Safety Data Sheet Diesel Conditioner & Antigel

Transcription

1 SECTION 1. IDENTIFICATION Commercial Product : Name Product number : SDS-Identcode : Product Use Description : Fuel additive Company : Wurth USA Inc. 93 Grant St Ramsey, NJ USA Telephone : Telefax : Responsible/issuing : prodsafe@wuerth.com person Emergency telephone number : SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Carcinogenicity : Category 2 Aspiration hazard : Category 1 GHS Label element Hazard pictograms : Signal word Hazard statements : Danger : H227 Combustible liquid. H304 May be fatal if swallowed and enters airways. 1 / 15

2 H315 Causes skin irritation. H319 Causes serious eye irritation. H351 Suspected of causing cancer. Precautionary statements : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. P281 Use personal protective equipment as required. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: 1 % 2 / 15

3 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Weight percent- Weight percent kerosine - unspecified >= 30 - < 50 2-butoxyethanol >= 10 - < 20 1,2,4-trimethylbenzene >= 5 - < 10 solvent naphtha (petroleum), light arom >= 5 - < 10 naphthalene >= 1 - < 5 xylene >= 1 - < 5 ethylbenzene >= < 1 cumene >= < 1 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). First aider needs to protect himself. Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off contaminated clothing and shoes immediately. Inhalation : If breathed in, move person into fresh air. Call a physician immediately. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Skin contact : Wash off with soap and water. Remove contaminated clothing. If irritation develops, get medical attention. Wash contaminated clothing before re-use. Eye contact : Protect unharmed eye. If easy to do, remove contact lens, if worn. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Ingestion : If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. If a person vomits when lying on his back, place him in the recovery position. Rinse mouth with water. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Notes to physician 3 / 15

4 Treatment : Treat symptomatically and supportively. SECTION 5. FIREFIGHTING MEASURES Form : liquid Flash point : 64.0 C (147.2 F) Suitable extinguishing media : Dry chemical Foam Carbon dioxide (CO2) Specific hazards during firefighting : Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition products may be formed under fire conditions (see section 10). Exposure to decomposition products may be a hazard to health. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6. ACCIDENTAL RELEASE MEASURES 4 / 15

5 Personal precautions : Refer to protective measures listed in sections 7 and 8. Use personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation, especially in confined areas. Avoid inhalation of vapour or mist. Environmental precautions : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Avoid release to the environment. Refer to special instructions/ Safety data sheets. Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. CERCLA Hazardous substances and corresponding RQs: final RQ lbs final RQ lbs final RQ ,000 lbs final RQ ,000 lbs final RQ SECTION 7. HANDLING AND STORAGE Handling Handling : For personal protection see section 8. Do not breathe vapours or spray mist. Avoid contact with skin and eyes. Use appropriate container to avoid environmental contamination. 5 / 15

6 Advice on protection : Normal measures for preventive fire protection. against fire and explosion Dust explosion class : Not applicable Storage Requirements for storage areas and containers Advice on common storage : Store in original container. Keep containers tightly closed in a dry, cool and wellventilated place. : Incompatible with oxidizing agents. Keep away from food, drink and animal feedingstuffs. Storage temperature : < 50 C (< 122 F) Other data : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components CAS-No. List Type: Value Update 2-butoxyethanol ACGIH TWA 20 ppm OSHA Z-1 TWA 50 ppm NIOSH REL TWA 5 ppm OSHA P0 TWA 25 ppm ,2,4-trimethylbenzene NIOSH REL TWA 25 ppm solvent naphtha 500 ppm 2, OSHA Z-1 TWA (petroleum), light arom naphthalene ACGIH TWA 10 ppm OSHA Z-1 TWA 10 ppm NIOSH REL TWA 10 ppm NIOSH REL ST 15 ppm OSHA P0 TWA 10 ppm OSHA P0 STEL 15 ppm / 15

