MATERIAL SAFETY DATA SHEET

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1 MATERIAL SAFETY DATA SHEET 1. Chemical Product and Company Identification MANUFACTURER: ADDRESS: UNITECH LUBRICANTS AMERICA INC. 605 COLBY DRIVE WATERLOO, ON, N2V 1A1 EMERGENCY PHONE NUMBER: (Mon - Fri: 8am - 5pm) PRODUCT NAME: Purgon SAD 264 PRODUCT TYPE: Liquid Spray Cleaner Concentrate PREPARED BY: OH&S Coordinator DATE OF ISSUE: DEC 10, 2011 SUPERCEDES: Rev 1 2. Composition/Information on Ingredients Mixture of non-ionic detergents, phosphates, amines and salts of organic acids Ingredient CAS No Percent Hazardous Triethanolamine % Yes 3. Hazards Identification Emergency Overview Irritating to eyes and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Potential Health Effects Inhalation: Vapour may cause irritation to the respiratory tract. Ingestion: Material is expected to cause irritation or burns to the gastrointestinal tract. Skin Contact: Causes irritation, redness, and pain, especially on prolonged or repeated contact. Eye Contact: Causes severe irritation. May cause redness, pain, blurred vision, and eye damage. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. Page 1/6

2 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Product will not ignite except if exposed to high temperature (> 212 F) for an extended time. Hazardous combustion products: Smoke, fumes, COx, NOx Explosion: Not considered to be an explosion hazard, except when extremely heated. Fire Extinguishing Media: Extinguish surrounding fire with suitable means. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Water spray may be used to keep fire exposed containers cool. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Collect with absorbent material and discard according to Federal, State and Local regulations. Keep product out of sewage systems or water bodies. Avoid entering into the ground. Page 2/6

3 7. Handling and Storage Storage place should provide protection against frost and heat. Best if stored between 40 and 100 F in a dry and ventilated area. Keep container tightly closed. Protect against physical damage. Avoid all contact of concentrate with eyes and skin. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: Triethanolamine: -ACGIH Threshold Limit Value (TLV): 5 ppm (TWA) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full face piece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves (PVC) and clean body-covering clothing. Eye Protection: Use chemical safety goggles and/or a full face shield when handling the concentrate. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear, colourless to light yellow liquid. Odour: Typical. Solubility: Miscible in water. Density: 1162 kg/m³ Page 3/6

4 ph: approx. 11 (1% solution) % Volatiles by 21 C (70 F): 0 Boiling Point: >100 C (212 F) Melting Point: ND Vapour Density (Air=1): ND Vapour Pressure (mm Hg): No information found Evaporation Rate (BuAc=1): No information found 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Avoid contact with oxidizers or strong acids. Conditions to Avoid: Cold, heat, incompatibles 11. Toxicological Information Oral rat LD50 Skin Effects Eye Effects >2000 mg/kg (calculated) Skin contact causes irritation Eye contact causes severe eye irritation 12. Ecological Information This product represents a hazard to water. Keep product out of sewage systems or water bodies. Avoid entering into the ground. Page 4/6

5 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated 15. Regulatory Information SARA Section 302 SARA Sections 313 CERCLA No No No SARA Hazard categories, SARA Sections 311/312 Acute Chronic Fire Reactivity Pressure Yes No No Yes No Chemical Inventories The ingredients of this product are on the following Chemical Substance Inventories: EINECS TSCA Poison Schedule: No information found. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 1 Label Hazard Warning: Irritating to eyes and skin. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label Precautions: Keep container closed. Avoid contact with eyes, skin, and clothing. Page 5/6

6 Label First Aid: In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. In case of skin contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, give large amounts of water to drink. Never give anything by mouth to an unconscious person. In all cases call a physician immediately. Product Use: Revision Information: Liquid spray cleaner concentrate No changes. ALL STATEMENTS, INFORMATION AND DATA PROVIDED IN THIS MSDS ARE BELIEVED TO BE ACCURATE AND RELIABLE. THIS INFORMATION IS PRESENTED WITHOUT GUARANTEE OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PURPOSE. NOTHING IS INTENDED AS PERMISSION INDUCEMENT TO VIOLATE ANY LAWS. SELLER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE OR LIABILITY RESULTING FROM THE USE OF THE PRODUCT IN THE BUYER S MANUFACTURING PROCESS OR IN COMBINATION WITH OTHER SUBSTANCES. Page 6/6

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