AR No. IR No. EIELSON AFB ALASKA. Administrative Record Cover Sheet NOTES:

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1 AR No. IR No. EIELSON AFB ALASKA NOTES: Administrative Record Cover Sheet

2 THE UNITED STATES AIR FORCE INSTALLATION RESTORATION PROGRAM SITE SAFETY AND HEALTH PLAN for SS67 and WP45/SS57 EIELSON AIR FORCE BASE, ALASKA Prepared for: Air Force Civil Engineer Center Contract No. W911KB-11-D-0005 Final November 2012

3 THE UNITED STATES AIR FORCE INSTALLATION RESTORATION PROGRAM SITE SAFETY AND HEALTH PLAN for SS67 and WP45/SS57 EIELSON AIR FORCE BASE, ALASKA Prepared for: Air Force Civil Engineer Center Contract No. W911KB-11-D-0005 Final November 2012

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6 TABLE OF CONTENTS SECTION PAGE ACRONYMS AND ABBREVIATIONS...v 1.0 INTRODUCTION AND PURPOSE PROJECT PURPOSE AND SCOPE SAFETY AND HEALTH POLICY STATEMENT ORIENTATION AND TRAINING BASIC OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION TRAINING First-Aid and Cardiopulmonary Resuscitation Training Bloodborne Pathogen Training SITE-SPECIFIC HEALTH AND SAFETY TRAINING Hearing Protection Training Respiratory Protection Training Personal Protective Equipment Hazard Communication DAILY SAFETY MEETINGS VISITOR TRAINING General Requirements Training Requirements Additional Visitor Requirements SITE SANITATION DISCIPLINARY ACTIONS SPECIAL MEDICAL TRAINING SUPPLEMENTAL TRAINING MEDICAL SURVEILLANCE PROGRAM MEDICAL SURVEILLANCE EMPLOYEE CONSULTATIONS SUBCONTRACTOR PERSONNEL SS67 AND WP45/SS57 GENERAL PROJECT TASKS PLANNED FIELD ACTIVITIES MULTI INCREMENT and Surface-Water Sampling I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc i HTRW-J07-05F45701-J FINAL 11/7/2012

7 TABLE OF CONTENTS (Continued) SECTION PAGE Soil Borings Monitoring Well Installation Soil Vapor Sampling SS67 AND WP45/SS57 HAZARD ELEMENTS Wildlife Uneven Terrain and Ice Weather Conditions Chemical Hazards Utility Lines Lifting and Moving Heavy Equipment Traffic Fire and Hot Work Garrison Slough and Other Water Bodies Debris Earthquakes Noise Protection Cold and Heat Stress Darkness During Winter Work Hand and Power Tools Wet Feet Bloodborne Pathogens PROJECT ORGANIZATION AND RESPONSIBILITIES SITE MANAGER HEALTH, SAFETY, AND ENVIRONMENT RESPONSIBILITIES SITE SAFETY AND HEALTH OFFICER RESPONSIBILITIES EMPLOYEE RESPONSIBILITIES (JACOBS AND SUBCONTRACTOR) SUBCONTRACTOR RESPONSIBILITIES VISITOR RESPONSIBILITIES SAFE PLANS OF ACTION I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc ii HTRW-J07-05F45701-J FINAL 11/7/2012

8 TABLE OF CONTENTS (Continued) SECTION PAGE 7.0 HEALTH, SAFETY, AND ENVIRONMENTAL PROCEDURES AND STANDARD OPERATING PROCEDURES AIR MONITORING PLAN PERSONAL PROTECTIVE EQUIPMENT HEARING PROTECTION EYE PROTECTION PROTECTIVE CLOTHING LEVELS OF PERSONAL PROTECTIVE EQUIPMENT Modified Level D Level C SITE CONTROL SITE CONTROL PROCEDURES WORK ZONES BUDDY SYSTEM COMMUNICATIONS SITE SAFETY AND SECURITY EQUIPMENT AND VEHICLE DECONTAMINATION PERSONNEL DECONTAMINATION WASTE HANDLING AND DISPOSAL INSPECTIONS SITE INSPECTIONS / SAFETY EVALUATION EQUIPMENT INSPECTIONS Vehicle Inspections Daily/Shift Inspections and Tests SAFETY OBSERVATION REPORTS SAFE PLAN OF ACTION ASSESSMENT EMERGENCY PROCEDURES HOSPITAL ROUTE EMERGENCY COMMUNICATION EMERGENCY MEDICAL TREATMENT I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc iii HTRW-J07-05F45701-J FINAL 11/7/2012

9 TABLE OF CONTENTS (Continued) SECTION PAGE 12.4 INCIDENT AND ACCIDENT REPORTING EPOSURE TO BLOODBORNE PATHOGENS EARTHQUAKE EVACUATION SPILL OR RELEASE PROCEDURES REFERENCES TABLES Table 5-1 Project Organization Table 8-1 Air Monitoring Requirements and Action Levels for WP45/SS ATTACHMENTS Attachment A-1 Attachment A-2 Attachment A-3 Attachment A-4 Attachment A-5 Attachment A-6 Attachment A-7 Attachment A-8 Attachment A-9 Project-Specific Contacts and Maps Hazard Communication Program Hazards Associated with the Contaminants of Potential Concern Activity Hazard Analysis Project-Specific Forms Health, Safety, and Environmental Procedures and Policies (on CD) Material Safety Data Sheets Alaska Department of Labor Physical Agent Data Sheets Response to Comments I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc iv HTRW-J07-05F45701-J FINAL 11/7/2012

10 ACRONYMS AND ABBREVIATIONS ADEC AFB AFCEC AHA CFR COPC DCE DRO GRO HAZWOPER HSE HSEP HSM IDW Jacobs LNAPL MI MIP MSDS OFR OSHA PADS PCB PID PM POL PPE ppm SM SOR SPA Alaska Department of Environmental Conservation Air Force Base Air Force Civil Engineer Center Activity Hazard Analysis Code of Federal Regulations contaminant of potential concern cis-1,2-dichloroethylene diesel-range organics gasoline-range organics Hazardous Waste Operations and Emergency Response Health, Safety, and Environment Health, Safety, and Environmental Procedure Health and Safety Manager investigation-derived waste Jacobs Engineering Group Inc. light nonaqueous-phase liquid MULTI INCREMENT (a registered trademark of EnviroStat, Inc.) membrane interface probe Material Safety Data Sheet Office of the Federal Register Occupational Safety and Health Administration Physical Agent Data Sheet polychlorinated biphenyl photoionization detector Project Manager petroleum, oil, and lubricants personal protective equipment parts per million Jacobs Site Manager Safety Observation Report Safe Plan of Action I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc v HTRW-J07-05F45701-J FINAL 11/7/2012

11 ACRONYMS AND ABBREVIATIONS (Continued) SSHO Site Safety and Health Officer SSHP Site Safety and Health Plan TBD to be determined TCE trichloroethylene USACE U.S. Army Corps of Engineers UO unexploded ordnance F degrees Fahrenheit I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc vi HTRW-J07-05F45701-J FINAL 11/7/2012

12 1.0 INTRODUCTION AND PURPOSE This Site Safety and Health Plan (SSHP) has been prepared by Jacobs Engineering Group Inc. (Jacobs) for the Air Force Civil Engineer Center (AFCEC) for field activities related to the SS67 and WP45/SS57 source areas at Eielson Air Force Base (AFB), Alaska. This work, scheduled to begin in late 2012, will be performed under Contract No. W911KB-11-D-0005, Task Order 07, administered by the U.S. Army Corps of Engineers, Alaska District (USACE). This SSHP governs the conduct of the work described in the Quality Assurance Project Plan Remedial Investigation Source Area SS67 (Air Force Center for Engineering and the Environment [AFCEE] 2012a) and the Quality Assurance Project Plan Supplemental Remedial Investigation Source Areas WP45/SS57 (AFCEE 2012c) prepared by EA Engineering, Science, and Technology, Inc. The overall purpose of this SSHP is to create a site health and safety program that effectively identifies, evaluates, controls, and reduces health and safety hazards. This SSHP discusses issues and procedures to be followed during mobilization, fieldwork, and demobilization. This SSHP is written to comply with applicable sections of the Code of Federal Regulations (CFR), Title 29, Sections 1904, and ; Office of the Federal Register (OFR) Hazardous Waste Operations and Emergency Response (OFR 2005); and the U.S. Army Corps of Engineers (USACE) Safety and Health Requirements Manual EM (USACE 2008). The Health and Safety Manager (HSM) and the Site Safety and Health Officer (SSHO) are required to be familiar with the following information: Applicable federal, state, and local regulations Health, Safety, and Environmental Procedures (HSEP) developed by Jacobs (to be available onsite) Procedures contained in the work plans for this project (AFCEE 2012b and 2012c) Requirements found in the USACE EM Safety and Health Requirements Manual (USACE 2008) This SSHP will be reviewed and updated as necessary to reflect current site conditions and operations. Modifications due to changing field conditions will require approval of individuals identified in Section 5.0. Copies will be made available to all personnel at the job site. Each supervisor, lead person, laborer, operator, and visitor will be held accountable and I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 1-1 HTRW-J07-05F45701-J FINAL 11/7/2012

13 responsible for working safely and following procedures and guidance set forth in this SSHP. The SSHO will be responsible for the onsite implementation of this SSHP. 1.1 PROJECT PURPOSE AND SCOPE This SSHP addresses activities to be conducted at SS67 and WP45/SS57 The scope of work includes characterization of sediment contamination at SS67 and characterization of soil, groundwater, and soil vapor contamination at WP45/SS57. Work will include sediment/soil/groundwater/soil vapor sampling, advancing borings, installation of monitoring wells, and screening with a membrane interface probe (MIP). These activities are discussed in detail in the work plans (AFCEE 2012b and 2012c). I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 1-2 HTRW-J07-05F45701-J FINAL 11/7/2012

14 1.2 SAFETY AND HEALTH POLICY STATEMENT Jacobs obligation is to provide a safe and secure work environment. It is our goal to take safety to the next level BeyondZero. Below is the Jacobs Corporate Safety Mission Statement. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 1-3 HTRW-J07-05F45701-J FINAL 11/7/2012

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16 2.0 ORIENTATION AND TRAINING Prior to the start of activities, all personnel working on this project and any new person visiting or conducting work on this project shall be briefed on this SSHP. Personnel shall commit to following applicable procedures by signing the Site Project Safety and Health Agreement Sign-Off Sheet (Attachment A-5, Exhibit 1), indicating they have been briefed and understand the requirements contained in this SSHP. Personnel assigned to or regularly entering the project site shall have received the training required in accordance with 29 CFR and other Occupational Safety and Health Administration (OSHA) regulations, as listed in this section. 2.1 BASIC OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION TRAINING General site workers must have completed the 40-hour Hazardous Waste Operations and Emergency Response (HAZWOPER) training course. Onsite management personnel must have an additional 8 hours of specialized supervisory training. Workers must have initial training or completed refresher training (8 hours) within the past 12 months. Training will be documented First-Aid and Cardiopulmonary Resuscitation Training At least two onsite employee will be currently certified in first-aid and cardiopulmonary resuscitation, with training equivalent to that provided by the American Red Cross Bloodborne Pathogen Training Personnel trained in first-aid and expected to administer first-aid will receive training in controlling exposures to bloodborne pathogens. This training will address the following topics: Bloodborne pathogen standards Description of the risks of exposure and how bloodborne pathogens are transmitted Management and employee responsibilities I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 2-1 HTRW-J07-05F45701-J FINAL 11/7/2012

17 Protection methods against exposure and decontamination procedures Post-exposure procedures Labeling and color-coding of infectious waste 2.2 SITE-SPECIFIC HEALTH AND SAFETY TRAINING Site-specific health and safety training will be conducted prior to field activities at each site. In particular, the training will stress emergency response procedures and will cover the chemical, biological, and physical hazards of the site and site operations Hearing Protection Training Site personnel with the potential for exposure to noise levels exceeding 85 decibels will be provided with training that addresses the following topics: Physical and psychological effects of high noise exposure Noise exposure limits Selection, use, and limitations of hearing protection devices Respiratory Protection Training In accordance with 29 CFR , all site personnel required to use respiratory protection devices will have received equipment-specific training. This training covers the use, limitations, inspection, maintenance, and cleaning of respiratory protection devices required for use under the conditions of this SSHP. Site-specific briefing/training will reinforce knowledge as necessary Personal Protective Equipment In accordance with OSHA 29 CFR 1910, Subpart I (Personal Protective Equipment [PPE]), PPE will be provided, used, and maintained in a sanitary and reliable condition. PPE will be of construction, design, and material to provide employees protection against known or anticipated hazards. PPE will be selected that properly and appropriately fits the employee. See Section 9.0 for a discussion of PPE requirements. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 2-2 HTRW-J07-05F45701-J FINAL 11/7/2012

18 2.2.4 Hazard Communication In order to comply with 29 CFR , Hazard Communication, the Hazard Communication Program (Attachment A-2) has been established. Employees will be briefed on this program and will be provided with a physical copy for review. 2.3 DAILY SAFETY MEETINGS Each day, a safety tailgate meeting for onsite employees (Jacobs, subcontractors, and government employees) will be conducted prior to beginning work. The safety tailgate meeting will identify potential hazards and risks that may be encountered during that day s activities. Additional discussions in the use of safety equipment, emergency medical procedures, emergency assistance notification procedures, Safety Observation Reports (SOR) (Attachment A-5), and accident prevention will serve to ensure that the work can and will be carried out in a safe and effective manner. The safety tailgate sign-in sheet (in Attachment A-5) will be used to document the meeting. 2.4 VISITOR TRAINING Site visitors are defined as persons who are not employed at the project site, who do not routinely enter restricted work areas, or whose presence is of short duration (e.g., 1 to 2 days at one time or one time per month). Visitors may include client personnel, Jacobs personnel, commercial vendors, political representatives, and auditors or inspectors from local, district, or federal agencies. Visitors shall be escorted at all times unless they meet the training requirements set forth in Section General Requirements The following requirements apply to visitors whose purpose is to observe site conditions or field activities without entering the exclusion zone: The SSHO will be notified of the nature and duration of the visit before visitors are permitted to enter the site. The visitors log will be completed, including the individual s name, date, and the name of the company or agency represented. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 2-3 HTRW-J07-05F45701-J FINAL 11/7/2012

19 The site visitor will be escorted by a Jacobs representative at all times while in the area. Visitors will comply with specific health and safety requirements, as applicable Training Requirements Visitors will receive site-specific training to ensure that potential hazards and risks are identified. This training will consist of a safety briefing by the SSHO that will include: Location and description of potential hazards and risks Required PPE Areas of the site that are closed to visitors The site evacuation plan and emergency procedures Hazard communication Other topics as deemed appropriate Additional Visitor Requirements Site visitors wishing to enter an exclusion zone during site operations will be subject to the same medical surveillance and OSHA training requirements as assigned site personnel. Documentation of training and medical surveillance will be presented to the SSHO prior to entry into the exclusion zone. 2.5 SITE SANITATION Regular housekeeping will occur regularly to provide a clean and uncluttered work environment. Drinking water will be available onsite for consumption by field personnel. Toilets will be either present on site or transportation to an offsite toilet facility will be provided as the site is normally an unattended location. 2.6 DISCIPLINARY ACTIONS If an employee fails to comply with established safety rules and regulations as presented in this SSHP, or corporate policies and procedures, the individual will be subject to the disciplinary actions outlined in the Jacobs personnel policy manual, which may include any of the following actions: I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 2-4 HTRW-J07-05F45701-J FINAL 11/7/2012

20 Verbal warning Written warning Suspension with or without pay Termination of employment The seriousness of the safety infraction and the frequency or past history of the employee s safety violations shall be considered in determining the appropriate disciplinary action. 2.7 SPECIAL MEDICAL TRAINING Special medical training is not anticipated for this project. Such training will be evaluated, as necessary, for each work assignment. 2.8 SUPPLEMENTAL TRAINING Supplemental training is not anticipated for this project. Such training will be evaluated, as necessary or as required because of changes in site conditions. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 2-5 HTRW-J07-05F45701-J FINAL 11/7/2012

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22 3.0 MEDICAL SURVEILLANCE PROGRAM Jacobs will use the services of an occupational physician with specialized training in occupational medicine to oversee the implementation of the medical monitoring program. The HSM or a designee will coordinate with the occupational physician to ensure that the necessary information is communicated concerning the operations to be performed, PPE requirements, and medical monitoring results. Jacobs will rely on the occupational physician to determine the medical examination and surveillance requirements. 3.1 MEDICAL SURVEILLANCE Each Jacobs employee is responsible for completing a monthly Hazardous Material Exposure and Field Activity Report and for notifying management if an incident or exposure occurs. Jacobs Anchorage Health and Safety Office ensures distribution of blank forms to appropriate employees, collects completed forms, and forwards completed forms to Corporate HSE for review and retention. Field personnel shall participate in a medical surveillance program. Field workers will provide the SSHO documentation (e.g., a physician s letter) of their participation in the medical program and evidence that they are current. Workers with medical limitations, as well as employers of subcontract employees, are responsible for notifying the SSHO of said limitations so work tasks will be appropriately assigned. Section 2.0 presents additional OSHA and site-specific health and safety training requirements. 3.2 EMPLOYEE CONSULTATIONS Each person in the medical surveillance program will receive a summary letter from the physician reporting the results of her/his physical. This letter will confirm that an individual is physically qualified to work on the project or will identify the reasons why the individual is not qualified. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 3-1 HTRW-J07-05F45701-J FINAL 11/7/2012

23 3.3 SUBCONTRACTOR PERSONNEL Subcontractors are required to submit certification of training and medical clearance for all personnel prior to mobilization. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 3-2 HTRW-J07-05F45701-J FINAL 11/7/2012

24 4.0 SS67 AND WP45/SS57 GENERAL PROJECT TASKS The SS67 and WP45/SS57 sites area located on Eielson AFB, approximately 24 miles southeast of Fairbanks, Alaska. SS67 is a portion of Garrison Slough that flows from the southern portion of Eielson AFB northward eventually exiting across the northern boundary of Eielson AFB. The SS67 portion of Garrison Slough passes through the developed portion of the base near Building 2350 and is predominantly channelized. WP45/SS57 is located in the central, developed portion of Eielson AFB adjacent to the main taxiway and encompasses an area of approximately 11 acres. 4.1 PLANNED FIELD ACTIVITIES Fieldwork is anticipated to begin in November The two sites share several safety requirements due to similar environmental and weather conditions. Workers must be familiar with work in cold weather, the equipment to be used, and must wear appropriate PPE, including hard hats, safety glasses, gloves, high-visibility safety vests, and safety-toe boots. For site SS67, fieldwork will consist of collecting MULTI INCREMENT (MI) sediment samples and surface-water samples to evaluate contamination by polychlorinated biphenyls (PCB), organochlorine pesticides, and mercury. For site WP45/SS57, fieldwork will consist of subsurface screening, drilling to obtain soil cores and install monitoring wells, and soil, groundwater, and soil vapor sampling to evaluate trichloroethylene (TCE), cis-1,2-dce, and benzene contamination MULTI INCREMENT and Surface-Water Sampling Planned activities include collection of 40 MI samples and 3 surface-water samples. Sampling will involve use of survey equipment and hand tools to locate and collect sediment and soil samples from surface and near-surface sediment. In 1997, an item of unexploded ordnance (UO) was identified at SS67 and removed. A subsequent geophysical survey in 2007 did not identify any additional UO. Any metal debris identified by the geophysical survey was removed. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-1 HTRW-J07-05F45701-J FINAL 11/7/2012

25 Prior to site work, reporting on the UO removal and the subsequent geophysical survey will be reviewed by a UO technician and a geophysicist in relation to HSEP 9.5 Unexploded Ordnance (included in Attachment A-6) to determine whether additional surveying is needed Soil Borings Planned soil borings are be drilled at 20 locations. Workers will follow the procedures outlined in this SSHP for work around heavy equipment (Section 4.2.7) Monitoring Well Installation Planned monitoring wells will be installed at 26 locations to 25 to 300 feet below ground surface (bgs) to extend the current monitoring network. Workers will follow the procedures outlined in this SSHP for work around heavy equipment (Section 4.2.7) Soil Vapor Sampling To evaluate the potential for vapor intrusion, five indoor, five outdoor, and five sub-slab soilgas samples are planned. Ground-penetrating radar will be used to check for utilities before installing sub-slab sampling points. 4.2 SS67 AND WP45/SS57 HAZARD ELEMENTS The following potential hazards associated with work at SS67 and WP45/SS57 have been identified: Wildlife Uneven terrain and ice Weather conditions Chemical hazards Utility lines Lifting and moving Heavy equipment Traffic I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-2 HTRW-J07-05F45701-J FINAL 11/7/2012

