Bio-Optica Milano S.p.a. Dehyol absolute

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1 Page n / 07 Safety Data Sheet Wear Road 2. Other Directive Incompatible protective and hazards. rail 67/548/EEC transport: airtight materials. goggles and following (ref. standard amendments 166). and adjustments 6. SKIN 3. Information Accidental Regulation PROTECTION not release (EC) available. 1907/2006 measures. (REACH) of the European Parliament 1. Wear ADR/RID 4. Information Identification Regulation category Class: not (EC) available. of I professional 1272/2008 the substance/mixture (CLP) long-sleeved of the 3 European overalls UN: and of Parliament the and company/undertaking 1987 safety footwear (ref. Directive 89/686/CEE and standard 344). Wash body with soap Packing 5. Personal Regulation Hazardous and Group: water precautions, (EC) decomposition after 790/2009 removing protective (I overalls. Atp. products. CLP) equipment IIof the European and emergency Parliament procedures RESPIRATORY Label: 6. Eliminate In Composition/information Product Regulation the event identifier sources of (EC) thermal PROTECTION 453/2010 of ignition decomposition of on the (cigarettes, ingredients. European or 3fire, flames, vapours Parliament sparks, potentially etc.) dangerous from the to air health in which may the be leak released. occurred. If there are no contraindications, spray If Proper 7. solid The the products Merck threshold Shipping Index. with Name: value - water 10th for Edition to one prevent or more ALCOHOLS, the of formation the substances N.O.S. of dust. (Ethanol, present Use breathing 2-Propanol) the equipment preparation if for fumes daily or powders exposure are in released the workplace into the or air. to Block a fraction the established 8. Code: leakage Toxicological Substances. Handling if there Chemical by the is information. company s no Safety hazard. prevention Do not handle protection damaged 10077E, 10077Q service containers is exceeded, or leaked product wear a mask before with donning an AX appropriate or universal protective filter, the gear. class Send (1, 2 away or 3) of Carriage 9. Product individuals Niosh which name - must by Registry who sea be (shipping): are chosen of Toxic not according suitably Effects of equipped. to Chemical the limit For concentration Substances information of use on (ref. risks standard for the environmental 141). and health, respiratory tract protection, ventilation The 10. and Information INRS personal use - of Fiche not breathing protection relevant. on Toxicologique toxicological equipment, protection (toxicological effects. equipment, refer the sheet) other such sections as masks of this with sheet. organic vapour and dust/mist cartridges, is necessary in the absence of 1.2. technical IMO 11. Acute Relevant Patty Class: effects: - measures Industrial identified stinging limiting Hygiene uses eyes. worker of and the Symptoms Toxicology substance exposure. 3 may The or UN: include: mixture protection and rubescence, 1987 provided uses advised by edema, masks against is pain any and case lachrymation. limited. Vapour inhalation may moderately irritate If the Packing 12. Environmental Mixtures. the N.I. upper substance Sax Group: respiratory - Dangerous precautions. in question trait. properties Contact is odourless of Industrial with II skin or Materials-7, its may olfactory cause 1989 threshold slight Edition irritation. is higher Ingestion than the relative may cause exposure health limit problems, and in the including event stomach of an emergency, pain and or sting, Label: Intended The when product nausea exposure must and not sickness. levels penetrate are the unknown sewers, 3 or surface the concentration In water, vitro ground medical-diagnostic of water oxygen and in neighbouring the disposable. workplace areas. Reagent is less for than microscopy. 17% volume, wear self-contained, open-circuit This Marine Contains: product Pollutant. compressed contains highly air breathing volatile NO substances, apparatus (ref. which standard may cause 137) serious or fresh depression air hose breathing of the central apparatus nervous for use system with full (CNS) face mask, and have half mask negative Proper Note Methods Details for Shipping mouthpiece users: effects, of and the material supplier Name: such (ref. as for drowsiness, standard of the containment safety dizziness, 138). data ALCOHOLS, and sheet cleaning slow reflexes, N.O.S. up. (Ethanol, narcosis. 