: Master FlorPlus 307 NS

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1 RISALAH DATA KESELAMATAN SAFETY DATA SHEET Tarikh Penyediaan : Nombor Rujukan : 09-Sep-14 Date Prepared : Reference No. : Master FlorPlus307NS_ _V1 BAHAGIAN 1 : PENGENALPASTIAN BAHAN / CAMPURAN DAN SYARIKAT BERKENAAN SECTION 1 : IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY UNDERTAKING 1.1 Maklumat Produk / Product identifier Nama Produk / Product Name : Master FlorPlus 307 NS 1.2 Penggunaan bahan atau campuran yang dikenalpasti dan penggunaan yang harus dielakkan Relevant identified uses of the substance or mixture and uses advised against Nama Kimia Chemical Name : Adunan simen dan batu baur keras (pigmen/tanpa pigmen) : Powdered blend of cement and quartz aggregates (with/without pigment) Huraian Produk / Product Description Berat Molekul / Molecular Weight Kumpulan Bahan Kimia Chemical Family Kegunaan Use : Bahan pengeras untuk lantai berasaskan simen Cement based floor hardener : Tiada / N/A : Tiada kaitan : Not applicable : Rujuk kepada risalah data produk. : Refer to product data sheet. 1.3 Maklumat Pembekal Risalah Data Keselamatan / Details of the Supplier of the Safety Data Sheet Nama dan Alamat Pengilang / Manufacturer's Name and Address : MC Bauchemie (Malaysia) Sdn Bhd Lot 996, Jalan Sungai Lalang, Batu 23, WDT 227, Semenyih, Selangor Darul Ehsan Nombor Telefon / Telephone No. : (603) Nombor Fax / Fax No. (603) Nama dan Alamat Pengimport/ Pengeluar Tempatan Importer's / Distributor's Name and Address : MC Bauchemie (Malaysia) Sdn Bhd Lot S113, 2nd Floor, Centrepoint, No. 3 Lebuh Bandar Utama, Bandar Utama, Petaling Jaya Selangor Darul Ehsan Nombor Telefon / Telephone No. : (603) Nombor Fax / Fax No. (603) E-mel / Nombor Telefon Kecemasan / : (603) Emergency Telephone No. Waktu Kerja / Opening hours : Isnin - Jumaat ( ) / Monday - Friday ( ) BAHAGIAN 2 : PENGENALPASTIAN BAHAYA SECTION 2 : HAZARDS IDENTIFICATION 2.1 Klasifikasi menurut Arahan 67/548/EEC & 1999/45/EC : Xi, R37/38, R41 Classification according to Directive 67/548/EEC & 1995/45/EC 2.2 Unsur-unsur Label / Label Elements Label menurut Arahan (EC) No 1272/2008 (CLP) / Labelling according to Regulation (EC) No 1272/2008 (CLP) Piktogram Bahaya/ Hazard Pictograms Ungkapan Simbol / Signal Word Bahaya / Danger Page 1 of 6

2 Unkapan Bahaya / Hazard Statements H315 - Merengsa kulit / Causes skin irritation H318 - Menjejaskan mata secara serius / Causes serious eye damage H335 - Boleh menyebabkan kerengsaan pernafasan / May cause respiratory irritation Kenyataan Berjaga-jaga / Precautionary Statements Pencegahan / Prevention : P280 - Pakai sarung tangan perlindungan/ pakaian perlindungan/ pelindung mata/ pelindung muka / Wear protective glove / protective clothing/ eye protection/ face protection. P261 - Elakkan dari menghidu debu/ wasap/ gas/ kabut/ wap/ semburan / Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 - Gunakan hanya di luar bangunan atau di kawasan yang mempunyai pengudaraan yang baik / Use only outdoors or in a well-ventilated area. Tindakbalas / Response : P302+P312 - JIKA TERKENA KULIT: Basuh dengan sabun dan air yang banyak / IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 - JIKA TERKENA MATA: Bilas berhati-hati dengan air selama beberapa minit. Tanggalkan kanta lekap, jika ada dan mudah dikeluarkan. Teruskan membilas. / IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 - JIKA TERSEDUT : Pindahkan mangsa ke udara segar dan biarkan berehat di kedudukan yang selesa untuk bernafas / IF INHALED : Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 - Hubungi ahli perubatan secepat mungkin / Immediately call a POISON CENTER or doctor/physician. P332 - Jikalau kulit merengsa, dapatkan nasihat perubatan / If skin irritation occurs: Get medical advice/ attention. P362 - Tanggalkan pakaian yang tercemar dan basuh sebelum memakai semula / Take off contaminated clothing and wash before reuse. P264 - Basuh tangan dengan sempurna selepas pengendalian / Wash hand thoroughly after handling. Penyimpanan / Storage : P403 + P233 - Simpan