SAFETY DATA SHEET WINSOR & NEWTON SANSODOR According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010
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1 SAFETY DATA SHEET According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Thinner for Oil Painting No specific uses advised against are identified Details of the supplier of the safety data sheet Supplier Contact person Manufacturer ColArt International Holdings Ltd. The Studio Building 21 Evesham Street London W11 4AJ United Kingdom +44 (0) Regulatory Manager ColArt International SA 5 Rue Rene Panhard Z.I.Nord Le Mans Cedex Emergency telephone number Emergency telephone 33 (0) This number is only available during office hours. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Environmental hazards Asp. Tox. 1 - H304 Not Classified Classification (67/548/EEC or 1999/45/EC) Xn;R65. R Label elements Pictogram Signal word Hazard statements Danger H304 May be fatal if swallowed and enters airways. 1/9
2 Precautionary statements Supplemental label information Contains Supplementary precautionary statements P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P331 Do NOT induce vomiting. P405 Store locked up. P501 Dispose of contents/container in accordance with national regulations. EUH066 Repeated exposure may cause skin dryness or cracking. Hydrocarbons, C14-C18, <2% aromatics P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P331 Do NOT induce vomiting. P405 Store locked up. P501 Dispose of contents/container to 2.3. Other hazards This product does not contain any substances classified as PBT or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hydrocarbons, C14-C18, <2% aromatics % CAS number: EC number: REACH registration number: Classification Asp. Tox. 1 - H304 Classification (67/548/EEC or 1999/45/EC) Xn;R65. R66. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information Inhalation Ingestion Skin contact Eye contact Protection of first aiders Get medical attention if any discomfort continues. Show this Safety Data Sheet to the medical personnel. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if symptoms are severe or persist. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately. Rinse with water. Rinse with water. Get medical attention if any discomfort continues. First aid personnel should wear appropriate protective equipment during any rescue Most important symptoms and effects, both acute and delayed General information Inhalation Ingestion Skin contact The severity of the symptoms described will vary dependent on the concentration and the length of exposure. No specific symptoms known. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Repeated exposure may cause skin dryness or cracking. 2/9
3 Eye contact No specific symptoms known. May be slightly irritating to eyes Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media The product is not flammable. Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media suitable for the surrounding fire. Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products Containers can burst violently or explode when heated, due to excessive pressure build-up. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters Avoid breathing fire gases or vapours. Evacuate area. Cool containers exposed to heat with water spray and remove them from the fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping the leak. Control run-off water by containing and keeping it out of sewers and watercourses. If risk of water pollution occurs, notify appropriate authorities. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. Firefighter's clothing conforming to European standard EN469 (including helmets, protective boots and gloves) will provide a basic level of protection for chemical incidents. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be taken without appropriate training or involving any personal risk Environmental precautions Environmental precautions Avoid discharge into drains or watercourses or onto the ground Methods and material for containment and cleaning up Methods for cleaning up Wear protective clothing as described in Section 8 of this safety data sheet. Clear up spills immediately and dispose of waste safely. If the product is soluble in water, dilute the spillage with water and mop it up. Alternatively, or if it is not water-soluble, absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. The contaminated absorbent may pose the same hazard as the spilled material. Label the containers containing waste and contaminated materials and remove from the area as soon as possible. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage. For waste disposal, see Section Reference to other sections Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health hazards. See Section 12 for additional information on ecological hazards. For waste disposal, see Section 13. SECTION 7: Handling and storage 3/9
4 7.1. Precautions for safe handling Usage precautions Advice on general occupational hygiene Read and follow manufacturer's recommendations. Wear protective clothing as described in Section 8 of this safety data sheet. Keep away from food, drink and animal feeding stuffs. Handle all packages and containers carefully to minimise spills. Keep container tightly sealed when not in use. Avoid the formation of mists. Do not handle until all safety precautions have been read and understood. Do not handle broken packages without protective equipment. Do not reuse empty containers. Wash promptly if skin becomes contaminated. Take off contaminated clothing. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage precautions Storage class Store locked up. Keep only in the original container. Keep container tightly closed, in a cool, well ventilated place. Keep containers upright. Protect containers from damage. Chemical storage Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective equipment Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection Environmental exposure controls Provide adequate ventilation. Avoid contact with eyes. Large Spillages: Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. No specific hand protection recommended. Wear appropriate clothing to prevent any possibility of skin contact. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. No specific recommendations. Provide adequate ventilation. Large Spillages: If ventilation is inadequate, suitable respiratory protection must be worn. Keep container tightly sealed when not in use. Avoid release to the environment. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Melting point Liquid Colourless. Mild. <-5 C 4/9