7 xylene OSHA Z-1 TWA 100 ppm OSHA P0 STEL 150 ppm OSHA P0 TWA 100 ppm ACGIH TWA 100 ppm ACGIH STEL 150 ppm ethylbenzene ACGIH TWA 20 ppm NIOSH REL TWA 100 ppm NIOSH REL ST 125 ppm OSHA Z-1 TWA 100 ppm cumene ACGIH TWA 50 ppm OSHA Z-1 TWA 50 ppm NIOSH REL TWA 50 ppm OSHA P0 TWA 50 ppm Engineering measures : Provide sufficient air exchange and/or exhaust in work rooms. Eye protection : Tightly fitting safety goggles Hand protection : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Skin and body protection : Wear suitable protective clothing. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. 7 / 15

8 General industrial hygiene practice. Avoid breathing vapours, mist or gas. Avoid contact with skin, eyes and clothing. When using do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Follow the skin protection plan. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form Physical state Colour Odour Odour Threshold Flash point Ignition temperature Thermal decomposition Lower explosion limit Upper explosion limit Flammability Molecular weight ph Vapour pressure Relative vapour density Evaporation rate Density Relative density Bulk density Water solubility Partition coefficient: n- octanol/water Solubility in other solvents Viscosity, dynamic Viscosity, kinematic : liquid : liquid : amber : 64.0 C (147.2 F) : 0.99 g/cm3 : insoluble 8 / 15

9 SECTION 10. STABILITY AND REACTIVITY Materials to avoid Hazardous decomposition products Hazardous reactions : Strong oxidizing agents : Build-up of dangerous/toxic fumes possible in cases of fire/high temperature. : Note: No decomposition if stored and applied as directed. SECTION 11. TOXICOLOGICAL INFORMATION Acute dermal toxicity : Acute toxicity estimate Dose: > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate Exposure time: 4 h Dose: > 40 mg/l Method: Calculation method Carcinogenicity : No data is available on the product itself. Reproductive toxicity : No data is available on the product itself. Teratogenicity : No data is available on the product itself. Further information : Even the smallest quantities that enter into the lung due to swallowing or subsequent vomiting can lead to a pulmonary oedema or pneumonia. Aspiration hazard if swallowed - can enter lungs and cause damage. Component: 2-butoxyethanol Acute oral toxicity: LD50 Rat Dose: 1,746 mg/kg Method: OECD Test Guideline 401 Acute dermal toxicity: LD50 Dose: > 1,000-2,000 mg/kg Acute inhalation toxicity: LC50 9 / 15

10 Dose: > mg/lexposure time: 4 h Skin irritation: Rabbit Result: irritating Method: Directive 67/548/EEC, Annex V, B.4. Eye irritation: Rabbit Result: Irritation to eyes, reversing within 7 days Method: OECD Test Guideline 405 Carcinogenicity: Not classifiable as a human carcinogen. Reproductive toxicity: No toxicity to reproduction Teratogenicity: Animal testing did not show any effects on foetal development. 1,2,4-trimethylbenzene Acute inhalation toxicity: LC50 Dose: > mg/lexposure time: 4 h Skin irritation: Result: Severe skin irritation Eye irritation: Result: irritating solvent naphtha (petroleum), light arom Carcinogenicity: Classified based on benzene content < 0.1% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note P) Mutagenicity: Classified based on benzene content < 0.1% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note P) naphthalene Acute oral toxicity: LD50 Dose: > 300-2,000 mg/kg Carcinogenicity: Suspected human carcinogens xylene Acute dermal toxicity: LD50 Dose: > 1,000-2,000 mg/kg Acute inhalation toxicity: LC50 Dose: > mg/lexposure time: 4 h Skin irritation: Result: Severe skin irritation ethylbenzene Acute inhalation toxicity: LC50 Dose: > mg/lexposure time: 4 h Carcinogenicity: OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or 10 / 15