di tempat yang mempunyai pengudaraan yang baik. Pastikan bekas sentiasa ditutup rapat / Store in a well-ventilated place. Keep container tightly closed. P405 - Kunci tempat simpanan / Store locked up. Pembuangan / Disposal : P501 - Pembuangan sisa di tempat yang dikhususkan / Dispose of contents/ /container to authorised landfill BAHAGIAN 3 : KOMPOSISI / MAKLUMAT RAMUAN SECTION 3 : COMPOSITION / INFORMATION ON INGREDIENT 3.1 Bahan / Substances : Rujuk bahan campuran di bawah / Refer section below for composition of mixtures 3.2 Bahan Campuran / Mixtures No. CAS / CAS No. Berat/ Weight Nama / Name % Simen Portland / Portland Cement Klasifikasi GHS / GHS Classification Kakisan / kerengsaan kulit 2, kerosakan mata yang serius / kerengsaan mata 1, STOT - SE - Kerengsaan saluran pernafasan 3; H315, H318, H335 Skin corrosion / irritation 2, serious eye damage / eye irritation 1, STOT - SE - respiratory tract irritation 3; H315, H318, H335 BAHAGIAN 4 : LANGKAH - LANGKAH PERTOLONGAN CEMAS SECTION 4 : FIRST AID MEASURES 4.1 Penerangan pertolongan cemas / Description of first aid measures Sentuhan mata Eye contact Sentuhan kulit Skin contact : Jikalau terkena mata, basuh mata dengan air bersih yang banyak dengan segera selama 15 minit. Dapatkan bantuan perubatan dengan segera jika kerengsaan berlaku. : If eyes are contaminated, flush them immediately without delay with large amount of clean water for at least 15 minutes. Seek medical attention immediately if irritation occurs. : Tanggalkan pakaian dan kasut yang tercemar - basuh terlebih dahulu sebelum memakainya semula. Bilas kulit yang terkena dengan air yang banyak selama 15 minit. Gunakan sabun untuk mencuci kulit yang terkena. : Remove contaminated clothes and shoes - launder before reuse. Wash all splashes immediately with plenty of water for 15 minutes. Use soap to clean the contaminated skin. Page 2 of 6

3 Penyedutan Inhalation Pengingesan Ingestion : Alih orang yang terdedah ke kawasan udara segar. Dapatkan pemeriksaan perubatan jika kesan mudarat ke atas kesihatan berterusan. : Remove the affected patient to fresh air place. Obtain medical assistance if symptoms persist. : Basuh mulut dengan air. Jika tertelan dan orang yang mengalami dedahan sedar, berikan sedikit air untuk minum. Jangan berikan apa-apa ke mulut orang yang tidak sedar. Hubungi doktor dengan segera. : Wash mouth with water. If ingested, and the exposed person is conscious, give small quantity of water to drink. Never give anything by mouth to an unconscious person. Contact a physician immediately. Nota untuk pegawai perubatan Note to physician : Tiada 4.2 Simptom dan kesan paling penting, kedua-dua acure dan lambat : Tiada Most important symptoms and effects, both acure and delayed Not available 4.3 Petunjuk bagi rawatan perubatan segera dan rawatan khas yang diperlukan : Tiada Indication of any immediate medical attention and special treatment needed Not available BAHAGIAN 5 : LANGKAH - LANGKAH PEMADAMAN KEBAKARAN SECTION 5 : FIREFIGHTING MEASURES 5.1 Media pemadaman kebakaran yang sesuai : Guna media/ agen pemadaman sesuai untuk lingkungan kebakaran. Suitable extinguishing media : Use extinguishing media suitable for the surrounding fire. 5.2 Bahaya khas yang diakibatkan dari bahan campuran : Tiada Special hazards arising from the substance or mixture : Not known 5.3 Nasihat untuk ahli bomba / Advice for firefighters Alat perlindungan khas untuk ahli bomba Protective equipment for firefighters : Gunakan peralatan perlindungan bersesuaian dan peralatan pernafasan berserta dengan penutup muka penuh dalam operasi mod tekanan positif : Wear appropriate protective equipment and self-contained breathing appratus (SCBA) with a full face-piece operated in positive pressure mode. BAHAGIAN 6 : LANGKAH - LANGKAH PENGAWALAN PELEPASAN TIDAK SENGAJA SECTION 6 : ACCIDENTAL RELEASE MEASURE 6.1 Langkah-langkah berjaga-jaga, alat perlindungan khas dan prosedur keselamatan Personal precautions, protective equipment and emergency procedures Kosongkan kawasan persekitaran. Halang kakitangan tidak berkaitan dan tidak dilindungi daripada masuk. Jangan sentuh atau jalan melalui bahan tertumpah. Elakkan menyedut wap/ kabus. Sediakan ventilasi yang mencukupi Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled through spilled material. Avoid breathing vapour/ mist. Provide adequate ventilation. 