CLASSIFICATION: FLAMMABLE LIQUIDS Category 3 TOXIC TO REPRODUCTION (Fertility) Category 2. H361 Suspected of damaging fertility

Transcription

1 SECTION 1: IDENTIFICATION PRODUCT NAME: PRODUCT CODE: SUGGESTED USE: RESTRICTIONS USE: SCS - Straight N Curl Serum Hair care N/A MANUFACTURER: Product Packaging West, Inc Vose Street North Hollywood, CA TELEPHONE: DISTRIBUTOR: Dennis Bernard, Inc. 142 Ely Harmony Road Freehold, NJ TELEPHONE: FAX: EMERGENCY PHONE: Dennis Bernard: SECTION 2: HAZARDS IDENTIFICATION CLASSIFICATION: FLAMMABLE LIQUIDS Category 3 TOXIC TO REPRODUCTION (Fertility) Category 2 SIGNAL WORD: Warning HAZARD STATEMENTS: PICTOGRAMS: H226 Flammable liquid and vapor. H361 Suspected of damaging fertility PRECAUTIONARY STATEMENTS: Prevention P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment P280 Wear protective gloves. Wear eye or face protection. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 Use explosion-proof electrical, ventilating, lighting and all Page 1 of 10

2 material-handling equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P233 Keep container lightly closed. Response Storage Disposal P308 + P313 IF exposed or concerned: Get medical attention. P405 Store locked up. P403 Store in well-ventilated place. P235 Keep cool. P501 Dispose of contents and container in accordance with all local, regional, national and international regulations. HAZARDS NOT OTHERWISE None known. CLASSIFIED: See toxicologlical information (Section 11) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS COMPONENT: CAS NUMBER: CONCENTRATION: octamethylcyclotetrasiloxane < 50% Any concentration shown as a range is to protect confidentiality. There are no additional ingredients which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment hence requires reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Page 2 of 10

3 SECTION 4: FIRST AID MEASURES IF INHALED: SKIN CONTACT: EYE CONTACT: IF INGESTED: No known respiratory concerns. No known skin irritations. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 5 minutes. Get medical attention if irritation occurs. Wash out mouth with water. Remove dentures if any. If vomiting occurs, the head should be kept ow so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. POTENTIAL ACUTE HEALTH EFFECTS: INHALATION: No known significant effects or critical hazards. SKIN CONTACT: EYE CONTACT: INGESTION: No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. OVER-EXPOSURE SIGNS/SYMPTOMS: INHALATION: SKIN CONTACT: EYE CONTACT: INGESTION: Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations No specific data. Page 3 of 10

4 Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Notes to physician: Specific treatments: Protection of first-aiders: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. No specific treatment. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) SECTION 5: FIRE-FIGHTING MEASURES FLAMMABILITY OVERVIEW: FLASH POINT: SUITABLE EXTINGUISHING MEDIA: UNSUITABLE EXTINGUISHING MEDIA: SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: HAZARDOUS COMBUSTION PRODUCTS: Flammable liquid and vapor. Closed cup. 56 C (132.8 F) Use dry chemical CO 2, water spray (fog) or foam. Do not use water jet. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Contains flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst. Page 4 of 10

5 SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: CONTAINMENT AND CLEAN UP: Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Avoid over-dispersal of spilled material and runoff contact with soil, waterways, drains, and sewers. Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if watersoluble, absorb with inert dry material and place in an appropriate waste disposal container. For large spills, contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. SECTION 7: HANDLING AND STORAGE SAFE HANDLING: SAFE STORAGE: Avoid over-exposure, read instructions before use. Avoid exposure during pregnancy. Do not use until all safety precautions have been read and understood. Do not get in eyes. Do not ingest. Avoid over-inhalation. Use only with adequate ventilation. Do not enter storage areas and confined spaces unless adequately ventilated. Keep the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Do not reuse container. Store in accordance with local regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Page 5 of 10

