SAFETY DATA SHEET. Specific target organ toxicity following repeated exposure Not classified < 15

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification SDS number Synonyms Texture paint Recommended use Interior use. Recommended restrictions Use in accordance with manufacturer's recommendations. Manufacturer/Importer/Supplier/Distributor information Company name CGC Inc. Address 350 Burnhamthorpe Road West, 5th Floor Mississauga, Ontario L5B 3J1 A Subsidiary of USG Corporation Telephone Website Emergency phone number Hazard(s) identification Physical hazards Health hazards Environmental hazards Label elements Not classified. Carcinogenicity Specific target organ toxicity following repeated exposure Not classified. Category 1A Category 2 Signal word Hazard statement Precautionary statements Prevention Response Storage Disposal Other hazards Supplemental information Danger May cause cancer. May cause damage to organs (lungs) through prolonged or repeated exposure. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapour. Wear protective gloves/protective clothing/eye protection/face protection. IF exposed or concerned: Get medical advice/attention. Store locked up. Dispose of in accordance with federal, provincial and local regulations. None known. None. 3. Composition/information on ingredients Mixtures Chemical name Kaolin Diatomite Kaolin, calcined CAS number % < < < Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

2 Titanium dioxide < 10 CAS number % Cristobalite < 5 Composition comments All concentrations are in percent by weight unless ingredient is a gas. Raw materials in this product contain respirable crystalline silica (cristobalite) as naturally occurring impurities. Since this product is a liquid slurry, the risk of inhaling particles is not expected during the recommended use of this product. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards Exposure to mists may cause temporary irritation to eyes, skin, nose, throat, and upper respiratory tract. Move injured person into fresh air and keep person calm under observation. Get medical attention if symptoms persist. Rinse area with plenty of water. Get medical attention if irritation develops or persists. Do not rub eyes. Flush thoroughly with water. If burning, redness, itching, pain, or other symptoms develop or persist get medical attention. Rinse mouth. Get medical attention if symptoms occur. Under normal conditions of intended use, this material does not pose a risk to health. Provide general supportive measures and treat symptomatically. Ensure that medical personnel are aware of the material(s) involved. Use fire-extinguishing media appropriate for surrounding materials. Not a fire hazard. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use standard firefighting procedures and consider the hazards of other involved materials. Cool material exposed to heat with water spray and remove it if no risk is involved. No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions See Section 8 of the SDS for Personal Protective Equipment. Prevent entry into confined areas or water systems. Dilute with water and mop or wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Dispose of waste according to local regulations. Avoid discharge to drains, sewers, and other water systems. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Minimize exposure to mists. In case of insufficient ventilation, wear suitable respiratory equipment. Observe good industrial hygiene practices. Use proper lifting techniques. Store in a cool, dry place. Store in a closed container away from incompatible materials. Protect from moisture. Keep away from heat. Do not use if material has spoiled, i.e., there is a mouldy appearance or an unpleasant odour. Keep containers closed when not in use Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

3 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit s TWA 2 mg/m3 Respirable fraction. TWA 10 mg/m3 TWA mg/m3 Respirable fraction. Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) TWA 2 mg/m3 Respirable. TWA 10 mg/m3 TWA mg/m3 Respirable particles mg/m3 Respirable. Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) TWA 2 mg/m3 Respirable. TWA 3 mg/m3 Respirable fraction. 10 mg/m3 Total dust. TWA mg/m3 Respirable fraction. Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) TWA 2 mg/m3 Respirable fraction. TWA 10 mg/m3 TWA mg/m3 Respirable fraction. Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) TWA 2 mg/m3 Respirable fraction. TWA 10 mg/m3 TWA 0.05 mg/m3 Respirable. Canada. Quebec OELs. (Ministry of Labour - Regulation Respecting the Quality of the Work Environment) TWA 5 mg/m3 Respirable dust. TWA 10 mg/m3 Total dust. TWA 0.05 mg/m3 Total dust Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

4 Biological limit values Appropriate engineering controls No biological exposure limits noted for the ingredient(s). Provide sufficient ventilation for operations causing dust formation. Observe occupational exposure limits and minimise the risk of exposure. Individual protection measures, such as personal protective equipment Eye/face protection Wear approved safety goggles. Skin protection Hand protection It is a good industrial hygiene practice to minimise skin contact. For prolonged or repeated skin contact use suitable protective gloves. Other Normal work clothing (long sleeved shirts and long pants) is recommended. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Use a NIOSH/MSHA approved air purifying respirator as needed to control exposure. Consult with respirator manufacturer to determine respirator selection, use, and limitations. Use positive pressure air supplied respirator for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow respirator protection program requirements (OSHA and ANSI Z88.2) for all respirator use. Observe any medical surveillance requirements. Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Physical state Liquid. Slurry. Colour Off-white. Odour Low to no odour. Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit upper (%) Vapour pressure Vapour density Relative density (H2O=1) Solubility(ies) Solubility (water) Soluble in water. Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity None. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Observe any medical surveillance requirements Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

