APRILFRESH ALCOHOL-FREE MOUTHWASH CTR000410; CTR000412; CTR000413; MSD_SDS0253 CTR000410; CTR000412; CTR Emergency Phone Fax

Transcription

1 Safety Data Sheet APRILFRESH ALCOHOLFREE MOUTHWASH Section 1. Identification Product Identifier Synonyms Manufacturer Stock Numbers Recommended use Uses advised against Manufacturer Contact Address APRILFRESH ALCOHOLFREE MOUTHWASH CTR000410; CTR000412; CTR000413; MSD_SDS0253 CTR000410; CTR000412; CTR Mouthwash. Dental care. Use only as directed. Medline Industries, Inc. One Medline Place Mundelein, IL, USA Section 2. Hazards Identification Phone Emergency Phone Fax (800) (800) CHEMTREC (847) Website Classification Signal Word Pictogram Hazard Statements Precautionary Statements Response Prevention Storage Disposal Ingredients of unknown toxicity No OSHA Hazard Classifications Applicable Category No OSHA Hazard Classifications Applicable 0% Page 1 of 9

2 Hazards not Otherwise Classified Unknown acute toxicity: Other information: Interactions with Other Chemicals: % of the mixture consists of ingredient(s) of unknown toxicity. May cause slight eye irritation. No information. Section 3. Ingredients CAS Ingredient Name Weight % DGlucitol 0% 10% ,2Propanediol 0% 10% Oxirane, methyl, polymer with oxirane 0% 10% Benzoic acid 0% 10% Benzoic acid, sodium salt 0% 10% ,2Benzisothiazol3(2H)one, 1,1dioxide, sodium salt 0% 10% Benzenemethanaminium, NethylN[4[[4[ethyl[(3sulfophenyl)methyl]amino]phenyl 0% 10% Proprietry Flavor 0% 10% Water 50% 100% Occupational exposure limits, if, are listed in Section 8. Section 4. FirstAid Measures General Advice: Eye Contact: Skin Contact: Inhalation: Ingestion: Most important symptoms and effects: Indication of any immediate medical attention and special treatment needed: Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid. Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. In the case of skin irritation or allergic reactions see a physician. Remove victim to fresh air. Seek medical attention if discomfort continues. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. No information. Notes to physician: Treat symptomatically. Page 2 of 9

3 Section 5. Fire Fighting Measures Suitable Extinguishing Media Unsuitable Extinguishing Media Specific hazards arising from the chemical: Hazardous combustion products: Explosion data: Protective Equipment and Precautions for Firefighters: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. CAUTION: Use of water spray when fighting fire may be inefficient. No information. Carbon oxides. Sensitivity to Mechanical Impact: No Sensitivity to static discharge: No As in any fire, wear selfcontained breathing apparatus pressuredemand, MSHA/NIOSH (approved or equivalent) and full protective gear. Section 6. Accidental Release Measures Personal precautions, Avoid contact with eyes. protective equipment and emergency procedures: Environmental Precautions: Refer to protective measures listed in Sections 7 and 8. Methods and Materials for Containment and Cleaning up: Section 7. Handling and Storage Methods for Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning up: Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Handling: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Storage: Keep container tightly closed. Incompatible Products: None known based on information supplied. Page 3 of 9

4 Section 8. Exposure Controls/Personal Protection Occupational Exposure Limits Ingredient Name ACGIH TLV OSHA PEL STEL DGlucitol 1,2Propanediol Oxirane, methyl, polymer with oxirane Benzoic acid Benzoic acid, sodium salt 1,2Benzisothiazol3(2H)one, 1,1dioxide, sodium salt Benzenemethanaminium, NethylN[4[[4[ethyl[(3 sulfophenyl)methyl]amino]phenyl Flavor Water Personal Protective Equipment Exposure guidelines: There is no exposure data pertaining to the Product. This section reflects exposure data pertaining to individual ingredients. Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFLCIO v. OSHA, 965 F.2d 962 (11th Cir,. 1992) Engineering Controls: Showers. Eyewash stations. Ventilation systems. Eye Protection: No special protective equipment required. Skin and Body Protection: No special protective equipment required. Respiratory Protection: No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Page 4 of 9

