1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING. Propanedioic Acid, 1,3-Diethyl Ester; Ethyl Malonate
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1 SAFETY DATA SHEET Preparation Date 13-Aug-2013 Revision Number 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Identifier Product Name DIETHYL MALONATE Other means of identification Product Code CAS Number Formula C7H12O4 Synonyms Propanedioic Acid, 1,3-Diethyl Ester; Ethyl Malonate Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Pharmaceutical Intermediate Repeated contact with food. Avoid prolonged contact with eyes, skin, and clothing. Details of the supplier of the safety data sheet Supplier Address ACETO CORPORATION 4 Tri Harbor Court Port Washington, NY Phone: (516) Fax: (516) aceto@aceto.com Emergency Telephone Number(s) ChemTrec: Outside of the United States: Classification 2. HAZARDS IDENTIFICATION Acute Toxicity - Oral Category 4 Acute Toxicity - Dermal Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Flammable liquids Category 4 Label elements Emergency Overview Page 1 / 10
2 Signal Word Warning Hazard statements Harmful if swallowed Harmful in contact with skin Harmful if inhaled Combustible liquid Appearance Colorless Physical State Liquid Odor Fruity Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keepawayfrom heat/sparks/openflames/hotsurfaces. Nosmoking Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water Call a POISON CENTER or doctor/physician if you feel unwell Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None known Other Information Harmfultoaquaticlife 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Propanedioic Acid, 1,3-Diethyl Ester; Ethyl Malonate Page 2 / 10
3 Formula C7H12O4 Chemical Name CAS-No Weight % 100 North American Hazard Indicator True First Aid Measures General Advice 4. FIRST AID MEASURES Show this safety data sheet to the doctor in attendance. Eye Contact Skin Contact Inhalation Ingestion Protection of First-aiders Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician. Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. Consult a physician. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Consult a physician. Do not induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Consult a physician. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Remove all sources of ignition. Most important symptoms and effects, both acute and delayed Main Symptoms Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable Properties Suitable Extinguishing Media Unsuitable Extinguishing Media Hazardous Combustion Products Combustible liquid. Water spray. Carbon dioxide (CO2). Dry powder. Foam. Water mist may be used to cool closed containers. Thermal decomposition or combustion may produce hazardous gases and/or materials. Explosion Data Sensitivity to mechanical impact Not available. Sensitivity to static discharge Not available. Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Risk of ignition. Page 3 / 10
4 Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Remove all sources of ignition. Local authorities should be advised if significant spillages cannot be contained. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Should not be released into the environment. Methods and material for containment and cleaning up Methods for Cleaning up Evacuate personnel to safe areas. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Ground and bond containers when transferring material. Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. Remove all sources of ignition. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for Safe Handling Handling Use only in an area equipped with a safety shower. Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Avoid repeated exposure. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Keep away from open flames, hot surfaces and sources of ignition. Conditions for safe storage, including any incompatibilities Storage Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labelled containers. Acids. Bases. Oxidizing agents. Reducing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Page 4 / 10
5 Individual protection measures, such as personal protective equipment Eye/face Protection Skin and body protection Respiratory Protection General Hygiene Considerations Tightly fitting safety goggles. Wear protective gloves and protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odor Threshold Colorless Liquid Fruity Property Values ph No data available Melting/freezing point -51 to -50 C Boiling Point/Range 199 C Flash Point 90 C Evaporation Rate Not available Flammability Limits in Air upper flammability limit lower flammability limit Not available Vapor Pressure C Vapor Density 5.52 g/l Specific Gravity C Water Solubility C Solubility in other solvents Partition coefficient: n-octanol/waternot available Autoignition temp ( C) 424 C Decomposition temperature No data available Viscosity, kinematic Viscosity, dynamic Not available Explosive Properties Oxidizing Properties Remarks Method Literary Reference Closed cup Estimated Other Information Softening Point Molecular Weight VOC Content Density Bulk Density 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Not applicable. Stable under normal conditions Heat, flames and sparks. Acids. Bases. Oxidizing agents. Reducing agents. Carbon Monoxide Carbon Dioxide (CO2) Page 5 / 10
6 Possibility of Hazardous Reactions None under normal processing 11. TOXICOLOGICAL INFORMATION Product Information Chemical Name LD50 Oral = µl/kg ( Rat ) LD50 Dermal LC50 Inhalation > 16 ml/kg ( Rabbit ) - The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) ATEmix (dermal) 500 mg/kg 1100 mg/kg Information on likely routes of exposure Eyes Skin Inhalation Ingestion Contact with eyes may cause irritation. Avoid contact with eyes. May be harmful in contact with skin. Substance may cause slight skin irritation. May cause dermatitis. Avoid contact with skin. May be harmful by inhalation. May cause irritation of the mucous membranes. May cause irritation of respiratory tract. May cause narcotic effects in high concentration. May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. May cause central nervous system effects. Information on toxicological effects Symptoms Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Eye damage/irritation Skin Corrosion/Irritation Sensitization Reproductive Effects Mutagenic Effects Developmental Effects STOT - single exposure STOT - Repeated Exposure Skin,rabbit: 500 mg/24h MLD Page 6 / 10
7 Chronic Toxicity Avoid repeated exposure. Prolonged skin contact may defat the skin and produce dermatitis. Aspiration Hazard Numerical measures of toxicity - Product Information ATEmix (inhalation-dust/mist) 1.5 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Chemical Name Freshwater Algae Data Freshwater Fish Species Data = mg/l EC50 Microtox Data = 3097 mg/l EC50 Pseudomonas putida 16 h Water Flea Data = mg/l EC50 Persistence / Degradability Bioaccumulation / Accumulation Mobility in Soil Chemical Name log Pow = DISPOSAL CONSIDERATIONS Waste treatment methods Waste Disposal Method Contaminated Packaging Contact waste disposal services. Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION DOT Emergency Response Guide Number TDG MEX 128 Page 7 / 10
8 ICAO IATA IMDG/IMO RID ADR ADN International Inventories U.S.A. (TSCA) Canada (DSL) EU (EINECS) EU (ELINCS) Japan (ENCS) China Korea (KECL) Philippines (PICCS) Australia (AICS) 15. REGULATORY INFORMATION Does not Comply Chemical Name U.S.A. (TSCA) Canada (DSL) EU (EINECS) EU (ELINCS) Present Present Present - Chemical Name Japan (ENCS) China Korea (KECL) Philippines (PICCS) Australia (AICS) Present (2)-913 Present Present Present Present Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes No Yes No No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) Page 8 / 10
9 CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. State Right-to-Know This product does not contain any State Right-to-Know chemicals. Chemical Name New Jersey Massachusetts sn 4007 Illinois Rhode Island Pennsylvania U.S. EPA Label Information EPA Pesticide Registration Number Not applicable Canada WHMIS Statement This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION NFPA Health 1 Flammability 2 Instability 0 Physical Hazard 0 Preparation Date Revision Date Revision Summary Not available 13-Aug Nov-2013 Page 9 / 10
10 Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 10 / 10
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