26 Fire Garrison Slough and other water bodies Debris Earthquakes Noise Cold and heat stress Darkness during winter work Hand and power tools Wet feet Bloodborne pathogens Wildlife Large mammals such as bear and moose as well as smaller mammals may be found in the area. These animals are not accustomed to human presence. Prudence should be exercised in any potential animal encounter. Workers will maintain a safe distance from wild animals, and avoid surprising them. When a bear is sighted, workers will calmly contact the SSHO, Jacobs Site Manager (SM), and/or co-workers in the area as soon as possible. Workers will be familiar with and follow HSEP 7.4 Working Safely around Wild Animals (in Attachment A-6) Uneven Terrain and Ice Work at SS67 will involve walking on wetland terrain that may be hummocky and difficult to traverse. Developed terrain at both sites may have hidden obstacles. During the winter months, ice may be encountered due to changing weather conditions, stream overflow, spilled water, and other reasons. Regardless of the terrain, caution must be taken when traversing areas by foot. The specific terrain should be considered when generating safe plans of action (SPA) for project tasks. Efforts will be made to use existing paths and trails when possible. Strap-on traction aids and/or traction sand may be needed to mitigate ice hazards. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-3 HTRW-J07-05F45701-J FINAL 11/7/2012

27 4.2.3 Weather Conditions Due to the potential for rapidly changing weather in Alaska, personnel should be fully advised of the need to dress warmly and in layers with a waterproof and/or windproof outer shell, as appropriate. Insulated safety footwear will be required for winter work. The need for adequate clothing will be discussed at project planning meetings and site safety orientations. Another hazard of the rapidly changing weather is that of electrical storms. In accordance with USACE EM , when conditions are such that lightning is observed, all drilling equipment operations shall cease. A period of 30 minutes between subsequent observations shall be observed prior to resuming work. Daily limits for working in windy conditions will be set during the morning safety tailgate meetings and will vary depending on project task, type of wind (gusty or steady), and wind chill factor Chemical Hazards The following chemical contaminants are suspected or known to be present onsite: Trichloroethylene (TCE) cis-1,2-dichloroethylene (DCE) Benzene Polychlorinated biphenyls (PCB) Organochlorine pesticides Mercury Attachment A-3 presents the hazards associated with the contaminant listed above. Attachment A-7 contains Material Safety Data Sheets (MSDS) for the chemical hazards listed above as well as chemicals brought to the site (i.e., gasoline and diesel) and solvents (i.e., methanol) associated with sample preservation. If any additional contaminants are found, the field team will ensure that the appropriate MSDSs are available onsite. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-4 HTRW-J07-05F45701-J FINAL 11/7/2012

28 4.2.5 Utility Lines Utility lines including electric, communication, water, and sewer may be present in drilling areas. These features will be located prior to commencing any drilling or other intrusive activities. If utilities are identified in the area, Jacobs HSEP Utility Clearance (in Attachment A-6) will be followed Lifting and Moving Using proper technique to lift and move heavy pieces of equipment is important to reduce the potential for back injury. The following precautions should be implemented when lifting or moving heavy objects: If mechanical devices are not available, ask another person to assist you. Bend at the knees, not the waist. Let your legs do the lifting. Do not twist while lifting. Bring the load as close to you as possible before lifting. When carrying heavy objects, be sure the path you are taking is free of obstructions and all slip, trip, and fall hazards. Use mechanical devices to move objects, investigation-derived waste (IDW), or generators that are too heavy to be moved manually Heavy Equipment Working around drilling equipment is one of the more significant hazards associated with activities at WP45/SS57. This section addresses the general safety procedures to apply while working around heavy equipment. Before any machinery or mechanized equipment is used, it will be inspected and certified to be in safe operating condition. Jacobs will designate a competent person to be responsible for the daily inspection of all machinery and equipment. Only designated and qualified personnel will operate machinery and mechanized equipment. Equipment deficiencies that affect safe operation will be corrected prior to continuing operation. The SM will determine the competent operator prior to the start of any heavy-equipment operations. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-5 HTRW-J07-05F45701-J FINAL 11/7/2012

29 4.2.8 Traffic Personnel will exercise vigilance to avoid vehicles and make eye contact with operators when working or passing nearby. If work will be conducted within a road right-of-way, a specific traffic control plan will be generated according to the Manual on Uniform Traffic Control Devices for Streets and Highways (U.S. Department of Transportation [DOT] 2009) Fire and Hot Work Fire extinguishers (Type ABC or BC) will be provided for each vehicle used onsite that are less than 5 years old and will be inspected prior to placement in a vehicle. Smoking is prohibited on the job site. Flammable and combustible liquids (such as fuel) will be stored in approved (OSHA and National Fire Protection Association Code 30) containers. A safety can or approved system will be used for dispensing flammable or combustible liquids; it will be stored in flammable storage cabinets or appropriate storage areas separated from occupied buildings. Flammable material will be separated from oxidizers by at least 20 feet. Vehicle fueling tanks will be grounded, and there will be bonding between the tank and vehicle being fueled. Spills will be cleaned up immediately and then reported, and wastes will be disposed of properly. Hot work (e.g., welding, brazing, high-speed grinding, and warming tooling with a weed burner) will require a permit issued in accordance with the Eielson AFB Fire Prevention Program. Permit issuers must be trained by the Fire Prevention Program. Call the Fire Prevention Program at to arrange for training Garrison Slough and Other Water Bodies Personnel entering Garrison Slough will exercise extreme caution. The work area along the slough is a low-lying area next to a channelized water course generally about 1 foot deep. Hummocky terrain with dead vegetation may cover low spots, increasing the danger of slips, trips, and falls. The nearby water course presents a risk of hypothermia during work in the winter months if a person falls in. If the water course is frozen over, personnel will not move I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-6 HTRW-J07-05F45701-J FINAL 11/7/2012

30 out onto the ice where there is a chance that the water beneath may be more than a few inches deep. Summer sediment sampling may encompass stretches of the Chatanika River, Piledriver Slough, the Chena River, and/or another body of water to be identified in the final Quality Assurance Project Plan for SS67. Such work will be guided by Jacobs HSEP 15.3 Work Over or Adjacent to Water (in Attachment A-6). Near-shore sediment sampling in water up to about 1 foot deep while wearing waders is probable. Key safety features of such work include wearing an appropriate personal flotation device, avoiding areas of strong current, having a throwable rescue line, and using the buddy system. If work over water is necessary (e.g., from a small boat), a detailed activity hazard analysis (AHA) for that activity will be developed before mobilizing for that work Debris Sharp objects including glass, metal, and wood debris may be present around the sites and near several of the off-site monitoring wells. Employees should be cognizant of these potential hazards and mitigate them as they are identified Earthquakes Earthquakes are the most likely natural disaster on Eielson AFB. Personnel will be familiar with the emergency evacuation routes and contacts provided in Attachment A-1. Muster points and procedures will be covered at site-specific safety orientations and reviewed periodically during daily safety tailgate meetings. After the earthquake has subsided, contact the Jacobs Anchorage home office and inform them of the status of the team Noise Protection Noise in excess of 85 decibels is expected during use of drill rigs, soil borings, and monitoring well installation. Foam ear plugs and ear muffs will be available. Employees should be cognizant of these potential hearing hazards via the AHA/SPA process and mitigate them as necessary. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-7 HTRW-J07-05F45701-J FINAL 11/7/2012

31 Cold and Heat Stress The SS67 and WP45/SS57 sites are located in the interior near Fairbanks, Alaska. Early winter temperatures average -2 to +12 degrees Fahrenheit ( F) with extremes of -45 to +49 F, and winter storms can bring wind and precipitation. Employees should be aware of the fluctuations in climatic conditions and dress themselves in the appropriate clothing beneath their PPE, including but not limited to thermal underwear, hats, gloves, jacket, insulated safety-toe boots, and other winter gear. During summer work, ambient temperatures above 80 F are common. Employees wearing impervious coveralls, Tyvek suits, or similar protective equipment should be aware of the potential risk of heat stress. When ambient air temperature falls below 30F or above 80F, the SSHO will monitor and recommend work/rest regimens to the SM. Work/rest regimens will be based upon the guidelines in the Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices (American Conference of Government Industrial Hygienists 2006). Additional guidance is provided by Jacobs HSEPs 11.4 Cold Stress Control and Heat Stress Control (in Attachment A-6) Darkness During Winter Work Artificial lighting will be needed during morning and afternoon hours for outdoor work. As a point of reference, on 1 December, sunrise is at 10:17 and sunset is at 14:58, providing 4 hours 41 minutes of relatively strong illumination, and twilight provides an additional 2 hours and 30 minutes of weaker light. Artificial lighting includes personal light-emitting diode headlamps, battery- or propane-powered lanterns, light plants powered by diesel generators, and similar devices. To maximize worker visibility in darkness, upper-body outerwear will include reflective strips. For winter work, the base color of the outerwear may be black (most visible against snow) or high-visibility yellow, orange, or pink. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-8 HTRW-J07-05F45701-J FINAL 11/7/2012

32 Hand and Power Tools Tools shall be inspected and in good working condition prior to being brought onto the project site. The use of power tools may be required during fieldwork. The proper tool should always be selected for the specific task. Shields, guards, and other safety mechanisms should always be left in place and operational. Use of power tools will be in accordance with the operating manual and manufacturer s instructions. Tools will be inspected prior to use to protect against breakage and potential injury Wet Feet Personnel entering Garrison Slough may wear rubber boots or waders (safety toes not required). This footwear should be inspected prior to use for absence of leaks and proper fit Bloodborne Pathogens Employees shall minimize the risk of exposure to bloodborne pathogens by practicing a combination of good personal hygiene, proper PPE, and safe work practices. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 4-9 HTRW-J07-05F45701-J FINAL 11/7/2012

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34 5.0 PROJECT ORGANIZATION AND RESPONSIBILITIES This section identifies project organization and personnel responsibilities for the management and implementation of this SSHP. It is the responsibility of each person to ensure that project personnel comply with safety rules and requirements. The following assignments have been established to assist with the maintenance of a safe project site: Table 5-1 Project Organization Organization Title Name Telephone USACE Contracting Officer s Representative Scott Kendall USACE Project Manager Meseret Ghebresllassie AFCEC Project Manager Pat Roth USAF Program Coordinator Kelly McGovern Project Manager Kevin Maher Health and Safety Manager Randall Jones Site Manager Sarah Belway Jacobs Site Safety and Health Officer* TBD Technical Lead Katie Bloom Project Geologist Dave Ward Lead Sampler Ida Petersen Project Chemist David Summerville Note: TBD = to be determined *SSHO resume and qualifications will be provided to USACE for review. The Jacobs Project Manager (PM) has overall responsibility for coordinating with the HSM to ensure that the project assignment goals are completed in a manner consistent with this SSHP. The SM or SSHO will be the on-site designated competent persons while work is occurring. 5.1 SITE MANAGER HEALTH, SAFETY, AND ENVIRONMENT RESPONSIBILITIES The SM shall have completed training outlined in Section 2.0 Orientation and Training. The SM has the following responsibilities: Understand Jacobs Health, Safety, and Environment (HSE) policies and procedures and this SSHP. Site management may, if the need arises, apply additional HSEPs or more stringent work practices. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 5-1 HTRW-J07-05F45701-J FINAL 11/7/2012

35 Effectively communicate and implement HSE policies and procedures, and the information contained within this SSHP. Provide the resources necessary to maintain a safe and healthful work environment and ensure implementation of HSE policies and procedures. Assign clear responsibilities to achieve a safe and healthful work environment. Verify that subordinates and subcontractors are executing these responsibilities properly. Enforce HSEPs and issue disciplinary actions and/or contractual actions when required. Ensure that HSE deficiencies identified in audits and inspections are promptly corrected. Implement Jacobs BeyondZero process. 5.2 SITE SAFETY AND HEALTH OFFICER RESPONSIBILITIES The SSHO reports administratively to the SM and functionally to the Jacobs Alaska Operations HSM. The credentials of the SSHO will be submitted for USACE review. As a member of the site management staff, the SSHO has the following responsibilities: Support and advise site management in its duty to implement HSE policies and procedures. Ensure the adequacy of Jacobs HSEPs to address site hazards. Assess compliance with HSE policies and procedures, promptly communicating concerns and recommendations to the SM for action. Take immediate action on any imminent danger observed. Review and approve PPE, safety equipment, and first-aid supplies. Educate site management in the application of HSE policies and procedures. Ensure HSE orientation of site employees and subcontractor personnel. Ensure prompt and adequate treatment for injured employees and subcontractor personnel. Ensure adequate investigation and analysis of accidents and incidents (non-injury and injury). Provide HSE information for the education of management, supervision, and employees concerning: - Accident analysis (cause, trends, results, and corrective action); - Analysis of inspection results and needed corrective actions; - Safe work procedures; and - HSE training requirements. Communicate and promote HSE excellence recognition programs. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 5-2 HTRW-J07-05F45701-J FINAL 11/7/2012

36 Ensure preparation, submittal, and/or maintenance of required HSE recordkeeping documentation such as inspection reports, training records, SPAs, SORs, injury logs, and accident investigation reports. Provide HSE evaluations of employees and supervisors to management as requested. 5.3 EMPLOYEE RESPONSIBILITIES (JACOBS AND SUBCONTRACTOR) Employee acceptance of the HSE policies and procedures is the ultimate key to success of the HSE program. Each Jacobs and subcontractor employee has the following responsibilities: Comply with procedures established for his/her safety and health and for preservation of the environment. Assist management and supervision in the positive development of coworker attitudes toward HSE and workplace morale. Suggest improvements in methods or procedures to prevent incidents and protect the environment. Stop, or bring attention to management, any unsafe acts or conditions and any potentially harmful environmental practices. Immediately correct imminent danger situations (e.g., exposure to falls from elevations, electrocution hazards, exposure to unprotected excavations). Notify supervisor when there is insufficient understanding of: - Task(s) to be performed; - HSEPs; or - Assigned safety equipment. Promptly report to supervisor personnel or property incidents or accidents, no matter how minor. Learn the approved HSE safe practices for each work task and practice them. Ask for assistance from the supervisor or the HSE department when unsure of a work task or its safe practice. Participate in and maintain an active interest in the HSE program. Be attentive to safety discussions led by the supervisor and request explanations of points not understood. Never bypass the function of a safety device. Immediately flag safety device malfunctions to warn others of the hazard and promptly report the malfunction to the appropriate supervisor. Promptly report any potential work-related injury or illness to the appropriate supervisor, no matter how minor the injury. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 5-3 HTRW-J07-05F45701-J FINAL 11/7/2012

37 Never attempt to perform a job alone when good judgment indicates assistance is needed. Inspect, use, and maintain the PPE provided. Never participate in clowning, scuffling, practical joking, or horseplay of any kind on the job. Be cautious in walking or moving around the work area to avoid slips, trips, or falls. Be especially cautious when weather conditions create a potentially slippery walking surface. Running is prohibited. Plan work and try to anticipate all potential hazards. Observe safe practices off the job as well as on the job. 5.4 SUBCONTRACTOR RESPONSIBILITIES Subcontractors shall perform the following specific duties: Follow the requirements set forth in this SSHP. Attend Supervising for Safety training, preferably at Jacobs prior to mobilization, but at a minimum before site work commences. Attend a site-specific orientation. Agree to abide by this SSHP by signing the Site Project Safety and Health Agreement Sign-Off Sheet (Attachment A-5, Exhibit 1) before working onsite. This sign-off sheet will be retained by the SSHO. Provide the SSHO with MSDSs and physical agent data sheets (PADS) copies for any hazardous chemicals brought onsite or physical exposures related to the subcontractor s activities onsite. Provide the SSHO with copies of required training certifications and medical authorizations to work onsite, including those required by 29 CFR (e) and (f) (OFR 2005). Develop SPAs that address specific hazards (e.g., underground utilities, traffic control) associated with tasks to be performed for each phase of work, including developing and providing specific work procedures to Jacobs for review of potential hazards. Ensure that workers are trained in safe and proper use of tools they may use. Appoint an onsite Competent Safety Representative for each job site. Provide necessary PPE to employees and ensure its proper use. Maintain necessary records and submit required reports. Conduct daily safety briefings. Obtain work permits as required. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 5-4 HTRW-J07-05F45701-J FINAL 11/7/2012

38 Conduct safety inspections on a daily basis, report discrepancies using the SOR form, and promptly correct unsafe conditions. Conduct regular inspections of equipment. Defective or unsafe equipment must be immediately repaired or red-tagged and taken out of service. Provide inspection documentation and corrective actions to the SSHO on a daily or other agreed upon basis. Provide subcontract information and subcontractor safety program requirements, as necessary. The SM will inform the subcontractor foreman or leader of any safety and health violations. The SSHO, SM, or any other Jacobs employee can direct the subcontractor to cease work if conditions are imminently dangerous. Work may resume when the unsafe condition is corrected and approved by the SSHO or SM. Repeated violations could cause termination of the subcontract. 5.5 VISITOR RESPONSIBILITIES A visitor entering a controlled area at the site must: Provide the SSHO with copies of required training certifications and medical authorizations, as required by 29 CFR (e) and (f) (OFR 2005); Provide the SSHO with MSDS and PADS copies for any hazardous chemicals brought to the site by the visitor and physical agents caused by the visitor s activities; and Comply with the provisions of this SSHP. Visitors must obtain clearance from the SSHO and sign the visitor check-in log before entering controlled areas. Visitors will receive a job-specific safety briefing and will be escorted at all times in controlled areas. Visitors in areas requiring PPE must have the appropriate training and PPE to gain entry. Jacobs is not responsible for distributing or obtaining PPE for visitors. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 5-5 HTRW-J07-05F45701-J FINAL 11/7/2012

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40 6.0 SAFE PLANS OF ACTION AHAs (Attachment A-4) have been developed in accordance with the USACE Safety and Health Requirements Manual (USACE 2008). These AHAs may not depict actual site conditions. As personnel undertake specific activities, SPAs will be developed after identifying actual site conditions and hazards. The SPA process will verify that protective measures are in place to mitigate incidents and that required resources are available for the specific activities. The SPAs will be developed by all parties involved in the activities (e.g., Jacobs and subcontractor personnel). I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 6-1 HTRW-J07-05F45701-J FINAL 11/7/2012

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42 7.0 HEALTH, SAFETY, AND ENVIRONMENTAL PROCEDURES AND STANDARD OPERATING PROCEDURES This SSHP brings together site- and task-specific corporate procedures (Jacobs HSEPs and project-specific standard operating procedures) and CFR requirements to create a concise and relevant document designed for usability by members of the project team. In case of conflict among the corporate procedures, the most stringent shall apply. The Jacobs HSEPs, located in Appendix D-6 and on JNet, present typical situations and hazards for frequently executed project tasks. HSEPs should be consulted when building an SPA for a task; if an HSEP does not exist, the SPA will require particular attention to detail. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 7-1 HTRW-J07-05F45701-J FINAL 11/7/2012

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44 8.0 AIR MONITORING PLAN Under supervision of the SSHO, air monitoring will be conducted where contaminant-bearing vapors or dust (Section 4.2.4), lead dust, or petroleum, oil, and lubricants (POL) may be present. Table 8-1 provides air monitoring requirements and action levels for the WP45/SS57 site; no breathing hazards are anticipated at the SS67 site. The type and extent of monitoring will depend upon site-specific conditions and the contaminants encountered at the sites. If a change in conditions is observed at either site, additional monitoring may be required. Breathing-zone as well as areal monitoring will be conducted to verify that the field team is using appropriate types and levels of PPE. Air monitoring results will be documented in the field logbooks or on monitoring forms. Monitoring instruments will be calibrated in accordance with manufacturer instructions. Calibrations will be documented in the field logbooks or on calibration forms. Field crews will use a photoionization detector (PID) equipped with a 10.6-electron-volt lamp as the primary method of monitoring. Based on historical monitoring data, the PID is considered protective of site personnel. This method is not considered complete but is the most readily available indicator of organic vapors in the atmosphere. Prior to PID use, background levels must be established by monitoring outside the exclusion zone or controlled area and upwind of the site. The PID reads in units of parts per million (ppm), and the readings should be sustained for one minute to determine exposure. Although the PID method is not sensitive enough to detect harmful levels of benzene, benzene has not been detected directly in the breathing zone at WP45/SS57. If the PID detects organic vapors (readings greater than 1 ppm above background) in the breathing zone at a site where benzene is a known contaminant of concern, the breathing zone shall be tested with a directreading instrument for benzene. If benzene is detected, personnel will wear passive dosimeters and will modify procedures in accordance with Table 8-1. Section 9.4 of this document provides general PPE recommendations and describes the various levels of respiratory protection. The AHAs contained in this SSHP (see Attachment A-4) address the required PPE for potential exposure for specific activities. Conditions that I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 8-1 HTRW-J07-05F45701-J FINAL 11/7/2012

