit Penilaian pemekaan: Tidak terdapat bukti pemekaan kulit yang berpotensi. Kemutagenan sel germa Penilaian kemutagenan: Struktur kimia tidak menunjukkan amaran khusus bagi kesan tersebut. Data eksperimen/dikira: Ujian Ames Bakteria: negatif Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kekarsinogenan Penilaian kekarsinogenan: Struktur kimia tidak menunjukkan amaran khusus bagi kesan tersebut. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Struktur kimia tidak menunjukkan amaran khusus bagi kesan tersebut.

7 Mukasurat (Page): 7/17 Ketoksikan perkembangan Penilaian keteratogenan: Tiada data diperoleh tentang ketoksikan. Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Maklumat yang ada tentang produk tidak memberi petunjuk tentang ketoksikan kepada organ sasaran selepas pendedahan secara berulang-ulang. Bahaya penyedutan Tiada bahaya penyedutan dijangka. 12. Maklumat Ekologi Keekotoksikan Ketoksikan kepada ikan: LC50 > 100 mg/l, Brachydanio rerio Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC0 > 100 mg/l, Pseudomonas putida Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Tidak boleh digunakan Keterusan dan boleh keterdegradasikan Penilaian biodegradasi dan penyingkiran (H2O): Mudah terbiodegradasikan (menurut kriteria OECD) Maklumat penyingkiran: Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Potensi Biotumpukan

8 Mukasurat (Page): 8/17 Penilaian potensi bioakumilasi: Tiada data diperoleh. 13. Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. Pembungkusan tercemar: Bungkusan yang tidak tercemar boleh diguna semula. Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya. 14. Maklumat Pengangkutan Pengangkutan domestik: Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan laut IMDG Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan udara IATA/ICAO Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan Peraturan lain

9 Mukasurat (Page): 9/17 Jika maklumat peraturan lain yang berkenaan tidak dinyatakan dibahagian lain didalam risalah data keselamatan ini, ianya akan dinyatakan bahagian ini. 16. Maklumat lain Maklumat bagi penggunaan yang dirancang: Produk ini adalah berkualiti untuk industri dan sekiranya tidak dinyatakan atau dipersetujui harus digunakan semata-mata untuk kegunaan industri. Ini termasuk penggunaan yang dinyatakan dan disyorkan. Sebarang tujuan penggunaan lain hendaklah dibincangkan dengan pengeluar. Secara khususnya, ini berkaitan dengan penggunaan bagi produk yang menjadi objek piawai dan peraturan khas Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

10 Mukasurat (Page): 10/17 1. Identification of the chemical and of the supplier Cegesoft PS 6 Chemical name: Triglyceride Use: Lipid layer enhancer Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: No need for classification according to GHS criteria for this product. Label elements and precautionary statement: The product does not require a hazard warning label in accordance with GHS criteria. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Vegetable oil CAS Number: First-Aid Measures General advice: If adverse health effects develop seek medical attention.

11 Mukasurat (Page): 11/17 If inhaled: not relevant. On skin contact: After contact with skin, wash immediately with plenty of water. On contact with eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Seek medical attention if necessary. On ingestion: Rinse mouth and then drink ml of water. Note to physician: Symptoms: No significant symptoms are expected due to the non-classification of the product. Note to physician: Hazards: No hazard is expected under intended use and appropriate handling. Treatment: Treat symptomatically. 5. Fire-Fighting Measures Suitable extinguishing media: water spray, carbon dioxide, dry powder, foam Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable absorbent material. For large amounts: Dike spillage. Pump off product. Dispose of absorbed material in accordance with regulations.

12 Mukasurat (Page): 12/17 7. Handling and Storage Handling Handle in accordance with good industrial hygiene and safety practice. Protection against fire and explosion: Take precautionary measures against static discharges. Avoid all sources of ignition: heat, sparks, open flame. Storage Segregate from oxidants. Suitable materials for containers: glass, Galvanized carbon steel (Zinc), Carbon steel (Iron) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Storage stability: Storage temperature: <= 30 C 8. Exposure controls and personal protection Components with occupational exposure limits vegetable oils, ; TWA value 10 mg/m3 (OEL (MY)), Mist Personal protective equipment Respiratory protection: Respiratory protection not required. Hand protection: Suitable are protective gloves with the following specification. The recommendation is valid for laboratory conditions, specific workplace conditions must be taken into consideration separately. Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): nitrile rubber (NBR) mm coating thickness Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust).

13 Mukasurat (Page): 13/17 General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: ph value: liquid yellowish almost odourless not applicable not applicable melting range: 2-10 C Boiling point: not determined Flash point: > 200 C Evaporation rate: Value can be approximated from Henry's Law Constant or vapor pressure. Flammability (solid/gas): not flammable Lower explosion limit: For liquids not relevant for classification and labelling. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: not determined Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Self ignition: not applicable Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: < 0.01 mbar (200 C) Density: g/cm3 (25 C) Relative vapour density (air): not applicable Solubility in water: insoluble

14 Mukasurat (Page): 14/17 Solubility (qualitative) solvent(s): distilled water insoluble Partitioning coefficient n-octanol/water (log Pow): not determined Viscosity, dynamic: Viscosity, kinematic: mpa*s (25 C) mpa*s (50 C) not determined Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. No further information available. 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: oxidizing agents Hazardous reactions: None if used for intended purpose. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Irritation Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin.

15 Mukasurat (Page): 15/17 Experimental/calculated data: Skin corrosion/irritation rabbit: Slightly irritating. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Serious eye damage/irritation rabbit: non-irritant The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Respiratory/Skin sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Germ cell mutagenicity Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect. Experimental/calculated data: Ames-test Bacteria: negative The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Reproductive toxicity Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect. Developmental toxicity Assessment of teratogenicity: No data was available concerning toxicity to development. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on available Data, the classification criteria are not met. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The information available on the product provides no indication of toxicity on target organs after repeated exposure. Aspiration hazard

16 Mukasurat (Page): 16/17 No aspiration hazard expected. 12. Ecological Information Ecotoxicity Toxicity to fish: LC50 > 100 mg/l, Brachydanio rerio The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Microorganisms/Effect on activated sludge: EC0 > 100 mg/l, Pseudomonas putida The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Mobility Assessment transport between environmental compartments: not applicable Persistence and degradability Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). Elimination information: The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Bioaccumulation potential Assessment bioaccumulation potential: No data available. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations

17 Mukasurat (Page): 17/17 Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated 15. Regulatory Information Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. 16. Other Information Information on intended use: This product is of industrial quality and unless otherwise specified or agreed intended exclusively for industrial use. This includes the mentioned and recommended usage. Any other intended applications should be discussed with the manufacturer. In particular this concerns the application for products that are the object of special standards and regulations. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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