1. Identification of the substance / preparation and of the company / undertaking

Transcription

1 Jarocol MP 1. Identification of the substance / preparation and of the company / undertaking Identification of the product : powder Ref. n : Supplier : KO B.V. rnhemseweg 87, 3832GK Leusden, The Netherlands P.O. Box 205, 3830E, Leusden, The Netherlands Phone: (+31) (0) Fax: (+31) (0) h.vogelezang@aako.nl Use : Hair dye. ( Cosmetics ) Emergency phone number : See supplier. ( Telephone number is accessible only during business hours. ) or Call local Poison Control Centre for assistance BE : NL : This service is only available to health professionals. DE : Hazards identification This product is considered to be hazardous. Classification : Classification of the substance according to Directive 67/548/EEC. Indication of danger: Harmful, Dangerous for the environment. R - phrases: Xn; R20/22 N; R51/53 Classification of the substance according to Regulation (EC) No. 1272/2008. Hazard categories: cute Tox. Oral 4; H302 cute Tox. Inh. 4; H332 quatic Chronic 2; H Composition / Information on ingredients Substance name Value(s) CS nr / EC nr / EC annex CERTIFICTE 3-aminophenol : > 99 % / / / Xn; R20/22 N; R cute Tox. 4 (inhal) cute Tox. 4 (oral) quatic Chronic 2 See heading 16, where the full text of each relevant R phrase shall be listed. 4. First id measures First aid - Inhalation : Remove victim to fresh air. - Skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. - Eye contact : Continue to rinse eye with clean water for 15 minutes, retracting eyelids often. - Ingestion : DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to an unconscious person. Seek medical attention immediately. Note to physician : Treat symptomatically. Revision nr : 2 Date : 3/8/2010 Supersedes : 25/7/2006 Page : 1

2 Jarocol MP 5. Fire-Fighting measures Extinguishing media - Suitable : dry chemical, foam, water spray, carbon dioxide - Not to be used : Do not use a heavy water stream. Special exposure hazards : Thermal decomposition generates: carbon oxides, nitrogen oxides Special procedures : Use normal individual fire protective equipment. Use self-contained breathing apparatus when in close proximity to fire. Use water spray to cool exposed surfaces. 6. ccidental release measures Technical measures Personal precautions Environmental precautions fter spillage and/or leakage : Dust may form explosive mixture in air. : Do not breathe dust. void contact with skin and eyes. Good ventilation of the workplace required. Wear recommended personal protective equipment. See Heading 8. : Prevent entry to sewers and public waters. : Clean up any spills as soon as possible, using an absorbent material to collect it. Collect spills and put it into appropriated container. Dilute residues and flush. 7. Handling and storage Precautions to be taken in handling and : Handle in accordance with good industrial hygiene and safety procedures. storage Handling : void dust production. void contact with skin and eyes. Good ventilation of the workplace required. Storage : Keep container closed when not in use. Keep in original containers. Store in dry, cool, well-ventilated area. 8. Exposure controls and personal protection Personal protection - Respiratory protection : pproved dust respirator - Hand protection : Wear suitable gloves resistant to chemical penetration. ( Use neoprene or rubber gloves. ) - Skin protection : Wear suitable protective clothing and chemical resistant boots - Eye protection : Chemical goggles or safety glasses. Industrial hygiene : Good ventilation of the workplace required. Local exhaust is recommended where dust may occur. Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Occupational Exposure Limits : Not established. 9. Physical and chemical properties Physical state : powder Colour : Off-white. Odour : Odourless. Melting point [ C] : Revision nr : 2 Date : 3/8/2010 Supersedes : 25/7/2006 Page : 2

3 Jarocol MP 10. Stability and reactivity Stability Hazardous decomposition products Hazardous reactions Materials to avoid Conditions to avoid : Stable under recommended storage and handling conditions. : Thermal decomposition generates: carbon oxides, nitrogen oxides : None under normal conditions. : Strong acids., Strong oxidizing agents : void dust production. Overheating. 11. Toxicological information cute toxicity - Oral : LD50 ( rat ) : 924 mg/kg Dermal irritation (rabbit) Eyes irritation (rabbit) Other toxicological information : Harmful by inhalation and if swallowed. 12. Ecological information Ecotoxicity 13. Disposal considerations Disposal EWC-Nr. (European waste catalogus): : Dispose in a safe manner in accordance with local/national regulations. Empty containers should be thoroughly rinsed with large quantities of clean water. WHEN TOTLLY EMPTY, containers are recyclable like any other packaging. : The mentioned EWC codes are recommendations on the basis of the suspected use of this product. Under certain circumstances also other EWC codes can be granted on the basis of the specific use and the facilities for waste treatment at the user other organic solvents, washing liquids and mother liquors 14. Transport information Hazard Label(s) LÉ : 6.1 Proper shipping name UN Number : 2512 H.I. nr : : 60 : UN2512 MINOPHENOLS (O-, M-, P-), 6.1, III, (E) Land transport DR/VLG : Class : 6.1 Packing group : III Limited Quantities : LQ 9 Remarks: Combination packaging: Maximum net quantity per inner packaging: 6 kg; per package: 30 kg. Sea transport IMO - Proper shipping name : UN2512 MINOPHENOLS (O-, M-, P-), 6.1, III, (E) IMO-IMDG code : Class : 6.1 Packing group : III EmS-Nr : F-, S- IMDG-Marine pollution : Yes. Revision nr : 2 Date : 3/8/2010 Supersedes : 25/7/2006 Page : 3

4 Jarocol MP 15. Regulatory information European Communities EC Labelling Symbol(s) R Phrase(s) S Phrase(s) êx ên : Harmful, Dangerous for the environment. : R 20/22 : Harmful by inhalation and if swallowed. R 51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : S 28 : fter contact with skin, wash immediately with plenty of S 61 : void release to the environment. Refer to special instructions/safety data sheets. Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Hazard Class and Category Code Health hazards : cute toxicity, Oral - Category 4 cute toxicity, Inhalation - Category 4 Environmental hazards : Hazardous to the aquatic environment - Chronic hazard - Category 2 Labelling Hazard pictograms Signal words Hazard statements MÄ MÅ : Warning : Harmful if swallowed. Harmful if inhaled. Toxic to aquatic life with long lasting effects. Precautionary statements - Prevention : void breathing dust, fume, gas, mist, vapours, spray. void release to the environment. - Response : IF SWLLOWED : Call a POISON CENTER or doctor if you feel unwell. IF INHLED : Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Collect spillage. 16. Other information Full text R phrases under heading 3 : : R 20/22 : Harmful by inhalation and if swallowed. R 51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Literature : International Maritime Dangerous Goods; 2006 edition; IMO European greement concerning the International Carriage of Dangerous Goods by Road (DR) Further information : Changes from previous version - See : Prepared by : HPV h.vogelezang@aako.nl The content and format of the MSDS are in accordance with Regulation (EC) No 1907/2006 and subsequent amendments. Revision nr : 2 Date : 3/8/2010 Supersedes : 25/7/2006 Page : 4

5 Jarocol MP DISCLIMER OF LIBILITY The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. End of document Revision nr : 2 Date : 3/8/2010 Supersedes : 25/7/2006 Page : 5