2-Propanol) The Identification. For liquid information products, contained suck Conc. into the %. a suitable present Classification container sheet are 67/548/EEC. (made based of on material our own not knowledge incompatible on Classification with the the date product) of 1272/2008 the and last soak version. (CLP). up any Users leaked must product verify with the 9. ETHANOL Transport suitability absorbent Physical and and by inert air: thoroughness chemical material (sand, properties. of provided vermiculite, information diatomeous according earth, to each Kieselguhr, specific use etc). of Collect the product the majority. of the remaining material and deposit in LD50 Name ETHANOL This containers document (Oral): for must disposal. not be For regarded solid products, as 1501 a guarantee mg/kg use Bio-Optica Rat spark on any proof specific Milano mechanical product S.p.a. property. tools to collect the leaked product and place in plastic containers. If 9.1. LC50 IATA: CAS F R11 Flam. Liq. 2 H225 Full The there Information address use (Inhalation): are of no this contraindications, basic product physical is not and use subject chemical jets 5,9 3 to mg/l/6h of our water UN: properties. direct Rat via to control; San eliminate 1987 Faustino, therefore, product 58users residues. must, under Make their sure own the responsibility, leakage site comply is well with aired. the Contaminated current health PROPAN-2-OL Packing Appearance District and material EC. safety and Group: should laws Country be and disposed regulations. of in The compliance producer II with is relieved the liquid provisions from Milano any set liability forth in arising point 13. from improper uses. LD50 Label: Colour INDEX. (Oral): mg/kg neutral Rat Italia 6.4. LC50 Proper PROPAN-2-OL Odour Reference (Inhalation): Shipping to other Name: sections. 72,6 ALCOHOLS, mg/l/4h Tel. characteristic Rat N.O.S. (Ethanol, Propanol) LD50 Odour Any CAS. information (Dermal): threshold on personal 20 protection - 50 and R67, disposal F R11, mg/kg Xi R36 Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336 Fax Not is Rat given available. in 0039 sections and ph. EC. Regulatory address information. of the competent person Melting responsible Handling INDEX. Ecological or freezing and for information. the storage. Safety point. Data Sheet info@bio-stain.it Boiling point. T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous Use Distillation Product Precautions Safety, this distribution for product range. health the Environment(N) for and safe according by environmental handling. to good regulations/legislation working practices. Not Bio-Optica available. Avoid specific Milano littering. S.p.a. Inform the the substance competent or mixture. authorities, should the product reach waterways or sewers Avoid Flash point. the or accumulation contaminate soil of electrostatic or vegetation. charges. < 10 C Seveso The Vapours Evaporation Emergency category. full wording may Rate telephone of ignite the Risk number with (R) explosion, 7b and hazard it (H) is phrases therefore is given necessary in section to avoid 16 of the accumulation sheet. keeping the windows and doors open, ensuring Flammability crossventilation. of solids Without and gases adequate ventilation, the Not vapours available. may accumulate at the bottom and ignite at a distance, if triggered off, with the risk Restrictions For Lower of Toxicity. flashback. urgent inflammability inquiries relating Keep to refer limit. far the to product away from or contained sources substances of heat, Not Please available. pursuant sparks contact and to Annex the bright nearest XVII flames. to Tossicology EC Regulation Do not smoke, and 1907/2006. Antivenin use matches Center or lighters. Keep the containers 4. Upper First Product. aid measures. Information earthed inflammability while not decanting available. limit. and wear antistatic boots Lower Vigorous Point. explosive stirring Description limit. and 3 - flow Hazards identification. through the pipings and Not equipment available. may cause the formation and accumulation of electrostatic charges due to the of first aid measures Upper low Persistence conductivity explosive and of limit. the degradability. product. In order to avoid the Not risk available. of fire outbreak and explosion never use compressed air during movement. Substances EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice. Vapour pressure. in Candidate List (Art. 59 REACH). None. SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash Vapour contaminated Classification Conditions densityfor clothing of safe the storage, before substance including using or them mixture. any incompatibilities. again Specific Store Bioaccumulative the gravity. containers sealed potential. and in a well ventilated place. 