Safety Data Sheet ETHYLENE GLYCOL - INDUSTRIAL GRADE Revision date : 2014/11/21 Version: 1.0

Transcription

1 / Safety Data Sheet ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2. dentfcaton Page: / /SOS GEN US/EN)!! Product dentfer used on the label ETHYLENE GLYCOL - NDUSTRAL GRADE! Recommended use of the chemcal and restrcton on use Recommended use*: ndustral chemcals; antfreezng agent; ntermedate; solvent(s); Monomer. - "-'- Unsutable-for use: Pharmaceutcal * The " Recommended use" dentfed for ths product s provded solely to comply wth a US Federal requrement and s not part of the seller's publshed specfcaton. The terms of ths Safety Data Sheet (SOS) do not create or nfer any warranty, express or mpled, ncludng by ncorporatonnto or reference n the seller's sales agreement. Detals of the suppler of the safety data sheet Company:_ Everchem Specalty Chemcals 400 N. Provdence Road Meda, PA 9063 USA Telephone j : ( /! / Emergency telephone number CHEMTREC: Other means of dentfcaton Molecular formula: CH(2)OH-CH(2)OH Chemcal famly: glycols Synonyms:,2-Ethanedol 2. Hazards dentfcaton Accordng to Regulaton 202 OSHA HazardCommuncaton Standard; 29 CFR Part 9O.200_ Classfcaton of the~ product Acute Tox. STOT RE 4 (oral) Acute toxcty 2 Specfc target organ toxcty - repeated exposure Label elements Everchem Specalty Chemcals Phone:

2 ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 2/ -.. Sgnal Word: Warnng Hazard Statement: H302 H373 Harmful f swallowed. May cause damage to organs(kdney) through prolonged or repeated exposure. Precautonary Statements(Preventon): P260 Do not breathe dust/gas/mst/vapours. P270 Do not eat, drnk or smoke when usng ths product. P264 Wash wth plenty of water and soap thoroughly after handlng. Precautonary Statements(Response): P3 Call a POSONCENTER or doctor/physcan. P30 + P330 F SWALLOWED: rnse mouth. Precautonary Statements(Dsposal): P50 Dspose of contents/contaner to hazardous or specal waste collecton pont. Hazards not otherwse classfed f applcable nformaton s provded n~ths secton on other hazards whch do not result n classfcatonbut whch may contrbute to the overall hazards of the substance or mxture. See secton 2 - Results of PBT and vpvb assessment. Accordng to Regulaton 994 OSHA Hazard Communcaton Standard; 29 CFR Part 9_0..200_ Emergency overvew WARNNG: Contans a component for whch embryotoxcty and teratogencty was observed n anmal studes, n the absence of maternal toxcty. MAY BE HARMFUL F SWALLOWED. MAY BE HARMFUL F NHALED. May be harmful f absorbed through skn. Prolonged and repeated exposure may affect CNS, lver and kdney. MAY CAUSE EYE, SKN ANDRESPRATORY TRACT RRTATON. Prolonged or repeated contact may result n dermatts. Chronc exposure may cause lver and kdney damage. Wear a NOSH-certfed (or equvalent) organc vapour/partculate resprator. Avodnhalaton of msts/vapours. Use wth local exhaust ventlaton. Avod contact wth the skn, eyes and clothng. Wear NOSH-certfed chemcal goggles. Eye wash fountans and safety showers must be easly accessble. Wear chemcal resstant protectve gloves. Wear protectve clothng.

3 ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 3 3. Composton / nformaton on ngredents Accordng to Regulaton 202 OSHA Hazard Communcaton Standard; 29 CFR Part CAS Number Content /W/W) Chemcal name >= <= 00.0 ethylene glycol % Acc.ordlnf:f to Regulaton 994 OSHA Hazard Communcaton Standard; 29 CFR Part 9". 0_._200 CAS Number Content /W/W\ Chemcal name >= <= 00.0 ethylene glycol % 4. Frst-Ad Measures " Descrpton of frst ad measures General advce: Remove contamnated clothng. f nhaled: Remove the affected ndvdual nto fresh ar and keep the person calm. Assst n breathng f necessary. mmedate medcal attenton requred. f on skn: Wash affected areas thoroughly wth soap and water. f rrtaton develops, seek medcal attenton. f n eyes: n case of contact wth the eyes, rnse mmedately for at least 5 mnutes wth plenty of water. f rrtatondevelops, seek medcal attenton. f swallowed: Rnse mouth and then drnk plenty of water. nduce vomtng. Never nduce vomtng or gve anythng by mouth f the vctm s unconscous or havng convulsons. mmedate medcal attenton requred. Most mportant symptoms and effects, both acute and delayed Symptoms: kdney damage Hazards: No hazard s expected under ntended use and approprate handlng. ndcaton of any mmedate medcal attenton and specal treatment needed Note to physcan Antdote: Treatment: Admnstraton of ethanol may counteract the effects of ethylene glycol, such as metabolc acdoss and renal damage. 4-Methylpyrazole (a compettve nhbtor of alcohol dehydrogenase) canbe used as an antdote n ethylene glycol posonng. Treat accordng to symptoms (decontamnaton, vtal functons), no known specfc antdote. Everchem Specalty Chemcals Phone:

