SDS 1. Identification of the substance/preparation and of the company/undertaking / Pengenalan Zat / Sediaan dan Syarikat / aku janji
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1 SDS 1. Identification of the substance/preparation and of the company/undertaking / Pengenalan Zat / Sediaan dan Syarikat / aku janji Identification of the product: Pengenalpastian produk: Product code: N3057 Kod Produk: N3057 Name of material: n-hexane Nama bahan: n-hexane Use of the substance/preparation: Penggunaan bahan / persediaan: Chromatography, analytical chemistry, determining refractive index of minerals. Kromatografi, kimia analisis, menentukan indeks biasan mineral. Manufacturer/supplier identification: Pengenalan Pengeluar / pembekal: Company : QREC (ASIA) SDN BHD Syarikat: Address : Lot 94A, Jalan Integrasi Rawang Alamat: Rawang, Selangor, Malaysia Telephone number : (Hunting Line) Nombor Telefon Fax number : Nombor faks qrecsea@gmail.com E-mel Emergency telephone : Telfon Kecemasan 2. Composition/information on ingredients / Komposisi / maklumat Ramuan Identification and amount of the components: Pengenalan dan jumlah komponen: Synonyms: n-caproylhydride. n-hexylhydride Sinonim: n-caproylhydride. n-hexylhydride CAS: CAS: Molecular weight: g/mol Berat molekul: 86,18 g / mol EC index no: SPR indeks no: EC number: Nombor EC: Formula: C6H14 Formula: C6H14 Safety Data Sheet 3. Hazards identification / Pengenalpastian bahaya -Classification of the substance or mixture -Classification Daripada bahan atau campuran -Classification according to Regulations (EC) No 1272/2008 -Classification Mengikut Peraturan-Peraturan (EC) No 1272/2008 GHS02 flame/ GHS02 api Flam.Liq. 3 H226 Flammable liquid and vapour. Flam.Liq. 3 H226 Cecair dan wap mudah ternyala. Page 1 of 9
2 GHS08 Health hazard/ bahaya kepada kesihatan Repr.2 H361f Suspected of damaging fertility (causing atrophy of the testes.) Dicurigai kemandulan (menyebabkan atrofi testis.) STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Boleh menyebabkan kerosakan kepada organ-organ melalui pendedahan yang berpanjangan atau berulangulang. Asp.Tox. 1 H304 May be fatal if swallowed and enters airways. Boleh membawa maut jika tertelan dan memasuki saluran pernafasan. GHS09 Environment/linkungan Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. Toksik kepada hidupan akuatik dengan kesan tahan lama. GHS07 Skin Irrit.2 H315 Causes skin irritation. Boleh menyebabkan kerengsaan kulit. STOT SE 3 H336 May cause drownsiness or dizziness. Boleh menyebabkan drownsiness atau pening. -Classification according to Directive 67/548/EEC or Directive 1999/45/EC -Classification Mengikut 67/548 / EEC atau Arahan 1999/45 / EC Xn; Harmful / Berbahaya R48/ : Harmful:danger of serious damage to health by prolonged exposure through inhalation.possible risk of impaired fertility. Harmful: may cause lung damage if swallowed. Memudaratkan: bahaya yang menjejaskan kesihatan secara serius melalui pendedahan yang berpanjangan dengan menghirup.mungkin berisiko timbulnya gangguan kesuburan. Memudaratkan: boleh menyebabkan kerosakan paru-paru jika ditelan. Xi; Irritant / merengsa R38: Irritating to skin./ Merengsa kepada kulit F; Highly flammable / Mudah terbakar R11: Highly flammable / Mudah terbakar N; Dangerous for the environment / Berbahaya kepada persekitaran R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. Toksik kepada organisma akuatik, boleh menyebabkan kesan buruk jangka panjang kepada persekitaran akuatik. R67: Vapours may cause drownsiness and dizinness. / Wap boleh menyebabkan drownsiness dan dizinness. Repr.Cat.3 Information concerning particular hazards for human and environment: Not applicable. Maklumat mengenai bahaya tertentu bagi manusia dan alam sekitar: Tidak berkenaan -Label elements / Unsur label Page 2 of 9
