: Hydrogen Peroxide, 3% w/w

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Product code Date of issue: 02/17/2014 Revision date: 10/31/2017 Supersedes: 01/06/2016 Version: 1.3 : Mixtures : : LC Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 H315 H318 Full text of H statements : see section 16 Causes skin irritation Causes serious eye damage 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS Other hazards which do not result in classification Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) Not applicable : H315 - Causes skin irritation H318 - Causes serious eye damage : P264 - Wash exposed skin thoroughly after handling P280 - Wear protective gloves, eye protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center or doctor/physician P321 - Specific treatment (see... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse : None under normal conditions. SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 10/31/2017 EN (English US) Page 1

2 3.2. Mixtures Name Product identifier % GHS-US classification Water (CAS-No.) Not classified Hydrogen Peroxide, 30% w/w (CAS-No.) Ox. Liq. 1, H271 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Corr. 1A, H314 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact Symptoms/effects after eye contact : Causes skin irritation. : Causes serious eye damage Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Safety glasses. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 10/31/2017 EN (English US) 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Wash exposed skin thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well ventilated place away from : incompatible materials, combustible materials. Keep container closed when not in use. : Strong bases. Strong reducing agents. metals. combustible materials. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (mg/m³) 1.4 mg/m³ ACGIH ACGIH TWA (ppm) 1 ppm OSHA OSHA PEL (TWA) (mg/m³) 1.4 mg/m³ OSHA OSHA PEL (TWA) (ppm) 1 ppm IDLH US IDLH (ppm) 75 ppm NIOSH NIOSH REL (TWA) (mg/m³) 1.4 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 1 ppm Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure Individual protection measures/personal protective equipment Personal protective equipment: Face shield. Gloves. Safety glasses. Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Respiratory protection not required in normal conditions Other information: Do not eat, drink or smoke during use. 10/31/2017 EN (English US) 3/7

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density : 1 Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Unstable on exposure to light Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials : Liquid : Colorless : None. : Non flammable. : Soluble in water. Strong reducing agents. Strong bases. metals. combustible materials Hazardous decomposition products oxygen. SECTION 11: Toxicological information Information on toxicological effects Likely routes of exposure Acute toxicity ATE US (oral) ATE US (gases) : Inhalation; Skin and eye contact 500 mg/kg body weight 4500 ppmv/4h 10/31/2017 EN (English US) 4/7

5 ATE US (vapors) ATE US (dust, mist) LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/effects after skin contact Symptoms/effects after eye contact 11 mg/l/4h 1.5 mg/l/4h mg/kg mg/kg body weight : Causes skin irritation. : Causes serious eye damage. 3 - Not classifiable : Based on available data, the classification criteria are not met. : Causes skin irritation. : Causes serious eye damage. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Persistence and degradability Persistence and degradability Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential Mobility in soil Other adverse effects Effect on the global warming GWPmix comment Other information : No known effects from this product. : No known effects from this product. : Avoid release to the environment. 10/31/2017 EN (English US) 5/7

6 SECTION 13: Disposal considerations Disposal methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. SECTION 15: Regulatory information US Federal regulations SARA Section 311/312 Hazard Classes Immediate (acute) health hazard All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory SARA Section 311/312 Hazard Classes Reactive hazard Immediate (acute) health hazard International regulations CANADA EU-Regulations National regulations US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 10/31/2017 Other information Full text of H-phrases: see section 16: H271 H302 H314 H315 H318 H332 : None. May cause fire or explosion; strong oxidizer Harmful if swallowed Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Harmful if inhaled 10/31/2017 EN (English US) 6/7

7 NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard Hazard Rating Health Flammability Physical Personal protection : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 1 - Materials that in themselves are normally stable but can become unstable at elevated temperatures and pressures. : OX - Materials that posses oxidizing properties. : 2 Moderate Hazard - Temporary or minor injury may occur : 0 Minimal Hazard - Materials that will not burn : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors. : B B - Safety glasses, Gloves SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 10/31/2017 EN (English US) 7/7