SYSTERM SAFETY DATA SHEET
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1 SAFETY DATA SHEET 1. Identification of the substance/preparation and of the company/undertaking Product name: Name and address of Supplier: Classic Chemicals Sdn Bhd 19, Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam,Selangor Emergency telephone no.: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories Flammable liquid, category 2 Eye irritation, category 2 Specific target organ toxicity (single exposure), category 3, narcotic effect Hazard statements Signal word Danger Hazard Statements Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Hazard symbols: F, Xi R-phrases R11 R36 R67 Highly flammable. Irritating to eyes. Vapours may cause drowsiness and dizziness.
2 SAFETY DATA SHEET Product name: S-phrases S7 Keep container tightly closed. S16 Keep away from sources of ignition - No smoking. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 3. Composition/information on ingredients Product name: Propan-2-ol CAS-No.: Molar mass: Molecular formula: C 3 H 8 O EC No.: Index no other means of identification 2-Hydroxy propane Dimethyl carbinol Isopropanol Isopropyl alcohol IPA 4. First aid measures After inhalation: Remove from exposure, rest and keep warm. In severe cases obtain medical attention. After skin contact: Wash off thoroughly with soap and water. Remove contaminated clothing and wash before re-use. In severe cause, obtain medical attention. After eye contact: Irrigate thoroughly with water for at least 10 minutes. If discomfort persists, obtain medical attention. After ingestion: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention. 5. Fire-fighting measures Suitable extinguishing media: Water spray, dry powder or vaporizing liquids Special risks: Highly flammable. Vapour/air mixture explosive. 6. Accidental release measures Shut off all sources of ignition. Inform others to keep at a safe distance. Wear appropriate protective clothing. If local regulations permit, mop up with plenty of water and run to waste, diluting greatly with running water. Otherwise transfer to container and arrange removal by disposal company. Wash site of spillage thoroughly with detergent and water. For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage container. Any residues should be treated as for small spillages.
3 SAFETY DATA SHEET Product name: 7. Handling and storage Handling: All electrical equipment must be flameproofed. Avoid contact with skin and eyes. Wash hands and face thoroughly after working with material. Contaminated clothing should be removed and washed before re-use. Storage: Store at room temperature (15 to 25 o C recommended). Keep well closed and protected from direct sunlight and moisture. Store small containers in suitable flammable liquid storage cabinets when not in use. Larger drums (2001) must be kept in purpose-built stores. 8. Exposure controls/personal protection As appropriate to the situation and the quantity handled. Engineering methods to control or prevent exposure are preferred. Methods could include process enclosure or mechanical ventilation. Respiratory protection: Self-contained breathing apparatus when vapours are generated. Ventilation; Eye protection: Glove protection: Other precautions: Fume cupboard, flameproof Goggles or face-shield Butyl rubber, Silver shield Plastic apron, sleeves, boots if handling large quantities 9. Physical and chemical properties Form: liquid Colour: colourless Odour: characteristic Viscosity dynamic (20 o C) 2.4 cps Melting temperature -89 o C Boiling temperature 82 o C Ignition temperature 425 o C Flash point 12 o C Explosion limits lower 2.3 % upper 12 % Vapour pressure (20 o C) 33 mmhg Relative vapour density 2.07 Density (20 o C) 0.78 g/ml Solubility in water (20 o C) Miscible in all proportions log P(o/w): 0.05
4 SAFETY DATA SHEET Product name: 10. Stability and reactivity Formation of peroxides possible. Substances to be avoided alkali metals, alkaline earth metals, aluminium, oxidizing agent( i.a. perchlorates, CrO 3, nitric acid, nitrogen oxides, hydrogen peroxide), organic nitro compounds. The possibility of reaction with other substances cannot be excluded. 11. Toxicological information After inhalation: Irritation symptoms in the respiratory tract. After skin contact: Slight irritation. Degreasing effect on the skin, possibly followed by secondary inflammation. After eye contact: Severe irritations. After absorption: headache, dizziness, inebriation, unconsciousness, narcosis. After uptake of large quantities: respiratory paralysis, coma. Further data LD 50 (oral,rat): 5045 mg/kg Skin irritation test (rabbit): moderate irritant effect No evidence of carcinogenic properties: Evidence of reproductive effects 12. Ecological information Low aquatic toxicity. Bioaccumulation potential: low (log Pow <2), Biological degradability: goods. Fish toxicity: LC 50 (Pimephales promelas): 11,130 mg/l/96h Daphnia toxicity: EC 50 (Daphnia magna): 3010 mg/l/ NOEC: 757 mg/l Algeal toxicity: EC 0 (Microcystis aeruginosa): 1,000 mg/l/8d No ecological problems are to be expected when the product is handled and used with due care and attention. 13. Disposal considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling. When recovery and recycling is not possible, incineration in a high temperature incinerator is the recommended method of disposal.