3 -Labelling according to Regulation (EC) No.1272/2008 The substance is classified and labelled according to the CLP regulation. -Hazard pictograms / Piktogram bahaya GHS02 GHS07 GHS08 GHS09 -Signal word Danger / Isyarat perkataan Bahaya -Hazard statements / kenyataan -Hazard H225 Highly flammable liquid and vapour. / Cecair mudah terbakar dan wap. H315 Causes skin irritation./ Boleh menyebabkan kerengsaan kulit. H361f Suspected of damaging fertility (causing atrophy of the testes) / Dicurigai kemandulan (menyebabkan atrofi testis) H336 May cause drownsiness or dizziness. / Boleh menyebabkan drownsiness atau pening. H373 May cause damage to organs through prolonged or repeated exposure. / Boleh menyebabkan kerosakan kepada organorgan melalui pendedahan yang berpanjangan atau berulang-ulang. H411 Toxic to aquatic life with long lasting effects./ Toksik kepada hidupan akuatik dengan kesan tahan lama. -Precautionary statements / pernyataan langkah perlindungan P210 Keep away from heat/sparks/open flames/hot surfaces.- No smoking Jauhkan daripada haba / percikan api / nyalaan terbuka / surfaces.- panas Jangan merokok P241 Use explosion-proof electrical/ventilating/lighting/equipment. Menggunakan letupan-bukti / pengalihudaraan / lampu / peralatan elektrik. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. JIKA TERTELAN: Segera hubungi PUSAT RACUN atau doktor / pakar perubatan P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. P405 P501 Rinse skin with water/shower. JIKA TERKENA KULIT (atau rambut): Buang / Ambil dengan segera semua pakaian yang tercemar. Bilas kulit dengan air / semburan. Store locked up. Store berkunci. Dispose of contents/container in accordance with local/regional/national/international regulations. Lupuskan kandungan / bekas mengikut peraturan-peraturan antarabangsa / tempatan / wilayah / negara. -Other hazards / bahaya lain -Results of PBT and vpvb assessment / Results PBT dan vpvb -PBT: Not applicable / PBT: Tidak berkenaan -vpvb: Not applicable / vpvb: Tidak berkenaan 4. First aid measures / Langkah pertolongan cemas After inhalation: Fresh air. Keep airways free. If necessary, apply mechanical ventilation or mouth-to-mouth resuscitation. Jika tersedut: Udara segar. Pastikan saluran udara percuma. Jika perlu, terpakai pengudaraan mekanikal atau mulut-ke-mulut. After skin contact: Wash off with plenty of water. Remove contaminated clothing. Jika terkena kulit: Basuh dengan air yang banyak. Tanggalkan pakaian yang tercemar After ingestion: Avoid vomiting (risk of aspiration). Subsequently administer: Activated charcoal (20-40 g in 10% slurry). No milk. No alcohol. No castor oil. No gastric lavage. Summon doctor. Selepas pemakanan: Elakkan muntah (resiko aspirasi). Sesudah itu berikan: Arang aktif (20-40 g dalam 10% bubur). Tidak ada susu. Tiada alkohol. Tiada minyak jarak. Tiada pembersihan gastrik. Dapatkan rawatan perubatan. After eye contact: Rinse out with plenty of water with the eyelid held wide open. Summon eye specialist. Jika terkena mata: Bilas dengan air yang banyak dengan kelopak mata yang diadakan terbuka luas. Hubungi dokter mata. Page 3 of 9
