Material Safety Data Sheet

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1 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI COMPLIANCE ORAL CO-THERAPY KIT 04/01/10 Material Safety Data Sheet Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. PRODUCT NAME: 3M ESPE OMNI COMPLIANCE ORAL CO-THERAPY KIT MANUFACTURER: 3M DIVISION: 3M ESPE Dental Products ADDRESS: 3M Center St. Paul, MN EMERGENCY PHONE: or (651) (24 hours) Issue Date: 04/01/10 Supercedes Date: 09/17/09 Document Group: ID Number(s): , This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for each of these components is included. Please do not separate the component MSDSs from this cover page. The document numbers of the MSDSs for components of this product are: , , Revision Changes: Copyright was modified. Kit: Component document group number(s) was modified. Kit: ID Number(s) was modified. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Page 1 of 2

2 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI COMPLIANCE ORAL CO-THERAPY KIT 04/01/10 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. Page 2 of 2

3 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/09 Material Safety Data Sheet Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) MANUFACTURER: 3M DIVISION: 3M ESPE Dental Products ADDRESS: 3M Center St. Paul, MN Issue Date: 10/06/09 Supercedes Date: 02/21/08 Document Group: EMERGENCY PHONE: or (651) (24 hours) Product Use: Intended Use: Limitations on Use: Specific Use: Dental Product For use only under dental supervision Dental preventative - Fluoride Treatment SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt FLAVOR Mixture < 2 GLYCERIN > 98 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Clear, slightly yellow liquid/gel with odor according to flavor General Physical Form: Liquid Immediate health, physical, and environmental hazards: No immediate health, physical, or environmental hazards anticipated. Page 1 of 7

4 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/ POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL 390 ºF [Test Method: Closed Cup] Page 2 of 7

5 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/ EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: (SCBA). Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Dispose of collected material as soon as possible. Observe precautions from other sections. Call 3M- HELPS line ( ) for more information on handling and managing the spill. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Avoid prolonged or repeated skin contact. Wash hands after handling and before eating. 7.2 STORAGE Store under normal warehouse conditions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection Avoid eye contact Skin Protection Avoid prolonged or repeated skin contact. Gloves not normally required. Page 3 of 7

6 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/ Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection Prevention of Swallowing Do not ingest. Wash hands after handling and before eating. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information GLYCERIN ACGIH TWA, as mist 10 mg/m3 GLYCERIN OSHA TWA, as mist, 5 mg/m3 Table Z-1 respirable GLYCERIN OSHA TWA, Vacated, as 10 mg/m3 mist, total dust GLYCERIN OSHA TWA, as mist, total dust 15 mg/m3 Table Z-1 VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Clear, slightly yellow liquid/gel with odor according to flavor General Physical Form: Liquid Autoignition temperature Flash Point 390 ºF [Test Method: Closed Cup] Flammable Limits - LEL Flammable Limits - UEL Boiling point 554 ºF Density 1.27 g/ml Vapor Density Vapor Pressure Specific Gravity 1.27 ph Melting point Solubility in Water Evaporation rate Kow - Oct/Water partition coef Viscosity Appreciable Page 4 of 7

7 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/09 SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition During Combustion During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Discharge spent solutions and small quantities of less than 5 gallons (20 liters) to a municipal or industrial wastewater treatment system. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. Page 5 of 7

8 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/09 SECTION 14:TRANSPORT INFORMATION ID Number(s): LE-F , , , , , , , , , , , , , , , , Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS CHEMICAL INVENTORIES This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the FDA. INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR Page 6 of 7

9 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI PERIOMED (0.63% STANNOUS FLUORIDE), JUST FOR KIDS (0.4% STANNOUS FLUORIDE), & OMNIGEL (0.4% STANNOUS FLUORIDE) 10/06/09 SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Copyright was modified. Section 8: Skin protection phrase was modified. Page Heading: Product name was modified. Section 9: Property description for optional properties was added Conditions to avoid was added Materials to avoid was added. Section 6: Release measures information was added. Section 6: Release measures information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 8: Skin/ hand protection phrase was added. Section 6: Release measures information was deleted. Section 10: Materials and conditions to avoid physical property was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at Page 7 of 7

10 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 Material Safety Data Sheet Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M ESPE OMNI CONTROLRX DENTIFRICE MANUFACTURER: 3M DIVISION: 3M ESPE Dental Products ADDRESS: 3M Center St. Paul, MN Issue Date: 03/19/10 Supercedes Date: 01/14/08 Document Group: EMERGENCY PHONE: or (651) (24 hours) Product Use: Intended Use: Specific Use: Dental product Dental preventative SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER SORBITOL SYNTHETIC CRYSTALLINE-FREE SILICA GEL GLYCERIN AMORPHOUS SILICA POLYETHYLENE-POLYPROPYLENE GLYCOL < 3 SODIUM FLUORIDE < 2 SODIUM SACCHARIN < 2 FLAVORINGS Mixture < 2 POLYETHYLENE GLYCOL < 2 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Paste Page 1 of 7