45 exceed action levels in Table 8-1 will require an upgrade of PPE until monitoring demonstrates otherwise. The SSHO, with the assistance of trained field personnel, will identify these conditions. Laboratory analysis will be considered when specific contaminants of concern have been identified, or no other method is available to monitor worker exposure. If samples are to be submitted to a laboratory, a blank sample filter will be submitted for quality control purposes. Results of the monitoring must be communicated to workers formally within 15 working days after receipt of the results. Off-site analysis is not anticipated for this project. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 8-2 HTRW-J07-05F45701-J FINAL 11/7/2012

46 Table 8-1 Air Monitoring Requirements and Action Levels for WP45/SS57 Instrument and Target Gas Tasks Action Levels PPE or Response Frequency 1 Calibration 2 PID for VOCs (except methane), minimum 10.6 electron volts, calibrated with isobutylene All tasks 0-10 ppm breathing zone (check for 1 ppm) ppm breathing zone ppm breathing zone >50 ppm breathing zone Measurements are relative to background Level D Level C Level B; stop and re-evaluate Stop work; reevaluate Monitor the breathing zone at the beginning of operations and whenever site conditions change. Levels C and B require continuous monitoring. Daily Direct-reading instrument or colorimetric tubes for benzene All tasks <5 ppm breathing zone 5-10 ppm breathing zone ppm breathing zone >25 ppm breathing zone Level D, 5 minutes Level C Level B; stop and re-evaluate Stop work; reevaluate Monitor if VOCs are detected in the breathing zone at greater than 1 ppm. Passive dosimeters will be used if benzene is detected. Daily; for tubes. Check the pump for leaks prior to use. Combustible gas meter As required >10% lower explosive limit (Oxygen must be >15 percent for the lower explosive level reading to be accurate.) Stop work; reevaluate (explosion hazard) Continuous monitoring of a confined space. Screening during excavation or before performing hot work if combustible gases could be present in more than trace concentrations. Daily Oxygen meter Confined space entry <19.5% Provide alternate air source (Level B) Screening before entering confined space. Daily >23.5% Explosion hazard, stop work, re-evaluate Notes: 1 Air monitoring shall be documented in field logbooks or on monitoring forms. 2 Calibrations shall be documented in the field logbooks or on calibration forms. Calibrate before first use and check calibration at the end of the day or if readings seem questionable. For definitions, see the Acronyms and Abbreviations section. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 8-3 HTRW-J07-05F45701-J FINAL 11/7/2012

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48 9.0 PERSONAL PROTECTIVE EQUIPMENT Workers are required to protect themselves from chemical and physical hazards, which for this project are described in Sections through In accordance with OSHA 29 CFR 1910, Subpart I (Personal Protective Equipment), appropriate PPE will be provided for each worker, properly sized, and used and maintained in a sanitary and reliable condition. PPE will be of design, material, and construction to protect workers from known or anticipated hazards. In general, field personnel shall wear the following PPE when onsite: Safety glasses with side shields or wrap-around design Hard hat Safety-toed boots High-visibility vest Gloves appropriate for the task Additional PPE (neoprene boots, impervious gloves, Tyvek coveralls) may be required for specific tasks or if conditions change. Additional information is contained in Jacobs HSEPs 13.6 Eye and Face Protection, 13.3 Head Protection, 13.5 Foot Protection, and 13.4 and Protection (all in Attachment A-6). 9.1 HEARING PROTECTION Adequate hearing protection is required in all areas that may expose workers to high levels of noise. This includes work areas around drill rigs and various other forms of noise-generating equipment. Loud noises are considered to be any noise over 85 decibels. From an arm s length away, if you have to raise your voice to be heard, you may need hearing protection. Hearing protection includes one or a combination of the following: Engineering controls (where feasible) Ear plugs Ear muffs I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 9-1 HTRW-J07-05F45701-J FINAL 11/7/2012

49 9.2 EYE PROTECTION Eye protection (safety glasses with side shields or wrap-around design) is required in all work areas. Eye protection may include the following devices: Safety glasses with side protection (basic protection; the minimum required when onsite) Chemical goggles (splash, dust, and foreign-object protection for the eyes) Face shields with safety glasses or goggles (splash, dust, and flying-particle protection for the whole face) Additional details and types of eye protection are described in Jacobs HSEP 13.6 Eye and Face Protection and may be needed for unanticipated tasks (e.g., welding). Fogging is a known problem of eye protection that is exacerbated by cold weather. Mitigation measures include applying an anti-fog treatment to the lenses or shield and selecting safety glasses that provide maximal ventilation while still meeting industry standards. 9.3 PROTECTIVE CLOTHING Clothing sufficient to protect workers from contact with substances such as petroleum or heat and cold is required. When gross contamination is encountered (i.e., during drilling and sampling), clothing required for preventing contact with hazardous substances may include the following items: Rain gear or Tyvek coveralls (poly-coated for liquid contact) Neoprene boots or poly-coated Tyvek booties Nitrile gloves, nitrile gloves over cotton gloves, or leather gloves over nitrile gloves Cut-resistant gloves (e.g., when using a self-retracting utility knife or handling opened core sleeves) Additional details and types of hand protection are described in Jacobs HSEP 13.4 Hand Protection. Hands are difficult to keep warm when working in extremely cold weather. Mitigation measures include engineering controls to create a warmer workspace (e.g., portable shelters I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 9-2 HTRW-J07-05F45701-J FINAL 11/7/2012

50 with heaters), the use of chemical heating packs inside gloves (and boots), and taking warmup breaks as necessary to maintain dexterity. 9.4 LEVELS OF PERSONAL PROTECTIVE EQUIPMENT Activities at SS67 and WP45/SS57 will most likely be conducted using modified Level D protection. Level C may be used if action levels are exceeded (Table 8-1), but this is highly unlikely. If air monitoring results indicate that Level B or higher is needed, then the work procedures will be re-evaluated and modified to reduce exposure before continuing Modified Level D Modified Level D PPE will be used for most fieldwork conducted for this project. A work uniform affording minimal contaminant protection is needed, for nuisance levels only. The following constitute modified Level D equipment and may be used as appropriate: Work clothes (e.g. coveralls) Task-appropriate gloves Safety-toe boots Boots, outer, chemical-resistant (disposable) (optional, as applicable) Boot-covers, outer, chemical-resistant (disposable) (optional, as applicable) Safety glasses with side protection (chemical splash goggles or face shield as applicable) Hard hat High-visibility outer wear (vest or jacket) Bug jacket (optional, for summer work in vegetated areas) Escape mask (optional, as applicable) Additionally, workers clothing will need to provide adequate protection from cold during winter work Level C Level C PPE is not anticipated to be required during this field effort but may be used at the discretion of the SSHO or if action levels (Table 8-1) are exceeded. Level C is appropriate I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 9-3 HTRW-J07-05F45701-J FINAL 11/7/2012

51 when the concentration(s) and type(s) of airborne substance(s) are known and the criteria for using air purifying respirators are met. The following equipment added to the modified Level D ensemble constitutes Level C PPE: Full-face or half-mask air-purifying respirator (National Institute of Occupational Safety and Health [NIOSH]-approved) with cartridges appropriate for the contaminants encountered Hooded chemical-resistant clothing (overalls, two-piece chemical-splash suit, disposable chemical-resistant overalls) (optional, as applicable) Gloves, outer, chemical-resistant (optional, as applicable) Gloves, inner, chemical-resistant (optional, as applicable) I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 9-4 HTRW-J07-05F45701-J FINAL 11/7/2012

52 10.0 SITE CONTROL 10.1 SITE CONTROL PROCEDURES Site controls will be implemented as described in HSEP Site Controls (Attachment A-6). Effective site control procedures will reduce the potential exposure of the project team, other workers in the vicinity, and the surrounding environment to onsite hazards through measures such as: Limiting site access only to essential personnel; Establishing work zones within the site; Conducting operations in a manner that minimizes the exposure of personnel and equipment and eliminates the potential for off-site dispersion; and Establishing decontamination procedures for personnel and equipment WORK ZONES Clearly delineated work zones help ensure that: Site personnel are adequately protected from existing hazards; Specific activities and hazards are confined to the appropriate areas; and Personnel can be accurately and quickly located and evacuated during an emergency. Personnel will use HSEP Site Controls as a guideline when establishing work zones; vehicles will be arranged to provide efficient evacuation due to wildlife or other emergencies BUDDY SYSTEM Jacobs policy is that all site work will be performed using the buddy system. Team members will keep in visual contact with each other at all times. The buddy must be capable of executing the following tasks: Assisting his/her partner Monitoring the partner for signs of chemical or other exposures (e.g., heat or cold) Periodically verifying the integrity of the partner s PPE I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 10-1 HTRW-J07-05F45701-J FINAL 11/7/2012

53 Notifying the SSHO when emergency help is needed Keeping the SM informed of location and expected time of return 10.4 COMMUNICATIONS Verbal communication at the sites could be impaired by onsite background noise caused by heavy equipment and the use of PPE. Hand signals will be established and communicated to personnel. Communication with off-site personnel will be via cell phone SITE SAFETY AND SECURITY Site security is essential to prevent unauthorized, unprotected, or unqualified people from being exposed to site hazards and protect established and safe working procedures. Site safety and security will be maintained by ensuring that any visitors to the site sign the visitors log and are given a site-specific briefing, and stopping work immediately if unauthorized personnel attempt to or succeed in accessing the work area. In this case, the worker shall notify the SSHO, SM, and PM immediately EQUIPMENT AND VEHICLE DECONTAMINATION Equipment used onsite will undergo decontamination prior to leaving the site to eliminate contaminant migration from the site as well as the potential for cross-contamination of sites. Gross decontamination includes the removal of potentially contaminated materials by use of a shovel or other hand tools and stiff bristle brushes for equipment contaminated by soil and by wiping visible contamination from equipment contaminated by water or free product. Materials removed during gross decontamination will be accumulated and managed with similar waste streams. Equipment used onsite will be completely decontaminated before it is moved to another site and prior to its return, before it is used in another well, or when it is no longer required onsite. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 10-2 HTRW-J07-05F45701-J FINAL 11/7/2012

54 10.7 PERSONNEL DECONTAMINATION Decontamination protects workers, the public, and the environment by limiting exposure to harmful substances and preventing the spread of contamination. At areas where an exclusion zone is necessary, all personnel exiting the exclusion zone will follow decontamination procedures. Under no circumstances (except emergency evacuation) will personnel be allowed to leave the exclusion zone before decontamination. The SM or PM may approve simplification of the procedures in the field when a determination has been made that adequate decontamination can be achieved with less effort. Decontamination procedures for the sites are as follows: 1. Wipe gross contamination off clothes and equipment. 2. Scrub boots and gloves in decontamination solution or detergent water, if necessary. 3. Step across to the next station and remove coveralls and gloves. Deposit in container with plastic liner. Remove coveralls (if applicable) after gloves. 4. Remove respirator and avoid touching face with fingers (if applicable). 5. Wash hands and face thoroughly WASTE HANDLING AND DISPOSAL Disposal of all wastes will be in accordance with state and federal requirements, as specified in the site-specific supplemental work plans (AFCEC 2012a and 2012b). I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 10-3 HTRW-J07-05F45701-J FINAL 11/7/2012

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56 11.0 INSPECTIONS 11.1 SITE INSPECTIONS / SAFETY EVALUATION The SSHO and site personnel will inspect the site daily for conditions that may vary from those expected in the SPAs. Changes will be addressed by amending the applicable SPA. Any changes should be reviewed with the SM and site personnel EQUIPMENT INSPECTIONS Any machinery or mechanized equipment shall be inspected and tested by a competent person to ensure that it is in safe operating condition prior to use at the site. Inspections and tests will be performed in accordance with the manufacturer s recommendations and documented. Records of tests and inspections will be maintained at the project office. Jacobs Standard Equipment Inspection Form (Attachment A-5, Exhibit 14) will be used to document the inspections Vehicle Inspections Motor vehicles owned or rented by Jacobs or subcontractors will be inspected prior to use. Deficiencies found during the inspection will be noted and corrected prior to equipment use. Attachment A-5, Exhibit 13 contains a rental vehicle inspection form. Vehicles that cannot be brought to safe operating condition will not be used. In addition to pre-use inspections, the vehicle s primary driver will be responsible for ensuring that scheduled and periodic maintenance occurs to maintain safe operable condition. At no time will anyone operate a vehicle believed to be unsafe. The vehicle should be equipped with safety equipment including the following items: Portable eyewash bottles First-aid kit Type A-B-C fire extinguisher I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 11-1 HTRW-J07-05F45701-J FINAL 11/7/2012

57 Daily/Shift Inspections and Tests Machinery and equipment shall be inspected daily (when in use) to ensure safe operating conditions as described below: Tests shall be conducted at the beginning of each shift during which equipment is to be used to determine that brakes and operating systems are in proper working condition and that required safety devices are in place and functional. Whenever any machinery or equipment is found to be unsafe, or when a deficiency affecting the safe operation of equipment is observed, the equipment shall be immediately taken out of service and its use prohibited until unsafe conditions have been corrected. A tag indicating that the equipment shall not be operated and that the tag shall not be removed will be placed in a conspicuous location on the equipment. Where required, lockout/tagout procedures will be followed. The tag shall remain in its attached location until it is demonstrated to the individual who found the equipment unsafe that the equipment is safe to operate. When deficiencies are corrected, the machinery or equipment will be re-tested and reinspected before being returned to service SAFETY OBSERVATION REPORTS Site personnel, not just the SSHO, will complete an SOR form (Attachment A-5, Exhibit 19) when real or potential unsafe acts or unsafe conditions have been identified. The success of this program increases when SORs completed by non-hse specialists exceed those completed by HSE specialists. This ensures that all personnel are developing safety-conscious attitudes. SORs will not be used for disciplinary purposes because they are intended to help communicate unsafe acts or conditions. SORs shall also be used to encourage and reward safe behavior. Providing positive reinforcement of a job or task well-executed is far more encouraging than recognizing unsafe behavior. Encouragement can be rewarding for the whole project, enticing the team to create a better and healthier work environment. Additionally, SORs can be used to communicate a better way of performing a task. Any corrective measures shall be documented on the SOR form. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 11-2 HTRW-J07-05F45701-J FINAL 11/7/2012

58 SORs shall be submitted to the SSHO within 24 hours of completion. Completed forms will be maintained with project records and a copy or record of SORs will be forwarded to the Jacobs Anchorage HSE Group weekly SAFE PLAN OF ACTION ASSESSMENT Management and HSE personnel will routinely monitor and assess the development and implementation of SPAs. This assessment will be made using the SPA assessment form (Attachment A-5, Exhibit 18) or other means that achieves the same result. The monitoring and assessment will be based on three criteria: Relative risks and activities, (e.g., working in extreme temperatures, confined space entry, lockout/tagout work) Complexity of the task Locations and varieties of tasks I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 11-3 HTRW-J07-05F45701-J FINAL 11/7/2012

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60 12.0 EMERGENCY PROCEDURES This section describes pre-emergency planning, emergency equipment and supplies, emergency procedures, emergency response and accident follow-up, evacuation information, contacts, post-incident notifications, recordkeeping, and vehicle accident procedures. Attachment A-1 lists contact names and numbers in case of an emergency as well as a map of the hospital location and route that will be posted on site HOSPITAL ROUTE The Fairbanks Memorial Hospital is approximately 24 miles away and is located at 1650 Cowles Street, Fairbanks. The hospital may be reached by exiting Eielson AFB and traveling north on the Richardson Highway. Take the ramp to AK-3/ Denali Park/ Nenana, and then merge onto the Robert Mitchell Expressway. Turn right onto Lathrop Street and then right onto 19 th Avenue. Fairbanks Memorial Hospital is on the left. Attachment A-1 contains a map of the suggested route EMERGENCY COMMUNICATION In addition to communication methods described in this SSHP, the following communication and contact methods will be used: Cell phone Air horn blast The following visual hand signals will be used: Clutching throat = Personal distress Arm waving and pointing towards the exit direction = Evacuate the area When calling for an emergency response, by cell phone, report the following information: Your name Your company s name Type of emergency and perceived severity Location of accident or injury I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 12-1 HTRW-J07-05F45701-J FINAL 11/7/2012

61 Time of incident Type of first-aid or response being given DO NOT HANG UP until the operator or emergency dispatcher has received the complete information and directs you to hang up. Notify the SSHO or SM and your supervisor immediately after hanging up the phone. Further information or assistance may be needed from you to complete the accident investigation process EMERGENCY MEDICAL TREATMENT Should a person become injured and require treatment beyond onsite first-aid, an Authorization for Medical Treatment form (Attachment A-5, Exhibit 7) will be taken to the medical facility treating the employee. The SM and/or SSHO will complete the top portion of the form, and the doctor at the medical facility will complete the bottom portion of the form INCIDENT AND ACCIDENT REPORTING The SM and SSHO will be notified promptly of any accidents. After ensuring that any injured personnel are receiving proper medical treatment and that such treatment has been duly authorized (Section 12.3, above), the SM will notify the HSM and the PM as soon as possible that an incident or accident has occurred. The PM will notify the client immediately in the event of a fatality, personnel admitted to a hospital, or property damage in any amount. The SM will provide the following information as it becomes available: Project name and number The location and circumstances of the accident Name and employer of any victims, and nature and extent of their injuries The name and address of the medical facility providing treatment The name of the attending physician or other medical professional SSHO name and phone number I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 12-2 HTRW-J07-05F45701-J FINAL 11/7/2012

62 In the aftermath of an incident or accident, the SM in consultation with the HSM and PM will determine whether there is a need for drug testing of any of the involved personnel. The SM will ensure that steps have been taken to secure the scene with no movement of material or equipment until the onsite portion of the investigation (photos, sketches, and measurements) is complete, and obtain signed statements from all witnesses. For accidents involving vehicles and heavy equipment, procedures in HSEP 5.2 Vehicle Accident (in Attachment A-6) shall be followed and a Vehicle Accident Report will be completed (Attachment A-5, Exhibit 12). For other accidents, use the Accident/Incident Investigation Report form (Attachment A-5, Exhibit 11). The accident investigation will be conducted in accordance with HSEP 5.1 Accident and Incidents Investigation and Reporting (in Attachment A-6). Daily records of all first-aid treatments not otherwise reportable will be maintained on the first-aid register and furnished to the HSM weekly EPOSURE TO BLOODBORNE PATHOGENS The following procedures will be implemented when a potential exposure to bloodborne pathogens occurs: The SSHO will be notified immediately whenever a first-aid incident occurs. If the SSHO determines that a potential exposure occurred, the SSHO will provide a report to the HSM and the PM that includes: - A description of the incident, including date and time. - Names of all first-aid providers who rendered assistance and a description of the type of barrier used by each. - A summary of exposure(s) and post-exposure prophylaxis to ensure that proper postexposure evaluation occurred and that follow-up procedures were made immediately available (a Jacobs policy requirement). The report will be recorded on the first-aid register EARTHQUAKE In the event of an earthquake, move to an open area away from equipment, structures, or utility poles if outdoors, or take cover beneath a desk or at least move away from book I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 12-3 HTRW-J07-05F45701-J FINAL 11/7/2012

63 shelves and office equipment that could shift if indoors, and wait for shaking to stop. Afterward, meet at the muster point (agreed upon during the daily safety tailgate meeting) and assess the situation, paying particular attention to the possibility of fuel leaks, especially propane. Contact the Jacobs Anchorage home office and inform them of the status of the team EVACUATION The SSHO and SM will coordinate with emergency service providers for the jobsite location. Contacts, contact numbers, and primary gathering points will be reviewed prior to mobilization. Attachment A-1 provides an emergency contact list that includes numbers for firefighters, state troopers, and medical facilities. If an evacuation of the work area is necessary, the following steps should be followed: After receiving the signal to evacuate, all non-response personnel are to leave the work area in an upwind direction and assemble at a pre-determined point. The SM will account for field team members at the assembly points. The SM will complete an incident report with applicable witness statements as soon as possible after an incident. Evacuation routes and assembly points will be designated to facilitate access and provide direction for emergency responders. All onsite personnel will be advised of evacuation routes and assembly points during the safety orientation and daily tailgate meetings. The SSHO or SM will document actual evacuation routes and assembly points whenever evacuation occurs SPILL OR RELEASE PROCEDURES The SSHO and SM shall be notified immediately when a spill or release occurs. Workers will take steps (if conditions are safe) to minimize the size of the spill, including shutting down affected equipment, deploying the spill kit, and scooping up the affected soil into a 5-gallon bucket. These steps should be included in the SPA for the activity. For POL spilled on land, a record must be maintained of any release greater than 1 gallon. For releases of fuels and fuel I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 12-4 HTRW-J07-05F45701-J FINAL 11/7/2012

64 additives greater than 1 gallon or oils greater than 10 gallons, the Eielson AFB Fire Department shall be notified at 911. (If in doubt, call 911.) If the immediate response proves insufficient to deal with the spill, a spill-specific SPA will be developed in consultation with the HSM to identify the procedures and PPE necessary to remediate the spill safely. After the SPA is in place and appropriate PPE has been obtained and donned, workers may re-enter the spill area and commence remediation. All cleanup actions will comply with 18 AAC 75 (ADEC 2012). Notification will proceed as outlined above in Section 12.4, and either the PM or the client will notify ADEC when a quantity greater than 10 gallons of POL has been released. Monthly reporting is required for quantities between 1 and 10 gallons, and no reporting is required for lesser quantities. I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 12-5 HTRW-J07-05F45701-J FINAL 11/7/2012

