SAFETY DATA SHEET. (REACH regulation (EC) n 1907/ n 453/2010)

Transcription

1 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 1/7 SAFETY DATA SHEET (REACH regulation (EC) n 1907/ n 453/2010) SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name : GTR PREMIUM Product code : Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Registered company name :. Address : 7 Rue Gutenberg Montreuil.France. Telephone : Fax : info@guardindustrie.com Emergency telephone number : +33 (0) Association/Organisation : INRS / ORFILA SECTION 2 : HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture In compliance with directives 67/548/EEC, 1999/45/EC and their amendments. Skin irritation (Xi, R 38). Eye irritation (Xi, R 36). May produce an allergic reaction. This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site. This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions of use Label elements In compliance with directives 67/548/EEC, 1999/45/EC and their amendments. Hazard symbols : Irritant Contains : Contains Risk phrase : R 36/38 Safety phrase : S 26 S 37 S 60 1-OCTANOL REACTION PRODUCTS WITH EPICHLOROHYDRIN AND 2-MERCAPTOETHANOL. May produce an allergic reaction. Irritating to eyes and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. This material and its container must be disposed of as hazardous waste.

2 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 2/ Other hazards The mixture does not contain any substances classified as 'Substances of Very High Concern' (SVHC) by the European CHemical s Agency (ECHA) under article 57 of REACH: The mixture satisfies neither the PBT nor the vpvb criteria for mixtures in accordance with annexe XIII of the REACH regulations EC 1907/2006. SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances No substances fulfil the criteria set forth in annexe II section A of the REACH regulation (EC) n 1907/ Mixtures Composition : Identification (EC) 1272/ /548/EEC Note % INDEX: 0001 CAS: EC: REACH: GHS07, GHS05 Dgr Met. Corr. 1, H290 Skin Corr. 1B, H314 C C;R34 Xn;R <= x % < 10 Acute Tox. 4, H332 ACIDE GLYCOLIQUE INDEX: GI RH. INF.1 CAS: ALCOOLS DE TYPE ISO EN C9-11 RICHES EN C10 ETHOXYLES INDEX: OCTANOL REACTION PRODUCTS WITH EPICHLOROHYDRIN AND 2-MERCAPTOETHANOL GHS07, GHS05 Dgr Acute Tox. 4, H302 Eye Dam. 1, H318 GHS07, GHS09 Wng Skin Sens. 1, H317 Eye Irrit. 2, H319 Aquatic Chronic 2, H411 Xn Xn;R22 Xi;R41 SECTION 4 : FIRST AID MEASURES As a general rule, in case of doubt or if symptoms persist, always call a doctor. NEVER induce swallowing by an unconscious person Description of first aid measures Xi,N Xi;R36-R43 N;R51/53 In the event of splashes or contact with eyes : Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open. 0 <= x % < <= x % < 2.5 In the event of swallowing : Do not give the patient anything orally. In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor. Seek medical attention, showing the label. Seek medical attention immediately, showing the label Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5 : FIREFIGHTING MEASURES Non-flammable Extinguishing media 5.2. Special hazards arising from the substance or mixture A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health. Do not breathe in smoke.

3 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 3/7 In the event of a fire, the following may be formed : - carbon monoxide (CO) - carbon dioxide (CO2) 5.3. Advice for firefighters SECTION 6 : ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Consult the safety measures listed under headings 7 and 8. For non fire-fighters Avoid any contact with the skin and eyes. For fire-fighters Fire-fighters will be equipped with suitable personal protective equipment (See section 8) Environmental precautions Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal. Prevent any material from entering drains or waterways Methods and material for containment and cleaning up Clean preferably with a detergent, do not use solvents Reference to other sections SECTION 7 : HANDLING AND STORAGE Requirements relating to storage premises apply to all facilities where the mixture is handled Precautions for safe handling Always wash hands after handling. Remove and wash contaminated clothing before re-using. Fire prevention : Prevent access by unauthorised personnel. Recommended equipment and procedures : For personal protection, see section 8. Observe precautions stated on label and also industrial safety regulations. Prohibited equipment and procedures : No smoking, eating or drinking in areas where the mixture is used Conditions for safe storage, including any incompatibilities Packaging Always keep in packaging made of an identical material to the original Specific end use(s) SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 8.2. Exposure controls Personal protection measures, such as personal protective equipment Use personal protective equipment that is clean and has been properly maintained. Store personal protective equipment in a clean place, away from the work area.

