Safety data sheet Luganil Blue NGR Revision date : 2006/07/17 Page: 1/5

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1 Revision date : 2006/07/17 Page: 1/5 1. Substance/preparation and company identification Company BASF CANADA 100 Milverton Drive Mississauga, ON L5R 4H1 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Synonyms: C.I. Acid Blue Hazardous ingredients Not WHMIS controlled. 3. Hazard identification Emergency overview NO PARTICULAR HAZARDS KNOWN. Potential health effects Acute toxicity: Virtually nontoxic after a single ingestion. Irritation: Not irritating to eyes and skin. 4. First-aid measures Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. If on skin: Wash thoroughly with soap and water. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open.

2 Revision date : 2006/07/17 Page: 2/5 If swallowed: Rinse mouth and then drink plenty of water. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-fighting measures Autoignition: Flammability: Suitable extinguishing media: dry extinguishing media, foam not readily ignited No data available. Unsuitable extinguishing media for safety reasons: carbon dioxide Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Cleanup: Avoid raising dust. For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. 7. Handling and storage Handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges. Storage Keep container tightly closed and dry; store in a cool place.

3 Revision date : 2006/07/17 Page: 3/5 8. Exposure controls and personal protection Personal protective equipment Respiratory protection: Respiratory protection may not be required under normal operating conditions if adequate ventilation is provided. Hand protection: Chemical resistant protective gloves Eye protection: Safety glasses with side-shields. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Due to the colouring properties of the product closed work clothes should be used, to avoid stains during manipulation. Employees should shower at the end of the shift. Remove contaminated clothing. Wash soiled clothing immediately. 9. Physical and chemical properties Form: powder Odour: odourless Odour threshold: No data available. Colour: blue ph value: 6-8 ( 10 g/l, 20 C) Melting point: > 200 C ( 1,013 hpa) Density: g/cm3 ( 20 C) Bulk density: kg/m3 Solubility in water: approx. 40 g/l ( 20 C) Solubility (qualitative): soluble solvent(s): polar solvents, 10. Stability and reactivity Conditions to avoid: Avoid humidity. Hazardous reactions: In spite of the dedusting carried out for reasons of industrial health a dust explosion hazard can not be excluded. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological information Acute toxicity Oral: LD50/rat: > 2,000 mg/kg Skin irritation: rabbit: non-irritant (Draize test)

4 Revision date : 2006/07/17 Page: 4/5 Eye irritation : rabbit: non-irritant (OECD Guideline 405) 12. Ecological information Environmental fate and transport Biodegradation: Test method: Static test Method of analysis: colour reduction Degree of elimination: % Bioaccumulation: low sewage pollution as a result of high exhaustion rate Adsorbable organically-bound halogen (AOX): This product contains no organically-bound halogen. Environmental toxicity Acute and prolonged toxicity to fish: DIN Part 15 golden orfe/lc50 (96 h): > 100 mg/l Toxicity to microorganisms: DIN Part 27 (draft) bacterium/ec50 (0.5 h): > 10,000 mg/l Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. Other ecotoxicological advice: Do not release untreated into natural waters. 13. Disposal considerations Waste disposal of substance: Must be dumped or incinerated in accordance with local regulations. Container disposal: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport information Land transport TDG Sea transport IMDG

5 Revision date : 2006/07/17 Page: 5/5 Air transport IATA/ICAO 15. Regulatory information Federal Regulations Registration status: DSL, CA released / listed Not WHMIS controlled. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. 16. Other information Local contact information BASF Canada Product Safety END OF DATA SHEET

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