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66 13.0 REFERENCES ADEC (Alaska Department of Environmental Conservation) (April). 18 AAC 75 Oil and Other Hazardous Substances Pollution Control. ACGIH (American Conference of Government Industrial Hygienists) Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. AFCEC (Air Force Civil Engineer Center). 2012a (in progress). Supplement to Quality Assurance Project Plan for Remedial Investigation Source Area WP45/SS57. Prepared by Jacobs Engineering Group Inc. AFCEC (Air Force Civil Engineer Center). 2012b (October). Supplement to Quality Assurance Project Plan for Remedial Investigation Source Area SS67. Prepared by Jacobs Engineering Group Inc. AFCEE (Air Force Center for Engineering and the Environment). 2012a (October). Supplemental Remedial Investigation/Feasibility Study Management Plan, Source Areas WP45/SS5., Eielson AFB, Alaska. Final (with tracked changes). AFCEE. 2012b (June). Quality Assurance Project Plan Remedial Investigation Source Area SS67. Eielson Air Force Base, Alaska. Draft Final. AFCEE. 2012c (February). Quality Assurance Project Plan Supplemental Remedial Investigation Source Areas WP45/SS5.; Eielson Air Force Base, Alaska. Final. DOT (U.S. Department of Transportation) Manual on Uniform Traffic Control Devices for Streets and Highways. Jacobs Engineering Group Inc. Health, Safety, and Environmental Procedures. Available on JNet: OFR (Office of the Federal Register) (October). Hazardous Waste Operations and Emergency Response. National Archives and Records Administration. 29 CFR and USACE (U.S. Army Corps of Engineers) (September). Safety and Health Requirements. EM I:\AE-HTRW\TO07-Eielson RI\WP\SSHP\SSHP Eielson RI.doc 13-1 HTRW-J07-05F45701-J FINAL 11/7/2012

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68 ATTACHMENT A-1 Project-Specific Contacts and Maps Project Contacts Emergency Response Contacts Emergency Route to Fairbanks Memorial Hospital, Fairbanks, Alaska

69 PROJECT CONTACTS Organization Title Name Telephone USACE Contracting Officer s Representative Scott Kendall (o) USACE Project Manager Meseret Ghebresllassie (o) AFCEC Project Manager Pat Roth (o) Jacobs Notes: (o) = office phone (m) = mobile phone TBD = to be determined USAF Program Coordinator Project Manager Field Services Manager Health and Safety Manager Site Manager Site Safety and Health Officer Technical Lead Project Geologist Lead Sampler Project Chemist Kelly McGovern Kevin Maher Jon McVay Randall Jones David Sallee David Sallee Katie Bloom Dave Ward Ida Petersen David Summerville (o) (m) (o) (m) (o) (m) (o) (m) (o) (m) (o) (m) (o) (m) (o) (m) (o) (m) (o) (m)

70 EMERGENCY RESPONSE CONTACTS Medical and Fire Emergency State that you are on Eielson AFB. The Fairbanks dispatcher will transfer you to the Eielson AFB dispatcher. Provide your exact location. State your full name, the particulars of your emergency, type of first-aid being given, and your requirements for assistance. Be patient and deliberate in your communication to ensure clarity. Listen to, record, and follow further instructions. DO NOT HANG UP until the dispatcher directs you to hang up. Fairbanks Memorial Hospital Eielson AFB Police Department Eielson AFB Fire Department or (base operator) 911 or (base operator) Poison Control Center Jacobs Emergency Medical Consultant (Dr. Baskous) Spills and Toxins National Response Center (Oil and Toxic Chemical Spills) Chemtel (Customer ID #JAC001) Poison Control Center

71 TRANSMITTER ROAD NORTH CONTINUED ON DETAIL A RICHARDSON HIGHWAY ARCTIC AVE FAIRBANKS MEMORIAL HOSPITAL SITE EMERGENCY ROOM ENTRANCE IS LOCATED OFF COWLES STREET APPROIMATELY ONE QUARTER BLOCK NORTH OF 19TH AVENUE MAIN GATE CENTRAL AVE FLIGHT LINE AVE CENTRAL AVE EIELSON AIR FORCE BASE WABASH AVE NORTH ST KODIAK ST BROADWAY AVE PROJECT LOCATION DIVISION ST. CLINIC LOCATION FAIRBANKS DETAIL B DETAIL A HOSPITAL AND CLINIC LOCATIONS EMERGENCY ROUTE EIELSON AFB, FAIRBANKS, ALASKA DATE: 24 October 2012 PROJECT MANAGER: FIGURE NO. : K. MAHER A-1

72 ATTACHMENT A-2 Hazard Communication Program

73 HAZARD COMMUNICATION PROGRAM PURPOSE AND SCOPE The Hazard Communication Program has been established to inform workers and subcontractors of potential site-specific chemical hazards and comply with the requirements of 29 CFR , Hazard Communication. Prior to starting fieldwork, all personnel will attend a health and safety orientation and will receive information and training on the following: Requirements contained in 29 CFR , Hazard Communication Chemicals present at the site Location and availability of a written hazard program Physical and health effects of the hazardous chemicals Methods and observation techniques used to determine the presence or release of hazardous chemicals How to lessen or prevent exposure to these hazardous chemicals through use of control/work practices and PPE Emergency procedures to follow if exposed to these chemicals How to read labels and review MSDSs to obtain appropriate hazard information Location of MSDSs Applicable Alaska Department of Labor PADS DEFINITIONS acute acute exposure asphyxiant Severe, often dangerous conditions in which relatively rapid changes occur. An intense exposure over a relatively short period of time. A chemical (gas or vapor) that can cause death or unconsciousness by suffocation. Simple asphyxiants, such as nitrogen, either use up or displace oxygen in the air. They become especially dangerous in confined or enclosed spaces. Chemical asphyxiants, such as carbon monoxide and hydrogen sulfide, interfere with the body's ability to absorb or transport oxygen to the tissues. 1

74 boiling point "C" or ceiling carcinogen CAS number cc cubic centimeter chemical chemical reaction chronic The temperature at which the vapor pressure of a liquid equals atmospheric pressure or at which the liquid changes to a vapor. The boiling point is usually expressed in degrees Fahrenheit ( F). If a flammable material has a low boiling point, it indicates a special fire hazard. A description usually seen in connection with a published exposure limit. It refers to the concentration that should not be exceeded, even for an instant. It may be written as TLV-C or Threshold Limit Value - Ceiling. (See also Threshold Limit Value.) A substance or physical agent that may cause cancer in animals or humans. Identifies a particular chemical by the Chemical Abstracts Service, a service of the American Chemical Society that indexes and compiles summaries of worldwide chemical literature called "Chemical Abstracts." A volumetric measurement, equal to 1 milliliter (ml). As broadly applied to the chemical industry, a naturally occurring substance or a compound produced by chemical reactions for either direct industrial and consumer use, or for reaction with other chemicals. A change in the arrangement of atoms or molecules to yield substances of different composition and properties. (See Reactivity). Persistent, prolonged, or repeated conditions chronic exposure A prolonged exposure occurring over a period of days, weeks, or years. combustible liquid concentration corrosive dermatitis dyspnea EPA According to the U.S. Department of Transportation (DOT) and the National Fire Protection Association (NFPA), combustible liquids are those having a flash point at or above 100ºF (37.8 degrees Celsius [ºC]). Combustible liquids do not ignite as easily as flammable liquids. However, combustible liquids can be ignited under certain circumstances and must be handled with caution. Substances, such as wood, paper, etc., are termed "ordinary combustibles." The amount of one substance mixed with, and in the presence of, another substance. For example, 5 parts (of acetone) per million (parts of air). A substance that, according to the DOT, causes visible destruction or permanent changes in human skin tissue at the site of contact. An inflammation or irritation of the skin. Shortness of breath; difficult or labored breathing. The U.S. Environmental Protection Agency (EPA) is the governmental agency responsible for administration of laws to control and/or reduce pollution of air, water, and land systems. 2

75 EPA number The number assigned to chemicals regulated by the EPA. flammable liquid By DOT and NFPA, a flammable liquid is one that has a flash point below 100ºF. (See Flash Point). flash point hazardous material ingestion inhalation irritant lower explosive limit (LEL) odor threshold OSHA oxygen deficiency reactivity time weighted average (TWA) The lowest temperature at which a liquid gives off enough vapor to form an ignitable mixture and burn when a source of ignition (sparks, open flames, cigarettes, etc.) is present. Two tests are used to determine the flash point: open and closed cup. The test method is indicated on the MSDS after the flash point. Any substance or compound that may produce adverse effects on the health and safety of humans. Taking a substance into the body through the mouth as food, drink, medicine, or unknowingly as on contaminated hands or cigarettes, etc. The breathing in of an airborne substance that may be in the form of gases, fumes, mists, vapors, dusts, or aerosols. A substance that produces an irritating effect when it contacts the skin, eyes, nose, or respiratory system. (Also known as Lower Flammable Limit.) The lowest concentration of a substance that will produce a fire or flash when an ignition source (flame, spark, etc.) is present. It is expressed in percent of vapor or gas in the air by volume. Below the LEL or LFL, the air/contaminant mixture is theoretically too "lean" to burn. (See also UEL) The minimum concentration of a substance at which a majority of test subjects can detect and identify the substance's characteristic odor. The Occupational Safety and Health Administration (OSHA) is a federal agency under the Department of Labor that publishes and enforces safety and health regulations for most business and industries in the United States. An atmosphere having less than the normal percentage of oxygen found in normal air. Normal air contains 20.8 percent oxygen at sea level. A substance's propensity to under a chemical reaction or change that may result in effects, which can be dangerous, such as explosion, burning, or generation of corrosive or toxic emissions. Reaction initiators, such as heat, other chemicals, dropping, etc., will usually be specified as "Conditions to Avoid" when a chemical's reactivity is described in an MSDS. The average concentration, over a given work period, e.g., 8-hour workday, of a person's exposure to a chemical or a potentially harmful agent. The average is determined by sampling for the contaminant during the period of exposure. 3

76 upper explosive limit (UEL) (Also known as Upper Flammable Limit.) The UEL is the highest concentration of a mixture that will burn or explode when an ignition source is present. Theoretically, above this limit, the mixture is said to be too "rich" to support combustion. The airborne concentration range between the LEL and the UEL constitutes the flammable range or explosive range. GENERAL The purpose of this Hazard Communication Program is to communicate the hazards of workplace chemicals and communicate protective measures to control the hazards. Hazard communication is accomplished by: Maintaining a list of all workplace chemicals; Labeling workplace chemical containers; Maintaining MSDSs for the workplace chemicals; and Implementing a training program to communicate the hazards of chemicals and appropriate protective measures. Upon completion of hazard communication training, Jacobs and subcontractor employees will understand the components of hazard communication, the hazards of the chemicals in their workplace, and the protective measures to control the hazards. HAZARD EVALUATION Chemical manufacturers are responsible for assessing a chemical s physical hazards, such as flammability, combustibility, explosion, reaction, radioactivity; and health hazards, such as irritation, corrosion, sensitization, or toxicity. Jacobs relies on its clients for chemical, product, and process-unit intermediate-stream hazard information. MSDSs shall be requested for chemicals and products purchased or brought onto the site. Personnel onsite rely on the evaluation performed by the chemical manufacturers or importers who originated the MSDSs for the accuracy of this information. 4

77 WRITTEN HAZARD COMMUNICATION A list of the chemicals used on this project will be maintained and updated when new chemicals are brought onsite. The SM will maintain the list of chemicals. List of Chemicals to Be Used Onsite Chemicals Used Onsite Alconox Antifreeze (ethylene glycol) Bear Spray Bentonite Bug Spray (DEET) Chemical Hand Warmers Diesel Eye Wash Fire Extinguisher Fogtech Gasoline Hydrochloric Acid Liquinox Methanol Nitric Acid Propane Sand Use Decontamination of sampling equipment Vehicle and equipment cooling systems Wildlife deterrent Filling bore holes Insect repellant Inside gloves and boots to warm hands and feet Fuel First-aid eye irrigation Extinguishing fires Anti-fog treatment for safety glasses Fuel Sample preservation Decontamination of sampling equipment Sample preservation Sample preservation Fuel Filling boreholes LABELS Labels and other forms of warnings are to be conspicuously placed on containers so the message is readily visible. The chemical manufacturer, importer, or distributor will label, tag, or mark the chemical container identifying the hazardous chemicals, appropriate hazard warnings, and name and address of the chemical manufacturer, importer, or responsible party. 5

78 Labeling Systems Multiple labeling systems are currently in use, including the National Fire Protection Association (NFPA) 704M labeling system, the Hazardous Materials Information System (HMIS), U.S. Department of Transportation (DOT) labeling system, the United Nations Hazard Class Number System, and others. National Paint & Coatings Association Hazardous Materials Information System The National Paint & Coatings Association HMIS is a five-part rectangle that provides identification of the chemical, acute health hazard, flammability, reactivity, PPE designations, and chronic health hazard information. HMIS uses standard labels to communicate hazards through the use of colors, numbers, letters of the alphabet, and symbols. Chemical identity is conveyed by the chemical name and should be the same as the name on the MSDS. The acute health (blue), flammability (red), reactivity (yellow) hazards are communicated by numerical ratings similar to the NFPA system. An alphabetical designation is used to denote recommended PPE. Chronic health hazards may be an abbreviated technique such as an asterisk placed on the label denoting reference to the specific MSDS, or the actual chronic information may be written on the label if space allows. Labels for Transfer Containers When materials are transferred from one container to another, the new container will be marked appropriately with the name of the material and hazard warning. MATERIAL SAFETY DATA SHEETS An MSDS will be maintained in the field files for each hazardous chemical brought onsite and will include the following information: The chemical name and common name of all ingredients that are health hazards The chemical name and common name of all ingredients that are physical hazards The physical and chemical characteristics of the hazardous chemical, such as vapor pressure, flash point The physical hazards of the hazardous chemical, including fire, explosion, reactivity 6

79 The primary routes of entry The permissible exposure limit, threshold limit value, and other exposure limit used by the manufacturer Whether the hazardous chemical is listed in the National Toxicology Program Annual Report on Carcinogens, International Agency for the Research on Cancer Monographs, or OSHA Applicable precautions for safe handling and use Applicable engineering controls, work practices, or PPE control measures known to the manufacturer Emergency and first-aid procedures Date the MSDS was prepared and name, address, and telephone number of the manufacturer WORKPLACE INVENTORY An up-to-date hazardous chemical inventory must be maintained. EMPLOYEE INFORMATION AND TRAINING Employees shall be informed of operations in their work area where hazardous chemicals are present, the location of the written Hazard Communication Program, list of hazardous chemicals, and MSDSs. Training will include methods and observations to detect a hazardous chemical in the workplace, the physical and health hazards of the hazardous chemicals in the workplace, the measures employees can take to protect themselves, an explanation of the labeling system, and MSDSs. Training will be documented using the Hazard Communication and Right-To-Know Training Form at the end of this Hazard Communication Program. TRADE SECRETS The chemical manufacturer may withhold specific chemical identity from an MSDS. For emergency or first-aid treatment or non-emergency conditions, the chemical manufacturer will disclose the specific chemical identity to a health professional. 7

80 HAZARD COMMUNICATION and RIGHT-TO-KNOW STANDARDS Name: Company & Location: 1. I have been informed about the Hazard Communication Program, Material Safety Data Sheets (MSDS), their use, location, and procedures for obtaining copies. 2. I have been informed that some of my work may involve exposure to toxic substances. 3. I have been informed about the right of employees to have access to relevant exposure and medical records and the procedures for requesting access. 4. I understand that the employer must respond to my request for additional information, in a reasonable amount of time to avoid the interruption of normal work operations, but within 15 days. Signature: Date: 8

81 ATTACHMENT A-3 Hazards Associated with the Contaminants of Potential Concern

82 HAZARDS ASSOCIATED WITH CONTAMINANTS OF POTENTIAL CONCERN Among the contaminants of potential concern at SS67 and WP45/SS57, previous investigations have shown that only benzene, cis-1,2-dichloroethylene (DCE), polychlorinated biphenyls (PCB), and trichloroethylene (TCE) have significant exposure potential to site workers. For SS67, mercury and organo-chlorine pesticides are also contaminants of potential concern because they bioaccumulate in fish. However, there is no completed exposure pathway because workers will not be ingesting fish from the site. Numerous additional organic compounds are contaminants of potential concern that have been detected at low levels, but they were omitted because their contributions to the cumulative risk presented by site materials is small. Thus, the primary hazards to workers presented by site contamination is as follows: Benzene: Hazards associated with benzene include: - Exposure Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact - Symptoms: Irritation to eyes, skin, and mucous membranes; dermatitis; headache, lassitude (weakness, exhaustion), blurred vision, dizziness, slurred speech, confusion, convulsions; chemical pneumonitis (aspiration of liquid); possible liver and kidney damage. Potential occupational carcinogen. - Target Organs: Eyes, skin, respiratory system, central nervous system, liver, kidneys OSHA permissible exposure limit (PEL): 1 ppm time-weighted average (TWA); ACGIH threshold limit value (TLV): 0.5 ppm 1,2-Dichloroethylene (DCE): Hazards associated with both the cis and trans isomers of 1,2- DCE include: - Exposure Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact - Symptoms: Irritation to eyes, skin, and mucous membranes; dermatitis; headache, lassitude (weakness, exhaustion), suffocation, tremors, blurred vision, dizziness, slurred speech, confusion, nausea, vomiting and convulsions; chemical pneumonitis (aspiration of liquid); irregular heartbeat or heart rhythm; possible liver and kidney damage. Potential occupational carcinogen. - Target Organs: Eyes, skin, respiratory system, central nervous system, liver, kidneys OSHA PEL: 200 ppm TWA; ACGIH TLV: 200 ppm

83 Polychlorinated Biphenyls (PCBs): Hazards associated with PCBs include: - Exposure Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact - Symptoms: Irritation to eyes, skin, and mucous membranes; visual disturbances; irritation of the respiratory system, headaches, nausea, dizziness and loss of coordination. Chronic effects include probable reproductive and developmental abnormalities. Probable human carcinogen. - Target Organs: Eyes, skin, respiratory system, central nervous system, liver, kidneys OSHA PEL: 0.5 mg/m 3 TWA; ACGIH TLV: 0.5 mg/m 3 Trichloroethylene (TCE): Hazards associated with TCE include: - Exposure Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact - Symptoms: Irritation and corneal injury to eye, tearing, burning pain; dermatitis, peripheral nervous system function impairment, temporary loss of touch; damage to the liver, chemical pneumonitis, and irritation of digestive tract; central nervous system effects such as nausea, headache, dizziness, unconsciousness and coma. Potential occupational carcinogen. - Target Organs: Eyes, skin, respiratory system, central nervous system, liver OSHA PEL: 100 ppm TWA ; ACGIH TLV: 50 ppm Attachment a-7 to the Health and Safety Plan contains MSDSs for chemicals that may be brought to the site for project activities. The above hazard descriptions and the MSDSs will be available onsite in the field file box.

