S2O washing machine cleaner Refresh Paks Version Number: 1.0 Date 20 th December 2014 Supersedes: Not applicable SAFETY DATA SHEET

Transcription

1 SAFETY DATA SHEET S2O washing machine cleaner Refresh Paks This Safety Data Sheet contains information about the potential risks to those involved in handling, transporting and working with this product, as well as describing potential risks to the environment. This information must be made available to those who may come into contact with the product or are responsible for its use. This Safety Data Sheet has been prepared in accordance with the formatting requirements described in the REACH Regulation (EC) No 1907/2006 and the CLP Regulation (EC) No 1272/2008. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier S2O washing machine cleaner Refresh Paks 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified use: Cleaning agent for washing machines Uses advised against: None 1.3 Details of the supplier of the safety data sheet TMGTV Inc. Front Suite, Flr High Street, Teddington Middlesex, TW11 8HH Tel: E mail: hbrunt@tmgtv.ca 1.4 Emergency telephone number Tel: CANUTEC: Hours: 24/7 SECTION 2: Hazards Identification 2.1 Classification of the substance or mixture Classification according to the Dangerous Preparations Directive 1999/45/EC: Xi; Irritant R36 Irritating to eyes Classification according to the Classification Labelling and Packaging Regulation (EC) No 1272/2008: Eye Irrit. 2, H319 Causes serious eye irritation 2.2 Label elements Page 1 of 7

2 Label according to the Classification Labelling and Packaging Regulation (EC) No 1272/2008: WARNING P264 Wash hands thoroughly after handling P305+ P351 + P338 IF IN EYES, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists, get medical advice Keep out of reach of children. 2.3 Other hazards None known. SECTION 3: Composition 3.1 Substances Not applicable product is a mixture. 3.2 Mixtures Solid mixture Chemical Name CAS # EC # % EU hazard Sodium carbonate, anhydrous Sodium carbonate peroxyhydrate Inorganic builders, sequestering agents and organic surfactants Index # < 25 Eye Irrit 2 H < 20 Ox Sol 2 H272 Acute Tox 4 H302 Eye dam 1 H318 To 100% No further hazardous impurities or substances considered PBT or vpvb present, above thresholds of concern, or substances with a community workplace exposure limit assigned which required reporting in this section See Section 16 for the full text of the H statements declared above. SECTION 4: First Aid Measures 4.1 Description of first aid measures EYE CONTACT: Wash thoroughly with water and obtain medical attention if signs of discomfort persist. INHALATION: Remove from exposure. If breathing becomes difficult call a doctor. SKIN CONTACT: Wash off with water. If irritation persists, seek medical advice. INGESTION: If swallowed, rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed Page 2 of 7

3 EYE CONTACT: If contents of the pack gets into the eye it may cause irritation with redness, stinging, watering of the eye. INHALATION: Inhalation is considered to be unlikely. No adverse effects. SKIN CONTACT: Not considered hazardous, but may cause slight irritation. INGESTION: Not considered hazardous. May cause irritation to GI tract and mouth. 4.3 Indication of any immediate medical attention and special treatments needed Symptomatic treatment as required for inorganic bases SECTION 5: Firefighting Measures 5.1 Extinguishing media Non flammable and will not support combustion Water spray, alcohol resistant foam, dry powder and carbon dioxide extinguishers are suitable. Use extinguishing media appropriate to the surrounding conditions. 5.2 Special hazards arising from the substance or mixture No special hazards. 5.3 Advice for fire fighters Fire fighters should wear protective clothing and breathing apparatus as appropriate. SECTION 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures No special precautions necessary. 6.2 Environmental precautions Prevent entry into sewers and watercourses. 6.3 Methods and materials for containment and clearing up Collect wipes and place in a sealable container for disposal. 6.4 References to other sections See section 8 and 13 for further advice. SECTION 7: Handling and Storage 7.1 Precautions for safe handling Ensure adequate ventilation (> 3 changes of air per hour) if risk of dust formation when handling solid. Avoid contact with eyes and prolonged contact with skin. 7.2 Conditions for safe storage, including any incompatibilities Store in its original labelled container. Keep out of reach of children and animals. 7.3 Specific end uses(s) No special precautions. SECTION 8: Exposure Controls/Personal Protection 8.1 Control parameters EXPOSURE LIMITS No components with specific exposure limits. 8.2 Exposure controls Engineering controls Page 3 of 7