4 5. Fire-fighting measures / Langkah memadam kebakaran Suitable extinguishing media: Powder, foam. Media pemadam yang sesuai: Serbuk, busa. Special risks: combustible, Vapours heavier than air, Formation of explosive mixtures possible with air at normal temperatures. Formation of combustion gases or dangerous vapours possible in event of fire. Risiko khusus: mudah terbakar, Wap lebih berat daripada udara, membentuk campuran letupan mungkin dengan udara pada suhu normal. Pembentukan gas-gas pembakaran atau uap berbahaya mungkin dalam kejadian kebakaran. Special protective equipment for fire fighting: Do not stay in dangerous zone without suitable chemical protection clothing and self-contained breathing apparatus. Peralatan pelindung khas untuk memadamkan api: Jangan tinggal di zon berbahaya tanpa pakaian perlindungan kimia yang sesuai dan alat pernafasan serba lengkap. Further information: Prevent fire-fighting water from entering surface water or groundwater. Cool container with spray water from a save distance. Take measures to prevent electrostatic charging. Maklumat lanjut: Elakkan air pemadam kebakaran memasuki air permukaan atau air bawah tanah. Bekas sejukkan dengan air semburan dari jauh menyimpan. Mengambil langkah-langkah untuk mencegah caj elektrostatik. 6. Accidental release measures /Langkah-langkah pengawalan pelepasan tidak sengaja Person-related precautionary measures: Do not inhale vapours/aerosols. Avoid substance contact. Ensure supply of fresh air in enclosed rooms. Langkah-langkah berjaga-jaga perseorangan: Jangan menyedut wap / aerosol. Elakkan sentuhan dengan bahan. Memastikan bekalan udara segar di dalam bilik tertutup. Environmental precautions: Do not allow to enter sewerage system (risk of explosion!). Langkah perlindungan alam sekitar: Jangan biarkannya memasuki sistem pembetungan (risiko letupan!). Procedures for cleaning / absorption: Take up with liquid-absorbent material. Forward for disposal, clean up. Prosedur pembersihan / penyerapan Ambil dengan bahan penyerap cairan. Teruskan ke pembuangan, membersihkan. 7. Handling and storage / Pengendalian dan penyimpanan Handling: Avoid generation of vapours/aerosols. Do not inhale substance. Work under hood. Keep away from sources of ignition. Take measures to prevent electrostatic charging. Penggunaan: Elakkan daripada generasi wap / aerosol. Jangan sedut bahan. Bekerja di bawah tenda. Jauhkan dari sumber api. Mengambil langkah-langkah untuk mencegah caj elektrostatik. Storage: Tightly closed in a well-ventilated place, away from sources of ignition and heat. Store at + 15 C to + 25 C. Penyimpanan: Tutup rapat di tempat yang mempunyai pengudaraan yang baik, jauh dari sumber api dan haba. Simpan pada + 15 C hingga + 25 C. 8. Exposure controls/personal protection / Kawalan pendedahan / perlindungan diri Exposure controls: Kawalan Pendedahan: Occupational exposure controls: The personal protective equipment must be selected according to the working place, based on the concentration and amount of the dangerous substance. The supplier should indicate the stability of the personal protective equipment to chemical reagents. Kawalan pendedahan pekerjaan: Peralatan pelindung diri mesti dipilih mengikut tempat kerja, berasaskan kepada kepekatan dan jumlah bahan yang berbahaya. Pembekal perlu menunjukkan kestabilan peralatan perlindungan peribadi untuk reagen kimia. Respiratory protection: Required when vapours/aerosols are generated. Perlindungan pernafasan: Diperlukan jika wap / aerosol dihasilkan. Hand protection: Required Perlindungan tangan: Diperlukan Protective gloves Eye protection: Required Perlindungan mata: Diperlukan Page 4 of 9