6.2 Peringatan alam sekitar / Environment precautions Elakkan penyebaran bahan tertumpah dan aliran dan bersentuh dengan tanah, saliran air, longkang dan pembentung. Maklumkan kepada pihak berkuasa yang berkaitan jika produk menyebabkan pencemaran persekitaran (pembentung, saliran air, tanah dan udara) Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewer, waterways, soil and air). 6.3 Kaedah dan bahan untuk penahanan kebocoron dan pembersihan / Methods and material for containment and cleaning up Hentikan kebocoron jika tidak berisiko. Alih bekas daripada kawasan tumpahan. Cairkan dengan air dan lap/ keringkan jika larut dalam air atau serapkan dengan bahan kering lengai dan tempatkan dalam bekas pelupusan sisa yang sesuai untuk pembuangan khusus menurut "Environmental Quality (Scheduled Waste) Regulation 2005" dan lain-lain panduan yang diisu oleh pihak DOE dan / atau pihak berkuasa tempatan. Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal containers for special waste disposal in accordance to Environmental Quality (Scheduled Waste) Regulation 2005 and other guidelines issued by DOE and / or local authorities. 6.4 Rujukan ke bahagian lain / Reference to other sections : Tiada / None BAHAGIAN 7 : PENGENDALIAN DAN PENYIMPANAN SECTION 7 : HANDLING AND STORAGE 7.1 Langkah-langkah pengendalian yang selamat / Precautions for safe handling Jangan merokok di tempat kerja. Elakkan daripada menyedut habuk, terkena pada kulit dan mata. Amalkan cara pengurusan industri yang baik. Do not smoke in working place. Avoid inhalation of dust, contact with skin and eyes. Observe good industrial practice. Page 3 of 6

4 7.2 Keadaan penyimpanan yang selamat, termasuk apa-apa ketidakserasian / Conditions for safe storage, including any imcompatibilities Simpan mengikut peraturan tempatan. Simpan di dalam bekas asal dan ditutup rapat. Simpan di tempat yang kering, sejuk dengan pengudaraan yang baik dan terlindung dari pancaran matahari. Store in accordance with local regulations. Store in tightly closed original containter. Keep from direct sunlight in a dry, cool and well-ventilated area. 7.3 Penggunaan akhir yang khusus / Specific end use : Tiada / None BAHAGIAN 8 : KAWALAN PENDEDAHAN / PERLINDUNGAN DIRI SECTION 8 : EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Parameter Kawalan / Control parameters Komponen dengan nilai kritikal yang memerlukan pemantauan di tempat kerja / Components with critical values that require monitoring at the workplace Nama Kimia / Chemical Name No. CAS / Had Pendedahan / Kadaran / CAS No. Exposure Limit Proportion Simen Portland / Portland Cement TWA 10mg/m³ (8 jam) / (8 hours) 25-50% 8.2 Kawalan-kawalan pendedahan / Exposure controls Kawalan kejuruteraan yang sesuai / Appropriate engineering control Kawalan pendedahan : Tiada keperluan ventilasi khas. Pengudaraan am yang baik hendaklah mencukupi untuk mengawal pekerjaan bahan cemar bawaan udara terdedah kepada pekerja. Jika produk ini mengandungi bahan-bahan/ ramuan dengan had pendedahan, guna proses tertutup, ventilasi ekzos setempat, atau kawalan kejuruteraan lain untuk memastikan pendedahan pekerja di bawah sebarang had atau kanun yang disyorkan Occupational exposure : No special ventilation requirements. Good general ventilation should be sufficient to control worker controls exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Langkah-langkah kebersihan Hygiene measures : Basuh kedua tangan, lengan dan muka sehingga bersih setelah mengendali produk kimia, sebelum makan, merokok dan menggunakan tandas pada akhir waktu kerja. Teknik yang sesuai harus digunakan apabila menanggalkan pakaian yang mungkin tercemar. Basuh pakaian tercemar sebelum memakai semula. Pastikan tempat mencuci mata dan pancuran air keselamatan berdekatan dengan lokasi tempat kerja. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory at the end of the working period. Appropriate techniques should be used to removed potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are closed to the workstation location Alat-alat perlindungan khas / Personal protective equipment Perlindungan mata : Kacamata keselamatan yang mematuhi kelulusan piawai perlu digunakan apabila risiko penilaian menunjukkan ianya perlu untuk mengelakkan pendedahan kepada percikan cecair, kabus atau debu. Eye protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Perlindungan badan Body protection Perlindungan tangan Protection of hands Perlindungan pernafasan Breathing equipment : Peralatan perlindungan peribadi untuk badan perlu dipilih berdasarkan tugas yang dilakukan dan melibatkan risiko dan perlulah diluluskan oleh pakar sebelum mengendalikan produk ini. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Sarung tangan kedap, tahan bahan kimia, yang mematuhi piawaian yang diluluskan hendaklah dipakai pada setiap masa apabila mengendalikan produk kimia jika penilaian risiko menunjukkan ini adalah perlu. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Guna alat penulen udara atau alat pernafasan bekal udara yang muat dengan baik yang mendapat kelulusan piawai jika risiko penilaian menunjukkan ianya perlu. Pemilihan alat pernafasan mesti berdasarkan tahap pendedahan diketahui atau dijangka, bahaya produk dan had selamat bekerja bagi alat pernafasan yang dipilih itu. : Use a proper fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the products and the safe working limits of the selected respirator Kawalan pendedahan alam sekitar / Environmental exposure controls Pelepasan daripada pengudaraan atau peralatan proses kerja hendaklah diperiksa untuk memastikan ianya mematuhi keperluan perundangan perlindungan alam sekitar. Bagi sesetengah kes, penyental wasap, penurus atau pengubahsuaian kejuruteraan terhadap peralatan proses adalah perlu bagi mengurangkan pengeluaran ke tahap yang dibenarkan. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Page 4 of 6

5 BAHAGIAN 9 : SIFAT - SIFAT FIZIKAL DAN KIMIA SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES 9.1 Maklumat tentang sifat-sifat fizikal dan kimia / Information on basic physical and chemical properties Rupa / Aspect : Serbuk kasar berwarna kelabu / Grey coloured coarse powder Bau / Odour : Tiada bau / Odourless Kebolehlarutan dalam air / Solubility in water : Separa larut / Partially soluble Takat Didih / Boiling Point : Tiada data / N/A Takat lebur / Melting Point : Tiada data / N/A Tekanan wap / Vapour pressure : Tiada data / N/A Nilai ph /ph value : Tiada data / N/A Peratusan bahan mudah meruap : Tiada / N/A Kadar penyejatan / : Tiada / N/A Percentage volatiles Evaporation rate Ketumpatan Pukal / Bulk Density : ~ 1600kg/m 3 Ketumpatan wap / : Tiada data / N/A Vapour density Suhu pengautocucuhan / : Tiada / N/A Takat kilat / Flash point : Tiada / N/A Autoignition temperature Had kemudahbakaran (%) / : Tiada / N/A Sifat-sifat lain jika berkenaan / : Tiada / N/A Flammable limit (%) Other properties if applicable BAHAGIAN 10 : KESTABILAN DAN KEREAKTIFAN SECTION 10 : STABILITY AND REACTIVITY 10.1 Kereaktifan / Reactivity : Tiada data / N/A 10.2 Kestabilan kimia / Chemical Stability : Produk ini stabil / Product is stable 10.3 Kemungkinan tindak balas berbahaya : Tiada Possibility of hazardous reactions N/A 10.4 Keadaan yang perlu dielak / Conditions to avoid : Tiada data / N/A 10.5 Bahan yang harus dielak / Incompatible materials : Tiada data / N/A 10.6 Kemungkinan pereputan berbahaya : Di bawah keadaan penyimpanan dan penggunaan normal, produk penguraian berbahaya tidak boleh dihasilkan. Possible of hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition is not produced. BAHAGIAN 11 : MAKLUMAT TOKSIKOLOGI SECTION 11 : TOXICOLOGICAL INFORMATION 11.1 Maklumat tentang kesan toksikologi / Information on toxicological effects Penyedutan/ Inhalation : Merengsa kepada sistem pernafasan / Irritating to respiratory system Pengingesan / : Merengsa kepada mulut, kerongkong dan perut / Ingestion Irritating to mouth, throat and stomach Sentuhan kulit / Skin Contact Sentuhan mata Eye contact Organ Sasaran Target Organs : Pemekaan melalui sentuhan kulit Irritating to skin contact : Merengsa kepada mata, risiko menjejaskan mata yang serius Severe irritating to eyes, risk of serious damage to eyes : Mengandungi bahan yang boleh menyebabkan kerosakan kepada paru-paru, saluran pernafasan, kulit, mata : Contain materials which may cause damage to lungs, upper respiratory tract, skin, eyes Keadaan kesihatan menjadi teruk akibat pendedahan berlebihan Medical conditions aggravated by over-exposure : Pendedahan berulangan atau berpanjangan kepada bahan boleh merosakkan organ sasaran. : Repeated or prolonged exposure to the substance can cause damage of of organs. Page 5 of 6

6 BAHAGIAN 12: MAKLUMAT EKOLOGI SECTION 12 : ECOLOGICAL INFORMATION 12.1 Ketoksikan / Toxicity Ketoksikan akuatik Aquatic toxicity : Tiada 12.2 Kemerosotan / Persistence and degradability Kebolehbiopemerosotan: Tiada Biodegradibility 12.3 Potensi pengumpulan bio / Bioaccumulation Pembiopengumpulan : Tiada Bioaccumulation 12.4 Kebolehgerakan di dalam tanah / Mobility in soil Kebolehgerakan : Tiada Mobility 12.5 Keputusan PBT dan vpvb penilaian / Results of PBT and vpvb assessment : Tiada / None 12.6 Kesan buruk yang lain / Other adverse effects : Tiada / None BAHAGIAN 13: MAKLUMAT PEMBUANGAN SECTION 13 : DISPOSAL INFORMATION 13.1 Kaedah pembuangan sisa / Waste treatment methods Haruslah dibuang sebagai sisa buangan khas. Pembuangan sisa ke unit/ bekas sisa buangan khas haruslah menurut "Environmental Quality (Scheduled Waste) Regulation 2005 " & lain-lain panduan yang diisuoleh DOE dan / atau pihak berkuasa tempatan. It must be disposed off as special waste. Must be disposed off in a special waste disposal unit in accordance with the Environmental Quality (Scheduled Waste) Regulation 2005 and other guidelines issued by DOE and / or local authorities. Pembuangan Bekas Container Disposal : Bekas-bekas yang tidak boleh dibersihkan haruslah dibuang sebagai sisa buangan produk. : Packaging that cannot be cleaned should be disposed off as product waste. BAHAGIAN 14: MAKLUMAT PENGANGKUTAN SECTION 14 : TRANSPORT INFORMATION Sentiasa mengangkut dalam bekas tertutup yang tegak dan selamat. Pastikan orang yang mengangkut produk tahu apa yang perlu dilakukan sekiranya berlaku kemalangan atau tumpahan. Penyediaan ini tidak diklasifikasi sebagai merbahaya mengikut peraturan pengangkutan antarabangsa (ARD/RID, IMDG, ICAO, IATA). Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. This preparation is not classified as dangerous accoring to international transport regulations (ARD/RID, IMDG or ICAO/IATA). BAHAGIAN 15: MAKLUMAT PENGAWALAN SECTION 15 : REGULATORY INFORMATION 15.2 Penilaian keselamatan kimia belum dijalankan / A chemical safety assessment has not been carried out BAHAGIAN 16: MAKLUMAT LAIN SECTION 16 : OTHER INFORMATION Maklumat yang terkandung di dalam Risalah Data Keselamatan ini adalah sejajar dengan tahap pengetahuan kami pada masa ianya diterbitkan. Bagaimanapun, pembekal tidak bertanggungjawab terhadap ketepatan atau kelengkapan maklumat yang terkandung di dalam. Maklumat yang terkandung dihasilkan semata sebagai panduan bagi langkah-langkah penanganan, penggunaan, pemprosesan penyimpanan, pengangkutan, pelupusan dan pelepasan. Penentuan kesesuaian sebarang bahan dan cara penggunaan adalah tanggungjawab pengguna. The information contained in this Safety Data Sheet is based on the present state of knowledge at the time of publication. The supplier does not assume any liability whatsoever for the accuracy or completeness of the information contained herein. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release measures. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. MC Bauchemie (Malaysia) Sdn Bhd Lot S113, 2nd Floor, Centrepoint, No. 3 Lebuh Bandar Utama, Bandar Utama, Petaling Jaya, Selangor Darul Ehsan Page 6 of 6

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