4 ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 4/ 5. Fre-Fghtng Measures Extngushng meda Sutable extngushng meda: water spray, foam, dry powder, gaseous extngushng meda, carbon doxde Specal hazards arsng from the substance or mxture Hazards durng fre-fghtng: See MSDS secton 7 - Handlng and storage. Advce for fre-fghters Protectve equpment for fre-fghtng: Frefghters should be equpped wth self-contaned breathng apparatus and tum-out gear. Further nformaton: Vapours are heaver than ar and may accumulate n low areas and travel a consderable dstance up to the source of gnton. n case of fre and/or exploson do not breathe fumes. mpact Senstvty: Remarks: Based on the chemcal structure there s no shock-senstvty. 6. Accdental release measures ; Personalprecautons, protectve equpment and emergency procedures Handle n accordance wth good ndustral hygene and safety practce. Envronmental precautons Ths product s regulated by CERCLA ('Superfund'). Methods and materal for contanment and cleanng up For resdues: Rnse away wth water. Splls should be contaned, soldfed, and placed n sutable contaners for dsposal. 7. Handlng and Storage Precautons for safe handlng Handle n accordance wth good ndustral hygene and safety practce. Protecton aganst fre and exploson: No exploson proofng necessary. Condtons for safe storage, ncludng any ncompatbltes No applcable nformaton avalable. Further nformaton on storage condtons: Keep contaner tghtly closed and dry; store n a cool place. Protect from ar. Protect from atmospherc humdty. Protect contents from the effects of lght. Keep contaner tghtly closed. Storage stablty: Storage temperature: < 40 V The stated storage temperature should be noted. Storage duraton: 2 Months

5 l f " / Safety Data Sheet ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 5 8. Exposure Controls/Personal Protecton Components wth occupatonal exposure lmts ethylene glycol OSHA PEL CLV 50 ppm 25 mglm3 ; ACGH TLV TLVvalue 00 mg/m3 aerosol ; Celng Lmt Advce on system desgn: Provdelocal exhaust ventlaton to control vapourslmsts. Personal protectve equpment Respratory protecton: Wear a NOSH-certfed (or equvalent) organc vapour/partculate resprator. Observe OSHA regulatons for resprator use (29 CFR 90.34). Hand protecton: Chemcalresstant protectve gloves, Consult wth glove manufacturer for testng data. Eye protecton: Tghtly fttng safety goggles (chemcal goggles). Wear face sheld f splashng hazard exsts. Body protecton: Body protecton must be chosen dependng on actvty and possble exposure, e.g. head protecton, apron, protectve boots, chemcal-protectonsut. General safety and hygene measures: No specal measures necessary f stored and handled correctly. Avod nhalaton of vapourslmsts. Wear protectve clothng as necessary toprevent contact. Wash soledclothngmmedately., { J.j " { j l' g. Physcal and Chemcal Propertes Form: Odour: Colour: ph value: Meltng pont: Bolngpont: Sublmaton pont: Flash pont: Flammablty: Lower explosonlmt: upper exploson lmt: Autognton: Vapour pressure: Densty: Relatve densty: Vapour densty: Parttonng coeffcent n- octanol/water (log Pow): lqud odourless colourless, clear oc 97.4 oc oc not flammable 398 oc 0.23 hpa. g/cm3. approx ( 500 g/kg, 20 'C) (nternal method) Lterature data. (,03 hpa) Lterature data. No applcable nformaton avaoable. Lterature data. For lquds not relevant for classfcaton and labellng. The lower exploson pont may be 5-5 'C below the Dash pont. For lquds not relevant for classfcaton and labeong. Lterature data. ( 25 oc) (measured) Lterature data. ( 20 'C) Lterature data. ( 20 oc) not determned ( 23 oc) (CalculatonHansch/Leo) Lterature data. Everchem Specalty Chemcals Phone:

