SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 1.1 Revision date: Product identifier: Sodium Cyanoborohydride

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1 SAFETY DATA SHEET Version: Identification Product identifier: Sodium Cyanoborohydride Other means of identification Product No.: C540, V037 Recommended use and restriction on use Recommended use: Not available. Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company Name: Avantor Performance Materials, Inc. Address: 3477 Corporate Parkway, Suite 200 Center Valley, PA Telephone: Customer Service: Fax: Contact Person: Environmental Health & Safety Emergency telephone number: 24 Hour Emergency: Chemtrec: Hazard(s) identification Hazard classification Physical hazards Flammable solid Category 2 Health hazards Acute toxicity (Oral) Category 2 Acute toxicity (Dermal) Category 2 Acute toxicity (Inhalation - dust and Category 2 mist) Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Unknown toxicity Acute toxicity, oral 100 % Acute toxicity, dermal 100 % Acute toxicity, inhalation, dust or mist 100 % Environmental hazards Label elements Acute hazards to the aquatic environment Chronic hazards to the aquatic environment Hazard symbol: Category 1 Category 1 SDS_US - SDS /10

2 Signal word: Hazard statement: Danger Flammable solid. Fatal if swallowed, in contact with skin or if inhaled. Causes severe skin burns and eye damage. Very toxic to aquatic life with long lasting effects. Precautionary statement Prevention: Response: Storage: Disposal: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. In case of fire: Use dry chemical powder for extinction. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Specific treatment is urgent (see this label). Wash contaminated clothing before reuse. Collect spillage. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not result in GHS classification: None. 3. Composition/information on ingredients Substances Chemical identity Common name and synonyms CAS number Content in percent (%)* % * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures General information: Get medical advice/attention if you feel unwell. Show this safety data sheet to the doctor in attendance. SDS_US - SDS /10

3 Ingestion: Inhalation: Skin contact: Eye contact: Call a physician or poison control center immediately. Rinse mouth. Never give liquid to an unconscious person. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not induce vomiting without advice from poison control center. Move to fresh air. If breathing stops, provide artificial respiration. If breathing is difficult, give oxygen. Call a physician or poison control center immediately. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. Call a physician or poison control center immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. Most important symptoms/effects, acute and delayed Symptoms: Causes severe skin and eye burns. Respiratory tract irritation. Causes digestive tract burns. This material may produce methemoglobin which, in sufficient concentration, causes cyanosis, a blue-gray discoloration of the skin and lips caused by a reduced ability of the blood to carry oxygen. Indication of immediate medical attention and special treatment needed Treatment: Treat symptomatically. Symptoms may be delayed. 5. Fire-fighting measures General fire hazards: Flammable solid. Powdered material may form explosive dust-air mixtures. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Dry chemical. Do not use water as an extinguisher. Flammable solid. Dust may form explosive mixture with air. Material reacts with water. Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Material reacts with water. Fight fire from a protected location. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: See Section 8 of the MSDS for Personal Protective Equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unauthorized personnel away. Ventilate closed spaces before entering them. SDS_US - SDS /10

4 Methods and material for containment and cleaning up: Notification Procedures: Environmental precautions: Avoid dust formation. Sweep up and place in a clearly labeled container for chemical waste. Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid release to the environment. 7. Handling and storage Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid generation and spreading of dust. Use personal protective equipment as required. Do not get in eyes, on skin, on clothing. Do not taste or swallow. Do not eat, drink or smoke when using the product. Use only with adequate ventilation. Wash hands thoroughly after handling. The substance is hygroscopic and will absorb water by contact with the moisture in the air. Keep container tightly closed. Keep in a cool, ventilated location far from heat source and flame Keep under nitrogen. 8. Exposure controls/personal protection Control parameters Occupational exposure limits Chemical identity Type Exposure Limit values Source - Inhalable fraction. - as CN Appropriate engineering controls STEL 6 mg/m3 US. ACGIH Threshold Limit Values (2011) TWA 2 mg/m3 US. ACGIH Threshold Limit Values (2011) PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) ( ) TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR ) (1989) Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin protection Hand protection: Other: Respiratory protection: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. An eye wash and safety shower must be available in the immediate work area. Wear safety glasses with side shields (or goggles). Wear a full-face respirator, if needed. Chemical resistant gloves Wear suitable protective clothing and gloves. In case of inadequate ventilation use suitable respirator. SDS_US - SDS /10

5 Hygiene measures: Provide eyewash station and safety shower. Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. Do not eat, drink or smoke when using the product. Wash contaminated clothing before reuse. 9. Physical and chemical properties Appearance Physical state: Solid Form: Powder. Color: White Odor: Odor threshold: ph: Melting point/freezing point: 240 C Initial boiling point and boiling range: Flash Point: Evaporation rate: Flammability (solid, gas): Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Relative density: 1.2 (20 C) Solubility(ies) Solubility in water: Soluble Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: 10. Stability and reactivity Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible materials: Hazardous decomposition products: No dangerous reaction known under conditions of normal use. Material is stable under normal conditions. Hazardous polymerization does not occur. Heat, sparks, flames. Contact with incompatible materials. Strong oxidizing agents. Water. Acids. Carbon monoxide Carbon dioxide Hydrogen cyanide. 11. Toxicological information Information on likely routes of exposure SDS_US - SDS /10