4 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 4/7 Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas. - Eye / face protection Avoid contact with eyes. Use eye protectors designed to protect against liquid splashes Before handling, wear safety goggles with protective sides accordance with standard EN166. In the event of high danger, protect the face with a face shield. Prescription glasses are not considered as protection. Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours. Provide eyewash stations in facilities where the product is handled constantly. - Hand protection Wear suitable protective gloves in the event of prolonged or repeated skin contact. Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN374. Gloves must be selected according to the application and duration of use at the workstation. Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required. Type of gloves recommended : - Natural latex - Nitrile rubber (butadiene-acrylonitrile copolymer rubber (NBR)) - PVC (polyvinyl chloride) - Butyl Rubber (Isobutylene-isoprene copolymer) Recommended properties : - Impervious gloves in accordance with standard EN374 - Body protection Avoid skin contact. Wear suitable protective clothing. Suitable type of protective clothing : In the event of substantial spatter, wear liquid-tight protective clothing against chemical risks (type 3) in accordance with EN14605 to prevent skin contact. In the event of a risk of splashing, wear protective clothing against chemical risks (type 6) in accordance with EN13034 to prevent skin contact. Work clothing worn by personnel shall be laundered regularly. After contact with the product, all parts of the body that have been soiled must be washed. N/A SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties General information : Physical state : fluid liquid. Important health, safety and environmental information ph : slightly acidic. Boiling point/boiling range : Flash point interval : not relevant. Vapour pressure (50 C) : not relevant. Density : > 1 Water solubility : Soluble. Melting point/melting range : Self-ignition temperature : Decomposition point/decomposition range :

5 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 5/ Other information SECTION 10 : STABILITY AND REACTIVITY Reactivity Chemical stability This mixture is stable under the recommended handling and storage conditions in section Possibility of hazardous reactions Conditions to avoid Avoid : - frost Incompatible materials Hazardous decomposition products The thermal decomposition may release/form : - carbon monoxide (CO) - carbon dioxide (CO2) SECTION 11 : TOXICOLOGICAL INFORMATION Information on toxicological effects May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours. May have reversible effects on the eyes, such as eye irritation which is totally reversible by the end of observation at 21 days Substances Acute toxicity : ACIDE GLYCOLIQUE (CAS: ) Oral route : DL50 = 2040 mg/kg Species : Rat (recommended by the CLP) Inhalation route : LC50 > 5.2 mg/l Species : Rat (recommended by the CLP) Mixture Respiratory or skin sensitisation : Contains at least one sensitising substance. May cause an allergic reaction. SECTION 12 : ECOLOGICAL INFORMATION Toxicity Mixtures No aquatic toxicity data available for the mixture Persistence and degradability Mixtures Biodegradability in water : Bioaccumulative potential Inherently biodegradable. Aerobic. OECD Guideline 302 B (Inherent biodegradability: Zahn-Wellens/EMPA Test)

6 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 6/ Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 : DISPOSAL CONSIDERATIONS Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC Waste treatment methods Do not pour into drains or waterways. Waste : Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals. Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company. Do not contaminate the ground or water with waste, do not dispose of waste into the environment. Soiled packaging : Empty container completely. Keep label(s) on container. Give to a certified disposal contractor. SECTION 14 : TRANSPORT INFORMATION Exempt from transport classification and labelling. Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport (ADR IMDG ICAO/IATA 2012). SECTION 15 : REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture - Classification and labelling information included in section 2: The following regulations have been used: - Directive 67/548/EEC and its adaptations - Directive 1999/45/EC and its adaptations - Regulation EC 1272/2008 modified by regulation EC 286/ Container information: - Particular provisions : Chemical safety assessment SECTION 16 : OTHER INFORMATION Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.

7 SAFETY DATA SHEET (REGULATION (EC) No 1907/ REACH) Date: 23/04/2014 Page 7/7 Title for H, EUH and R indications mentioned in section 3 : H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. R 20 Harmful by inhalation. R 22 Harmful if swallowed. R 34 Causes burns. R 36 Irritating to eyes. R 41 Risk of serious damage to eyes. R 43 May cause sensitisation by skin contact. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Abbreviations : ADR : European agreement concerning the international carriage of dangerous goods by Road. IMDG : International Maritime Dangerous Goods. IATA : International Air Transport Association. ICAO : International Civil Aviation Organisation RID : Regulations concerning the International carriage of Dangerous goods by rail. WGK : Wassergefahrdungsklasse (Water Hazard Class).