5 Tightly sealed goggles Skin protection: Acid-resistant protective clothing. Application of skin- protective barrier cream recommended. Perlindungan kulit: pakaian perlindungan Asid-tahan. Permohonan kulit pelindung krim disyorkan. Industrial hygiene: Immediately change contaminated clothing. Wash hands and face after working with substance. Kebersihan industri: Segera menukar pakaian yang tercemar. Basuh tangan dan muka selepas bekerja dengan bahan. 9. Physical and chemical properties / Sifat-sifat fizikal dan kimia General information: Maklumat am: Form: Liquid Bentuk: Cecair Colour: Colourless Warna: Tidak berwarna Odour: Benzine-like Bau: Benzine seperti Important health, safety and environmental information: Kesihatan, keselamatan dan persekitaran: ph value: -- nilai ph: - Boiling temperature: 69 ºC Suhu didih: 69 C Flash point: -22 ºC Takat kilat: -22 C Explosion limits (low): 1.0 Vol% Had Letupan (rendah): 1.0 Vol% Explosion limits (high): 8.1 Vol% Had Letupan (tinggi) 8.1 Vol% Vapour pressure: (20 ºC) 160 hpa Tekanan uap: (20 º C) 160 hpa Density (20 C): 0.66 g/cm3 Ketumpatan (20 C): 0.66 g / cm3 Solubility in water: (20 C): g/l Kelarutan dalam air (20 C): is g / l Solubility in: ethanol (20 C): miscible chloroform (20 C): miscible Kelarutan dalam: etanol (20 C): kloroform larut (20 C): larut Partition coefficient n-octanol/water: log P (o/w): 4.11 Pekali sekatan n-oktanol / air: log P (o / w): 4.11 Viscosity: (20 ºC) 0.31 mpas Kelikatan (20 C) 0.31 mpas Relative vapour density: 2.79 Ketumpatan wap relatif: 2.79 Refractive index: -- Indeks biasan: - Melting temperature: ºC Suhu lebur: -94,3 C Ignition temperature: 240 ºC Suhu pencucuhan: 240 C 10. Stability and reactivity / Kestabilan dan kereaktifan Conditions to be avoided: Heating / Conditions to be avoided: Heating Page 5 of 9
6 Keadaan yang perlu dielakkan: Pemanasan Substances to be avoided: Strong oxidizing agents. Bahan yang perlu dielakkan: agen pengoksidaan yang kuat. Hazardous decomposition products: Not available. Produk penguraian yang berbahaya: Tiada. Further information: Highly flammable. Unsuitable working materials: rubber, various plastics. Exposable with air in a vaporous/gaseous state, Maklumat lanjut: Sangat mudah terbakar. Bahan-bahan yang tidak sesuai untuk bekerja: getah, macam plastik. Exposable dengan udara dalam keadaan uap / gas, 11. Toxicological information / maklumat toksikologi Acute toxicity: Acute toxicity: LD50(oral, rat): mg/kg LD50 (oral, rat): mg / kg LC50 (inhalation, rat): ppm(v) /4h. LC50 (inhalation, rat): ppm (V) / 4h. LD50 (dermal, rabbit): > 2000 mg/kg LD50 (dermal, rabbit):> 2000 mg / kg Specific symptoms in animal studies: Eye irritation test (rabbit): Slight irritations. Specific symptoms in animal studies: Eye irritation test (rabbit): Slight irritations. Subacute to chronic toxicity: Animal experiments suggest that the substance may lead to an impairment of reproductive performance also in man. Subacute to chronic toxicity: Animal experiments suggest that the substance may lead to an impairment of reproductive performance also in man. Mutagenicity: Bacterian mutagenicity: Salmonella typhimurium: negative Mutagenisitas: Mutagenisitas Bacterian: typhimurium Salmonella: Negatif Further toxicological information: Maklumat toksikologi Lanjut: After inhalation: Irritating to respiratory system, drowziness, drowsiness. Jika tersedut: Merengsa kepada sistem pernafasan, perasaan mengantuk, mengantuk. After skin contact: Danger of skin absorption; irritations. Jika terkena kulit: Bahaya penyerapan kulit; iritasi. After eye contact: Slight irritations. Risk of corneal clouding Jika terkena mata: Iritasi ringan. Risiko kornea berkabut After ingestion: Nausea. Damage of lungs Setelah menelan: Loya. Kerosakan paru-paru After absorption of large quantities: Narcosis. Setelah penyerapan dengan kuantiti yang banyak: Narcosis. After aspiration of vomit: Risk of aspiration upon vomiting: pneumonia. Setelah muntah: Risiko pernapasan selama muntah: radang