0,795 Kg/l INHALATION: Remove to open air. If breathing is irregular, seek medical advice. Information INGESTION: Solubility not available. Obtain immediate medical attention. partially Induce soluble in water Substances The product subject is classified to authorisarion as hazardous (Annex XIV pursuant REACH). to the provisions vomiting only set forth if indicated Directives by the 67/548/EEC doctor. Never and 1999/45/EC give anything and/or by EC mouth Regulation to an /2008 Partition Specific coefficient: end unconscious use(s). person. n-octanol/water None. (CLP) (and subsequent amendments and supplements). The product thus requires a safety datasheet that complies with the provisions Ignition Information Mobility temperature. of in not EC soil. available. Regulationn 1907/2006 and subsequent amendments Any Information Decomposition Most additional not important information temperature. available. symptoms concerning and effects, the risks both for acute health and and/or delayed. the environment are given in sections 11 and 12 of this sheet. 8. Viscosity For Exposure symptoms controls/personal and effects caused protection. Healthcare controls. by the contained substances see chap Danger Reactive Results Properties of PBT and vpvb assessment. Workers Symbols: exposed to this chemical F-Xi agent must not undergo health checks, provided that available risk-assessment data prove that the risks 8.1. Information 4.3. Control Indication parameters. not available. related to the of workers' any immediate health and medical safety are attention modest and special that the treatment 98/24/EC needed. directive is respected R Other Follow phrases: information. doctor's orders Name VOC Other (Directive adverse 1999/13/EC) effects. : 100,00 Type % - 794,69CountryTWA/8h g/litre Chemical safety assessment. STEL/15min The Information VOC full (volatile wording not carbon) available. of the : Risk (R) and hazard (H) phrases 54,83 is given % - in 435,70 section 16 of the g/litre. mg/m3 sheet. ppm mg/m3 ppm 5. Firefighting measures. No chemical safety assessment has been processed for the mixture and the substances it contains ETHANOL Stability and reactivity. TLV-ACGIH Disposal Label elements. Extinguishing considerations. media. OEL IRL 1000 SUITABLE EXTINGUISHING MEDIA Other Reactivity. information Hazard Waste labelling treatment pursuant methods. to Directives 67/548/EEC and 1999/45/EC WEL and UK subsequent amendments 1000 and supplements. The extinction equipment should contain carbon dioxide, foam or chemical powders. For product leaks and spills that have not caught fire, There Reuse, are when no particular possible. risks Product of reaction residues with should other substances be considered in normal special conditions hazardous of use. waste. The hazard level of waste containing this product Text nebulised of hazard water (H) can indications be used to mentioned dispel flammable in section fumes 2-3 of and the protect sheet: the individuals taking part in stemming the leak. PROPAN-2-OL should be evaluated Xi according to applicable regulations. TLV-ACGIH F Skin EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS Disposal Chemical must stability. be performed through an authorised waste OEL management firm, IRL in compliance with 400 national and local regulations. 500 Skin Do Flam. not use Liq. jets 2 of Flammable water. Water liquid, is not category effective 2 for putting out fires but can be used to cool containers exposed to flames to prevent CONTAMINATED The product is stable PACKAGING in normal conditions of use and storage. WEL UK Skin explosions. Eye Irrit. 2 Eye irritation, category 2 Contaminated STOT SE 3 packaging Specific must target be recovered organ toxicity or disposed - single of exposure, in compliance category with 3 national waste management regulations Possibility of hazardous reactions Special H225 hazards arising Highly from flammable the substance liquid and or vapour. mixture The Exposure vapours HAZARDS Transport H319 CAUSED controls. may information. also explosive mixtures with the air. IRRITANT Causes BY EXPOSURE serious eye IN THE irritation. EVT OF FIRE HIGHLY FLAMMABLE H336 May cause drowsiness or dizziness. Excess pressure may form in containers exposed to fire at a risk of explosion. These As ETHANOL: Do the use risk of adequate of explosion not breathe goods must combustion be transported technical on contact products equipment with: must alkaline always metals, take alkaline priority oxides, over personal calcium protection hypochlorite, equipment, sulphur make monofluoride, sure that acetic the workplace anhydride R11 HIGHLY FLAMMABLE. is (carbon by vehicles oxide, authorized toxic pyrolysis to the products, carriage etc). of dangerous goods according to the provisions set out in the current Text edition well (with R36 of aired acids), of risk the (R) through Code concentrated phrases of effective IRRITATING International mentioned hydrogen local TO in Carriage aspiration section EYES. peroxide, of 2-3 Dangerous or of perchlorates, bad