5 SAFETY DATA SHEET Product name: 14. Transport information Transport over land ADR/RID ADR/RID class: Name of material: ISOPROPANOL Sea transport IMDG IMDG class: 3 UN-No.: 1219 Packaging group: II Correct technical name: ISOPROPANOL Air transport ICAO-TI and IATA-DGR ICAO/IATA class: 3 UN/ID-No.: 1219 Packaging group: II Correct technical name: ISOPROPANOL 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (WGK) 1 Chemical Safety Assessment No data available 16. Other information Relevant R-, H- and EUH-phrases (Number and full text) R11 Highly flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness. Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness. Revision Date: 01 Jan 2016 The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product.
6 LEMBARAN DATA KESELAMATAN 1. Pengenalpastian bahan / sediaan dan syarikat / aku janji Nama produk: Nama dan alamat pembekal: Classic Chemicals Sdn Bhd 19,Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam,Selangor Telefon kecemasan no.: Pengenalan Bahaya Pengelasan bahan atau campuran Pengelasan mengikut Peraturan (EC) No 1272/2008 [S] Kelas bahaya dan kategori bahaya Cecair mudah terbakar, kategori 2 Kerengsaan mata, kategori 2 Khusus organ sasaran ketoksikan (pendedahan tunggal), kategori 3, kesan narkotik penyata bahaya Perkataan isyarat Penyata Bahaya Pernyataan langkah P210 P280 P305 + P351 + P338 Bahaya Cecair sangat mudah terbakar dan wap. Boleh menyebabkan kerengsaan mata yang serius. Boleh menyebabkan rasa mengantuk atau pening. Jauhkan daripada haba / percikan api / nyalaan terbuka / permukaan panas. Dilarang merokok. Pakai sarung tangan / pakaian pelindung / perlindungan mata / muka. JIKA MATA: Bilas dengan berhati-hati dengan air selama beberapa minit. Padam kenalan kanta, jika ada dan mudah untuk dilakukan. Teruskan membilas. Simbol Bahaya: F, Xi Frasa-R R11 R36 R67 yang sangat mudah terbakar. Merengsa kepada mata. Wap boleh menyebabkan mengantuk dan pening.