84 ATTACHMENT A-4 Activity Hazard Analysis

85 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB AHProject Number: 05F45701 Project: Various Sites, Eielson AFB Location: Eielson AFB, Alaska Prepared By: Christopher Fell Date: 21 October 2012 Reviewed By: Date: Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 001 Mobilization/ Demobilization: Travel to Airport 002 Mobilization/ Demobilization: Air Travel Struck By/Against Caught Between Equipment Damage Property Damage Exposure Struck By/Against Caught Between Strain/Sprain (Lifting) Slip/Trip/Fall Noise Airline Crash P P F F P P P P P P P/F/E A E/A E/A E/A A/S A E/A A E S D/E/S/W /A Wear/carry appropriate clothing for weather conditions at both the departure and arrival locations Do not exceed vehicle capacity (load or occupancy) Wear seat belts Obey speed limit Watch for other drivers Do not talk or text on cell phones Establish eye contact with other vehicles in congested areas Practice defensive driving strategies Dress appropriately Employ proper lifting technique Assess if it appears unsafe to fly Follow airline instructions when boarding/ de-boarding the plane Maintain 3-points of contact while boarding/de-boarding planes. Listen to the safety briefing and ask questions Use hearing protection Notes: Page 1 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

86 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 003 Mobilization/ Demobilization: HAZMAT Material Shipping 004 Mobilization/ Demobilization: Loading/Unloading Equipment Improper Shipping Exposure Damage To Aircraft Struck By/Against Caught Between Crushing Fall From Height Equipment Damage Property Damage F P F/E P P P P F F A A A A A A/W A/E/S E/A/W E/A Use appropriate PPE for handling each item, this should be detailed on the SPA for handling various HAZMAT items Prepare an inventory and stage potential HAZMAT items Personnel trained in Department of Transportation/International Air Transport Association shipping regulations should obtain proper paperwork for shipping Proper packaging, labeling, and markings should be provided for each HAZMAT item Maintain HAZMAT inventory during project activities Communicate that an item has shipped to personnel at the destination location Modified level D PPE is required Discuss loading/unloading procedures prior to beginning work Stay out of the area if not required Stay clear of pinch points Communicate actively with vehicle/equipment operators, wear fall protection if applicable, use backup alarms/spotters/channelization devices Use backup alarm on heavy equipment Use radios or hand signals Notes: Page 2 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

87 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 005 Mobilization / Operations: Equipment Inspections Cuts/Lacerations Struck By/Against Caught Between Burns Fall From Height 006 Operations: Driving Equipment Damage Property Damage Struck By/Against P P P P P F F P A/S A A/S A/S A/S/E A/W A/W A/W Modified level D PPE is required Use cut-resistant gloves Use lockout/tagout procedures during equipment inspections Use proper blocking techniques to prevent inadvertent equipment motion Discharge stored energy (hydraulics) Permit equipment to cool down Use fall protection/ladders to make inspections Do not inspect engine compartment with equipment running Perform vehicle walk around before operating the vehicle Place safety cone on the ground at the end of the vehicle in the intended direction of travel Use spotters when backing Limit backing when possible Keep headlights on at all times Obey posted and un-posted speed limits Practice defensive driving techniques Notes: Page 3 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

88 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 007 Operations: Surveying 008 Operations: Drilling/Monitoring Well Installation Cuts/Lacerations Struck By/Against Caught Between Strain/Sprain (Lifting) Slip/Trip/Fall COPC Exposure Strain/Sprain (Lifting) Slip/Trip/Fall COPC Exposure Cuts/Lacerations Struck By/Against Caught Between Utility Strikes Spreading COPCs Hearing Damage Fire P P P P P P P P P P P P F F/E P P/E/F A/S A A A/S A/E A/S A/S A E/S/D A/S A/W/S A/W A/E/D/S A/E/D S A/E/S Modified level D PPE is required Use proper PPE/decontamination to prevent COPC exposure (i.e. nitrile gloves, booties, Tyvek) when working in an area designated as an exclusion zone Wear cut resistant gloves Stay aware of traffic Communicate with operators and shut equipment down before entering the No Zone Use proper posture when using survey equipment. Walk carefully on uneven ground or around excavations Call in locate requests (811), get base utility clearance, locate utilities visually, and use geophysical techniques Modified level D PPE and hearing protection are required Wear cut-resistant and nitrile gloves Discuss HAZCOM with all onsite personnel Employ proper lifting techniques Watch footing and walk deliberately Communicate with operators and do not enter No Zone unless equipment is shut down Stay away from drilling machinery when in operation Follow base and Jacobs requirements for hot work, e.g., for welding, high-speed grinding, or using a weed burner to warm tooling in cold weather. Notes: Page 4 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

89 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 009 Environmental: Garrison Slough MI Sampling 010 Operations: Monitoring Well Development Strain/Sprain (Lifting) Slip/Trip/Fall COPC Exposure Cuts/Lacerations Exposure (Weather) Drowning Slips/Trips/Falls Strain/Sprain (Lifting) Cuts/Lacerations COPC exposure Exposure (Weather) P P P P P P P P P P P A/S A A/E/S A/S A/S A/S A/E A A/S A/S/E A/S Modified level D PPE is required Wear cut resistant and nitrile gloves Wear proper footwear Discuss HAZCOM with all onsite personnel Walk deliberately and carefully on uneven terrain Wear weather-appropriate clothing and take warming breaks if becoming cold Do not walk on to ice covering the open channel of the slough if water is more than a few inches deep Work with a buddy and keep track of each other Wear a life jacket where appropriate Modified level D PPE is required Wear cut-resistant gloves Wear nitrile gloves when sampling, tyvek and booties, if appropriate Use proper lifting techniques Discuss HAZCOM with all onsite personnel Wear weather-appropriate clothing and take warming breaks if becoming cold Notes: Page 5 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

90 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 011 Environmental: Sampling/MIP Screening 012 Operations: Environmental Factors Cuts/Lacerations Struck By/Against Caught Between Strain/Sprain (Lifting) Slip/Trip/Fall Drowning COPC Exposure Wind Rain Snow Cold Heat Visibility Darkness Ice P P P P P P P P/F P/F P/F P/F P/F P/F P/F/E P/E A/S A A A A/S A A/E/S A/S A/S A/S A/S A/S A/S E/S A/E/S Modified level D PPE and hearing protection are required Use cut-resistant gloves when working with glassware Communicate and shut down equipment before entering the No Zone Use proper lifting techniques Always work with a buddy Stay away from pinch points on the drill rig Communicate with the driller and plan work flow together Set up MIP screening equipment where it will not interfere with drilling operations Follow PADS Vehicle headlights should be on at all times Wear proper clothing Take warm-up breaks Shut down work if conditions create an unsafe environment that cannot be effectively mitigated Treat safety glasses with anti-fog material Use appropriate artificial lighting (headlamps, lanterns, light plants, etc.) Avoid ice, spread traction sand, use traction aids on boots, move with care Notes: Page 6 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

91 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 013 Operations: Fatigue Long Work Hours Monotonous Tasks Overuse Injuries P P P A A A Comply with GHSEP on fatigue management Complete fatigue risk assessments when working long hours Limit consecutive days worked Vary tasks to prevent complacency Take frequent breaks Think tasks through and plan for them before execution 014 Operations: UO Explosion P/F/E A/S/W Review of report on UO found during a previous investigation of Garrison Slough and the subsequent geophysical investigation by qualified personnel (UO/Geophysicist). Additional geophysical/uo investigation if determined to be necessary by review of previous work. 015 Operations: Heavy Equipment Decontamination Spreading COPCs Caught Between Cuts/Lacerations Slip/Trip/Fall P/F/E P P P A/W A/E A/S A/S Modified level D PPE is required Wear cut-resistant gloves Perform dry decontamination of equipment when leaving the exclusion zone Perform wet decontamination as needed Use lockout/tagout on equipment while not in use Conduct wipe sampling / rinse sampling to assess decontamination techniques Use PPE to create a barrier (i.e. booties, Tyvek, nitrile gloves, etc) Washing hands when moving to a new task Wash clothing frequently Take showers regularly, or as needed for decontamination Notes: Page 7 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

92 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 016 Operations: Wildlife/Domestic Animals 017 Operations: Traffic Control 018 Operations: Underground Utilities Bear Moose Insects Equipment Damage Spreading PCBs Cuts/Lacerations Struck By/Against Caught Between Strain/Sprain (Lifting) Slip/Trip/Fall Electrocution Equipment Damage Property Damage Slip/Trip/Fall Crushing P P P F E P P P P P P F F P P A/S A/S A/S E/S/W A A/S E/S A A A/S D/W/A A/W/E A/W/E A A/S Follow HSEP 7.4, Working Safely Around Wild Animals Communicate observations to project team Keep bear spray and air horns nearby or on your person Observe the area prior to exit from vehicle Pay attention to surroundings Use insect-netting jackets and insect repellant Avoid wasp nests Modified level D PPE is required Use cones, barricades, and/or flaggers to channelize and direct traffic Utilize a blocker vehicle when working on a roadway or its shoulder Wear abrasion/pinch/cut-resistant gloves as appropriate Employ proper lifting techniques Watch for traffic and act accordingly Use a backup spotter when needed Modified level D PPE is required Use geophysical methods and manual exposure of utility lines prior to excavation Survey and mark known utilities Maintain utility location markings throughout site work Install barricades around open excavation/potholes/borings Notes: Page 8 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

93 Activity Hazard Analysis SS67 and WP45/SS57 Eielson AFB Ref. Number Activity or Element Hazard Asset Preliminary Risk Assessment High Med Low Control Type Controls Final Risk Assessment H M L 019 Operations: Decontamination Water Drowning PCB Exposure Spreading COPCS Slip/Trip/Fall Struck By/Against Lifting Strain/Sprain P P E P P P A/S A/S D/E A/S A A/S Modified level D PPE is required Containerize decontamination water in closed top containers (e.g. drums) Utilize secondary containment to prevent spills (e.g. duck ponds or kiddy pools) Notes: Page 9 Asset: P = Personnel, F = Facilities and equipment, E = Environment Control Type: D = Design, E = Engineering control, S = Safety device, W = Warning device, A = Administrative control

94 ATTACHMENT A-5 Project-Specific Forms Exhibit 1 Exhibit 2 Exhibit 3 Exhibit 4 Exhibit 5 Exhibit 6 Exhibit 7 Exhibit 8 Exhibit 9 Exhibit 10 Exhibit 11 Exhibit 12 Exhibit 13 Exhibit 14 Exhibit 15 Exhibit 16 Exhibit 17 Exhibit 18 Exhibit 19 Exhibit 20 Exhibit 21 Exhibit 22 Site Project Safety and Health Agreement Approval of Modification Visitor Check-In Log Safety Observation Report Air Monitoring Record Exposure Monitoring Log Authorization for Medical Treatment Daily Health and Safety Report Welding-Brazing-Hot Work Permit Health & Safety Instrument Calibration Log Accident-Incident Investigation Report Vehicle Accident Report Rental Equipment Condition Report for Automobiles- Trucks Standard Equipment Inspection Form Hazardous Material Exposure and Field Activity Report Site Tailgate Meeting and Exclusion Zone Entry Log SPA Form SPA Assessment Form SOR Form Drug, Alcohol, and Contraband Policy Form CEPOD Immediate Report of Accident USACE Accident Investigation Report

95 Exhibit 1 Site Project Safety and Health Agreement Sign-Off Sheet Project Team: Title Signature Date I am familiar with and agree to abide by this SSHP.

96 Exhibit 2 Approvals of Modifications Change Number Effective Date Table Number Changed Content of Change Jacobs Approval Health and Safety Manager Client Approval

97 Exhibit 3 Visitor Check-In Log Project Name: Project No.: Date: Name Representing Destination In Time (24-Hour) Out

98 Exhibit 4 Safety Observation Report Date: Time: Originator: Project: Location: Observation: Supervisor: Action Person: Check Box That Applies: Safe Behavior Observed (No Further Action Required) Proper Procedures Followed Unsafe Behavior Unsafe Condition If Non-compliance describe non-compliance below: Corrective Action: Further Action or Help Needed? Action Person Signature: (follow- Date Closed: up) Action Person Notified: Yes/No

99 Exhibit 5 Air Monitoring Record Employee Name: Employee No.: Company: Title: Project Name: Date Sampled: Sampled By: Project Number: Sampling Method and Analyte: Collection Media: Charcoal Filter (Total) Passive Dosimeter Collector Mfg: Tube Silica Gel Filter (Resp.) Other: Size/Type: Chromosorb Impinger Lot #: Sample Type: Personal - TWA Blank Does Sampling Represent Typical Exposure? Personal Peak Bulk Temperature Collector Mfg: Area Other Humidity: Wind: Source Activities During Sample Collection: Sample Pump: Mfg & Model #: Serial #: Calibrator: Type: Mfg & Model #: Serial #: Calibration Date: Calibrated By: Sample # Time On Time Off Total Time Pre Cal Flow Rate Post Cal Flow Rate Average Flow Rate Sample Volume Analytical Result TWA Descriptive Data: (Engineering controls or PPE used, work activities, sample interferences etc.) Date: Signature: Send results to: File; Project Manager; H&S; Employee

100 Exhibit 6 Exposure Monitoring Log Project Name: Project No. Date: Location Monitored: Activity Monitored: Site No. Atmospheric Conditions: Time (24-Hour Clock) Background Monitor (depth) FID (ppm) PID (ppm) Readings %O 2 %LEL H 2 S Mini-Ram Other Samplers Initials

101 Exhibit 7 Authorization for Medical Treatment TO: Dr. Address: Date: This form signed by our representative is your authority to render treatment to: (Employee) in accordance with the provisions of and under the conditions prescribed by the Workers Compensation Act. Unless the case is an emergency, kindly obtain authorization for surgery, radical procedures, or hospitalization from the insurance carrier. Send your bill and report to us at the address listed below. Authorized Representative Date of Injury: Location: Job No. How Injury Occurred: Please complete and return by mail to the following address to ensure prompt payment of charges: Risk Manager 1111 South Arroyo Parkway Pasadena, CA Diagnosis of Injury: Disposition of Patient: FOR DOCTOR S USE ONLY Occupational Non-Occupational Unable to Determine Able to resume regular duties Able to resume regular duties next workday Able to resume restricted duties with the following limitations: Unable to return to work, estimated length of disability: Return for follow-up visit on (Date) Doctor s Signature

102 Exhibit 8 Daily Health and Safety Report Contract Nu mber / Delivery O rder Number: Project Title: Location: Date: List Contra ctors/organizations Present: WEATHER CONDITIONS Temp Low: Temp Hi: Comments: Wind Speed: Conditions: Zero Accident Process Safe Plans of Action in effect today: Yes No Total Project SPAs generated to date: Were any Safety Observation Reports (SORs) generated today? (List Individually) Yes No Total SORs for today: Total SORs since mobilization: Check any of the following inspections performed today: Health and Safety Inspections Heavy Equipment Hand Tools Site Office Drill Rig Misc. Electrical Excavation PPE Other Cranes Storage Areas Sanitation Facilities Monitoring Instruments Misc. Equipment Exclusion Zone Operations List:

103 Daily Health and Safety Report (Continued) Observation/Comments made during the daily inspections : Air Monitoring Was air monitoring performed within the breathing zone today? N/A Yes No Did the air monitoring results exceed the PEL? N/A Yes No Have Air Samples Been Collected for Laboratory Analysis? Yes No TYPE OF TEST (personal, area, perimeter) TEST METHOD/MATRI QUANTITY OF SAMPLES General Health and Safety WORKER PROTECTION LEVELS THIS DATE: LEVEL A LEVEL B LEVEL C LEVEL D N/A Was any work activity conducted within a confined space? Yes No Was any work activity conducted within an area determined to be immediately dangerous to life and health? Yes No Were approved decontamination procedures used on workers and equipment as required? N/A Yes No Was a Safety Tailgate Meeting held this day? (See attached) Yes No Was there any Lost Time accidents this day? (If YES, attach copy of completed accident report) Yes No Was hazardous waste/materials released into the environment? (If YES, attach copy of spill report) Yes No (SM) Date Health and Safety Date

104 Exhibit 9 Welding/Brazing/Hot Work Permit PERMIT # Issued by: Approved by SSHO: Date Permit Issued: Time Permit Issued: Expiration Date: Operation to be Performed: Location of Operation: Special Precautions: TESTING Location of Testing Time Percentage of LEL Percentage of O 2 Initials CHECKLIST Item N/A Yes Initials of Inspector Surround equipment and operation safe for hot work Tank purged Extinguisher present No combustibles within 35 feet of operation or items protected by covers or removed from area No flammables within 50 feet Worker has proper protective equipment to perform function Safety blankets available Flammable gases greater than 10% present additional precaution needed to perform operation Fire watch required Welding unit inspected Adequate ventilation available The location where the work is to be performed has been examined, necessary precautions taken to provide for worker safety and for the area to be a fire safe environment for performing these functions. Permission is granted for the work to be performed. Signature of SSHO performing inspection and issuing the permit: I am fully qualified to perform this operation and understand my responsibilities outlined by the inspection just conducted. Signature of welder/on scene supervisor performing operation:

105 Exhibit 10 Health & Safety Instrument Calibration Log PROJECT NO.: PROJECT LOCATION: PROJECT ACTIVITY: Date Time Instrument Mfg Model Serial No. Calibration Gas Lot No. Concentration BKG Counts Span Settings Initials FIELD TEAM LEADER SIGNATURE

106 Exhibit 11 Accident/Incident Investigation Report Date of Accident/Incident: Time of Accident/Incident: Company: Date of Investigation: Job Number: Client: Location of Accident/Incident: Did injury result? Yes/No, If yes, provide Employee Name(s): S.S. No.: Skill: Yrs. in this Skill: Yrs. with Company: Describe Type of Injury: Was property damaged? Yes/No, Describe damage/owner: Is damaged property secured/maintained? Yes/No, Person Maintaining Names of Witnesses/Coworkers (With Social Security No.): Weather / Wind Conditions: List/Describe all personal protective equipment (PPE) in use by person exposed or injured: If Chemicals Involved: Name(s) of Chemical(s) Encountered: Form of Chemicals (Solid, Liquid, Gas, Vapor, Dust, Mist Fume): Describe Radiological Materials (if any): Volume or Quantity Released: Description of Accident/Incident:

107 Accident/Incident Investigation Report (Continued) Contributing Factors: What corrective actions are being taken to prevent recurrence? Also list the person responsible for implementing and the target completion date for each item. Was an SPA/JSA developed for the task being performed? Yes/No, If yes, attach a copy. Was a permit issued? Yes/No, If yes, attach a copy of the permit in effect at time of the Accident/Incident. Indirect cause of Accident/Incident: Lack of: Training, Resources, Belief (*explain) Basic cause of Accident/Incident: Failure to: Plan, Direct, Organize, Control (*explain) INVESTIGATION TEAM MEMBERS: Injured / Involved: Supervisor: Site Manager: Health and Safety Representative: Name Name Name Name Signature Signature Signature Signature Name (Others) Title Signature Name (Others) Title Signature Client Representative(s) Contacted: Agency Representative(s) Contacted: * Attach additional sheets and supplemental data & information as necessary. ** Distribution: Original must be filed on-site; 1 copy must be sent promptly to the Corporate Health and Safety Department.

108 Accident/Incident Investigation Report (Continued) Please print or type. Witness Statement Name: Title: Social Security Number: Date: Time: Temporary Address: Phone No. Permanent Address: Phone No. Location at Time of Accident: Describe, to the best of your knowledge, what happened just before, during, and just after the accident: Signature

109 Exhibit 12 Vehicle Accident Report CLAIM REPORTING: RISK MANAGEMENT DEPT.: Toll Free: (877) Phone: (225) Fax: (225) Company or Subsidiary Name: Date of Accident: Time of Accident: AM PM Location of Accident: Client Facility/Project Site Office Other Nearest Intersection, City & State: COMPANY VEHICLE: Driver: Date of Birth: Office / Project No. Assigned to: Name(s) of Passengers: Work Address: Home Address: Work Phone No. Supervisor Name: Home Phone No. Supervisor Phone No. Vehicle Owner: Company Owned Leased Rental Personal Vehicle No.: License No.: Make and Model: Vehicle Identification No.: Has Driver completed Jacobs Recognized Driver Training? Yes No OTHER VEHICLE: Driver: Home Address: Work Phone No. Home Phone No. Driver s License no. (Including State) Vehicle Owner: Make and Model: Relation to Owner: Insurance Company: Insurance Agent: Insurance Agent Phone No.:

110 Vehicle Accident Report (Continued) Policy No.: INCIDENT DESCRIPTION Contact with Other Vehicle Fixed Object Pedestrian Other Details: DESCRIPTION OF DAMAGE TO VEHICLE: Company Vehicle: Est. Repair Cost $ Where Vehicle can be seen: Other Vehicle: Est. Repair Cost $ Where Vehicle can be seen: INJURIES / WITNESSES: Company Vehicle: Name and age of Injured Witnesses Relation to Driver of Company Vehicle: Other Vehicle: Name and age of Injured Witnesses Relation to Other Vehicle: Name of Investigating Officer: Badge No. Police Report No. Citations: OTHER PROPERTY DAMAGE: Owner s Name, Address and Phone No. Describe Damage: Report Submitted By: Date:

111 Vehicle Accident Report (Continued) DIAGRAM OF ACCIDENT

112 Exhibit 13 Rental Equipment Condition Report for Automobiles/Trucks CLIENT PROJECT NO. VEHICLE TYPE AGENCY RECEIVED FROM MAKE/MODEL MILEAGE Out MILEAGE In Yes or No Where Appropriate G - New or in Good Condition R - Requires Repairs N - Items Not Applicable BODY & INTERIOR Inspection Sticker License/Sticker Upholstery Heater/Defroster Door Locks Door Handles Air Conditioner Steering Lighting System Body Floor Boards/Mats Paint ENGINE & OPERATING SYSTEMS Oil Level and Condition Oil Leaks Operating Condition Water Lvel/Anti-Freeze Tire Condition/Lugs Cooling System/Hoses Transmission Transmission Level/Condition Battery Condition Corrosion/terminal Connections Tire Pressure Lug Nuts Fan/ Alternator Belts Control Panel, Gauges Jack, Tire Tool Spare Tire Exhaust System Windshield Wipers Brakes

113 Rental Equipment Condition Report for Au tomobiles/trucks (Continued) Windows, Windshield Parking Brake REMARKS: Initial Inspection By Date