the air sheet: vent. Goods If perchloric such by Road operations (ADR) acid, perchloronitrile, do and not in make all the applicable possible mercury to nitrate, national keep the nitric regulations. concentration acid, silver and of the nitric product acid, below silver 5.3. These Advice R67 nitrate, the goods permitted silver nitrate for firefighters. must VAPOURS be workplace packed and ammonia, MAY in exposure their CAUSE silver original thresholds DROWSINESS oxide packagings and a ammonia, suitable AND or in DIZZINESS. respiratory strong packagings oxidising tract made protection agents, of nitrogen materials must be dioxide. resistant used. See Can to product react their dangerously content label for and hazard with: not reacting details dangerously during bromoacetylene, R11 use. Ask your chlorine chemical acetylene, substance bromine suppliers trifluoride, for advice chromium when trioxide, choosing chromyl personal chloride, protection oxiranes, equipment. fluorine, Personal potassium protection tert-butoxide, equipment GERAL INFORMATION with it. HIGHLY People FLAMMABLE. loading and unloading dangerous goods must be trained all the risks deriving from these substances and on all actions must lithium R36 S 9comply hydride, with phosphorus the Use jets that of must water be to taken IRRITATING KEEP rules cool in CONTAINER trioxide, force indicated black the case TO containers of emergency EYES. IN platinum, A below. to WELL-VTILATED zirconium (IV) chloride, prevent situations. product decomposition PLACE. zirconium (IV) iodide. Forms an explosive mixture with the air. and the development of substances potentially hazardous for HAND R67 S16PROTECTION VAPOURS KEEP AWAY MAY FROM CAUSE SOURCES DROWSINESS OF IGNITION AND DIZZINESS. - NO SMOKING. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Protect Conditions S25 hands to with avoid. AVOID category CONTACT I (ref. Directive WITH EYES. 89/686/EEC and standard 374) work gloves, such as those in latex, PVC or equivalent. The contaminated water and the remains of the fire according to applicable regulations. following Avoid S26overheating, should be electrostatic IN considered CASE OF discharge when CONTACT choosing and WITH all sources work EYES, glove of RINSE ignition. material: IMMEDIATELY degradation, WITH breakage PLTY times OF WATER and permeation. AND SEEK Work MEDICAL glove resistance to SPECIAL GERAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS preparations BIBLIOGRAPHY should be ADVICE. checked before use, as it can be unpredictable. Gloves limit depends on the duration of exposure. Hardhat 1. with visor, fireproof clothing (fireproof jacket and trousers with ties around arms, legs and waist) work gloves (fireproof, cut proof and EYE ETHANOL: Directive S33 PROTECTION avoid 1999/45/EC exposure TAKE and to PRECAUTIONARY following sources amendments of heat and MEASURES naked flames. AGAINST STATIC DISCHARGES. dielectric), self-respirator (self-protector).

2 Page n. 2 / Other hazards. 3. Composition/information on ingredients Substances. Information not relevant Mixtures. Contains: Identification. Conc. %. Classification 67/548/EEC. Classification 1272/2008 (CLP). ETHANOL CAS F R11 Flam. Liq. 2 H225 EC INDEX PROPAN-2-OL CAS R67, F R11, Xi R36 Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336 EC INDEX T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous for the Environment(N) The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. 4. First aid measures Description of first aid measures. EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice. SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash contaminated clothing before using them again. INHALATION: Remove to open air. If breathing is irregular, seek medical advice. INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person Most important symptoms and effects, both acute and delayed. For symptoms and effects caused by the contained substances see chap Indication of any immediate medical attention and special treatment needed. Follow doctor's orders. 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING MEDIA The extinction equipment should contain carbon dioxide, foam or chemical powders. For product leaks and spills that have not caught fire, nebulised water can be used to dispel flammable fumes and protect the individuals taking part in stemming the leak. EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent explosions Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc) Advice for firefighters. GERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Hardhat with visor, fireproof clothing (fireproof jacket and trousers with ties around arms, legs and waist) work gloves (fireproof, cut proof and dielectric), self-respirator (self-protector).