4 Normal room ventilation is expected to be adequate. Estimated 3 exchanges of air per hour. Respiratory protection Not required. Hand Protection If handling bulk solid or prolonged contact is expected, then suitable gloves may be required. Butyl rubber, nitrile rubber may be suitable, but glove manufacturer s recommendations should always be checked. Eye protection If handling bulk solid, then safety glasses or goggles are recommended. Skin protection If handling bulk solid or prolonged contact is expected, then suitable protective clothing such as overalls with sleeves should be worn. Remove protective clothing when contaminated and wash before reuse. Environmental Exposure Controls Not normally required. SECTION 9: Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance: White powder Odour: No specific odour Odour threshold: No data ph: Approximately Melting point: > 100 Boiling point: Will decompose. Inorganic solids Flashpoint: Solid with no volatile component Evaporation rate: Not applicable Flammability (solids, gas): Not applicable Upper/lower flammability limits: Not applicable Vapour pressure: Solid with no volatile component Vapour density: Solid with no volatile component Relative density: > 1 Solubility in water: Completely soluble in water Solubility in other solvents: No data Partition coefficient (log Kow): No data Autoignition temperature: No data Decomposition temperature: No data Viscosity: Solid Explosive properties: Not classified as explosive Oxidising properties: Not classified as oxidising. Contains oxidising agent below threshold for classification 9.2 Other information None SECTION 10: Stability and Reactivity 10.1 Reactivity No specific test data related to reactivity is available for this product or its components 10.2 Chemical stability Stable under normal conditions. Page 4 of 7

5 10.3 Possibility of hazardous reactions None expected Conditions to avoid No specific instruction 10.5 Incompatible materials Avoid exposure to strong reducing agents 10.6 Hazardous decomposition products None known. SECTION 11: Toxicological Information 11.1 Information on toxicological effects The product has not been tested. Assessment is based on consideration of component substances. (a) acute toxicity The product has not been tested Mixture not considered to be harmful by ingestion, inhalation or on skin based on toxicity of ingredients (b) skin corrosion/irritation Mildly alkaline solid with ph 7-9 considered to be mildly irritating to skin, but not requiring classification. (c) serious eye damage/irritation Data on ingredients suggests the mixture is likely to be an eye irritant. (d) respiratory/skin sensitisation This product contains no known potential sensitisers. (e) germ cell mutagenicity No indication that any components above thresholds of concern are potential mutagens. (f) carcinogenicity No indication that any components above thresholds of concern are potential carcinogens. (g) reproductive toxicity No indication that any components above thresholds of concern are potentially toxic for reproduction. (h) STOT-single exposure No adverse effects expected from any components (i) STOT-repeated exposure No adverse effects expected from any components (j) aspiration hazard Solid. Not applicable. SECTION 12: Ecological Information The product has not been tested. Assessment is based on consideration of the components Toxicity This product contains no components considered harmful to the environment at concentrations present. The product contains low levels of non-ionic and anionic surfactants considered harmful to aquatic organisms in their concentrated forms Persistence and degradability The surfactants in the product comply with the biodegradability criteria laid down in Regulation (EC) No. 648/2004 on detergents Bioaccumulative potential None of the components are considered to be significantly bioaccumulative 12.4 Mobility in soil The product is soluble in water and potentially mobile in soil 12.5 Results of PBT and vpvb assessment The active components are not PBT or vpvb Page 5 of 7

6 12.6 Other adverse effects No known significant effects or critical hazards SECTION 13: Disposal Considerations 13.1 Waste treatment methods Waste solid and packaging should be disposed of in accordance with local regulations. Disposal as domestic low hazard waste is possible, but for disposal following non-domestic use, confirm with local operators. SECTION 14: Transport Information Not classified as hazardous for transport UN Number None 14.2 UN Proper shipping name None 14.3 Transport hazard class(es) None 14.4 Packing group None 14.5 Environmental hazards None 14.6 Special precautions for user None 14.7 Transport in bulk according to Not applicable Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This product is subject to the Detergent Regulation (EC) No 648/2004 EU Regulation (EC) No. 1907/2006 (REACH) The supplier has not yet registered any of the components 15.2 Chemical Safety Assessment A CSR for the components is not available SECTION 16: Other Information Revision information: First EU SDS H Statements used in Section 3: H272 May intensify fire; oxidiser H302 Harmful if swallowed H318 Causes serious eye damage H319 Causes serious eye irritation Abbreviations and acronyms: CLP Classification, Labelling and Packaging Regulation (EC) No 1272/2008 EC European Community/Commission EU European Union Page 6 of 7

7 PBT Persistent, Bioaccumulative and Toxic REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 SDS Safety Data Sheet TWA time-weighted average vpvb very Persistent, very Bioaccumulative Sources of key data: Source: European Chemicals Agency, Method used for classification of mixture: Ingredient-based approaches and expert judgment Page 7 of 7