114 Exhibit 14 Standard Equipment Inspection Form Make Type Year of Manufacture Date Model Serial No. Hours Employee ID Inspector Name Fill in appropriate boxes Company Name Supervisor Name Engine Attachment Attachment A. SERVICE CHECKS PRE-FIELD MOBILIZATION: ITEM OK AMT NEEDED ITEM OK Radiator & Freeze Protection Transmission Final Drives Engine Hydraulic System Lubrication Points Batteries Differential/Plan Tandems Fuel Level Drain Fuel Sediment Pivot Shaft AMT ADDED B. EQUIPMENT INSPECTION PRE-FIELD MOBILIZATION Engine Compartment Radiator Fan & Shrouds Air Induction and Filter Belts Pulleys Exhaust & Rain Cap Battery & Cables Hydraulic Cylinders Operators Comp. Controls & Linkages Hoses & Lines Oil Leaks Fuel Leaks Coolant Fasteners Cracks Guards & Covers Cutting Edges Sprockets Rollers & Idlers Tracks or Tires CONDITION Bad/Good/ Excellent Attn Needed Explanation Corrected? (Y/N)

115 Standard Equipment Inspection Form (Continued) B. EQUIPMENT INSPECTION PRE-FIELD MOBILIZATION (continued) Engine Governor Control Trans Operation Trans Linkage Steering System Service Brakes Parking Brake Unusual Noise Gauges Operational Gauges Normal Backup Alarm Heater & Fan Switches Wipers & Washer Lights Horn Seat & Seat Belts Windows Doors General Appearance: Machine Damage: CONDITION Bad/Good/ Excellent Attn Needed Explanation Corrected? (Y/N) NOTES: NOTES (continued):

116 Standard Equipment Inspection Form (Continued) Deficiencies noted: Yes No Explain: Deficiencies fixed: Yes No Date: Inspection 100% complete Yes No Subcontractor Signature Date all items passed inspection: Jacobs Representative Date:

117 Exhibit 15 Hazardous Material Exposure and Field Activity Report Employee s Office Location: Anchorage For: Month Year NAME OF EMPLOYEE: CHECK HERE FOR: NO SITE VISITS PART I - SITE VISITS TO NON-ECLUSION ZONES SITE NAME/ DURATION OF LOCATION ACTIVITY SITE VISIT (HOURS) PART II - SITE VISITS TO ECLUSION ZONES (For additional room, use back of form) CHEMICAL OR EPOSURE DURATION OF LEVEL OF SITE NAME/ OTHER MATERIALS POTENTIAL SITE VISIT PROTECTION LOCATION ACTIVITY PRESENT (I.M.S.) HOURS USED *I = Incidental Potential for exposure is 1/10 or under the exposure limit level. M = Moderate Potential for exposure is >1/10 up to, but not including, the exposure limit level. S = Significant Potential for exposure at or above exposure limit level. EMPLOYEE SIGNATURE DATE Return to: Jacobs Safety Officer, Jacobs Engineering, 4300 B Street, Suite 600, Anchorage, AK 99503

118 Exhibit 16 Site Tailgate Meeting and Exclusion Zone Entry Log Facility: Date: Client: Specific Location: Type of Work: Chemicals Brought to Site: Conducted by: Time: Project Number: MSDSs available: Yes No Protective Clothing/Equipment: HEALTH AND SAFETY TOPICS PRESENTED Chemical Hazards: Physical Hazard: Emergency Procedures: Emergency Response Hospital/Clinic: Address: Special Equipment: Evacuation Route: General Discussion Information:

119 Site Tailgate Meeting and Exclusion Zone Entry Log (Continued) ATTENDEES Entered Exclusion Zone Printed Name Company SS# Signature Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No Yes No

120 Exhibit 17 Safe Plan of Action Project No Job/Task Date Steps of Task Hazard/Reaction to Change Safe Plan Resources

121 Exhibit 17 Safe Plan of Action (Continued) Steps of Task Hazard/Reaction to Change Safe Plan Resources Team Members Signatures The signature of the supervisor confirms the completion of the hazard assessment and Safe Plan of Action by the crew. Instructions: 1. Write name of job or task in space provided. 2. Conduct walk-through survey of work area. 3. Write the steps of the task in a safe sequence. 4. List all possible hazards involved in each step and reaction to change. 5. In the Safe Plan column, state actions that will be taken to prevent the hazards or injury from reaction to change. 6. In Resources column, list equipment, tools, etc. needed to do the job. 8. Ask each team member, who helped develop and will use this SPA, to sign in spaces provided. 9. Review the SPA at the end of the task for improvements. Work shall stop when conditions change, the job changes, or a deficiency in the plan is discovered, and the current SPA will be modified or a new SPA created.

122 Exhibit 17 Safe Plan of Action (Continued) Review checklist while completing front page of SPA. Check all that apply. A new SPA is required if the job scope or work conditions change. Required Permits Hazards Safe Plan Confined Space Overhead Utilities Power de-energization required Insulation blankets required Wire watcher required Critical Lift Required clearance distance = Ft. Safe work zone marked Hot Work Crane or other Signalman assigned Tag lines in use Area around crane barricaded Lock Out/Tag Out Lifting Equipment Lifting equipment inspected Personnel protected from overhead load Soil Disturbance (Over 12 ) Underground Utilities Reviewed as-builts Subsurface surveys Received dig permit Utility Clearance Required clearance distance = Ft. Safe work zone Marked Required PPE Electrical Hard Hat, Class C Reviewed electrical safety procedures Hard Hat, Class E (Elect. Protect) Excavations Lock Out/Tag Out/Try Out Permit required? Confirm that equipment is de-energized Permits Inspected prior to entering Proper sloping/shoring Ear Plugs/Ear Muffs Barricades provided Access/egress provided Protection from accumulated water Eye Protection: Fire Hazard Hot Work Permit Fire Extinguishers Fire watch Safety Glasses Adjacent area protected Unnecessary flammable material removed Face Shield Vehicular Traffic or Traffic Barricades Cones Signs Flagmen Lane closure Chemical Goggles Heavy Equipment Communication with equipment operator Welding Hood Noise >85 db Hearing protection is required: Ear plugs Ear Muffs Both Hand Protection: Hand & Power Tools: Inspect general cond. GFCI in use Identified PPE required for each tool Cut Resistant Gloves Reviewed safety requirements in operators manual(s) Guarding OK Welders Gloves Hand Hazards List sharp tools, material, equipment: Nitrile Gloves PPE gloves, etc. Protected sharp edges as necessary Surgical Gloves Manual Lifting Reviewed proper lifting tech. Identified material requiring lifting equipment Rubber Gloves Hand protection required Back support belts Elect. Insulated Gloves Ladders Inspect general cond. before use Ladder inspected with in last quarter Arm Sleeves Ladder tied off or held Proper angle and placement Reviewed ladder safety Foot Protection: Scaffolds Inspect general condition before usetags in place Properly secured Sturdy Work Boots Toe boards used Footings adequate Materials properly stored on scaffold Safety Toe Boots Slips, Trips Falls Inspect for trip hazards Hazards marked Tools & material properly stored Rubber Boots Extension cords properly secured Work zone free of debris Rubber Boot Covers Pinch Points List potential pinch points: desks, doors, file cabinets, other boxes Dielectric Footwear Working near operating equipment Hand/Body positioning Respiratory. Protection: Dust Mask Working w/ Chemicals List specific chemicals involved and list hazards and precaution on front side. Reviewed MSDS Exposure Monitoring required Have proper containers and labels. Identified proper PPE (respirators, clothing, gloves, etc.) Air Purifying Respirator Asbestos or Lead Paint Areas to be worked may contain asbestos or lead paint Asbestos controls incorporated Supplied Air Respirator Potential Lead based point controls in place Exposure monitoring conducted. SCBA Heat Stress Potential Heat stress monitoring (>85 o ) Liquids available Cool down periods Emergency Escape Respirator Sun Screen Reviewed Heat Stress symptoms Special Clothing: Cold Stress Potential Proper clothing (i.e.. gloves, coat, coveralls) Wind chill <32 o Reviewed Cold Stress symptoms Warm up periods Tyvek Environmental Air emissions Water discharge Hazardous wastes Other wastes Poly Coated Tyvek Pollution prevention Waste minimization Fire Resistant Coveralls Natural or Site Hazards Weather Terrain Adjacent operations or processes Biological hazards Rain Suit Animals/reptiles/insects hazards Safety Vest Adjacent Work/Processes Notified them of our presence Other workers adjacent, above, or below. Fall Protection: Coordinated with adjacent supervisor/customer/operator Need barriers between. Barricades/covers Caution barricade tape required Danger barricade tape required Rigid railing required Harness Covers over opening Warning signs required Double Lanyard Required Anchorage Point Available Additional Anchorage Connector Needed e.g. Cross Arm Strap, etc. Retractable Device Needed Horizontal Life Line System Req d. Fall Clearance Distance Adequate Fall Rescue/Retrieval Plan Set Up Additional Information:

123 Exhibit 18 SPA Assessment Card HSEP 2.16f2 Assessment Observation For printing, download printer-ready version of pocket card in PDF file posted on JNet as HSEP 2.16f3.

124 Exhibit 19 Safety Observation Report Date: Time: Observer: Company: Project: Site Manager or SSHO: Type: Safe Behavior Safe Condition Unsafe Behavior Unsafe Condition Action Person: Location: Observation: Subject/Title: Details: Corrective Action: Further Action or Help Needed? YES NO Action Person: Signature: Date Closed: Hazard Category (check all that apply) Aerial Work Platforms Barricades/flagging/signage Communication/Coordination Electrical Hazard Energy Isolation / LOTO Environmental Excavation Hazard Fall Protection/Prevention Fire Protection/Prevention Hazard Communication Heavy Equipment Hoisting/Lifting/Rigging Housekeeping Intellectual Property/Trade Secrets Ladders/Platforms/Scaffolds Motor Vehicles Other Personal Protective Equipment Procedure Violation Slip/Trip/Fall SPA/SWP Tools/Equipment/Materials Weather Welding/Cutting/Grinding

125 Global Policy Supplement Drug, Alcohol and Contraband Policy Issuing Department: Corporate Human Resources Document No: GPS Page: Revision & Effective Date: Rev. 0, 21-Jun-10 1 of 9 Previous Revision & Effective Date: n/a 1.0 PURPOSE OF PROCEDURE PROCESS OBJECTIVE SCOPE OF APPLICATION PROCESS REQUIREMENTS Illicit Drug Use Alcohol Use and Misuse Use of Prescription Medications Contraband Searches Federal Drug-Free Workplace Act of Employee Assistance Education Drug & Alcohol Testing Job Applicants Current Employees Reasonable Suspicion Testing Post-Incident Testing Unannounced Testing Follow-Up Testing Pre-Access/Pre-Assignment Testing Consequences of a "Positive" Test Refusing a Test Procedures for Drug and Alcohol Testing Consent Collection and Chain-of-Custody Testing Methods Notification compliance with all applicable laws Attachments...6 RETURN TO WORK AGREEMENT...7 CONSENT...8 EMPLOYEE CERTIFICATION PURPOSE OF PROCEDURE Jacobs Engineering Group Inc., its subsidiaries and affiliated companies (hereinafter, "the Company"), recognizes its responsibility to employ all necessary measures to ensure a safe and healthful working environment for employees, to protect and preserve our property and that of others, and to cooperate with our clients in our mutual efforts to provide safe and efficient operations while maintaining conditions conducive to attaining the highest possible work standards. This responsibility, in a potentially dangerous industry, which demands comprehensive safety measures, extends not only to the protection and well being of our employees and job sites, but to our customers, the community, and general public as well. Our commitment to the protection of our employees, property and the public is evidenced by the implementation of programs and procedures, which ensure compliance with appropriate safety measures and all applicable laws and Copyright 2010 by Jacobs Engineering Group Inc. All rights reserved. The contents of this document are proprietary and produced for the exclusive benefit of Jacobs Engineering Group Inc and its affiliated companies. No part of this document may be reproduced, stored in a retrieval system, or transmitted, in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written approval of Jacobs Engineering Group Inc. The applicable version of this document resides in the Business Practices section of All copies are considered to be uncontrolled. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

126 GSP Page 2 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun-10 regulations. 2.0 PROCESS OBJECTIVE This Drug, Alcohol, & Contraband Policy sets out the Company's policy and procedures regarding: (i) the illegal use, sale, possession, transfer, or other misconduct involving drugs; (ii) the use and misuse of legal drugs; (iii) alcohol use and misuse; and (iv) the possession of illegal or contraband items, such as weapons and drug paraphernalia, prohibited by law or by Company policy. 3.0 SCOPE OF APPLICATION This policy applies, without exception, to all employees, job applicants, and subcontractors working at a Company job site or at a customer s job site. Employees who are subject to federal drug and/or alcohol testing requirements (for example, U.S. Department of Defense, Energy, or Transportation drug- and alcohol-testing regulations) will be so notified and must comply with this policy and with the applicable policy implementing those regulations. Employees who are covered by a collective bargaining agreement may be subject to different terms and will be notified of any modifications to this policy. 4.0 PROCESS REQUIREMENTS The Company strictly prohibits the unlawful use, sale, attempted sale, manufacture, possession, conveyance, purchase, attempted purchase, distribution, cultivation, transfer, or dispensing of any illicit substance, at any time and in any manner. This prohibition includes the use or possession of prescription medications for which the employee does not have a valid prescription. 4.1 ILLICIT DRUG USE Illicit substance includes all drugs, narcotics, inhalants and intoxicants for which possession or misuse is made illegal under federal, state, or local law, and includes prescription medication for which the individual does not have a valid prescription. Prescription medication and over-thecounter drugs used in a manner inconsistent with prescription or dosing directions also are considered illicit drugs, as may be other chemical intoxicants used in a manner inconsistent with their intended purpose. Alcohol also is a drug subject to abuse, although its use and misuse is treated separately under this policy. 4.2 ALCOHOL USE AND MISUSE The use or abuse of alcohol while on the job or in a Company vehicle is strictly prohibited. Management for such functions as dinners, conferences, award ceremonies and celebrations may authorize alcohol purchase or consumption. However, the use or abuse of alcohol off the job, which impairs performance on the job, is prohibited. Employees are prohibited from reporting to work with alcohol in their systems and from bringing any alcoholic beverage to the work location. A confirmed test result between and percent alcohol may result in a suspension of 24 hours. Prior to returning to work, a negative alcohol test must be obtained. A confirmed positive test showing the presence of 0.04 percent or more alcohol in an employee s system is a violation of this policy. 4.3 USE OF PRESCRIPTION MEDICATIONS Employees who use prescription and/or over-the-counter medication, which could impair their ability to perform safely, are responsible for notifying their immediate supervisor or the Health Services Department so that steps can be taken to minimize the safety risks posed by such use. Any information about an employee s use of medication will be treated as confidential and shared with Company personnel on a need-to-know basis. It is each employee s responsibility to consult with his or her health-care provider and/or to review relevant dosing instructions to determine whether the use of that medication could lead to impairment. No medication containing alcohol should be used during or immediately before an individual s scheduled shift, unless by prescription. The Company reserves the rights to transfer, reassign, or, if necessary, place an employee on leave of absence if the employee may pose a safety risk while using medication. Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

127 GSP Page 3 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun CONTRABAND The Company also prohibits the use, possession, distribution, or sale of any drug paraphernalia, look-alike drugs, firearms, weapons, unauthorized explosives, stolen property, or other contraband while on Company business and/or at any job site or premises. Contraband is any item the use or possession of which is prohibited by law, Company policy, or work rules. Job sites and premises include all Company property, including Company-owned motor vehicles, Company quarters, Company parking lots, and any other location at which Company employees may work, including client job sites and premises. 5.0 SEARCHES If the Company suspects that an employee or on-site contractor is in possession of illegal drugs, alcohol, or contraband in violation of this Policy, the Company may request the individual to submit to a search of his or her person, personal effects, vehicles, lockers, baggage, and Company quarters. In addition, the Company may periodically conduct searches of individuals entering or leaving work sites at random. By entering into or being present at a job site, while on Company time, or representing the Company in any way, an individual is deemed to have consented to such searches. If an individual is asked to submit to a search, and refuses, that individual will be considered insubordinate and will be escorted off the job site and disciplined, as appropriate. Searches will be conducted by management personnel and may or may not be conducted in the presence of the person whose property or work area is searched. Any suspected contraband will be confiscated, and may be turned over to law enforcement as appropriate. The Company representative conducting the search will give any person whose property is confiscated a receipt for that property. 6.0 FEDERAL DRUG-FREE WORKPLACE ACT OF 1988 To fulfill its obligations under the Federal Drug-Free Workplace Act of 1988, the Company requires any employee working directly or indirectly on a Federal Government project who is convicted of any drug-related crime occurring in the workplace to notify the Company within five (5) days of the conviction. The Company is required to notify the government agencies with which it contracts within ten (10) days of any employee s conviction on such charges. Education regarding the dangers of illegal drug use and alcohol abuse will be provided as detailed in Section V, below. The Company will impose discipline for employees convicted of any offense involving illegal drugs, up to and including dismissal from employment. 7.0 EMPLOYEE ASSISTANCE The Company encourages employees who believe they have a problem with alcohol or drugs, legal or illegal, to seek assistance. The Company offers employees access to its Employee Assistance Program (EAP), which can offer referral to appropriate services and rehabilitation programs that emphasize education, prevention, counseling, and treatment. Moreover, employees may be eligible for a leave of absence to participate in such a program. Employees may ask for an appointment with the EAP Coordinator assigned to your location, in writing or in person, by contacting the appropriate Human Resources representative or the Health Services Department. Each request for assistance will be treated as confidential, and only those persons with a need to know will be informed of an employee s request. Although requests for assistance are confidential, entering such a program cannot absolve nor protect employees from the consequences of substandard work performance or policy violations. Therefore, it is the responsibility of each employee to seek assistance before the employee s alcohol- or drug-abuse problems lead to a violation of this or another Company policy justifying disciplinary action. An employee s decision to seek help voluntarily will not be used as a basis for disciplinary action against the employee, although the employee may be transferred, given work restrictions, or placed on leave, as the Company deems appropriate, while the employee seeks assistance and/or until the employee is drug- and alcohol-free. An employee s decision to seek assistance under this policy Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

128 GSP Page 4 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun-10 will be considered voluntary only if the employee seeks assistance prior to being found in violation of this policy or being asked to take a drug and/or alcohol test. Regardless of how an employee determines to seek assistance, a failure to successfully complete a recommended course of treatment to the Company s satisfaction will be grounds for termination. All employees returning to employment following rehabilitation will be required to sign a Return-to- Work Agreement, which will include: An agreement that the employee will continue to participate in any follow-up treatment and/or counseling recommended by the treatment provider, to the provider and the Company s satisfaction; A requirement that the employee submit to unannounced follow-up testing, for a period of up to two (2) years as recommended by the employee s rehabilitation provider, to encourage and insure the employee remains drug and/or alcohol free; An agreement that a refusal to submit or a positive drug and/or alcohol test during this period shall be grounds for immediate dismissal; and An agreement that the employee understands that s/he must maintain an acceptable attendance and performance record, and must comply with all other Company policies at all times. 8.0 EDUCATION As part of the Company s efforts to encourage employees to become or remain drug-free, information and training will be provided on an on-going basis, as the Company deems appropriate, regarding the effects of drug and alcohol abuse. The local Personnel Department will assist with employee and supervisory education and training regarding the dangers of drug and alcohol use in the workplace. Materials on drug and alcohol use will be made available to both employees and supervision. The Company will also provide periodic supervisory training to assist in identifying the behavioural and physiological signs of alcohol and drug use. 9.0 DRUG & ALCOHOL TESTING In furtherance of its goal of ensuring a substance abuse free workplace, the Company has established the following drug and alcohol testing procedures for its employees and applicants for employment. The Company may require employees and job applicants to submit urine, saliva, hair, blood, sweat, and/or breath samples for the purpose of checking for the presence of illicit drugs or alcohol, for both job applicants and employees, as defined in sections 9.1 and JOB APPLICANTS All job applicants must take and pass a mandatory drug test as soon as practical following their acceptance of a conditional offer of employment, and prior to the actual time they commence employment with the Company. Applicants who apply to safety-sensitive positions at client projects may also be asked to agree to comply with the client s substance-abuse prevention rules, and will be notified of any such requirements at the time of the conditional offer of employment. Job applicants who test positive for illicit drug use will not be hired. Any applicant who tests positive for drugs may not re-apply for a position with the Company for at least six months. A job applicant s refusal to submit to drug testing, or attempt to tamper with, substitute for, adulterate, dilute, or otherwise falsify a test sample will result in denial of employment. 9.2 CURRENT EMPLOYEES Reasonable Suspicion Testing The Company may require employees to submit to drug and/or alcohol testing whenever Company Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