3 Page n. 3 / 7 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. Eliminate sources of ignition (cigarettes, flames, sparks, etc.) from the air in which the leak occurred. If there are no contraindications, spray solid products with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there is no hazard. Do not handle damaged containers or leaked product before donning appropriate protective gear. Send away individuals who are not suitably equipped. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, refer to the other sections of this sheet Environmental precautions. The product must not penetrate the sewers, surface water, ground water and neighbouring areas Methods and material for containment and cleaning up. For liquid products, suck into a suitable container (made of material not incompatible with the product) and soak up any leaked product with absorbent inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit in containers for disposal. For solid products, use spark proof mechanical tools to collect the leaked product and place in plastic containers. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point Reference to other sections. Any information on personal protection and disposal is given in sections 8 and Handling and storage Precautions for safe handling. Avoid the accumulation of electrostatic charges. Vapours may ignite with explosion, it is therefore necessary to avoid accumulation keeping the windows and doors open, ensuring crossventilation. Without adequate ventilation, the vapours may accumulate at the bottom and ignite at a distance, if triggered off, with the risk of flashback. Keep far away from sources of heat, sparks and bright flames. Do not smoke, use matches or lighters. Keep the containers earthed while decanting and wear antistatic boots. Vigorous stirring and flow through the pipings and equipment may cause the formation and accumulation of electrostatic charges due to the low conductivity of the product. In order to avoid the risk of fire outbreak and explosion never use compressed air during movement Conditions for safe storage, including any incompatibilities. Store the containers sealed and in a well ventilated place Specific end use(s). 8. Exposure controls/personal protection Control parameters. Name Type Country TWA/8h STEL/15min mg/m3 ppm mg/m3 ppm ETHANOL TLV-ACGIH 1000 OEL IRL 1000 WEL UK 1000 PROPAN-2-OL TLV-ACGIH Skin OEL IRL Skin WEL UK Skin 8.2. Exposure controls. As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product below the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details during use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipment must comply with the rules in force indicated below. HAND PROTECTION Protect hands with category I (ref. Directive 89/686/EEC and standard 374) work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as it can be unpredictable. Gloves limit depends on the duration of exposure. EYE PROTECTION

4 Page n. 4 / 7 Wear protective airtight goggles (ref. standard 166). SKIN PROTECTION Wear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard 344). Wash body with soap and water after removing overalls. RESPIRATORY PROTECTION If the threshold value for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company s prevention and protection service is exceeded, wear a mask with an AX or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard 141). The use of breathing protection equipment, such as masks with organic vapour and dust/mist cartridges, is necessary in the absence of technical measures limiting worker exposure. The protection provided by masks is in any case limited. If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, open-circuit compressed air breathing apparatus (ref. standard 137) or fresh air hose breathing apparatus for use with full face mask, half mask or mouthpiece (ref. standard 138). 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance liquid Colour neutral Odour characteristic Odour threshold. ph. Melting or freezing point. Boiling point. Distillation range. Flash point. < 10 C. Evaporation Rate Flammability of solids and gases Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Specific gravity. 0,795 Kg/l Solubility partially soluble in water Partition coefficient: n-octanol/water Ignition temperature. Decomposition temperature. Viscosity Reactive Properties 9.2. Other information. VOC (Directive 1999/13/EC) : 100,00 % - 794,69 g/litre. VOC (volatile carbon) : 54,83 % - 435,70 g/litre. 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances in normal conditions of use Chemical stability. The product is stable in normal conditions of use and storage Possibility of hazardous reactions. The vapours may also form explosive mixtures with the air. ETHANOL: risk of explosion on contact with: alkaline metals, alkaline oxides, calcium hypochlorite, sulphur monofluoride, acetic anhydride (with acids), concentrated hydrogen peroxide, perchlorates, perchloric acid, perchloronitrile, mercury nitrate, nitric acid, silver and nitric acid, silver nitrate, silver nitrate and ammonia, silver oxide and ammonia, strong oxidising agents, nitrogen dioxide. Can react dangerously with: bromoacetylene, chlorine acetylene, bromine trifluoride, chromium trioxide, chromyl chloride, oxiranes, fluorine, potassium tert-butoxide, lithium hydride, phosphorus trioxide, black platinum, zirconium (IV) chloride, zirconium (IV) iodide. Forms an explosive mixture with the air Conditions to avoid. Avoid overheating, electrostatic discharge and all sources of ignition. ETHANOL: avoid exposure to sources of heat and naked flames.

