MATERIAL SAFETY DATA SHEET HMIS: H2* F3 R1

Transcription

1 HMIS: H2* F3 R1 WHMIS: B2;D1B Revised Date: 09/10/2003 Prepared date: 09/16/2003 Section 1: Chemical Product and Company Identification PREPARED FOR: PLYMART, INC. P.O. BOX 127 BORING, OR US Emergency Phone Number: Information Number: PREPARED BY: Akzo Nobel Coatings Inc Cross Street S.E. Salem, OR US (800) (503) Product No. Tradename: F N/AP Product - Class: 30 SHEEN RELVETTE Customer Part No. MII: 0201 Customer ShipTo ID: Hazardous Ingredients Section 2: Composition, Information on Ingredients Ingredient Data #ETHYL BENZENE 0.26 Cas No mm/Hg@68F 125ppm 15 Min. 125ppm 15 Min. ORAL-LD mg/Kg Rat DERM-LD mg/Kg Rabbit #XYLENE, MIXED ISOMERS 1.95 Cas No mm/Hg@68F 1 15 Min. ORAL-LD mg/Kg Rat DERM-LD50 >1700mg/Kg Rabbit INHAL-LC ppm Rat-4 Hour #TOLUENE 3.78 (METHYL BENZENE) Cas No

2 330-30F /10/2003 PAGE # 2 (TOLUOL) 22.00mm/Hg@68F * * 1* 15 Min. 1* 15 Min. ORAL-LD50 636mg/Kg Rat DERM-LD mg/Kg Rabbit INHAL-LC mg/Kg Rat-4 Hour ISOPROPANOL (ISOPROPYL ALCOHOL) Cas No mm/Hg@68F 400ppm 400ppm 500ppm 15 Min. 500ppm 15 Min. ORAL-LD mg/Kg Rat DERM-LD mg/Kg Rabbit INHAL-LC ppm Rat-8 Hour ISOBUTYLATE U/F RESIN Cas No ORAL-LD50 >5000mg/Kg Rat DERM-LD50 >5000mg/Kg Rabbit ISOBUTANOL (2-METHYL-1-PROPANOL) Cas No (ISOBUTYL ALCOHOL) 9.00mm/Hg@68F ORAL-LD mg/Kg Rat DERM-LD mg/Kg Rabbit INHAL-LC50 >8000ppm Rat-4 Hour METHYL ISOAMYL KETONE Cas No mm/Hg@68F ORAL-LD mg/Kg Rat DERM-LD mg/Kg Rabbit INHAL-LC ppm Rat-6 Hour ISOBUTYL ACETATE (ACETIC ACID, ISOBUTYL ESTER) Cas No mm/Hg@68F 1 1 ORAL-LD50 >4350mg/Kg Rat DERM-LD50 >17400mg/Kg Rabbit INHAL-LC ppm Rat-4 Hour NITROCELLULOSE Cas No

3 330-30F /10/2003 PAGE # 3 ORAL-LD50 >5000mg/Kg Rat BUTYL ACETATE (ACETIC ACID, BUTYL ESTER) Cas No (BUTYL ETHANOATE) 8.00mm/Hg@68F ppm 15 Min. 200ppm Min. ORAL-LD mg/Kg Rat DERM-LD50 >8770mg/Kg GUINEA PIG INHAL-LC50 >1800ppm Rat-6 Hour ETHYL ALCOHOL Cas No mm/Hg@68F 1000ppm 1000ppm ORAL-LD mg/Kg Rat DERM-LD mg/Kg Rabbit INHAL-LC ppm Rat-10 Hour DIMETHYL KETONE (2-PROPANONE) Cas No (ACETONE) mm/Hg@68F 500ppm Min. 1000ppm 15 Min. ORAL-LD mg/Kg Rat DERM-LD50 >15800mg/Kg Rat INHAL-LC mg/Kg Rat-8 Hour #This material is subject to reporting under SARA TITLE III, SECTION 313 * (Skin) EFFECTS OF OVEREXPOSURE : Section 3: Hazards Identification Skin : CAUSES SKIN IRRITATION. Other effects of skin contact may include : dermatitis, dehydration, discoloration, sensitization. Eye : CAUSES EYE IRRITATION. Other effects of eye contact may include : tearing, redness, swelling, burning. Inhalation : MAY CAUSE NOSE AND THROAT IRRITATION. MAY CAUSE LUNG IRRITATION. Other effects of inhalation may include : nausea, cough, dizziness, weakness, headache, drowsiness, fatigue, excitation, vomiting, diarrhea, CNS effects, incoordination, narcosis, confusion. Skin absorption : CAN BE ABSORBED THROUGH THE SKIN. Effects may include : nausea, vomiting, drowsiness, CNS effects. Ingestion : HARMFUL IF SWALLOWED. Other effects of ingestion may include : gastroenteritis, abdominal pain, irritation, gastric disturbances, nausea, vomiting, diarrhea, weakness, headache, dizziness, drowsiness, fatigue, incoordination, CNS effects, high blood sugar.