129 GSP Page 5 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun-10 management has information about an employee s conduct that would cause a reasonable person to believe that the employee is demonstrating signs of impairment due to alcohol or drugs, appears unfit for duty, or is otherwise in violation of this Policy Post-Incident Testing The Company may ask employees who are involved in a workplace incident which results, or could have resulted in an injury to any person requiring medical attention (other than first aid), and/or property damage, to submit to post-incident tests for drugs and/or alcohol as part of the investigation of any such incident Unannounced Testing Employees are subject to unannounced drug testing and those who work in safety-sensitive positions will be subject to unannounced alcohol testing, depending upon the nature of their assignment and responsibilities, as well as upon the drug- and alcohol-testing requirements of the Company s customers if the employees are to work on a customer s job site or project. Employees who are subject to this requirement will be so notified at the time they are conditionally offered employment with the Company or are offered a transfer to a position subject to such testing. Employees subject to testing may be selected at random or by other means, such as by job classification or work site Follow-Up Testing Unannounced follow-up testing may be required as a condition of continued employment during and after an employee has participated in a treatment program for drug or alcohol abuse, as recommended by the employee s substance-abuse treatment provider and approved by the Company, for a period not to exceed two years Pre-Access/Pre-Assignment Testing If an employee accepts a safety sensitive position or is transferred from one position or job site to another safety sensitive position or job site with different testing requirements, that employee may be required to take and pass a drug and/or alcohol screen before being allowed access to the job site Consequences of a "Positive" Test An employee whose alcohol or drug test is positive, regardless of the reason for the test, is considered to be in violation of Company policy and will be subject to adverse employment action, up to and including termination. Termination will be the standard disciplinary action unless there is a collective bargaining agreement, statutory requirement or other legal prohibition to termination. Anyone terminated for violation of this policy may not re-apply for a position with the Company for a minimum of six months Refusing a Test An employee or job applicant s refusal to submit to drug and/or alcohol testing will be considered insubordination and grounds for disciplinary action, up to and including termination. Attempts to tamper with, substitute, adulterate, dilute, or otherwise falsify a test sample are grounds for termination, and furthermore are punishable under criminal statutes in several states PROCEDURES FOR DRUG AND ALCOHOL TESTING 10.1 CONSENT No alcohol test will be administered, sample collected, or drug test conducted on any sample without the written consent of the person to be tested. A person s refusal to submit to a proper test will be viewed as insubordination and will subject the employee to disciplinary action, up to and including termination. The Company will pay the costs of all drug and/or alcohol tests it requires of job applicants and employees. Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

130 GSP Page 6 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun COLLECTION AND CHAIN-OF-CUSTODY Persons being tested will be asked to provide a test sample by the collection site person. Procedures for collection of urine specimens will allow for reasonable individual privacy, unless there is a reason to believe the individual may alter or substitute the specimen to be provided. Urine samples will be tested for temperature, and may be tested for adulterants or subject to other validation procedures, as appropriate. The collection site person and the person being tested will maintain chain-of-custody procedures at all times, and will follow the specimen collection procedures endorsed by the U.S. Department of Transportation for federally mandated testing TESTING METHODS All urine samples will be screened using an immunoassay technique and all presumptive positive tests will be confirmed using gas chromatography/mass spectrometry (GC/MS) or other equally sensitive methodology. A certified laboratory will perform all confirmatory tests. The Company currently tests for cannabinoids (marijuana), cocaine metabolites, amphetamines (including methamphetamines), opiates, phencyclidine (PCP), and alcohol, and may test for other illicit drugs at its discretion or as required by a client or by federal regulations, in which case, employees will be advised of the substances for which the Company or the client may test. Typically, breath and/or saliva tests will be used to detect the presence of alcohol, and positive tests will be confirmed with a second breath test. An alcohol test will be considered positive if it shows the presence of 0.04 percent or more blood-alcohol content. Tests will seek information about the presence of drugs and alcohol in an individual s system, and will not test for any other medical condition NOTIFICATION Any individual who tests positive for illicit drug use will be so notified by an independent Medical Review Officer ( MRO ) (typically, a medical doctor with an expertise in toxicology), and given an opportunity to provide the MRO with any legitimate reasons he or she may have that would explain the positive alcohol or drug test. If the individual provides an explanation acceptable to the MRO that the positive drug-test result is due to factors other than the consumption of alcohol or illicit drugs, the MRO will order the laboratory to disregard the positive test and will report the test as negative to the Company. Individuals may request a copy of their own positive test result. In addition, an individual who tests positive for drugs may request that his or her positive urine sample be sent to an independent laboratory for a second confirmatory test, at the individual's expense, although the Company may suspend, transfer, or take other appropriate action against the individual pending the results of any such re-test. All test results will be treated as confidential, and disseminated within the Company only on a needto-know basis. Test results will not be released outside the Company without the written consent of the tested individual, except when necessary to defend an action in an administrative proceeding or court of law or otherwise required by a court of law COMPLIANCE WITH ALL APPLICABLE LAWS The Company will implement this policy, including its drug and alcohol testing policy, in a manner that complies with relevant federal, state, and local law ATTACHMENTS Return to Work Agreement Consent Employee Notification Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

131 GSP Page 7 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun-10 RETURN TO WORK AGREEMENT DRUG, ALCOHOL AND CONTRABAND POLICY POST REHABILITATION/TREATMENT/COUNSELING As consideration for the Company granting the request for continued employment or re-employment, the following conditions shall prevail: 1. The Employee shall submit to the Company proof of his or her enrolment in an alcohol and/or abuse follow-up treatment, counselling or rehabilitation program. Proof of Employee s attendance at all required sessions must be submitted to the Company on a weekly basis. Attendance will be monitored closely. 2. For a period of two (2) years, the Employee agrees to voluntarily submit to testing for alcohol and/or illegal drugs on a random basis as requested by the Company. The Employee s failure of such test during this period or the Employee s refusal to submit to such testing shall be grounds for immediate termination. 3. The Employee must maintain an acceptable attendance and performance record and comply with all other Company policies upon his or her return to work. For a period of two (2) years, any absence by the Employee will require a written doctor s certificate detailing the reason for such absence. If such absence(s) is the result of alcohol and/or illegal drug use, the Employee will be terminated. 4. The costs of rehabilitation not covered by the group medical insurance plan of the Company shall be borne by the Employee. 5. Nothing in this Agreement alters your status with the Company. The Company desires your employment relationship with it to be successful. 6. Failure of the Employee to comply with all of the above conditions will result in the Employee s immediate termination. I voluntarily agree to all of the above conditions and I sign this Agreement on my own free will, without duress. Date Applicant/Employee Signature Witness Signature Applicant/Employee Printed Name Witness Printed Name Applicant/Employee Social Security No. Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

132 GSP Page 8 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun-10 CONSENT To Submit to Drug and/or Alcohol Testing As a Condition of Employment with Jacobs Engineering Group Inc., (its subsidiaries and affiliated companies hereinafter, "the Company") I,, hereby consent and agree to drug and/or alcohol testing as a condition of consideration for employment and/or continued employment by the Company. I further acknowledge that I have been informed of, and have agreed to comply with the Company s Drug, Alcohol & Contraband Policy. I understand that information regarding the test results may be used as grounds for adverse employment action, including denial of employment and/or termination of my employment with the Company. I further understand and acknowledge that: 1. The Company will pay the cost of all required drug and/or alcohol tests; 2. The test results will be released to the Company and may be used by the Company in determining any adverse employment action that may be taken against me, 3. If the laboratory results of my drug and/or alcohol test indicate a positive result, I will have an opportunity to discuss and rebut that result by consulting with a Medical Review Officer; and to request a second confirmatory drug test on that sample, at my own expense; and that the Medical Review Officer will determine whether there is a legitimate medical explanation for any positive drug test and; 4. I have the right to refuse to submit to such testing; understanding, however, that my refusal to submit to, or to cooperate with such testing shall be considered a refusal to submit to testing subject to denial of employment or termination in accordance with the Company's Drug, Alcohol & Contraband Policy. I agree that the Company has made no representations, inducements, or statements, other than those in writing, about the testing, and that I consent to be tested. I hereby further certify that the Company has provided me with a copy of its Drug, Alcohol & Contraband Policy; that I have read and do understand that Policy; and that I agree to abide by the terms and conditions of the Policy. Date Applicant/Employee Signature Witness Signature Applicant/Employee Printed Name Witness Printed Name Applicant/Employee Social Security No. Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

133 GSP Page 9 of 9 Drug, Alcohol and Contraband Policy Rev.0, Effective 21-Jun-10 EMPLOYEE CERTIFICATION Jacobs Engineering Group Inc., (Its subsidiaries and affiliated companies hereinafter, "the Company") I hereby certify that the Company has provided me with a copy of its Drug, Alcohol & Contraband Policy; that I have read and understand the Policy; and that I agree to abide by the terms and conditions of the Policy. I do understand that nothing in this policy is intended to create a contract, and I agree that no such contract is created by this Policy. Date Witness Signature Witness Printed Name Employee Signature Employee Printed Name Employee Social Security No. Copyright 2010, Jacobs Engineering Group Inc. File Name: GPS Drug, Alcohol, and Contraband Policy.doc

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136 (For Safety Staff only) REPORT NO. EROC CODE UNITED STATES ARMY CORPS OF ENGINEERS ACCIDENT INVESTIGATION REPORT REQUIREMENT CONTROL SYMBOL: CEEC-S-8(R2) (For Use of this Form See Help Menu and USACE Suppl to AR ) 1. ACCIDENT CLASSIFICATION PERSONNEL CLASSIFICATION INJURY/ILLNESS/FATAL PROPERTY DAMAGE MOTOR VEHICLE INVOLVED DIVING GOVERNMENT CIVILIAN CONTRACTOR PUBLIC MILITARY FATAL OTHER FIRE INVOLVED FIRE INVOLVED 2. PERSONAL DATA a. Name (Last, First, MI) b. AGE c. SE d. SOCIAL SECURITY NUMBER e. GRADE MALE FEMALE f. JOB SERIES/TITLE g. DUTY STATUS AT TIME OF ACCIDENT h. EMPLOYMENT STATUS AT TIME OF ACCIDENT OTHER OTHER ON DUTY OFF DUTY TDY ARMY ACTIVE PERMANENT TEMPORARY OTHER (Specify) ARMY RESERVE FOREIGN NATIONAL STUDENT VOLUNTEER SEASONAL 3. GENERAL INFORMATION a. DATE OF ACCIDENT (month/day/year) b. TIME OF ACCIDENT (Military time) c. EACT LOCATION OF ACCIDENT hrs d. CONTRACTOR'S NAME e. CONTRACT NUMBER f. TYPE OF CONTRACT g. HAZARDOUS/TOIC WASTE ACTIVITY CONSTRUCTION SERVICE SUPERFUND DERP (2) SUBCONTRACTOR: CIVIL WORKS MILITARY A/E DREDGE IRP OTHER (Specify) OTHER (Specify) OTHER (Specify) 4. CONSTRUCTION ACTIVITIES ONLY (Fill in line and corresponding code number in box from list - see help menu) a. CONSTRUCTION ACTIVITY (CODE) b. TYPE OF CONSTRUCTION EQUIPMENT (CODE) # (1) PRIME: 5. INJURY/ILLNESS INFORMATION (Include name on line and corresponding code number in box for items e, f & g - see help menu) a. SEVERITY OF ILLNESS/INJURY b. ESTIMATED c. ESTIMATED d. ESTIMATED DAYS (CODE) DAYS LOST DAYS HOSPIT- RESTRICTED DUTY ALIZED # # e. BODY PART AFFECTED PRIMARY SECONDARY f. NATURE OF ILLNESS/INJURY (CODE) # (CODE) # (CODE) # g. TYPE AND SOURCE OF INJURY/ILLNESS TYPE SOURCE (CODE) # (CODE) # 6. PUBLIC FATALITY (Fill in line and correspondence code number in box - see help menu) a. ACTIVITY AT TIME OF ACCIDENT (CODE) b. PERSONAL FLOATATION DEVICE USED? # YES NO N/A 7. MOTOR VEHICLE ACCIDENT a. TYPE OF VEHICLE b. TYPE OF COLLISION c. SEAT BELTS USED NOT USED NOT AVAILABLE PICKUP/VAN TRUCK AUTOMOBILE OTHER (Specify) SIDE SWIPE BROADSIDE OTHER (Specify) HEAD ON ROLL OVER REAR END BACKING (1) FRONT SEAT (2) REAR SEAT 8. PROPERTY/MATERIAL INVOLVED a. NAME OF ITEM b. OWNERSHIP c. $ AMOUNT OF DAMAGE (1) (2) (3) 9. VESSEL/FLOATING PLANT ACCIDENT (Fill in line and correspondence code number in box from list - see help menu) a. TYPE OF VESSEL/FLOATING PLANT (CODE) b. TYPE OF COLLISION/MISHAP (CODE) # # 10. ACCIDENT DESCRIPTION (Use additional paper, if necessary) ENG FORM 3394, MAR 99 Version 2 EDITION OF SEP 89 IS OBSOLETE. Page 1 of 4 pages (Proponent: CESO )

137 11. CAUSAL FACTOR(S) (Read Instruction Before Completing) a. (Explain YES answers in item 13) DESIGN: Was design of facility, workplace or equipment a factor? INSPECTION/MAINTENANCE: Were inspection & maintenance procedures a factor? PERSON'S PHYSICAL CONDITION: In your opinion, was the physical condition of the person a factor? OPERATING PROCEDURES: Were operating procedures a factor? JOB PRACTICES: Were any job safety/health practices not followed when the accident occurred? HUMAN FACTORS: Did any human factors such as, size or strength of person, etc., contribute to accident? ENVIRONMENTAL FACTORS: Did heat, cold, dust, sun, glare, etc., contribute to the accident? YES NO a. (CONTINUED) YES NO CHEMICAL AND PHYSICAL AGENT FACTORS: Did exposure to chemical agents, such as dust, fumes, mists, vapors or physical agents, such as, noise, radiation, etc., contribute to accident? OFFICE FACTORS: Did office setting such as, lifting office furniture, carrying, stooping, etc., contribute to the accident? SUPPORT FACTORS: Were inappropriate tools/resources provided to properly perform the activity/task? PERSONAL PROTECTIVE EQUIPMENT: Did the improper selection, use or maintenance of personal protective equipment contribute to the accident? DRUGS/ALCOHOL: In your opinion, was drugs or alcohol a factor to the accident b. WAS A WRITTEN JOB/ACTIVITY HAZARD ANALYSIS COMPLETED FOR TASK BEING PERFORMED AT TIME OF ACCIDENT? YES (If yes, attach a copy.) NO 12. a. WAS PERSON TRAINED TO PERFORM ACTIVITY/TASK? TRAINING b. TYPE OF TRAINING. c. DATE OF MOST RECENT FORMAL TRAINING. YES NO CLASSROOM ON JOB (Month) (Day) (Year) 13. FULLY EPLAIN WHAT ALLOWED OR CAUSED THE ACCIDENT; INCLUDE DIRECT AND INDIRECT CAUSES (See instruction for definition of direct and indirect causes.) (Use additional paper, if necessary) a. DIRECT CAUSE b. INDIRECT CAUSE(S) 14. DESCRIBE FULLY: ACTION(S) TAKEN, ANTICIPATED OR RECOMMENDED TO ELIMINATE CAUSE(S). 15. DATES FOR ACTIONS IDENTIFIED IN BLOCK 14. a. BEGINNING (Month/Day/Year) b. ANTICIPATED COMPLETION (Month/Day/Year) c. SIGNATURE AND TITLE OF SUPERVISOR COMPLETING REPORT CORPS CONTRACTOR 16. a. CONCUR b. NON CONCUR c. COMMENTS d. DATE (Mo/Da/Yr) e. ORGANIZATION IDENTIFIER (Div, Br, Sect) f. OFFICE SYMBOL MANAGEMENT REVIEW (1st) SIGNATURE TITLE DATE 17. a. CONCUR b. NON CONCUR c. COMMENTS MANAGEMENT REVIEW (2nd - Chief Operations, Construction, Engineering, etc.) SIGNATURE TITLE DATE 18. a. SAFETY AND OCCUPATIONAL HEALTH OFFICE REVIEW CONCUR b. NON CONCUR c. ADDITIONAL ACTIONS/COMMENTS SIGNATURE TITLE DATE 19. COMMENTS COMMAND APPROVAL COMMANDER SIGNATURE DATE Page 2 of 4 pages *U.S. GOVERNMENT PRINTING OFFICE:

138 10. ACCIDENT DESCRIPTION (Continuation) 13a. DIRECT CAUSE (Continuation) Page 3 of 4 pages

139 13b. INDIRECT CAUSES (Continuation) 14. ACTION(S) TAKEN, ANTICIPATED, OR RECOMMENDED TO ELIMINATE CAUSE(S) (Continuation) Page 4 of 4 pages

140 ATTACHMENT A-6 Health, Safety, and Environmental Procedures and Policies (on CD) 1.2 Project Health, Safety, and Environmental Management (click to open) 11.6 Occupational Noise 11.7 Spill Containment 1.3 Chemical Hazard Communication 11.9 Decontamination 1.6 Field Site Mobilization HSE Requirements Level A Decontamination 2.2 Safety Evaluation Process Level B Decontamination 2.16 Safe Plan of Action Level C Decontamination 2.17 Safety Observation Report Level D Decontamination 2.22 Hazard Analysis 12.1 Health Hazard Evaluation 3.1 HSE Training 13.1 Personal Protective Equipment 4.1 Medical Monitoring Program for Environmental Project Work 13.2 PPE Program for Environmental Activities 4.4 First-Aid Program 13.3 Head Protection 5.1 Accidents and Incidents Investigation and 13.4 Hand Protection Reporting 13.5 Foot Protection 5.2 Vehicle Accidents 13.6 Eye and Face Protection Site Control 14.1 Emergency Evacuation Utility Clearance 14.2 Earthquake Emergency Planning and Response 15.3 Work Over or Adjacent to Water 7.4 Working Safely Around Wild Animals 18.4 Small Tools and Equipment 8.6 Material Handling and Storage 20.1 Fire Prevention 8.10 Drilling and Drill Rig Safety 20.2 General Fire Protection 9.5 Unexploded Ordnance 20.3 Fire Extinguishers 11.2 Bloodborne Pathogen Exposure Control Program 21.2 Motor Vehicle Safety 21.4 Travel Safety 11.4 Cold Stress Control Fatigue Risk Management 11.5 Heat Stress Control GPS Drug, Alcohol and Contraband Policy

141 ATTACHMENT A-7 Material Safety Data Sheets Alconox Antifreeze (all brands) Bear Spray Bentonite Bug Spray (DEET) Chemical Hand Warmers Diesel Eyewash Fire Extinguisher (ABC) Fogtech (anti-fog treatment) Gasoline Hydrochloric Acid Liquinox Methanol Nitric Acid Propane Sand (quartz)

142 MATERIAL SAFETY DATA SHEET ALCONO Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Union REACH Regulations PRODUCT NAME: SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION ALCONO CHEMICAL FAMILY NAME: Detergent. PRODUCT USE: Critical-cleaning detergent for laboratory, healthcare and industrial applications U.N. NUMBER: Not Applicable U.N. DANGEROUS GOODS CLASS: Non-Regulated Material SUPPLIER/MANUFACTURER'S NAME: Alconox, Inc. ADDRESS: 30 Glenn St., Suite 309, White Plains, NY USA EMERGENCY PHONE: TOLL-FREE in USA/Canada International calls BUSINESS PHONE: DATE OF PREPARATION: May 2011 DATE OF LAST REVISION: February 2008 SECTION 2 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is a white granular powder with little or no odor. Exposure can be irritating to eyes, respiratory system and skin. It is a non-flammable solid. The Environmental effects of this product have not been investigated. US DOT SYMBOLS CANADA (WHMIS) SYMBOLS EUROPEAN and (GHS) Hazard Symbols Non-Regulated Signal Word: Warning! EU LABELING AND CLASSIFICATION: Classification of the substance or mixture according to Regulation (EC) No1272/2008 Annex 1 EC# This substance is not classified in the Annex I of Directive 67/548/EEC EC# This substance is not classified in the Annex I of Directive 67/548/EEC EC# This substance is not classified in the Annex I of Directive 67/548/EEC EC# This substance is not classified in the Annex I of Directive 67/548/EEC EC# Index# EC# This substance is not classified in the Annex I of Directive 67/548/EEC GHS Hazard Classification(s): Eye Irritant Category 2A Hazard Statement(s): Precautionary Statement(s): H319: Causes serious eye irritation P260: Do not breath dust/fume/gas/mist/vapors/spray P264: Wash hands thoroughly after handling P271: Use only in well ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection/ Hazard Symbol(s): [i] Irritant May 2011 Page 1 of 7 Rev 1