paru-paru. After absorption: Drowsiness, fatigue, narcosis. Selepas penyerapan: Mengantuk, letih, pembiusan. Further information: The following applies to aliphatic hydrocarbons (6-18 C) in general: Inhalation may lead to the formation of oedemas in the respiratory tract. After long-term exposure to the chemical: CNS disorders, paralysis symptoms. The product should be handled with the care usual when dealing with chemicals. Maklumat lanjut: Berikut ini berlaku untuk hidrokarbon alifatik (6-18 C) secara umum: Penyedutan boleh menyebabkan pembentukan oedema dalam saluran pernafasan. Setelah lama terdedah dengan bahan kimia: gangguan CNS, gejala lumpuh. Produk ini harus ditangani dengan hati-hati yang biasa ketika berhadapan dengan bahan kimia. Page 6 of 9
7 12. Ecological information / maklumat ekologi Ecotoxic effects: Toxic to acquatic organisms, may cause long-term effects in the aquatic environment. Substance floats on the water surface. Kesan ekotoksik: Toksik kepada organisma acquatic, boleh menyebabkan kesan jangka panjang kepada persekitaran akuatik. Bahan terapung di atas permukaan air. Fish toxicity: C. auratus CL50: 4 mg/l /24h. Keracunan ikan: C. auratus CL50: 4 mg / l / 24 h. Daphnia toxicity: Daphnia magna EC50: 2.1 mg/l /48h. Daphnia ketoksikan: Daphnia magna EC50: 2.1 mg / l / 48 jam. Algeal toxicity: Chlorella vulgaris CI50: 1079 mg/l /96h. Ketoksikan Algeal: Chlorella vulgaris CI50: 1079 mg / l / 96h. Mobility: log P (o/w): 4.11 Mobiliti: P log (o / w): 4.11 Bioaccumulative potential: Bioaccumulation Bioconcentration factor: Potensi biologis: Pengumpulan Bio Faktor biokonsentrasi: Further ecologic data: Do not allow to enter waters, waste water, or soil!. Data ekologik lebih lanjut: Jangan biarkan ia memasuki perairan, air limbah atau tanah!. 13. Disposal considerations Product: There are no uniform EU Regulations for the disposal of chemicals or residues. Chemical residues generally count as special waste. The disposal of the latter is regulated in the EU member countries through corresponding laws and regulations. We recommend that you contact either the authorities in charge or approved waste disposal companies which will advise you on how to dispose of special waste. Produk: Tiada Peraturan EU seragam untuk pelupusan bahan kimia atau baki. Sisa-sisa kimia umumnya mengira sisa buangan khusus. Pelupusan yang kedua dikawal di negara-negara anggota Kesatuan Eropah melalui undang-undang dan peraturan-peraturan yang berkaitan. Kami mengesyorkan anda menghubungi sama ada pihak berkuasa yang menjaga atau syarikat-syarikat pelupusan bahan buangan yang diluluskan yang akan menasihati anda tentang cara untuk melupuskan sisa buangan khusus. Packaging: Disposal in compliance with official regulations. Handle contaminated packaging in the same way as the substance itself. If not officially specified differently, non-contaminated packaging may be treated like household waste or recycled. Pembungkusan: Pelupusan mematuhi peraturan rasmi. Mengendalikan pembungkusan yang tercemar dengan cara yang sama sebagai bahan itu sendiri. Jika tidak secara rasmi dinyatakan berbeza, pembungkusan bukan tercemar boleh dilayan seperti sampah rumah atau dikitar semula. 14. Transport information / maklumat pengangkutan Road transport: UN-No: 1208 ADR class: 3 F1 II Correct technical name: HEXANES Sea transport: UN-No: 1208 IMDG class: 3 II Correct technical name: HEXANES Air transport: UN-No: 1208 IATA/ICAO class: 3 II Correct technical name: HEXANES Page 7 of 9