7 LEMBARAN DATA KESELAMATAN Nama produk: S-ungkapan S7 S16 S24 / 25 S26 Pastikan bekas sentiasa ditutup. Jauhkan dari punca pencucuhan - Dilarang merokok. Elakkan daripada terkena kulit dan mata. Jika bersentuhan dengan mata, basuh segera dengan menggunakan air yang banyak dan dapatkan nasihat perubatan. 3. Komposisi / maklumat bahan Nama produk: propan-2-ol CAS-No.: Jisim molar: Formula molekul: C 3 H 8 O SPR No.: Indeks No.: cara pengenalan lain 2-Hydroxy propana dimetil carbinol Isopropanol Isopropyl alkohol IPA 4. Langkah-langkah pertolongan cemas Jika tersedut:jauhi dari pendedahan, rehat dan menyimpan panas. Dalam kes-kes yang teruk mendapatkan perubatan perhatian. Jika terkena kulit: Basuh sehingga bersih dengan sabun dan air. Tanggalkan pakaian yang tercemar dan basuh sebelum diguna semula. Jika terkena banyak, dapatkan rawatan perubatan. Jika terkena mata: Mengairi kulit dengan rapi menggunakan air selama sekurang-kurangnya 10 minit. Jika ketidakselesaan berterusan, dapatkan rawatan perubatan. Selepas pengambilan: Basuh mulut sehingga bersih dengan air dan beri banyak air untuk diminum. Dapatkan rawatan perubatan. 5. Langkah memadam kebakaran Media pemadam yang sesuai: Semburan air, serbuk kering atau vaporizing cecair Risiko khas: Sangat mudah terbakar. Wap / campuran udara bahan letupan. 6. Langkah-langkah pengawalan pelepasan tidak sengaja Tutup semua punca pencucuhan. Maklumkan kepada orang lain berada di jarak yang selamat. Pakai pakaian perlindungan yang sesuai. Jika peraturan tempatan membenarkan, menyerap dengan air yang banyak dan menjalankan membuang, mencairkan sangat dengan air yang mengalir. Memindahkan ke dalam bekas dan mengatur penyingkiran oleh syarikat pelupusan. Basuh tapak tumpahan sehingga bersih dengan sabun dan air. Untuk tumpahan besar cecair harus lengkap dengan pasir atau tanah dan kedua-dua cecair dan pepejal dipindahkan untuk menyelamatkan bekas. Apa-apa sisa perlu dirawat sebagai untuk tumpahan kecil.
8 LEMBARAN DATA KESELAMATAN Nama produk: 7. Pengendalian dan penyimpanan Pengendalian: Semua peralatan elektrik mesti flameproofed. Elakkan daripada terkena kulit dan mata. Basuh tangan dan muka sehingga bersih setelah bekerja dengan bahan. Pakaian yang tercemar hendaklah dikeluarkan dan dibasuh sebelum digunakan semula. Penyimpanan: Simpan pada suhu bilik (15 hingga 25 o C disyorkan). Pastikan juga ditutup dan dilindungi daripada cahaya matahari langsung dan kelembapan. Simpan bekas kecil dalam mudah terbakar kabinet penyimpanan cecair yang sesuai apabila tidak digunakan. Gendang besar (2001) mesti disimpan di kedai-kedai yang dibina khas. 8. Kawalan pendedahan / perlindungan diri Seperti yang bersesuaian dengan keadaan dan kuantiti yang dikendalikan. Kaedah kejuruteraan untuk mengawal atau mencegah pendedahan adalah pilihan. Kaedah boleh termasuk ruang proses tertutup atau pengudaraan mekanikal. Perlindungan Pernafasan: alat pernafasan serba lengkap apabila wap dihasilkan. Pengudaraan; Almari wasap, kalis Perlindungan mata: Gogal atau perisai muka Perlindungan sarung tangan: Butil getah, perisai perak Langkah berjaga-jaga lain: apron plastik, lengan, but - jika pengendalian kuantiti yang besar 9. Sifat-sifat fizikal dan kimia Bentuk: cecair Warna: tidak berwarna Bau: ciri-ciri Kelikatan dinamik (20 o C) 2.4 cps Suhu lebur -89 o C Suhu mendidih 82 o C Suhu pencucuhan 425 o C Takat kilat 12 o C Had letupan yang lebih rendah 2.3% atas 12% Tekanan wap (20 o C) 33 mmhg Ketumpatan wap relatif 2.07 Ketumpatan (20 o C) 0.78 g / ml Keterlarutan dalam Air (20 o C) larut dalam semua bahagian log P (o / w): 0.05
