Safety Data Sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/5 * 1 Identification of substance: - Product details: - - Application of the substance / the preparation Sealing mortar - Manufacturer/Supplier: KERAKOLL S.p.A. Via dell'artigianato, Sassuolo (MODENA) ITALY Tel Fax safety@kerakoll.com - Informing department: Product safety department - Emergency information: Hazards identification - Hazard designation: Xi Irritant - Information pertaining to particular dangers for man and environment The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. R 36/37/38 Irritating to eyes, respiratory system and skin. R 43 May cause sensitisation by skin contact. - Classification system The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. * 3 Composition/information on ingredients - Chemical characterization - Description: Mixture consisting of the following components. - Dangerous components: CAS: Portland Cement Xi; R 36/37/ % EINECS: (Contain reducing agents: Cr VI < 0,0002%) Natural hydraulic lime NHL 3,5 Xi; R 37/ % - Additional information For the wording of the listed risk phrases refer to section First aid measures - After inhalation Supply fresh air and call for doctor for safety reasons. In case of unconsciousness bring patient into stable side position for transport. - After skin contact Instantly wash with water and soap and rinse thoroughly. - After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. - After swallowing In case of persistent symptoms consult doctor. 5 Fire fighting measures - Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. (Contd. on page 2)

2 Page 2/5 - Protective equipment: No special measures required. (Contd. of page 1) 6 Accidental release measures - Person-related safety precautions: Not required. - Measures for environmental protection: Do not allow to enter drainage system, surface or ground water. - Measures for cleaning/collecting: Ensure adequate ventilation. 7 Handling and storage - Handling - Information for safe handling: Ensure good ventilation/exhaustion at the workplace. - Information about protection against explosions and fires: No special measures required. - Storage - Requirements to be met by storerooms and containers: No special requirements. - Information about storage in one common storage facility: Not required. - Further information about storage conditions: Keep container tightly sealed. * 8 Exposure controls and personal protection - Additional information about design of technical systems: No further data; see item 7. - Components with limit values that require monitoring at the workplace: Portland Cement (Contain reducing agents: Cr VI < 0,0002%) (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust calcium carbonate (25-50%) OEL Long-term value: 10 mg/m³ Natural hydraulic lime NHL 3,5 (1-2.5%) OEL Short-term value: 5 mg/m³ Long-term value: 10 mg/m³ - Additional information: The lists that were valid during the compilation were used as basis. - Personal protective equipment - General protective and hygienic measures Keep away from foodstuffs, beverages and food. Take off immediately all contaminated clothing Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. - Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. - Protection of hands: Protective gloves. - Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. - Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 3)

3 Page 3/5 - Eye protection: Tightly sealed safety glasses. (Contd. of page 2) 9 Physical and chemical properties: - General Information Form: Colour: Odour: - Change in condition Melting point/melting range: Not determined Boiling point/boiling range: Not determined - Flash point: Not applicable Solid. According to product specification Characteristic - Self-inflammability: Product is not selfigniting. - Danger of explosion: Product is not explosive. - Density at 20 C 1.12 g/cm³ - Solubility in / Miscibility with Water: Unsoluble Organic solvents: 0.0 % 10 Stability and reactivity - Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. - Dangerous reactions No dangerous reactions known - Dangerous products of decomposition: No dangerous decomposition products known 11 Toxicological information - Acute toxicity: - Primary irritant effect: - on the skin: Irritant to skin and mucous membranes. - on the eye: Irritant effect. - Sensitization: Sensitization possible by skin contact. - Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Irritant - Sensitisation May cause sensitisation by skin contact. 12 Ecological information: - General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. (Contd. on page 4)

4 Page 4/5 (Contd. of page 3) * 13 Disposal considerations - Product: - Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. - Waste disposal key number: Concrete - Uncleaned packagings: - Recommendation: Disposal must be made according to official regulations. 14 Transport information - Land transport ADR/RID (cross-border) - ADR/RID-GGVS/E Class: - - Maritime transport IMDG: - IMDG Class: - - Marine pollutant: No - Air transport ICAO-TI and IATA-DGR: - ICAO/IATA Class: - * 15 Regulatory information - Designation according to EC guidelines: The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV) - Code letter and hazard designation of product: Xi Irritant - Hazard-determining components of labelling: Portland Cement (Contain reducing agents: Cr VI < 0,0002%) - Risk phrases: 36/37/38 Irritating to eyes, respiratory system and skin. 43 May cause sensitisation by skin contact. - Safety phrases: 2 Keep out of the reach of children. 24/25 Avoid contact with skin and eyes. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 37 Wear suitable gloves. 46 If swallowed, seek medical advice immediately and show this container or label. 56 Dispose of this material and its container to hazardous or special waste collection point. 60 This material and its container must be disposed of as hazardous waste. 64 If swallowed, rinse mouth with water (only if the person is conscious). - National regulations The product is subject to classification in accordance with the prevailing version of the regulations on hazardous materials. - Additional classification according to Decree on Hazardous Materials, Annex II: - (Contd. on page 5)

5 Page 5/5 - Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. (Contd. of page 4) 16 Other information: - Relevant R-phrases 36/37/38 Irritating to eyes, respiratory system and skin. 37/38 Irritating to respiratory system and skin. 41 Risk of serious damage to eyes. 43 May cause sensitisation by skin contact. - Department issuing data specification sheet: SCP - Contact: Dr. G. Ghirardini c/o Kerakoll S.p.A. tel fax Others regulations The safety data sheet has been drawn up in accordance with European directives 1999/45/EC, 2001/58/EC, 2001/59/EC and 2001/60/EC. - * Data compared to the previous version altered.