8 Pengangkutan jalan: PBB-No: 1208 Kelas ADR: 3 F1 II Nama teknikal Benar: HEXANES Pengangkutan laut: PBB-No: 1208 Kelas IMDG: 3 II Nama teknikal Benar: HEXANES Pengangkutan udara: PBB-No: 1208 Kelas IATA / ICAO: 3 II 15. Regulatory information / maklumat pengawalan EC-classification: This product has been included in the dangerous substances index with its corresponding EC index number, so it has been classified according to the 67/548/EEC directive and its later adaptations. EC-Klasifikasi: Produk ini telah dimasukkan dalam indeks bahan-bahan berbahaya dengan nombor indeks EC yang sesuai, jadi ia telah dikelaskan mengikut 67/548 / EEC dan arahan penyesuaian lampaunya. Symbol: F (Highly flammable), Xn (Harmful), N (Dangerous for the environment) Symbol: F (highly flammable), Xn (Harmful), N (Dangerous for the environment) R-phrases: /20-51/ highly flammable, Irritating to skin. Harmful: danger of serious damage to health by prolonged exposure. Toxic to aquatic organisms, may cause long-term effects in the aquatic environment. Possible risk of impaired fertility, Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. R-phrases: / / highly flammable, Irritating to skin. Harmful: danger of serious damage to health by prolonged exposure. Toxic to aquatic organisms, may cause long-term effects in the aquatic environment. Possible risk of impaired fertility, Harmful: may cause lung damage if swallowed. Vapors may cause drowsiness and dizziness. S-phrases: / Keep container in a well ventilated place. Keep away from sources of ignition - No Smoking. Do not empty into drains. Take precautionary measures against static discharges. Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/safety data sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. S-phrases: / Keep container in a well ventilated place. Keep away from sources of ignition - No Smoking. Do not empty into drains. Take precautionary measures against static discharges. Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions / Safety data sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. EC-Index-No: Other information / Maklumat Lain Reason for the revision: General update. Date: 01/1/2015 Sebab bagi semakan: update Negara. Tarikh: 2015/01/01 No warranty, expressed or implied for a particular purpose or otherwise is made, except the products herein discussed comply to the chemical description on the labels. Buyer assumers risks of the use, storage and handling. Producer or distributors shall not be liable for any incidental or consequential damages arising directly or indirectly in connection with the purchase, use, storage or handling of this product. The information contained herein is, to the best of our knowledge, true and accurate. However, a ll recommendations or suggestions are made without guarantee, since the conditions of use are beyond our control. We disclaim any liability incurred in connection with the use of these data or suggestions. Tiada jaminan, tersurat atau tersirat untuk tujuan tertentu atau sebaliknya dibuat, kecuali produk di sini dibincangkan Page 8 of 9
9 mematuhi Penerangan kimia pada label. Pembeli assumers risiko penggunaan, penyimpanan dan pengendalian. Pengeluar atau pengedar tidak akan bertanggungjawab ke atas sebarang kerosakan sampingan atau berbangkit yang timbul secara langsung atau tidak langsung berkaitan dengan pembelian, penggunaan, penyimpanan atau pengendalian produk ini. Maklumat yang terkandung di sini adalah, sepanjang pengetahuan kami, benar dan tepat. Walau bagaimanapun, semua syor atau cadangan adalah dibuat tanpa jaminan, kerana keadaan-keadaan penggunaan adalah di luar kawalan kami. Kami menafikan sebarang liabiliti yang ditanggung berkaitan dengan penggunaan ini data atau cadangan. Page 9 of 9
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