6 f Safety Data Sheet ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 6/ Self-gnton temperature: Thermal decomposton: Vscosty, dynamc: Vscosty, knematc: Partcle sze: Solublty n water: Mscblty wth water: Solublty (quanttatve): Solublty (qualtatve): Molar mass: Evaporatonrate: Based on ts structural propertes the product s not classfed as self-gntng. No decompostonf correctly stored and handled. 6. mpa.s ( 25 oc) Lterature data. No applcable nformaton avalable. The substance / product s marketed or used n a non sold or granular form. mscble mscble n all proportons No applcable nformaton avalable. soluble solvent(s): polar solvents, glmol not determned J } } { 0. Stablty and Reactvty Reactvty No applcable nformaton avalable. Corroson to metals: No corrosve effect on metal. E } J Oxdzng propertes: Based on ts structural propertes the product s not classfed as oxdzng. Formaton of Remarks: Forms no flammable gases nthe flammable gases: presence of water. Chemcal stablty The product s stable f stored and handled as prescrbed/ndcated. Possblty of hazardous reactons The product s chemcally stable. No hazardous reactons when stored and handled accordng tonstructons. Condtons to avod > 40 degrees Celsus Avod humdty. Avod daylght. Dsregard of the condtons mentoned may result n undesrable decomposton reactons. Avod extreme temperatures. Avod mosture.!" ncompatble materals strong oxdzng agents alkal or alkalne-earth metal, aldehydes, alumnum compounds Hazardous decomposton products Decomposton products: Possble decomposton products: carbonyl compounds, Doxolan dervatves Thermal decomposton: No decomposton f correctly stored and handled.

7 , Safety Data Sheet ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Verson: Page: 7/ /SDS GEN US/EN\. Toxcologcal nformaton Prmary routes of exposure Routes of entry for solds and lquds are ngeston and nhalaton, but may nclude eye or skn contact. Routes of entry for gases nclude nhalaton and eye contact. Skn contact may be a route of entry for lquefed gases. z Acute Toxcty/Effects Acute toxcty Assessment of acute toxcty: Of moderate toxcty after sngle ngeston. Of low toxcty after short.. term skn contact. Oral Type of value: LD (human) Value: approx.,600 mg/kg The European Unon(EU) has classfed ths substance as 'harmful'. nhalaton_ Type of value: LC5O Speces:rat (male/female) Value: > 2.5 mg/ Exposure tme: 6 h An aerosol was tested. E { Dermal_ Type of value: LD5O Speces: mouse (male/female) Value: > 3,500 mg/kg Assessment other acute effects Assessment of STOT sngle: The avalable nformaton s not suffcent for evaluaton. E rrtaton / corroson Assessment of rrtatng effects: Not rrtatng to eyes and skn. Skn Speces: rabbt Result: non-rrtant Method: -Test Eyg Speces: rabbt Result: non-rrtant Method: -Test Senstzaton_ Assessment of senstzaton: Skn senstzng effects were not observed n anmal studes. Human data do not fully exclude a skn senstzng potental. Gunea pg maxmzaton test Speces: gunea pg Result: Non-senstzng. Aspraton Hazard

8 ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 8 No aspraton hazard expected. Chronc Toxcty/Effects Repeated dose toxctv Assessment ofrepeated dose toxcty: The substance may cause damage to the kdney after repeated ngeston. The substance may cause damage to the kdney afterrepeated skn contact wth hgh doses. Genetc toxctv Assessment of mutagen(cty: The substance was not mutagenc n bactera. The substance was not mutagenc n mammalan cell culture. The substance was not mutagenc n a test wth mammals. Carcnoqenctv Assessment of carcnogencty: n long-term studes n rats and mce n whch the substance was gven by feed, a carcnogenc effect was not observed. Reproductve toxctv Assessment ofreproducton toxcty: Theresults of anmal studes gave no ndcaton of a fertlty mparng effect. Teratoqenctv Assessment of teratogencty: n anmal studes the substance caused malformatons when gven at hgh doses. However, therelevance of ths result for humans sunclear. Symptoms of Exposure kdney damage Medcal condtons aggravated by overexposure_ ndvduals wth pre-exstng dseases of the skn,respratory dsorders or mpared functon for the lver/kdneys may have ncreased susceptblty to excessve exposures. 2. Ecologcal nformaton j Toxcty Aquatc toxcty Assessment of aquatc toxcty: There s a hgh probablty that the product s not acutely harmful to aquatc organsms. Thenhbton of the degradaton actvty of actvated sludge s not antcpated when ntroduced to bologcal treatment plants n approprate low concentratons. Toxctv to fsh LC5O(96 h) 72,860 mg/, Pmephales promo/as (EPA 72-, statc) Aquatc nvertebrates EC5O (48 h) > 00 mg/, Daphna magna (OECD Gudelne 202, part, statc) Aquatc plants EC5O(96 h) 6,500-3,000 mgll (growthrate), Selenastrum caprcomutum Chronc toxctv to fsh No observed effect concentraton (7 d) 5,380 mg/, Pmephales promo/as

