Mercuric Sulfate, ACS

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1 Safety Data Sheet Mercuric Sulfate, ACS 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Mercuric Sulfate, ACS Synonyms/Generic Names: Mercuric (II) Sulfate, Mercury Sulfate Product Number: 3430 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI For More Information Call: (Monday-Friday 8:00-4:30) In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week) 2. HAZARDS IDENTIFICATION OSHA Hazards: Target organ effect, Highly toxic by inhalation, Highly toxic by ingestion, Highly toxic by skin absorption Target Organs: Blood, Kidneys, Liver, Nerves, Bone, Spleen Signal Word: Danger Pictograms: GHS Classification: Acute toxicity, Oral Category 2 Acute toxicity, Inhalation Category 2 Acute toxicity, Dermal Category 1 Specific target organ toxicity - repeated exposure Category 2 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1 GHS Label Elements, including precautionary statements: Hazard Statements: H300+H310+H330 H373 H410 Fatal if swallowed, in contact with skin or if inhaled. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Revised on 04/27/2016 Page 1 of 6

2 Precautionary Statements: P260 Do not breathe dust/fume/gas/mist/vapors/spray. P262 do not get in eyes, on skin, or on clothing. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 In case of inadequate ventilation, wear respiratory protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P321 Specific treatment is urgent (see first aid instruction on this label). P330 Rinse mouth. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. Potential Health Effects Causes eye irritation. Inhalation May be fatal if inhaled. Causes respiratory tract irritation. May be fatal if absorbed through skin. Causes skin irritation. Ingestion May be fatal if swallowed. NFPA Ratings Health 3 Flammability 0 Reactivity 0 Specific hazard HMIS Ratings Health 3 Fire 0 Reactivity 0 Personal 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % CAS # EINECS# / ELINCS# Formula Molecular Weight Mercuric Sulfate > HgSO g/mol 4. FIRST-AID MEASURES Inhalation Ingestion Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention immediately. Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention immediately. Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable (and unsuitable) extinguishing media Special protective equipment and precautions for firefighters Product is not flammable. Use appropriate media for adjacent fire. Cool containers with water. Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Revised on 04/27/2016 Page 2 of 6

3 Specific hazards arising from the chemical Emits toxic fumes (sulfur oxides, mercury/mercury oxides) under fire conditions. (See also Stability and Reactivity section). 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up See section 8 for recommendations on the use of personal protective equipment. Prevent spillage from entering drains. Any release to the environment may be subject to federal/national or local reporting requirements. Pick up and arrange disposal without creating dust. Sweep up and place in suitable, closed containers for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. 7. HANDLING AND STORAGE Precautions for safe handling See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts. Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area. Store under inert gas. Light sensitive. Moisture sensitive. Air sensitive. Keep away from incompatible materials (see section 10 for incompatibilities). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Component Exposure Limits Basis Entity Mercuric Sulfate mg/m 3 TLV ACGIH 0.1 mg/m 3 CEIL OSHA 0.1 mg/m 3 CEIL NIOSH TWA: Time Weighted Average over 8 hours of work. TLV: Threshold Limit Value over 8 hours of work. REL: Recommended Exposure Limit PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit during x minutes. IDLH: Immediately Dangerous to Life or Health WEEL: Workplace Environmental Exposure Levels CEIL: Ceiling Personal Protection Wear chemical safety glasses or goggles. Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Wear nitrile or rubber gloves, and full body covering. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Other Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. Revised on 04/27/2016 Page 3 of 6

4 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.) Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limit Vapor pressure Vapor density Density Solubility (ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature White, crystalline solid. Not Flammable Not Flammable Not Explosive g/cm3 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable Will not occur. Strong oxidizing agents. Sulfur oxides, mercury/mercury oxides. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Mercuric Sulfate Respiratory Ingestion Carcinogenicity IARC ACGIH NTP OSHA LD50 Dermal - rat mg/kg LD50 Oral - rat - 57 mg/kg 3- Group 3: Not classifiable as to its carcinogenicity to humans (mercury sulfate). A5: Not suspected as a human carcinogen (mercury sulfate). No components of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No components of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Irritation, redness, itchiness. Irritation, redness, watering eyes, itchiness. Respiratory Irritation, coughing, wheezing, headache, tremors. Ingestion Irritation, nausea, vomiting, diarrhea, salivation, tremors. Revised on 04/27/2016 Page 4 of 6

5 Chronic Toxicity Teratogenicity Mutagenicity Embryotoxicity Specific Target Organ Toxicity Reproductive Toxicity Respiratory/ Sensitization The substance is toxic to blood, kidneys, lungs, the nervous system, the reproductive system, liver, mucous membranes. May cause damage to organs through prolonged or repeated exposure. 12. ECOLOGICAL INFORMATION Ecotoxicity Mercuric Sulfate Aquatic Vertebrate Aquatic Invertebrate Terrestrial LC50 - Oncorhynchus gorbuscha mg/l - 7 d Growth inhibition EC50 - Pseudokirchneriella subcapitata mg/l - 14 d Persistence and Degradability Bioaccumulative Potential Mobility in Soil PBT and vpvb Assessment Other Adverse Effects Very toxic to aquatic life with long lasting effects. 13. DISPOSAL CONSIDERATIONS Waste Residues Product Containers Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residue. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORTATION INFORMATION US DOT TDG IMDG Marine Pollutant IATA/ICAO UN1645, Mercury sulfate, 6.1, pg II UN1645, MERCURY SULFATE, 6.1, pg II UN1645, MERCURY SULFATE, 6.1, pg II Yes UN1645, Mercury sulfate, 6.1, pg II Revised on 04/27/2016 Page 5 of 6

6 15. REGULATORY INFORMATION TSCA Inventory Status DSCL (EEC) California Proposition 65 SARA 302 SARA 304 SARA 311 SARA 312 SARA 313 WHMIS Canada All ingredients are listed on the TSCA inventory. All ingredients are listed on the DSCL inventory. Listed: Mercury Sulfate Not Listed Not Listed Acute Health Hazard, Chronic Health Hazard Acute Health Hazard, Chronic Health Hazard Not Listed Class D-1A: Poisonous and infectious material- Immediate and serious effects- Very toxic Class E: Corrosive material 16. OTHER INFORMATION Revision Date Revision Revision 2 07/31/2013 Revision 3 04/27/2016 Disclaimer: Columbus Chemical Industries, Inc. ( Columbus ) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. Revised on 04/27/2016 Page 6 of 6

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