Revision Number: Issue date: 06/23/ PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 06/23/ PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE M-NT 1800 MU B IDH number: CONVERSION COATING known as TECTALIS 1800 Product type: Conversion coating Restriction of Use: None identified Region: United States Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut Contact information: Telephone: (860) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW NOT CLASSIFIED. READ ENTIRE SAFETY DATA SHEET. None HAZARD CLASS HAZARD CATEGORY None PICTOGRAM(S) None Precautionary Statements Prevention: Response: Storage: Disposal: Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Cupric nitrate * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. Page 1 of 6

2 4. FIRST AID MEASURES Inhalation: Skin contact: If inhaled, immediately remove the affected person to fresh air. Get medical attention. For skin contact flush with large amounts of water. Remove contaminated clothing and footwear. Wash clothing before reuse. Obtain medical attention if irritation persists. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Drink 1 or 2 glasses of water. Symptoms: See Section 11. Notes to physician: Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Use media appropriate for surrounding material. Wear full protective clothing. Wear self-contained breathing apparatus. This product is an aqueous mixture which will not burn. If evaporated to dryness, solid residue is an oxidizing agent and may cause spontaneous ignition of combustible materials. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Do not allow product to enter sewer or waterways. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. For industrial use only. For safe storage, store between 40 F (4.4 C) and 110 F (43.3 C) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 6

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Cupric nitrate 0.2 mg/m3 TWA (as Cu) Fume. 1 mg/m3 TWA (as Cu) Dust and mist. None None None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Ventilation should effectively remove and prevent buildup of any vapor/mist/fume/dust generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR ) and ANSI's standard for respiratory protection (Z ). A written respiratory protection program, including provisions for medical certification, training, fit-testing, exposure assessments, maintenance, inspection, cleaning, and convenient, sanitary storage, must be implemented. If concentrations are below the TLV and/or PEL, a NIOSH approved disposable dust/mist respirator may be used for personal comfort. For concentrations above the TLV and/or PEL but less than 10 times these limits, a NIOSH approved half-face piece respirator equipped with dust-mist cartridges may be used. For concentrations greater than 10 times the TLV and/or PEL, consult the NIOSH respirator decision logic found in Publication No or ANSI Z Note: ANSI Z requires the use of a HEPA filter if the particle size distribution of the contaminant is unknown. WARNING! Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. If concentrations are below the TLV and/or PEL, a NIOSH approved disposable dust/mist respirator may be used for personal comfort. For concentrations above the TLV and/or PEL but less than 10 times these limits, a NIOSH approved half-facepiece respirator equipped with dust-mist cartridges may be used. For concentrations greater than 10 times these limits, consult the NIOSH respirator decision logic found in Publication No or ANSI Z Wear chemical goggles; face shield (if splashing is possible). Wear impervious gloves for prolonged contact. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended. Suitable glove materials may include: Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Light blue Odor: Odorless Odor threshold: ph: Vapor pressure: Boiling point/range: > 100 C (> 212 F)calculated Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Complete Partition coefficient (n-octanol/water): Page 3 of 6

4 VOC content: Viscosity: Decomposition temperature: 0 % (calculated) 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable at normal conditions. None under normal processing. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Strong alkalis. This product may react with strong alkalies. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: This product is irritating to the respiratory system. This product may cause irritation to the skin. Contact can cause moderate to severe irritation and possible injury to the eyes. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Cupric nitrate Oral LD50 (Rat) = 940 mg/kg Hazardous Component(s) NTP Carcinogen IARC Carcinogen Allergen, Blood, Cardiac, Central nervous system, Developmental, Gastrointestinal, Immune system, Irritant, Kidney, Liver, Mutagen, Sensory, Skin, Vascular OSHA Carcinogen (Specifically Regulated) Cupric nitrate No No No 12. ECOLOGICAL INFORMATION Ecological information: Toxic to aquatic organisms Page 4 of 6

5 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III DOT Hazardous Substance(s): Cupric nitrate International Air Transportation (ICAO/IATA) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. (Copper(II)nitrate) Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Copper(II)nitrate) Hazard class or division: 9 Identification number: UN 3082 Packing group: III Marine pollutant: Copper(II)nitrate Additional information: IMDG-Code: Segregation group 1- Acids United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimis None above reporting de minimis. Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Cupric nitrate (CAS# ). Cupric nitrate (CAS# ) 100 lbs. (45.4 kg) No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Page 5 of 6

6 Prepared by: Regulatory Affairs Issue date: 06/23/2017 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6