MATERIAL SAFETY DATA SHEET

Transcription

1 Page 1 of 8 1 CHEMICAL PRODUCT AND COMPANY INFORMATION Product Description TOLUENE-D8 (D, 99.5%) Cambridge Isotope Laboratories, Inc. 50 Frontage Rd ANDOVER, MA USA Web Site Phone Numbers Emergency Contact Emergency Phone Customer Service Phone Transportation cilsales@isotope.com Chemtrec (24 hours) (8:30-5:30 EST) (24 hours) 2 HAZARDS IDENTIFICATION OSHA Hazards Flammable liquid, Irritant, Teratogen, Reproductive hazard. Target Organs Bladder, Liver, Kidney, Brain. GHS Classification Flammable liquids (Category 2) Aspiration Hazard (Category 1) Skin irritation (Category 2) Eye irritation (Category 2) Acute toxicity, Inhalation (Category 4) Reproductive toxicity (Category 2) Specific Target Organ Toxicity - Single exposure (Category 2) Hazardous to the aquatic environment, acute (Category 2) GHS Label Information Signal Word Danger

2 Page 2 of 8 Hazards Identification Flame Health hazard Exclamation mark Hazard Statement(s) Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. Suspected of damaging fertility or the unborn child. May cause damage to organs. Toxic to aquatic life. Precautionary Statement(s) Keep away from heat/sparks/open flames/hot surfaces- No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse with water for several minutes. Remove contact lenses. Do NOT induce vomiting. HMIS Ratings Chronic Health * Physical 0 Flammability 3 Health 2 Reactivity 0 NFPA Codes Fire 3 Health 2 Reactivity 0 Potential Health Effects Eyes Ingestion Inhalation Skin Causes eye irritation. Aspiration hazard if swallowed - can enter lungs and cause damage. Harmful if inhaled. Causes respiratory tract irritation. Vapors may cause drowsiness and dizziness. May be harmful if absorbed through the skin. Causes skin irritation. 3 COMPOSITION / INFORMATION ON INGREDIENTS Composition / Information on Ingredients Chemical Formula C6D5CD3

3 Page 3 of 8 Molecular Weight CAS No EC No Index No FIRST AID MEASURES First Aid Measures Eyes Ingestion Inhalation Skin Additional Information Flush eye with water for 15 minutes. Get medical attention. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Wash off with soap and plenty of water. Consult a physician. Move out of dangerous area. Consult a physician and show this safety data sheet. 5 FIRE FIGHTING MEASURE Fire Fighting Measures Extinguishing Media Fire Fighting Equipment Fire Fighting Procedures For large fires, apply water from as far as possible applied in large quantities as a mist or spray. For small fires, use "alcohol" foam, dry chemical or carbon dioxide. Wear self contained breathing apparatus for fire fighting if necessary. Use water spray to cool unopened containers. 6 ACCIDENTAL RELEASE MEASURES Accidental Release Measures Personal Precautions Environmental Precautions Use personal protective equipment, and ensure adequate ventilation. Avoid breathing vapors, mist, gas. Remove ignition sources, and move personnel to safe area. Vapors accumulate especially in low areas to form explosive concentrations. Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

4 Page 4 of 8 Methods and materials for containment and cleanup Contain spillage, then collect with non-combustible absorbent material. Disposal should be in accordance with applicable Federal, State and local regulations. 7 HANDLING AND STORAGE Precautions for Safe Handling Handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking. Take measures to prevent build up of electrostatic charge. Conditions for Safe Storage Storage Keep container tightly closed in a cool, dry and well-ventilated place. Opened containers must be carefully resealed and kept upright to prevent leakage. 8 EXPOSURE CONTROL / PERSONAL PROTECTION OSHA HAZARDOUS COMPONENTS (29 CFR ) CHEMICAL NAME OSHA PEL ACGIH TLV TOLUENE TWA 100 ppm 20 ppm STEL 150 ppm Personal Protecton Eyes - Face Skin Respiratory Protective Clothing Work Hygienic Practices Wear safety glasses with side shields (or goggles) and a face shield. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Wear appropriate NIOSH/MSHA approved respirator. Wear suitable gloves. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 9 PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties (Unlabeled Compound) Form Color Liquid Colouress

