Material Safety Data Sheet acc. to ISO/DIS 11014

Transcription

1 Page 1/6 1 Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Adhesives Details of the supplier of the safety data sheet Manufacturer/Supplier: UHU GmbH & Co.KG Herrmannstraße 7 D Bühl (Baden) Tel.:0049-(0) Fax: 0049-(0) info@uhu.boltongroup.de Information department: CRD Emergency telephone number: 0049-(0) / Composition/information on ingredients Chemical characterization: Mixtures Description: Adhesive Dangerous components: alkoxy-cyanoacrylate % 3 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Void Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. Safety phrases: Keep out of the reach of children. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Special labelling of certain preparations: Cyanacrylate. DANGER. Glues skin and eyelids within seconds. Should be kept out of children's reach. Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 1 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. (Contd. on page 2)

2 Page 2/6 vpvb: Not applicable. (Contd. of page 1) 4 First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air. After skin contact: Rinse with warm water. Do not pull solidified product away from the skin. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Seek immediate medical advice. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fire with alcohol resistant foam. Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: No special measures required. Methods and material for containment and cleaning up: Send for recovery or disposal in suitable receptacles. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. (Contd. on page 3)

3 Page 3/6 (Contd. of page 2) Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Avoid contact with the eyes and skin. Avoid direct contact with the chemical/ the product/ the preparation by organizational measures. Breathing equipment: Not required. Protection of hands: Not required. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Pasty Color: Colorless Odor: Characteristic Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 85 C (5mbar) Flash point: 125 C Ignition temperature: 400 C Danger of explosion: Product does not present an explosion hazard. Density at 20 C: 1.03 g/cm³ Solubility in / Miscibility with Water: Viscosity: Dynamic at 20 C: Not miscible or difficult to mix. 50 mpas Solvent content: Organic solvents: 0.0 % Solids content: 11.1 % 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions Exothermic polymerization. Reacts with water. Reacts with amines. (Contd. on page 4)

4 Page 4/6 Hazardous decomposition products: No dangerous decomposition products known. (Contd. of page 3) 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: 12 Ecological information Toxicity Acquatic toxicity: No further relevant information available. Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system. Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 13 Disposal considerations Waste treatment methods Recommendation: Disposal must be made according to official regulations. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information TDG (Transport dangerous goods): TDG class: - UN-Number: - Maritime transport IMDG: IMDG Class: - UN Number: - Marine pollutant: No Air transport IO-TI and IATA-DGR: IO/IATA Class: - UN/ID Number: - Special precautions for user Not applicable. Transport/Additional information: Not dangerous according to the above specifications. (Contd. on page 5)

5 Page 5/6 (Contd. of page 4) 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): TS (Toxic Substances Control Act): Siliciumdioxid polymethylmethacrylate Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Cancerogenity categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) polymethylmethacrylate 3 NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Canadian substance listings: Canadian Domestic Substances List (DSL) Siliciumdioxid polymethylmethacrylate Canadian Ingredient Disclosure list (limit 0.1%) Canadian Ingredient Disclosure list (limit 1%) Product related hazard informations: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. (Contd. on page 6)

6 Page 6/6 (Contd. of page 5) Safety phrases: Keep out of the reach of children. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Special labeling of certain preparations: Cyanacrylate. DANGER. Glues skin and eyelids within seconds. Should be kept out of children's reach. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing MSDS: CRD Contact: Frau A. Liar, Herr Dr. C. Hanf