5 Section 9. Physical and Chemical Properties Physical State Liquid Color Clear, light blue waterthin liquid Odor Sweet, Mint Odor Threshold No information Solubility Miscible in water Partition coefficient Water/noctanol VOC% Viscosity Specific Gravity Density lbs/gal Pounds per Cubic Foot Flash Point FP Method Ph 4.0 Melting Point Boiling Point Boiling Range LEL UEL Evaporation Rate Flammability Decomposition Temperature Autoignition Temperature Vapor Pressure Vapor Density Page 5 of 9

6 Section 10. Stability and Reactivity Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Hazardous Polymerization Conditions to avoid: Incompatibility (Materials to Avoid): Hazardous Decomposition or Byproducts:. Stable under recommended storage conditions. None under normal processing. Does not occur. None known None known. Carbon oxides. Section 11. Toxicological Information There is no data for this product. The information included in this section describes the potential hazards of the individual ingredients. Likely Routes of Exposure: Product Information: Eye Specific test data for the substance or mixture is not. Likely Routes of Exposure: Product Information: Skin Contact Specific test data for the substance or mixture is not. Likely Routes of Exposure: Product Information: Inhalation Specific test data for the substance or mixture is not. Likely Routes of Exposure: Product Information: Ingestion Specific test data for the substance or mixture is not. Component Information: Water CASNo > 90 ml/kg (Rat) Propylene Glycol CASNo = mg/kg (Rat) = mg/kg (Rabbit) Poloxamer 407 CASNo = 5700 mg/kg (Rat) = 320 mg/m3 (Rat) 4 h Benzoic Acid CASNo = 1700 mg/kg (Rat) > 26 mg/m3 (Rat) 1 h Page 6 of 9

7 Information on Toxicological Effects: Delayedimmediate effects, also chronic effects from short & long term exposure: Sodium Benzoate CASNo = 2100 mg/kg (Rat) Symptoms: No information. Sensitization: No information. Mutagenic Effects: No information. Carcinogenicity: The information below indicates whether each agency has listed any ingredient as a carcinogen. Sodium Saccharin CASNo IARC: Group 3 Blue 1 CASNo IARC: Group 3 Reproductive Toxicity: Specific Target Organ Toxicity Single exposure: Specific Target Organ Toxicity Repeated exposure: Chronic Toxicity: Target Organ Effects: Aspiration hazard: Numerical measures of toxicity: IARC (International Agency for Research of Cancer) Group 3 Not Classifiable as to Carcinogenicity in Humans. No information. No information. No information. No known effect based on information supplied. None known. No information. Product Information: The following values are calculated based on chapter 3.1 of the GHS document. Not applicable. Section 12. Ecological Information Ecotoxicity: Persistence and degradability: Bioaccumulation: Other adverse effects: There is no ecological data on the Product. The Product ingredients are expected to be safe for the environment at concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with the conventional solid waste management practices. No information. No information. No information. No information. Page 7 of 9

8 Section 13. Disposal Waste Disposal Methods: Contaminated packaging: California Hazardous Waste Codes: Section 14. Transport Information This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste. If chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. 134 UN Number UN Proper Shipping Name DOT Classification Packing Group Not Regulated Not Regulated Not Regulated Section 15. Regulatory Information SARA 311/312: SARA 302: SARA 313: TSCA: CERCLA Hazardous Substance List: Clean Air Act (CAA) Section 112, 112 (r): New Jersey Right to Know Components: Massachusetts Right to Know Components: Pennsylvania Right to Know Components: Rhode Island Right to Know Components: Benzoic acid. Benzoic acid. PROPYLENE GLYCOL. BENZOIC ACID. BENZOIC ACID. 1,2Propanediol. BENZOIC ACID. propylene glycol. Page 8 of 9

9 Section 16. Other Information Revision Date 1/15/2016 * * The exact percentage (concentration) of composition has been withheld as a trade secret. Legend Not Applicable N.E. Not Established N.D. Not Determined HMIS (U.S.A.): Health 1 Hazard HMIS (U.S.A.): Flammability O HMIS (U.S.A.): Physical O Hazard HMIS (U.S.A.): Personal X Protection National Fire Protection 1 Association (U.S.A): Health Hazard National Fire Protection O Association (U.S.A): Flammability National Fire Protection O Association (U.S.A): Instability Hazard National Fire Protection None. Association (U.S.A): Physical and Chemical Hazards Additional Information The information contained herein is furnished without warranty or legal responsibility of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees Page 9 of 9