6 Ingestion: Inhalation: Skin contact: Eye contact: Fatal if swallowed. May cause burns of the gastrointestinal tract if swallowed. Fatal if inhaled. May cause irritation to the respiratory system. Fatal in contact with skin. Causes severe skin burns. Causes serious eye damage. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Dermal Inhalation Repeated dose toxicity Skin corrosion/irritation Causes severe skin burns. Serious eye damage/eye irritation Causes serious eye damage. Respiratory or skin sensitization Carcinogenicity Not a skin sensitizer. This substance has no evidence of carcinogenic properties. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ cell mutagenicity In vitro In vivo Reproductive toxicity No mutagenic components identified No mutagenic components identified No components toxic to reproduction Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard SDS_US - SDS /10

7 Other effects: Not classified This material may produce methemoglobin which, in sufficient concentration, causes cyanosis, a blue-gray discoloration of the skin and lips caused by a reduced ability of the blood to carry oxygen. 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic invertebrates Chronic hazards to the aquatic environment: Fish Aquatic invertebrates Toxicity to Aquatic Plants Persistence and degradability Biodegradation BOD/COD ratio There are no data on the degradability of this product. Bioaccumulative potential Bioconcentration factor (BCF) No data available on bioaccumulation. Partition coefficient n-octanol / water (log Kow) Mobility in soil: Other adverse effects: Very toxic to aquatic life with long lasting effects. 13. Disposal considerations Disposal instructions: Contaminated packaging: Discharge, treatment, or disposal may be subject to national, state, or local laws. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Do not allow to enter drains, sewers or watercourses. Since emptied containers retain product residue, follow label warnings even after container is emptied. SDS_US - SDS /10

8 14. Transport information DOT UN number: UN 3179 UN proper shipping name: Transport hazard class(es) Class(es): 4.1, 6.1 Label(s): 4.1, 6.1 Packing group: Marine Pollutant: Flammable solid, toxic, inorganic, n.o.s.( ) II No IMDG UN number: UN 3179 UN proper shipping name: Transport hazard class(es) Class(es): 4.1, 6.1 Label(s): 4.1, 6.1 EmS No.: F-A, S-G Packing group: Marine Pollutant: FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S.( ) II No IATA UN number: UN 3179 Proper Shipping Name: Transport hazard class(es): Class(es): 4.1, 6.1 Label(s): 4.1, 6.1 Marine Pollutant: Packing group: Flammable solid, toxic, inorganic, n.o.s.( ) No II 15. Regulatory information US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.4): Superfund amendments and reauthorization act of 1986 (SARA) Hazard categories X Acute (Immediate) X Chronic (Delayed) X Fire X Reactive Pressure Generating SARA 302 Extremely hazardous substance None present or none present in regulated quantities. SARA 304 Emergency release notification Chemical identity RQ SDS_US - SDS /10

9 SARA 311/312 Hazardous chemical Chemical identity Threshold Planning Quantity 500 lbs SARA 313 (TRI reporting) Chemical identity Reporting threshold for other users Reporting threshold for manufacturing and processing lbs lbs. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ): None present or none present in regulated quantities. US state regulations US. California Proposition 65 No ingredient regulated by CA Prop 65 present. US. New Jersey Worker and Community Right-to-Know Act Listed US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances Listed US. Rhode Island RTK Listed Inventory Status: Australia AICS: Canada DSL Inventory List: EU EINECS List: EU ELINCS List: Japan (ENCS) List: EU No Longer Polymers List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: 16.Other information, including date of preparation or last revision SDS_US - SDS /10

10 NFPA Hazard ID Flammability Health Reactivity Special hazard. Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe : Water reactive Issue date: Revision date: Version #: 1.1 Further information: Disclaimer: THE INFORMATION PRESENTED IN THIS MATERIAL SAFETY DATA SHEET (MSDS/SDS) WAS PREPARED BY TECHNICAL PERSONNEL BASED ON DATA THAT THEY BELIEVE IN THEIR GOOD FAITH JUDGMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED HEREIN IS PROVIDED AS IS, AND AVANTOR PERFORMANCE MATERIALS MAKES AND GIVES NO REPRESENTATIONS OR WARRANTIES WHATSOEVER, AND EXPRESSLY DISCLAIMS ALL WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT TO WHICH IT RELATES, WHETHER EXPRESS, IMPLIED, OR STATUTORY, INCLUDING WITHOUT LIMITATION, WARRANTIES OF ACCURACY, COMPLETENESS, MERCHANTABILITY, NON- INFRINGEMENT, PERFORMANCE, SAFETY, SUITABILITY, STABILITY, AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES ARISING FROM COURSE OF DEALING, COURSE OF PERFORMANCE, OR USAGE OF TRADE. THIS MSDS/SDS IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT, AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER AND CONDITIONS OF USE, HANDLING, STORAGE, OR DISPOSAL OF THE PRODUCT. INDIVIDUALS RECEIVING THIS MSDS/SDS MUST ALWAYS EXERCISE THEIR OWN INDEPENDENT JUDGMENT IN DETERMINING THE APPROPRIATENESS OF SUCH ISSUES. ACCORDINGLY, AVANTOR PERFORMANCE MATERIALS ASSUMES NO LIABILITY WHATSOEVER FOR THE USE OF OR RELIANCE UPON THIS INFORMATION. NO SUGGESTIONS FOR USE ARE INTENDED AS, AND NOTHING HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL, STATE, LOCAL, OR FOREIGN LAWS. AVANTOR PERFORMANCE MATERIALS REMINDS YOU THAT IT IS YOUR LEGAL DUTY TO MAKE ALL INFORMATION IN THIS MSDS/SDS AVAILABLE TO YOUR EMPLOYEES. SDS_US - SDS /10