5 Page n. 5 / Incompatible materials Hazardous decomposition products. In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released. 11. Toxicological information Information on toxicological effects. Acute effects: stinging eyes. Symptoms may include: rubescence, edema, pain and lachrymation. Vapour inhalation may moderately irritate the upper respiratory trait. Contact with skin may cause slight irritation. Ingestion may cause health problems, including stomach pain and sting, nausea and sickness. This product contains highly volatile substances, which may cause serious depression of the central nervous system (CNS) and have negative effects, such as drowsiness, dizziness, slow reflexes, narcosis. ETHANOL LD50 (Oral): LC50 (Inhalation): PROPAN-2-OL LD50 (Oral): LC50 (Inhalation): LD50 (Dermal): 1501 mg/kg Rat 5,9 mg/l/6h Rat 4710 mg/kg Rat 72,6 mg/l/4h Rat mg/kg Rat 12. Ecological information. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects. 13. Disposal considerations Waste treatment methods. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14. Transport information. These goods must be transported by vehicles authorized to the carriage of dangerous goods according to the provisions set out in the current edition of the Code of International Carriage of Dangerous Goods by Road (ADR) and in all the applicable national regulations. These goods must be packed in their original packagings or in packagings made of materials resistant to their content and not reacting dangerously with it. People loading and unloading dangerous goods must be trained on all the risks deriving from these substances and on all actions that must be taken in case of emergency situations.

6 Page n. 6 / 7 Road and rail transport: ADR/RID Class: 3 UN: 1987 Packing Group: II Label: 3 Proper Shipping Name: ALCOHOLS, N.O.S. (Ethanol, 2-Propanol) Carriage by sea (shipping): IMO Class: 3 UN: 1987 Packing Group: II Label: 3 Marine Pollutant. NO Proper Shipping Name: ALCOHOLS, N.O.S. (Ethanol, 2-Propanol) Transport by air: IATA: 3 UN: 1987 Packing Group: II Label: 3 Proper Shipping Name: ALCOHOLS, N.O.S. (Ethanol, 2-Propanol) 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. 7b Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Product. Point Substances in Candidate List (Art. 59 REACH). None. Substances subject to authorisarion (Annex XIV REACH). None. Healthcare controls. Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected Chemical safety assessment. No chemical safety assessment has been processed for the mixture and the substances it contains. 16. Other information. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Flam. Liq. 2 Flammable liquid, category 2 Eye Irrit. 2 Eye irritation, category 2 STOT SE 3 Specific target organ toxicity - single exposure, category 3 H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Text of risk (R) phrases mentioned in section 2-3 of the sheet: R11 R36 R67 HIGHLY FLAMMABLE. IRRITATING TO EYES. VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS. GERAL BIBLIOGRAPHY 1. Directive 1999/45/EC and following amendments

7 Page n. 7 / 7 2. Directive 67/548/EEC and following amendments and adjustments 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EC) 453/2010 of the European Parliament 7. The Merck Index. - 10th Edition 8. Handling Chemical Safety 9. Niosh - Registry of Toxic Effects of Chemical Substances 10. INRS - Fiche Toxicologique (toxicological sheet) 11. Patty - Industrial Hygiene and Toxicology 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.

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