5 Page 5 of 8 ph No data available Melting Point -93 C (-135 F) Boiling Point C ( F) Flashpoint 4.0 C (39.2 F) Lower Explosion 1.2% (V) Limit Upper Explosion 7% (V) Limit Vapor Pressure 29.1 hpa (21.8 mmhg) at 20.0 C (68.0 F) Density g/ml at 25 C (77 F) Solubility in Water No data available Auto Ignition 535 C (995 F) Temperature 10 STABILITY AND REACTIVITY Stability and Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Hazardous decomposition products Materials to avoid Stable if stored under recommended conditions. Vapors may form explosive mixture with air. Keep away from heat, sparks and flame. Hazardous decomposition products formed under fire conditions. - Carbon oxides. Strong oxidizing agents. 11 TOXICOLOGICAL INFORMATION Acute Toxicity LC50 Inhilation Rat 4 h - 12,500-28,800 mg/m3 LD50 Dermal 12,196 mg/kg Rabbit LD50 Oral Rat > 5,580 mg/kg Serious Eyes - rabbit - Severe eye irritation - 24 h Damage/Eye Irritation Skin Corrosion/Irritation Skin - rabbit - Skin irritation - 24 h

6 Page 6 of 8 Inhalation Respiratory or Skin Sensitization Germ Cell Mutagenicity IARC NTP OSHA Reproductive Toxicity May be fatal if swollowed and enters airways. Not available Not available 3 - Group 3: not classifiable as to its carcinogenicity to humans. No component of this product present at levels greater than or equal to 0.1% is identifiable as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Damage to fetus possible. Suspected human reproductive toxicant. Specific Target Organ Toxicity Single Exposure May cause damage to organs. Repeated Exposure No data available Other Information RTECS XS ECOLOGICAL INFORMATION Toxicity Toxicity to Fish LC50 Toxicity to Daphnia and Other Aquatic Invertebrates EC50 Toxicity to Algae and Other Aquatic Plants ErC50 Longterm Aquatic Hazard NOEC Lepomis macrochirus (Bluegill) mg/l - 96 h Daphnia magna (Water flea) 8.00 mg/l - 24 h Chlorella vulgaris (Fresh water algae) mg/l - 24 h Pimephales promelas (fathead minnow) mg/l - 7 d Bioaccumulative Leuciscus idus (Golden orfe) - 3 d. Bioconcentration factor (BCF) : 94 Potential Mobility in Soil PBT and vpvb Assessment Not available. Not available.

7 Page 7 of 8 Other Adverse Effects Not available. 13 DISPOSAL CONSIDERATIONS Disposal Considerations Product Disposal Contaminated Packaging Waste materials should be disposed of under conditions which meet Federal, State, and Local environmental control regulations. Dispose of as unused product. 14 TRANSPORT INFORMATION Transportation Information-DOT/IATA/IMDG UN Number 1294 Prop. Ship. Name Toluene Hazard Class 3 Packing Group II Reportable Quantity 1000 lbs (RQ) DOT US Marine Pollutant No Poison Inhalation No Hazard 15 REGULATORY INFORMATION Regulatory Information Flammable liquid, Irritant, Teratogen, Reproductive hazard. SARA Sara 302 Component Sara 313 Component SARA 311/312 Hazards Fire (Y/N) Acute (Y/N) No chemicals in this material are subject to the reporting requirements. Yes. Y Y

8 Page 8 of 8 Chronic (Y/N) Y STATE REGULATIONS Massachusetts Right to Know Pennsylvania Right to Know New Jersey Right to Know California Proposition 65 Yes Yes Yes WARNING! This product contains a chemical known by the state of California to cause birth defects or other reproductive harm. Canada DSL Status EU Hazard All components of this product are on the Canadian DSL list. Flammable. Severe irritant. Safety Statements Wear suitable protective clothing and gloves. If swallowed, seek medical advice immediately and show this container or label. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. 16 OTHER INFORMATION Additional MSDS Information This product is not radioactive. The data given for this product are those of the corresponding unlabeled compound, unless specifically indicated otherwise. Health and safety data for labeled compounds are generally not available, but are assumed to be similar or identical to the corresponding unlabeled compound. Approved On 12/31/12 Version Number 2