9 LEMBARAN DATA KESELAMATAN Nama produk: 10. Kestabilan dan Kereaktifan Mungkin pembentukan peroksida. Bahan yang perlu dielakkan logam alkali, logam alkali bumi, aluminium, agen pengoksidaan (i.a., perklorat, CrO3, asid nitrik, oksida nitrogen, hidrogen peroksida), sebatian nitro organik. Kemungkinan tindak balas dengan bahan-bahan lain tidak boleh dikecualikan. 11. Maklumat toksikologi Jika tersedut: gejala Kerengsaan dalam saluran pernafasan. Jika terkena kulit: Kerengsaan sedikit. Nyahgris kesan pada kulit, mungkin diikuti oleh keradangan menengah. Jika terkena mata: kegatalan teruk. Selepas penyerapan: sakit kepala, pening, mabuk, tidak sedarkan diri, narkosis. Selepas pengambilan kuantiti yang banyak: lumpuh pernafasan, koma. Maklumat lanjut LD 50 (lisan, rat): 5045 mg / kg Ujian perengsaan kulit (arnab) Kesan kerengsaan sederhana Tiada bukti sifat karsinogen: Bukti kesan pembiakan 12. Maklumat ekologi Ketoksikan akuatik rendah. Berpotensi Pengumpulan Bio: rendah (log Pow <2), degradasi biologi: barangbarang. Keracunan ikan: LC 50 (Pimefales promelas): mg / l / 96h Daphnia ketoksikan: EC 50 (Daphnia magna): 3010 mg / l / NOEC: 757 mg / l Ketoksikan Algeal: EC 0 (Microcystis aeruginosa): 1,000 mg / l / 8d Tiada masalah ekologi yang diharapkan apabila produk dikendalikan dan digunakan dengan cermat dan perhatian. 13. Maklumat pelupusan Sisa kimia biasanya diklasifikasikan sebagai sisa khas, dan oleh itu adalah dilindungi oleh peraturanperaturan yang berbeza mengikut lokasi. Hubungi pihak berkuasa pelupusan sisa tempatan anda untuk mendapatkan nasihat, atau berpindah kepada syarikat pelupusan kimia. Berkumur bekas kosong teliti sebelum kembali untuk dikitar semula. Apabila pemulihan dan kitar semula tidak mungkin, pembakaran di dalam pembakar suhu yang tinggi adalah kaedah yang disyorkan untuk pelepusan.
10 LEMBARAN DATA KESELAMATAN Nama produk: 14. Maklumat pengangkutan Pengangkutan ke atas jalan ADR / RID ADR / RID: Nama bahan: ISOPROPANOL Pengangkutan laut IMDG Kelas IMDG: 3 UN.: 1219 Kumpulan Pembungkusan: II Nama teknikal yang betul: ISOPROPANOL Pengangkutan udara ICAO-TI dan IATA-DGR Kelas ICAO / IATA: 3 UN / ID-No.: 1219 Kumpulan pembungkusan: II Nama teknikal Betul: ISOPROPANOL 15. Maklumat pengawalan Keselamatan, kesihatan dan persekitaran / undang-undang khusus untuk bahan atau campuran Bahaya air kelas (WGK) 1 Penilaian Keselamatan Kimia Data tidak terdapat 16. Maklumat lain R- berkaitan, H- dan EUH Frasa (Nombor dan teks penuh) R11 yang sangat mudah terbakar. R36 Merengsa kepada mata. R67 Wap boleh menyebabkan mengantuk dan pening. Cecair sangat mudah terbakar dan wap. Boleh menyebabkan kerengsaan mata yang serius. Boleh menyebabkan rasa mengantuk atau pening. Tarikh Semakan: 1 Januari 2016 Maklumat yang terkandung dalam dokumen ini adalah berdasarkan pada keadaan pengetahuan semasa kami. Ia menyifatkan produk dengan mengambil kira langkah-langkah keselamatan yang sesuai. Ia tidak mewakili jaminan sifat-sifat produk.
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