4 330-30F /10/2003 PAGE # 4 PRIMARY ROUTE(S) OF ENTRY: inhalation, skin contact, ingestion, eyes. MEDICAL CONDITIONS THAT CAN BE AGGRAVATED: pulmonary conditions, skin disorders, liver conditions, kidney conditions, respiratory conditions, neurological disorders, cardiovascular diseases, reproductive system disorders. CHRONIC HEALTH HAZARDS: Repeated OVEREXPOSURE to this product may cause: central nervous system damage, kidney damage, liver abnormalities, cardiac abnormalities, reproductive organ damage, birth defects, dermatitis, hearing damage. Caution: Contains a urea-formaldehyde resin which, under certain conditions, could release formaldehyde in quantities sufficient to require monitoring under OSHA regulations. Formaldehyde is a suspect carcinogen. Contains ethylbenzene, which has been shown to cause cancer in laboratory animals by inhalation and is listed as a suspect carcinogen by IARC (Group-2B). NOTICE: Reports have associated repeated and prolonged OVEREXPOSURE to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents of this package may be harmful or fatal. Section 4: First Aid Measures SKIN CONTACT: Flush with plenty of water. Remove contaminated clothing and wash before reuse. Remove and destroy contaminated shoes. EYE CONTACT: Flush with water for at least 15 minutes and get medical attention. INHALATION: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Get medical attention. INGESTION: Get medical attention IMMEDIATELY. Section 5: Fire Fighting Measures EXTINGUISHING MEDIA: Foam, Carbon Dioxide or Dry Chemical. UNUSUAL FIRE AND EXPLOSION HAZARDS: During emergency conditions, overexposure to decomposition products (See Section VI - Reactivity Data) may cause a health hazard; symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIREFIGHTING PROCEDURES: Water may be ineffective in fighting fire. If water is used to cool closed containers to prevent pressure build-up, fog nozzles are preferred. Full protective equipment, including self-contained breathing apparatus is needed to protect firefighters from exposure to coating's hazardous ingredients and hazardous decomposition products. Section 6: Accidental Release Measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Wear appropriate safety equipment as listed in Section VIII; assume for all hazardous ingredients listed in Section II, that the TLV, PEL and LEL limits will be exceeded. Absorb on inert material and dispose of as below. Section 7: Handling and Storage PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: All equipment should be grounded. Keep containers closed when not in use. Store in a clean, dry area. Store below 120 degrees Fahrenheit. Store away from ignition sources. Store in well-ventilated area. Avoid exposure to light. Avoid strong oxidizing agents. Avoid contact with fumes or hot surfaces. OTHER PRECAUTIONS: All precautions must be observed. Empty container may retain product residues.