9 ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 9/ Chronc toxctv to aquatcnvertebrates No observed effect concentraton (7 d) 8,590 mg/, Cerodaphna sp. Assessment of terrestral toxctv Study scentfcally not justfed. Mcroorgansms/Effect on actvated sludge Toxctv to mcroorqansms DN EN SO 892 aerobc actvated sludge, domestc/ec2o (30 mn): >,995 mg/ The product has not been tested. The statement has been derved from substances/products of a smlar structure or composton. Persstence and degradablty Assessment bodeqradaton and~elmnaton(h2o\ Readly bodegradable (accordng to OECD crtera). Elmnatonnformaton % DOC reducton(0 d)(oecd 30 A (new verson))(aerobc, actvated sludge, domestc) Assessment of stabltv n water Accordng to structural propertes, hydrolyss s not expected/probable. Boaccumulatve potental Assessment boaccumulaton potental Because of the n-octanol/water dstrbuton coeffcent (log Pow) accumulaton n organsms s not to be expected. ' Mobltyn sol Assessment transport between envronmental compartments The substance wll not evaporate nto the atmosphere from the water surface. Adsorptonto sold sol phase s not expected. 3. Dsposal consderatons Waste dsposal of substance: Do not dscharge nto waterways or sewer systems wthout proper authorzaton. Dspose of n a lcensed faclty. Dspose of n accordance wth natonal, state and local regulatons. Contaner dsposal: Dspose of n a lcensed faclty. Recommend crushng, puncturng or other means to prevent unauthorzed use of used contaners. 4. Transport nformaton Landtransport USDOT Not classfed as a dangerous good under transport regulatons Sea transport

10 J j Safety Data Sheet ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204//2 Page: 0/ MOG Not classfed as a dangerous good under transport regulatons Ar transport ATA/CAO Not classfed as a dangerous good under transport regulatons 5. Regulatory nformaton Federal Reaulatons } S!! Regstraton status: Chemcal TSCA, US released / lsted EPCRA 3/32 (Hazard categores): CERCLA RQ CAS Number 5000 LBS Reportable Quantty for release: State regulatons Acute; Chronc Chemcalname ethylene glycol 5,000 lb ; ' State RTK MA, NJ, PA NFPA Hazard codes: Health : 2 Fre: CAS Number Reactvty: 0 Chemcal name ethylene glycol Specal:! j { HMS ratng Health: 2u Flammablty: Physcal hazard:0 Assessment of_the hazard classes ~accordnq to UN GHS crtera (most recent verson): Acute Tox. STOT RE 4 (oral) 2 Acute toxcty Specfc target organ toxcty`repeated exposure 6. Other nformaton We support worldwde Responsble Care@ ntatves. We value the health and safety of our employees, customers, supplers and neghbors, and the protecton of the envronment. Our commtment to Responsble Care s ntegral to conductng our busness and operatng our facltes n a safe and envronmentally responsble fashon, supportng our customers and supplers n ensurng the safe and envronmentally sound handlng of our products, and mnmzng the mpact of our operatons on socety and the envronment durng producton, storage, transport, use and dsposal of our products.

11 ETHYLENE GLYCOL - NDUSTRAL GRADE Revson date : 204// /SOS Page: / GEN US/EN\ MPORTANT: WHLE THE DESCRPTONS, DESGNS, DATA AND NFORMATON CONTANED HEREN ARE PRESENTED N GOOD FATH AND BELEVED TO BE ACCURATE, T S PROVDED FOR YOUR GUDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSNG OR APPLCATON/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMNE THE SUTABLTY OF A PRODUCT FOR YOUR PARTCULAR PURPOSE PROR TO USE. NO WARRANTES OF ANY KND, ETHER EXPRESSED OR MPLED, NCLUDNG WARRANTES OF MERCHANTABLTY OR FTNESS FOR A PARTCULAR PURPOSE, ARE MADE REGARDNG PRODUCTS DESCRBED OR DESGNS, DATA OR NFORMATON SET FORTH, OR THAT THE PRODUCTS, DESGNS, DATA OR NFORMATON MAY BE USED WTHOUT NFRNGNG THE NTELLECTUAL PROPERTY RGHTS OF OTHERS. N NO CASE SHALL THE DESCRPTONS, NFORMATON, DATA OR DESGNS PROVDED BE CONSDERED A PART OF OUR TERMS AND CONDTONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRPTONS, DESGNS, DATA, AND NFORMATON FURNSHED BY OUR COMPANY HEREUNDER ARE GVEN GRATS AND WE ASSUME NO OBLGATON OR LABLTY FOR THE DESCRPTON, DESGNS,DATA AND NFORMATON GVEN OR RESULTS OBTANED, ALL SUCH BENG GVEN AND ACCEPTED AT YOUR RSK. END OF DATA SHEET! \ l r 3! E :! ~! /