5 Initial boiling point and range Flash point Upper/lower flammability or explosive limits mm Hg >93 C CC (Closed cup). : 0.5 Vapour pressure C Relative density 15 C Bulk density Solubility(ies) Partition coefficient Auto-ignition temperature 800 kg/m³ Insoluble in water Scientifically unjustified. >200 C Viscosity C 9.2. Other information Particle size Not applicable. SECTION 10: Stability and reactivity Reactivity Reactivity There are no known reactivity hazards associated with this product Chemical stability Stability Stable at normal ambient temperatures and when used as recommended. Stable under the prescribed storage conditions Possibility of hazardous reactions Possibility of hazardous reactions No potentially hazardous reactions known Conditions to avoid Conditions to avoid There are no known conditions that are likely to result in a hazardous situation Incompatible materials Materials to avoid No specific material or group of materials is likely to react with the product to produce a hazardous situation Hazardous decomposition products Hazardous decomposition products Does not decompose when used and stored as recommended. Thermal decomposition or combustion products may include the following substances: Harmful gases or vapours. SECTION 11: Toxicological information Information on toxicological effects Other health effects Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg) Species Notes (oral LD₅₀) There is no evidence that the product can cause cancer. 5,000.0 Rat 5/9
6 Acute toxicity - dermal Acute toxicity dermal (LD₅₀ mg/kg) Species Notes (dermal LD₅₀) Acute toxicity - inhalation Notes (inhalation LC₅₀) Skin corrosion/irritation Animal data Serious eye damage/irritation Serious eye damage/irritation Respiratory sensitisation Respiratory sensitisation Skin sensitisation Skin sensitisation Germ cell mutagenicity Genotoxicity - in vitro Genotoxicity - in vivo Carcinogenicity Carcinogenicity IARC carcinogenicity Reproductive toxicity Reproductive toxicity - fertility Reproductive toxicity - development 2,000.0 Rabbit Repeated exposure may cause skin dryness or cracking. Chromosome aberration: Negative. None of the ingredients are listed or exempt. Specific target organ toxicity - single exposure STOT - single exposure Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Asp. Tox. 1 - H304 May be fatal if swallowed and enters airways. Pneumonia may be the result if vomited material containing solvents reaches the lungs. General information Inhalation Ingestion Skin contact Eye contact The severity of the symptoms described will vary dependent on the concentration and the length of exposure. No specific symptoms known. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Repeated exposure may cause skin dryness or cracking. No specific symptoms known. 6/9
7 Route of entry Target organs Ingestion Inhalation Skin and/or eye contact No specific target organs known. SECTION 12: Ecological Information Ecotoxicity Not regarded as dangerous for the environment. However, large or frequent spills may have hazardous effects on the environment Toxicity Toxicity Acute toxicity - fish Acute toxicity - aquatic invertebrates Acute toxicity - microorganisms Acute toxicity - terrestrial Chronic toxicity - fish early life stage Chronic toxicity - aquatic invertebrates LC₅₀, 96 hours: >1028 mg/l, Fish EC₅₀, 48 hours: >3000 mg/l, Daphnia magna EC₅₀, 3 hours, > 3 hours: 100 mg/l, Activated sludge Scientifically unjustified., 28 days, > 28 days: 1000 mg/l,, 21 days, > 21 days: 1000 mg/l, Daphnia magna Persistence and degradability Persistence and degradability Phototransformation Biodegradation The degradability of the product is not known. Technically not feasible. Air. - : water - 74 Degradation (%): > 28 days Bioaccumulative potential Bioaccumulative potential Partition coefficient No data available on bioaccumulation. Scientifically unjustified Mobility in soil Mobility No data available Results of PBT and vpvb assessment Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria Other adverse effects Other adverse effects None known. SECTION 13: Disposal considerations Waste treatment methods 7/9
8 General information Disposal methods Waste class The generation of waste should be minimised or avoided wherever possible. Reuse or recycle products wherever possible. This material and its container must be disposed of in a safe way. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority * - waste paint and varnish containing organic solvents or other dangerous substances SECTION 14: Transport information General Road transport notes Rail transport notes Sea transport notes Air transport notes The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID). Not classified. Not classified. Not classified. Not classified UN number Not applicable UN proper shipping name No information required Transport hazard class(es) No information required Packing group No information required Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user No information required Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Health and Safety at Work etc. Act 1974 (as amended). The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No. 716). The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"]. EH40/2005 Workplace exposure limits. 8/9
9 EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) No 453/2010 of 20 May Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Dangerous Preparations Directive 1999/45/EC. Dangerous Substances Directive 67/548/EEC Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Classification procedures according to Regulation (EC) 1272/2008 Training advice Asp. Tox. 1 - H304: : Calculation method. Read and follow manufacturer's recommendations. Revision date 20/08/2015 Revision 5 Supersedes date 14/07/2015 Risk phrases in full Hazard statements in full R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. H304 May be fatal if swallowed and enters airways. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 9/9
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