5 330-30F /10/2003 PAGE # 5 Section 8: Exposure Controls, Personal Protection PROTECTIVE GLOVES: Chemical resistant protective gloves should be worn when handling this product. Check with glove manufacturer to determine proper glove type. EYE PROTECTION: Splash-proof chemical goggles should be worn. RESPIRATORY PROTECTION: Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during application and handling unless air monitoring demonstrates vapor/mist levels below applicable limits. Follow respirator manufacturer's recommendations for selection and use. VENTILATION: Sufficient ventilation must be provided to maintain airborne concentrations below TLV, PEL and LEL limits as listed in Section II. OTHER PROTECTIVE EQUIPMENT: Eye bath and safety shower should be provided. Chemical resistant apron should be worn. HYGIENIC PRACTICES: Good personal hygiene practices are required at all times when handling chemicals. These practices include, but are not limited to, washing when safety equipment is removed, at the end of each shift or when going on breaks and especially if contamination occurs. Physical state: Unit Weight: SpGr: ph: Odor and appearance: Odor threshold (ppm): Boiling Range: % Volatile (vol) Vapor is heavier than Air. Evaporation rate is slower than ether. Flammability Class (OSHA) FLAMMABLE LIQUID - 1B FP:(CLOSED) LEL Material is STABLE under non-emergency conditions. Material WILL NOT undergo hazardous polymerization. Section 9: Physical and Chemical Properties -4F ( -20C) 1.04% Section 10: Stability and Reactivity HAZARDOUS DECOMPOSITION PRODUCTS: oxides of carbon, oxides of nitrogen, hydrogen cyanide, toxic fumes, various hydrocarbons, formaldehyde, aldehydes, acids, methane, peroxides, carboxylic acids. CONDITIONS TO AVOID: temperatures above 120 degrees, open flame, sparks, light, moisture. MATERIALS TO AVOID: alkali, acids, oxidizers, amines, alkali metal, lead, ammonia, copper alloys. Section 11: Toxicological Information Also see Section 2: Composition, Information on Ingredients. Liquid 7.51 Lb/gal(U.S.) (0.89 KG/L) (9.01 Lb/gal(imp) ) F (56C) - 298F (148 C) 82.44%

6 330-30F /10/2003 PAGE # 6 No information available. Section 12: Ecological Information Section 13: Disposal Considerations WASTE DISPOSAL METHODS: Dispose of in accordance with FEDERAL, STATE and local regulations. Incineration is the preferred method of disposal. Section 14: Transport Information DOT Proper Shipping Classification - PAINT, 3, UN1263, PG II Section 15: Regulatory Information This product contains the following SARA Title III, Section 313, reportable materials: ethylbenzene, toluene, xylene (mixed isomers), This product contains one or more components which are not on the TSCA Inventory and this product is for R&D USE ONLY. Use of the material for commer VOC Data Lb/Gal(U.S.): Less Water (EPA): 5.62 Less Water & Exempt (EPA): 5.28 Total Organic Solvents: 5.62 Total Non-Exempt Solvents: 3.93 Organic Solvent Density: 6.82 Section 16: Other Information The absence of a positive finding indicates that we believe, to the best of our knowledge, that the negative is true. Disclaimer: While Akzo Nobel Coatings believes that the data contained herein are accurate and derived from qualified sources, the data are not to be taken as a warranty or representation for which Akzo Nobel Coatings assumes legal responsibility. They are offered solely for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with applicable Federal, State, Provincial and local laws and regulations. ABBREVIATIONS USED IN PREPARING THIS MSDS: # - Pounds % - Percent > - Greater Than < - Less - At ABBREVIATIONS USED IN PREPARING THIS MSDS: C - Degrees Celsius CAS NO - Chemical Abstract Number CEIL - Ceiling Limit CEPA - Canadian Environmental Protection Act CFR - Code of Federal Regulations CNS - Central Nervous System DERM-LD50 - Dermal Lethal Dose (50% Death) DOT - Department of Transportation EPA - U.S. Environmental Protection Agency F - Degrees Fahrenheit FP - Flash Point HMIS - Hazardous Material Information System IARC - International Agency for Research on Cancer

7 330-30F /10/2003 PAGE # 7 IMDG - International Maritime Dangerous Goods INHAL-LC50 - Inhalation Lethal Concentration (50% Death) Lb/gal - Pounds Per Gallon LEL - Lower Explosion Limit mg/l - Milligrams Per Liter mg/m3 - Milligrams per Meter Cubed mm/hg - Millimeters of Mercury N/AP - Non-applicable - Not Available NA - Not Available or Non-applicable NTP - National Toxicology Program ORAL-LD50 - Oral Lethal Dose (50% Death) OSHA - Occupational Safety and Health Administration PEL - Permissable Exposure Limit ppm - Parts Per Million SARA - Superfund Amendments & Reauthorization Act (1986) STEL - Short Term Exposure Limit TLV - Threshold Limit Value TSCA - Toxic Substances Control Act TWA - Time Weighted Average VOC - Volatile Organic Compound WHMIS - Workplace Hazardous Materials Information System