11 potential carcinogen by OSHA. NTP IARC naphthalene ethylbenzene naphthalene cumene SECTION 12. ECOLOGICAL INFORMATION Additional ecological information : The product should not be allowed to enter drains, water courses or the soil. Component: 2-butoxyethanol Toxicity to fish: LC50 Species: Oncorhynchus mykiss (rainbow trout) Dose: 1,474 mg/l Exposure time: 96 h Acute and prolonged toxicity for aquatic invertebrates: EC50 Species: Daphnia magna (Water flea) Dose: 1,550 mg/l Exposure time: 48 h Toxicity to algae: EC50 Species: Pseudokirchneriella subcapitata (green algae) Dose: 911 mg/l Exposure time: 72 h Toxicity to algae: NOEC Species: Pseudokirchneriella subcapitata (green algae) Dose: 88 mg/l Exposure time: 72 h SECTION 13. DISPOSAL CONSIDERATIONS 11 / 15

12 Adequate disposal : In accordance with local and national regulations. Do not dispose of waste into sewer. This material and its container must be disposed of as hazardous waste. Do not dispose of together with household waste. SECTION 14. TRANSPORT INFORMATION DOT 49 CFR ID No : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. : (1,2,4-trimethylbenzene, naphthalene) Class : 9 Packing group : III Labels : 9 Emergency Response : 171 Guidebook Number TDGR ID No : UN 3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Class : 9 Packing group : III Labels : 9 ICAO/IATA-DGR ID No : UN 3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s. (1,2,4-trimethylbenzene, naphthalene) Class : 9 Packaging group : III ICAO-Labels : 9 Packing instruction (cargo : 964 aircraft) Packing instruction : 964 (passenger aircraft) Packing instruction : Y964 (passenger aircraft) Environmentally hazardous : no IMDG-Code 12 / 15

13 ID No : UN 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1,2,4-trimethylbenzene, naphthalene) Class : 9 Packaging group : III IMDG-Labels : 9 EmS Number 1 : F-A EmS Number 2 : S-F Marine pollutant : yes SECTION 15. REGULATORY INFORMATION SARA 311/312 Hazards : Fire Hazard Acute Health Hazard Chronic Health Hazard CERCLA Reportable Quantity : 2,000 lbs EPCRA_313 US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR ) - Supplier Notification Required The following components are subject to reporting levels established by SARA Title III, Section 313: Components CAS-No. xylene ethylbenzene ,2,4-trimethylbenzene naphthalene butoxyethanol EPCRA_302 US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance (40 CFR 355, Appendix A) The following components are subject to reporting levels established by SARA Title III, Section 302: Components CAS-No. vinyl acetate PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap ) Components 13 / 15 CAS-No.

14 kerosine - unspecified butoxyethanol ,2,4-trimethylbenzene solvent naphtha (petroleum), light arom naphthalene xylene Ethylhexan-1-ol ethylbenzene cumene vinyl acetate MASS RTK US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section ) Components CAS-No. 2-butoxyethanol ,2,4-trimethylbenzene naphthalene xylene Ethylhexan-1-ol vinyl acetate NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) Components CAS-No. kerosine - unspecified butoxyethanol ,2,4-trimethylbenzene solvent naphtha (petroleum), light arom naphthalene xylene ethylbenzene California Prop. 65 : WARNING! This product contains a chemical known to the State of California to cause cancer. 14 / 15

15 Health Reactivity Safety Data Sheet SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: HEALTH FLAMMABILITY 3* 2 PHYSICAL 0 Specific Hazard 0 = Insignificant, 1 =Slight, 2 =Moderate, 3 =High, 4 = Extreme The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by : SAP Business Compliance Services GmbH Birlenbacher Str. 19 D Siegen Germany Telephone: +49-(0) Revision Date : 05/27/2015 Date of last issue : 01/05/2015 Date of first issue : 09/24/ / 15