6 SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS COMPONENT: CAS NUMBER: EXPOSURE LIMIT BASIS octamethylcyclotetrasiloxane None PERSONAL PROTECTIVE EQUIPMENT EYE PROTECTION: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. HAND PROTECTION: SKIN PROTECTION: RESPIRATORY PROTECTION: None. None. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: COLOR: ODOR: ODOR THRESHOLD: ph: MELTING / FREEZING POINT: BOILING POINT: FLASH POINT: EVAPORATION RATE: FLAMMABILITY (SOLID, GAS) FLAMMABILITY / EXPLOSION LIMIT: VAPOR 20 O C VAPOR DENSITY: Liquid. Yellow. To match standard. Not tested. < C (384.7 F) < 56 C (132.8 F) Not Tested. Not Tested. Not Tested. Page 6 of 10

7 SPECIFIC GRAVITY: DENSITY: SOLUBILITY IN WATER: Insoluble PARTITION COEFFICIENT: AUTOIGNITION TEMPERATURE: DECOMPOSITION TEMPERATURE: >150 C (>302 F) VISCOSITY: cps (DV-II Spindle 3 RPM 10) SECTION 10: STABILITY AND REACTIVITY CHEMICAL STABILITY: CONDITIONS AND MATERIALS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: The product is stable. Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. When exposed to high temperatures may produce hazardous decomposition products. Decomposition products may include the following materials: Formaldehyde. SECTION 11: TOXICOLOGICAL INFORMATION ACUTE TOXICITY COMPONENT TEST SPECIES RESULT DOSE octamethylcyclotetrasiloxane Rat Rat Rat LC50 Inhalation Vapor LD50 Dermal LD50 Oral 36 gm/m mg/kg 1540 mg/kg POTENTIAL HEALTH EFFECTS INHALATION: SKIN: EYES: INGESTION: SIGNS AND SYMPTOMS OF EXPOSURE: CHRONIC EFFECTS OF LONG- TERM EXPOSURE: See Section 4. See Section 4. Page 7 of 10

8 CARCINOGENICITY: MUTAGENICITY: SECTION 12: ECOLOGICAL INFORMATION ACUTE ECOTOXICITY COMPONENT RESULT SPECIES EXPOSURE octamethylcyclotetrasiloxane Chronic NOEC 1.7 to 15µg/l Fresh Water Daphnia Daphnia Magna 21 days Chronic NOEC 4.4 µg/l Fresh Water Fish Oncorhynchus mykiss Egg 93 days ECOLOGICAL EFFECTS PERSISTENCE AND DEGRADABILITY: BIOACCUMULATION POTENTIAL: MOBILITY IN SOIL: OTHER ADVERSE EFFECTS: SECTION 13: DISPOSAL CONSIDERATIONS DISPOSAL: CONTAMINATED PACKAGING: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. SECTION 14: TRANSPORTATION INFORMATION UN NUMBER: UN PROPER SHIPPING NAME: UN1993 FLAMMABLE LIQUID, N.O.S. Page 8 of 10

9 TRANSPORT HAZARD CLASSES: 3 SUB RISK: PACKING GROUP: ENVIRONMENTAL HAZARDS: SPECIAL PRECAUTIONS FOR USER: ADDITIONAL INFORMATION: III No. Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials. Limited quantity: Yes. Packaging Instruction Passenger and Cargo Aircraft Quantity Limitation: 60 L Packaging Instructions: 355 Cargo Aircraft Quantity Limitation: 220 L Packaging Instructions: 366 Passenger Aircraft Only Quantity Limitation: 10 L Packaging Instructions: Y344 Emergency Schedules (EmS): F-E, _S-E_ Special provisions: 223, 274, 955, A3 Viscous Substance Exemption: This class 3 material can be considered non-hazardous in packagings up to 30 L. Exempted according to (viscous substance exemption) SECTION 15: REGULATORY INFORMATION US FEDERAL SARA 302 COMPONENTS: SARA 311/312: SARA 313 COMPONENTS: No products were found. Fire hazard. Delayed chronic health hazard. Page 9 of 10

10 TSCA INVENTORY: TSCA 8(d) H and S data reporting: decamethylcyclopentasiloxane; dodecamethylcyclohexasiloxane TSCA 12(b) one-time export: octamethylcyclotetrasiloxane EUROPEAN UNION EC INVENTORY: STATE REGULATIONS CA PROP 65: United States inventory (TSCA 8b): All components are listed or exempted. All components are listed or exempted. CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of This product is not known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION SDS VERSION: REVISION DATE: N/A Notice to reader: To the best of our knowledge, the information contain herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 10 of 10