11 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 Odor, Color, Grade: Opaque paste with berry or vanillamint flavor. General Physical Form: Solid Immediate health, physical, and environmental hazards: are expected. No immediate health, physical, or environmental hazards 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Inhalation: No health effects are expected. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Inhalation: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. No need for first aid is anticipated. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL 5.2 EXTINGUISHING MEDIA Page 2 of 7

12 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: (SCBA). Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line ( ) for more information on handling and managing the spill. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from oxidizing agents. Store at room temperature. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection Avoid eye contact Skin Protection Avoid prolonged or repeated skin contact Respiratory Protection Page 3 of 7

13 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 Not applicable Prevention of Swallowing Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information POLYETHYLENE GLYCOL AIHA TWA, as particulate 10 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Density Vapor Density Vapor Pressure Specific Gravity ph Melting point Solubility in Water Evaporation rate Kow - Oct/Water partition coef Viscosity Paste Opaque paste with berry or vanillamint flavor. Solid 1.04 g/cm [Ref Std: WATER=1] Appreciable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid None known 10.2 Materials to avoid Strong oxidizing agents Page 4 of 7

14 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition During Combustion During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Since regulations vary, consult applicable regulations or authorities before disposal. Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LE-F , , , , Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION Page 5 of 7

15 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS CHEMICAL INVENTORIES This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the FDA. INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Copyright was modified. Page Heading: Product name was modified. Section 14: ID Number(s) Template 1 was modified. Section 9: Property description for optional properties was added. Page 6 of 7

16 MATERIAL SAFETY DATA SHEET 3M ESPE OMNI CONTROLRX DENTIFRICE 03/19/10 Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guidelines data source legend was added. Section 10.1 Conditions to avoid was added. Section 10.2 Materials to avoid was added. Section 6: Release measures information was added. Section 10: Materials to avoid physical property was added. Section 10: Conditions to avoid physical property was added. Section 6: Release measures information was deleted. Section 10: Materials and conditions to avoid physical property was deleted. Section 8: Exposure guidelines information - none - was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at Page 7 of 7

17 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/09 Material Safety Data Sheet Copyright, 2009, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M ESPE OMN PERIOMIX MIXING SOLUTION MANUFACTURER: 3M DIVISION: 3M ESPE Dental Products ADDRESS: 3M Center St. Paul, MN Issue Date: 09/16/09 Supercedes Date: 01/11/08 Document Group: EMERGENCY PHONE: or (651) (24 hours) Product Use: Intended Use: Specific Use: Dental Product Mixing Solution for use in combination with PerioMed. SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER GLYCERIN POLYETHYLENE-POLYPROPYLENE GLYCOL VANILLAMINT FLAVOR Mixture < 1 SODIUM SACCHARIN < 0.1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Odor consistent with flavoring, Clear General Physical Form: Liquid Immediate health, physical, and environmental hazards: anticipated. No immediate health, physical, or environmental hazards Page 1 of 7

18 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/ POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL 5.2 EXTINGUISHING MEDIA Page 2 of 7

19 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/09 Non-combustible. Choose material suitable for surrounding fire. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: (SCBA). Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line ( ) for more information on handling and managing the spill. Contain spill. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Avoid prolonged or repeated skin contact. Wash hands after handling and before eating. 7.2 STORAGE Store in a cool, dry place. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection Avoid eye contact Skin Protection Avoid prolonged or repeated skin contact. Gloves not normally required Respiratory Protection Not applicable. Page 3 of 7

20 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/ Prevention of Swallowing Do not ingest. Wash hands after handling and before eating. 8.3 EXPOSURE GUIDELINES None Established SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Liquid Odor, Color, Grade: Odor consistent with flavoring, Clear General Physical Form: Liquid Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point >=212 ºF Density 1 g/ml Vapor Density Vapor Pressure Specific Gravity ph Melting point Solubility in Water <=18 mmhg 1 [Ref Std: WATER=1] Complete SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition During Combustion During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Page 4 of 7

21 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/09 SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Since regulations vary, consult applicable regulations or authorities before disposal. Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LE-F , Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS STATE REGULATIONS CHEMICAL INVENTORIES This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the FDA. Page 5 of 7

22 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/09 INTERNATIONAL REGULATIONS This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Reason for Reissue: Added/Deleted stock numbers. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Copyright was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Skin protection phrase was modified. Section 8: Prevention of swallowing information was modified. Page Heading: Product name was modified. Sections 3 and 9: Odor, color, grade information was modified. Section 1: Initial issue message was modified. Section 14: ID Number(s) Template 1 was modified. Sections 3 and 9: Specific physical form information was added. Sections 3 and 9: Specific physical form heading was added. Section 16: Reason for reissue heading was added. Section 16: Reason for reissue phrase was added. Section 14: ID Number Heading Template 1 was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a Page 6 of 7

23 MATERIAL SAFETY DATA SHEET 3M ESPE OMN PERIOMIX MIXING SOLUTION 09/16/09 particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at Page 7 of 7

MATERIAL SAFETY DATA SHEET 12115/ SERIES 3M ESPE CLINPRO % SODIUM FLUORIDE 5000 ppm F- DENTIFRICE 02/01/11

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