5 Other information Bulk density kg/l VOC (Weight %) 50.4 g/l (Calculated by EPA Method 24) 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerisation does not occur. None known. None known. Above 800 C (1472 F) limestone (CaCO3) can decompose to lime (CaO) and release carbon dioxide (CO2). 11. Toxicological information Information on likely routes of exposure Inhalation Inhalation of mist may cause irritation to throat and or nasal passages. Skin contact The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin. Eye contact Direct contact with airborne particulates may cause temporary irritation. Ingestion Ingestion may cause irritation and stomach discomfort. Symptoms related to the Irritation of eyes and mucous membranes. Skin irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Neither inhalation nor skin contact contribute to acute toxicity of the substance or mixture. However, may cause discomfort if swallowed. Species Test results Acute Dermal LD50 Inhalation LC50 Oral LD50 Skin corrosion/irritation Serious eye damage/eye irritation Rat Rat Rat > 5000 mg/kg > 2 mg/l, 4 Hours > 5000 mg/kg Prolonged or repeated skin contact may cause drying, cracking, or irritation. Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitisation Canada - Alberta OELs: Irritant Irritant Irritant Respiratory sensitisation Not a respiratory sensitiser. Skin sensitisation The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals after repeated contact. For detailed information, see section 16. Germ cell mutagenicity Carcinogenicity Data does not suggest that this product or any components present at greater than 0.1% are mutagenic or genotoxic. May cause cancer. Titanium Dioxide is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

6 ACGIH Carcinogens A2 Suspected human carcinogen. A4 Not classifiable as a human carcinogen. A4 Not classifiable as a human carcinogen. Canada - Alberta OELs: Carcinogen category Suspected human carcinogen. Canada - Manitoba OELs: carcinogenicity KAOLIN, RESPIRABLE FRACTION (CAS ) Not classifiable as a human carcinogen. SILICA, CRYSTALLINE-CRISTOBALITE, RESPIRABLE Suspected human carcinogen. FRACTION (CAS Not classifiable as a human carcinogen. Canada - Quebec OELs: Carcinogen category Detected carcinogenic effect in animals. IARC Monographs. Overall Evaluation of Carcinogenicity 1 Carcinogenic to humans. Diatomite (CAS ) 3 Not classifiable as to its carcinogenicity to humans. Reproductive toxicity Not expected to be a reproductive hazard. Specific target organ toxicity - No data available, but none expected. single exposure Specific target organ toxicity - May cause damage to organs (lungs) through prolonged or repeated exposure. repeated exposure Aspiration hazard Not an aspiration hazard. Chronic effects See section Ecological information Ecotoxicity Aquatic Acute Crustacea Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. LC50 TDG Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Species Daphnia magna Bioaccumulation is not expected. No data available. None expected. Test results > 1.1 g/l, 48 Hours Dispose of in accordance with federal, provincial and local regulations. Recycle responsibly. Dispose of in accordance with local regulations. Not regulated. Dispose of in accordance with local regulations. Dispose of in accordance with local regulations Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

7 15. Regulatory information Canadian regulations This product has been classified in accordance with the hazard criteria of the HPR and the SDS contains all the information required by the HPR. Controlled Drugs and Substances Act Not regulated. Export Control List (CEPA 1999, Schedule 3) Not listed. Greenhouse Gases Not listed. Precursor Control Regulations Not regulated. International regulations Stockholm Convention Rotterdam Convention Kyoto protocol Montreal Protocol Basel Convention 16. Other information Issue date 18-February-2016 Revision date 18-February-2016 Version No. 02 Further information Crystalline silica (cristobalite): Since this product is a liquid slurry, the risk of inhaling particles is not expected during the recommended use of this product. However, this product contains crystalline silica. Prolonged and repeated exposures to airborne free respirable crystalline silica can result in lung silicosis and/or lung cancer. Titanium dioxide: In lifetime inhalation studies of experimental rats, airborne nano-sized (15-40 nanometer particle size range) particles caused lung tissue overload, chronic inflammation and subsequent tumor formation. Because of these study results, titanium dioxide was classified by IARC as a 2B (possibly carcinogenic to humans). However, other laboratory animals such as mice and hamsters did not develop lung tumors under similar testing conditions. Furthermore, results of two major human epidemiology studies among titanium dioxide workers in the US and in Europe did not demonstrate an elevated lung cancer risk, and did not suggest an association between occupational exposure to titanium dioxide and risk for cancer. The titanium dioxide contained in this product is embedded, and generation of airborne nano-sized titanium dioxide particles is not expected. Skin Sensitization Potential: This product contains an amount of Triazinetriethanol (THT) (CAS No ) that is within the approved EPA regulated limits. THT can act as a sensitizer. Numerous human studies with concentrations up to 1% yielded negative (no sensitization) results. However, some results showed positive reactions in concentrations <0.5% mostly in persons with eczema. Ethylene glycol: This product contains a small amount of ethylene glycol, which has been shown to cause kidney damage in animal studies via repeated oral exposure (ingestion). However, such exposures are not expected to occur during normal use of this product. If ingested, call a poison center or doctor if you feel unwell. NFPA ratings Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Health: 1 Flammability: 0 Instability: Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8

8 NFPA ratings List of abbreviations References Disclaimer ACGIH: American Conference of Governmental Industrial Hygienists. NFPA: National Fire Protection Association. Registry of Toxic Effects of Chemical Substances (RTECS) HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity Torben et al. (2001). Environmental and Health Assessment of Substances in Household Detergents and Cosmetic Products. This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment Version #: 02 Revision date: 18-February-2016 Issue date: 18-February / 8