143 MATERIAL SAFETY DATA SHEET Risk Phrases: R20: Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin Safety Phrases: S8: Keep container dry S22: Do not breath dust S24/25: Avoid contact with skin and eyes ALCONO HEALTH HAZARDS OR RISKS FROM EPOSURE: ACUTE: Exposure to this product may cause irritation of the eyes, respiratory system and skin. Ingestion may cause gastrointestinal irritation including pain, vomiting or diarrhea. CHRONIC: This product contains an ingredient which may be corrosive. TARGET ORGANS: ACUTE: Eye, respiratory System, Skin CHRONIC: None Known SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTS HAZARDOUS INGREDIENTS: CAS # EINECS # ICSC # WT % Sodium Bicarbonate % Sodium (C10 C16) Alkylbenzene Sulfonate Not Listed 10 20% Sodium Tripolyphosphate % Tetrasodium Pyrophosphate % Sodium Carbonate % Sodium Alcohol Sulfate % Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or respiratory sensitizers). NOTE: HAZARD CLASSIFICATION; RISK PHRASES HAZARD CLASSIFICATION: None RISK PHRASES: None HAZARD CLASSIFICATION: None RISK PHRASES: None HAZARD CLASSIFICATION: None RISK PHRASES: None HAZARD CLASSIFICATION: None RISK PHRASES: None HAZARD CLASSIFICATION: [i] Irritant RISK PHRASES: R36 HAZARD CLASSIFICATION: None RISK PHRASES: None ALL WHMIS required information is included in appropriate sections based on the ANSI Z format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250: SECTION 4 - FIRST-AID MEASURES Contaminated individuals of chemical exposure must be taken for medical attention if any adverse effect occurs. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS to health professional with contaminated individual. EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists. Remove contaminated clothing. Launder before re-use. INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention if breathing dificulty continues. INGESTION: If product is swallowed, call physician or poison control center for most current information. If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or MSDS with the victim to the health professional. MEDICAL CONDITIONS AGGRAVATED BY EPOSURE: Pre-existing skin, or eye problems may be aggravated by prolonged contact. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure. May 2011 Page 2 of 7 Rev 1

144 MATERIAL SAFETY DATA SHEET ALCONO SECTION 5 - FIRE-FIGHTING MEASURES FLASH POINT: Not Flammable AUTOIGNITION TEMPERATURE: Not Applicable FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): NA Upper (UEL): NA FIRE ETINGUISHING MATERIALS: As appropriate for surrounding fire. Carbon dioxide, foam, dry chemical, halon, or water spray. UNUSUAL FIRE AND EPLOSION HAZARDS: This product is non-flammable and has no known explosion hazards. Explosion Sensitivity to Mechanical Impact: Not Sensitive. Explosion Sensitivity to Static Discharge: Not Sensitive SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. NFPA RATING SYSTEM Flammability HMIS RATING SYSTEM HAZARDOUS MATERIAL IDENTIFICATION SYSTEM HEALTH HAZARD (BLUE) 1 0 FLAMMABILITY HAZARD (RED) 0 Health 1 - Other 0 Reactivity PHYSICAL HAZARD (YELLOW) 0 PROTECTIVE EQUIPMENT EYES RESPIRATORY HANDS BODY See Sect 8 See Sect 8 For Routine Industrial Use and Handling Applications Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard SECTION 6 - ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Personnel should be trained for spill response operations. SPILLS: Contain spill if safe to do so. Prevent entry into drains, sewers, and other waterways. Sweep, shovel or vacuum spilled material and place in an appropriate container for re-use or disposal. Avoid dust generation if possible. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). SECTION 7 - HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing dusts generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES: Containers of this product must be properly labeled. Store containers in a cool, dry location. Keep container tightly closed when not in use. Store away from strong acids or oxidizers. May 2011 Page 3 of 7 Rev 1

145 MATERIAL SAFETY DATA SHEET ALCONO EPOSURE LIMITS/GUIDELINES: SECTION 8 - EPOSURE CONTROLS - PERSONAL PROTECTION Chemical Name CAS# ACGIH TWA OSHA TWA SWA Sodium Bicarbonate mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Sodium (C10 C16) Alkylbenzene Sulfonate mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Sodium Tripolyphosphate mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Tetrasodium Pyrophosphate mg/m³ 5 mg/m³ 5 mg/m³ Sodium Carbonate mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Sodium Alcohol Sulfate mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Currently, International exposure limits are not established for the components of this product. Please check with competent authority in each country for the most recent limits in place. VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided below. Use local exhaust ventilation to control airborne dust. Ensure eyewash/safety shower stations are available near areas where this product is used. The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at ) or equivalent standard of Canada, or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Based on test data, exposure limits should not be exceeded under normal use conditions when using Alconox Detergent. Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR ), equivalent U.S. State standards, Canadian CSA Standard Z , the European Standard EN149, or EU member states. EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR or appropriate Canadian Standards. HAND PROTECTION: Use chemical resistant gloves to prevent skin contact.. If necessary, refer to U.S. OSHA 29 CFR or appropriate Standards of Canada. BODY PROTECTION: Use body protection appropriate to prevent contact (e.g. lab coat, overalls). If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES PHYSICAL STATE: Solid APPEARANCE & ODOR: White granular powder with little or no odor. ODOR THRESHOLD (PPM): Not Available VAPOR PRESSURE (mmhg): Not Applicable VAPOR DENSITY (AIR=1): Not Applicable. BY WEIGHT: Not Available EVAPORATION RATE (nbuac = 1): Not Applicable. BOILING POINT (C ): Not Applicable. FREEZING POINT (C ): Not Applicable. ph: 9.5 (1% aqueous solution) SPECIFIC GRAVITY 20 C: (WATER =1) SOLUBILITY IN WATER (%) >10% w/w COEFFICIENT OF WATER/OIL DIST.: Not Available VOC: None CHEMICAL FAMILY: Detergent May 2011 Page 4 of 7 Rev 1

146 MATERIAL SAFETY DATA SHEET SECTION 10 - STABILITY and REACTIVITY STABILITY: Product is stable DECOMPOSITION PRODUCTS: When heated to decomposition this product produces Oxides of carbon (COx) MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids and strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Contact with incompatible materials and dust generation. SECTION 11 - TOICOLOGICAL INFORMATION ALCONO TOICITY DATA: Toxicity data is available for mixture: CAS# LD50 Oral (Rat) 4090 mg/kg CAS# LD50 Oral (Mouse) 6600 mg/kg CAS# LC50 Inhalation 2300 mg/m³ 2H (Rat) CAS# LC50 Inhalation 1200 mg/m³ 2H (Mouse) CAS# LD50 Oral (Rat) 3120 mg/kg CAS# LD50 Oral 3100 mg/kg (Mouse) CAS# LD50 Oral (Rat) 4000 mg/kg SUSPECTED CANCER AGENT: None of the ingredients are found on the following lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC and therefore is not considered to be, nor suspected to be a cancer-causing agent by these agencies. IRRITANCY OF PRODUCT: Contact with this product can be irritating to exposed skin, eyes and respiratory system. SENSITIZATION OF PRODUCT: This product is not considered a sensitizer. REPRODUCTIVE TOICITY INFORMATION: No information concerning the effects of this product and its components on the human reproductive system. SECTION 12 - ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: No Data available at this time. EFFECT OF MATERIAL ON PLANTS or ANIMALS: No evidence is currently available on this product s effects on plants or animals. EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product s effects on aquatic life. SECTION 13 - DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations, those of Canada, Australia, EU Member States and Japan. SECTION 14 - TRANSPORTATION INFORMATION US DOT; IATA; IMO; ADR: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR BY THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Non-Regulated Material HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable UN IDENTIFICATION NUMBER: Not Applicable PACKING GROUP: Not Applicable. DOT LABEL(S) REQUIRED: Not Applicable NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2004): Not Applicable MARINE POLLUTANT: None of the ingredients are classified by the DOT as a Marine Pollutant (as defined by 49 CFR , Appendix B) U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS: This product is not classified as dangerous goods, per U.S. DOT regulations, under 49 CFR TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not classified as Dangerous Goods, per regulations of Transport Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): This product is not classified as Dangerous Goods, by rules of IATA: INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION: This product is not classified as Dangerous Goods by the International Maritime Organization. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): May 2011 Page 5 of 7 Rev 1

147 MATERIAL SAFETY DATA SHEET This product is not classified by the United Nations Economic Commission for Europe to be dangerous goods. SECTION 15 - REGULATORY INFORMATION ALCONO UNITED STATES REGULATIONS SARA REPORTING REQUIREMENTS: This product is not subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows: None TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of chemicals. SARA 311/312: Acute Health: Yes Chronic Health: No Fire: No Reactivity: No U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR U.S. CERCLA REPORTABLE QUANTITY (RQ): None CALIFORNIA SAFE DRINKING WATER AND TOIC ENFORCEMENT ACT (PROPOSITION 65): None of the ingredients are on the California Proposition 65 lists. CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: All of the components of this product are on the DSL Inventory CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this product is on the CEPA First Priorities Substance Lists. CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This product is categorized as a Controlled Product, Hazard Class D2B as per the Controlled Product Regulations EUROPEAN ECONOMIC COMMUNITY INFORMATION: EU LABELING AND CLASSIFICATION: Classification of the mixture according to Regulation (EC) No1272/2008. See section 2 for details. AUSTRALIAN INFORMATION FOR PRODUCT: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: All components of this product are listed on the AICS. STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable. JAPANESE INFORMATION FOR PRODUCT: JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Asia-Pac: Australian Inventory of Chemical Substances (AICS): Korean Existing Chemicals List (ECL): Japanese Existing National Inventory of Chemical Substances (ENCS): Philippines Inventory if Chemicals and Chemical Substances (PICCS): Swiss Giftliste List of Toxic Substances: U.S. TSCA: Listed Listed Listed Listed Listed Listed Listed SECTION 16 - OTHER INFORMATION PREPARED BY: Paul Eigbrett Global Safety Management, Cross Creek Blvd. Suite 440, Tampa, FL May 2011 Page 6 of 7 Rev 1

148 MATERIAL SAFETY DATA SHEET ALCONO Disclaimer: To the best of Alconox, Inc. knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness is not guaranteed and no warranties of any type either express or implied are provided. The information contained herein relates only to this specific product. ANNE: IDENTIFIED USES OF ALCONO AND DIRECTIONS FOR USE Used to clean: Healthcare instruments, laboratory ware, vacuum equipment, tissue culture ware, personal protective equipment, sampling apparatus, catheters, tubing, pipes, radioactive contaminated articles, optical parts, electronic components, pharmaceutical apparatus, cosmetics manufacturing equipment, metal castings, forgings and stampings, industrial parts, tanks and reactors. Authorized by USDA for use in federally inspected meat and poultry plants. Passes inhibitory residue test for water analysis. FDA certified. Used to remove: Soil, grit, grime, buffing compound, slime, grease, oils, blood, tissue, salts, deposits, particulates, solvents, chemicals, radioisotopes, radioactive contaminations, silicon oils, mold release agents. Surfaces cleaned: Corrosion inhibited formulation recommended for glass, metal, stainless steel, porcelain, ceramic, plastic, rubber and fiberglass. Can be used on soft metals such as copper, aluminum, zinc and magnesium if rinsed promptly. Corrosion testing may be advisable. Cleaning method: Soak, brush, sponge, cloth, ultrasonic, flow through clean-inplace. Will foam not for spray or machine use. Directions: Make a fresh 1% solution (2 1/2 Tbsp. per gal., 1 1/4 oz. per gal. or 10 grams per liter) in cold, warm, or hot water. If available use warm water. Use cold water for blood stains. For difficult soils, raise water temperature and use more detergent. Clean by soak, circulate, wipe, or ultrasonic method. Not for spray machines, will foam. For nonabrasive scouring, make paste. Use 2% solution to soak frozen stopcocks. To remove silver tarnish, soak in 1% solution in aluminum container. RINSE THOROUGHLY preferably with running water. For critical cleaning, do final or all rinsing in distilled, deionized, or purified water. For food contact surfaces, rinse with potable water. Used on a wide range of glass, ceramic, plastic, and metal surfaces. Corrosion testing may be advisable. May 2011 Page 7 of 7 Rev 1

149 SECTION 1: IDENTIFICATION MSDS ID: MSDSP149 PRODUCT NAME: PRESTONE ANTIFREEZE/COOLANT Product Number: AF777 Formula Number: YA721, YA718, YA718B MANUFACTURER: Prestone Products Corporation 39 Old Ridgebury Road Danbury, CT INFORMATION PHONE NUMBER: (203) PRESTONE ANTIFREEZE/COOLANT MSDSP149 EMERGENCY PHONE NUMBER: CHEMTREC in the District of Columbia MSDS DATE OF PREPARATION/REVISION: 10/18/99 SECTION 2: PRODUCT COMPONENTS HAZARDOUS COMPONENTS CAS# PERCENT EPOSURE LIMITS Ethylene Glycol None Established-OSHA PEL (aerosol) 100 mg/m3 Ceiling ACGIH TLV Diethylene Glycol None Established OSHA PEL, ACGIH TLV Non-Hazardous Ingredients >1% Water SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Eye and upper respiratory irritant. May cause nausea, vomiting, headache, drowsiness, blurred vision, convulsions, coma or death if ingested or inhaled. Prolonged or repeated skin contact may cause dermatitis or skin sensitization. POTENTIAL HEALTH EFFECTS: INHALATION: May cause irritation of the nose and throat with headache, particularly from mists. High vapor concentrations caused, for example, by heating the material in an enclosed and poorly ventilated workplace, may produce nausea, vomiting, headache, dizziness and irregular eye movements. 1

150 PRESTONE ANTIFREEZE/COOLANT MSDSP149 SKIN CONTACT: No evidence of adverse effects from available information. EYE CONTACT: Liquid, vapors or mist may cause discomfort in the eye with persistent conjunctivitis, seen as slight excess redness or conjunctiva. Serious corneal injury is not anticipated. INGESTION: Following ingestion, a bitter taste may be noted. May cause abdominal discomfort or pain, nausea, vomiting, dizziness, drowsiness, malaise, blurring of vision, irritability, back pain, decrease in urine output, kidney failure, and central nervous system effects, including irregular eye movements, convulsions and coma. Cardiac failure and pulmonary edema may develop. Severe kidney damage which may be fatal may follow the swallowing of ethylene glycol. A few reports have been published describing the development of weakness of the facial muscles, diminishing hearing, and difficulty with swallowing, during the late stages of severe poisoning. CHRONIC EFFECTS: Prolonged or repeated inhalation exposure may produce signs of central nervous system involvement, particularly dizziness and jerking eye movements. Prolonged or repeated skin contact may cause skin sensitization and an associated dermatitis in some individuals. Ethylene glycol has been found to cause birth defects in laboratory animals. The significance of this finding to humans has not been determined. See section 11 for additional information. MEDICAL CONDITIONS AGGRAVATED BY EPOSURE: The available toxicological information and a knowledge of the physical and chemical properties of the material suggest that overexposure in unlikely to aggravate existing medical conditions. CARCINOGEN: None of the components of these products is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. SECTION 4: FIRST AID MEASURES INHALATION: Remove the victim to fresh air. If breathing has stopped administer artificial respiration. If breathing is difficult, have medical personnel administer oxygen. Get medical attention. SKIN CONTACT: Remove contaminated clothing. Immediately wash contacted area thoroughly with soap and water. If irritation persists, get medical attention. EYE CONTACT: Immediately flush eyes with large amounts of water for 15 minutes. Get medical attention if irritation persists. INGESTION: Seek immediate medical attention. Immediately call local poison control center or go to an emergency department. Never give anything by mouth to or induce vomiting in an unconscious or drowsy person. 2

151 PRESTONE ANTIFREEZE/COOLANT MSDSP149 NOTES TO PHYSICIAN: The principal toxic effects of ethylene glycol, when swallowed, are kidney damage and metabolic acidosis. The combination of metabolic acidosis, an osmol gap and oxalate crystals in the urine is evidence of ethylene glycol poisoning. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. Respiratory support with mechanical ventilation may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth, and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and dysphagia. Ethanol is antidotal and its early administration may block the formation of nephrotoxic metabolites of ethylene glycol in the liver. The objective is to rapidly achieve and maintain a blood ethanol level of approximately 100 mg/dl by giving a loading dose of ethanol followed by a maintenance dose. Intravenous administration of ethanol is the preferred route. Ethanol blood levels should be checked frequently. Hemodialysis may be required. 4-Methylpyrazole (Antizole(R) or Fomepizole), a potent inhibitor of alcohol dehydrogenase, has been used therapeutically to decrease the metabolic consequences of ethylene glycol poisoning. Additional therapeutic modalities which may decrease the adverse consequences of ethylene glycol metabolism are the administration of both thiamine and pyridoxine. As there are complicated and serious overdoses, we recommend you consult with the toxicologists at your poison control center. This antidote is now approved by the F.D.A. and in many cases has replaced ethanol in the treatment of ethylene glycol poisoning. SECTION 5: FIRE AND EPLOSION DATA FLASH POINT: 242 F (117 C) TOC 220 F (104 C) PMCC AUTOIGNITION TEMPERATURE: Not determined FLAMMABILITY LIMITS: LEL: 3.2% UEL: 15.3% ETINGUISHING MEDIA: For large fires, use alcohol type or all-purpose foams. For small fires, use water spray, carbon dioxide or dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Do not spray pool fires directly. Cool fire exposed containers with water. Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. UNUSUAL FIRE HAZARDS: A solid stream of water or foam directed into hot, burning liquid can cause frothing. 3

152 PRESTONE ANTIFREEZE/COOLANT MSDSP149 HAZARDOUS COMBUSTION PRODUCTS: Burning may produce carbon monoxide and carbon dioxide. SECTION 6: ACCIDENTAL RELEASE MEASURES Wear appropriate protective clothing and equipment (See Section 8). Collect with absorbent material and place in appropriate, labeled container for disposal or, if permitted flush spill area with water. SECTION 7: HANDLING AND STORAGE DANGER: Harmful or Fatal if Swallowed Do not drink antifreeze or solution. Avoid eye and prolonged or repeated skin contact. Avoid breathing vapors or mists. Wash exposed skin thoroughly with soap and water after use. Do not store in opened or unlabeled containers. Keep container away from open flames and excessive heat. Do not reuse empty containers unless properly cleaned. Empty containers retain product residue and may be dangerous. Do not cut, weld, drill, etc. containers, even empty. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without any obvious ignition sources. Published "autoignition" or "ignition" temperatures cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions. Use of this product in elevated temperature applications should be thoroughly evaluated to assure safe operating conditions. SECTION 8: EPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: Use general ventilation or local exhaust as required to maintain exposures below the occupational exposure limits. RESPIRATORY PROTECTION: For operations where the TLV is exceeded a NIOSH approved respirator with organic vapor cartridges and dust/mist prefilters or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration. Select and use in accordance with 29 CFR and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. GLOVES: Chemical resistant gloves such as neoprene or PVC where contact is possible 4

153 EYE PROTECTION: Splash-proof goggles. PRESTONE ANTIFREEZE/COOLANT MSDSP149 OTHER PROTECTIVE EQUIPMENT/CLOTHING: Appropriate protective clothing as needed to minimize skin contact. Suitable washing and eye flushing facilities should be available in the work area. Contaminated clothing should be removed and laundered before re-use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: Yellow liquid with a mild odor. ph: Not determined SPECIFIC GRAVITY: 1.12 BOILING POINT (F): 334 F VAPOR PRESSURE: Less than 0.1 FREEZING POINT (F): -8 F VAPOR DENSITY: 2.1 SOLUBILITY IN WATER: 100% EVAPORATION RATE: Less than 1 PERCENT VOLATILE: None VISCOSITY: Not determine SECTION 10: STABILITY AND REACTIVITY STABILITY: Stable CONDITIONS TO AVOID: None known. INCOMPATIBILITY: Normally unreactive, however, avoid strong bases at high temperatures, strong acids, strong oxidizing agents, and materials reactive with hydroxyl compounds. DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide. HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None known. SECTION 11: TOICOLOGICAL INFORMATION ACUTE TOICITY VALUES: Ethylene Glycol: LD50 Oral Rat: 4700 mg/kg LD50 Skin Rabbit: 9530 mg/kg Diethylene Glycol: LD50 Oral Rat: 12,565 mg/kg LD50 Skin Rabbit: 11,890 mg/kg SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations 150, 1,000 and 2,500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentrations, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure 5

154 PRESTONE ANTIFREEZE/COOLANT MSDSP149 resulted in maternal toxicity (1,000 and 2,500 mg/m3) and developmental toxicity in with minimal evidence of teratogenicity (2,500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen; there is currently no available information to suggest that ethylene glycol caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity; exposure to high aerosol concentration is only minimally effective in producing developmental toxicity; the major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous invitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. This products contains less than 0.5% tolytriazole which has demonstrates mutagenic activity in a bacterial test system. A correlation has been established between mutagenic activity and carcinogenic activity for many chemicals. Tolytriazole has not been identified as a carcinogen or probable carcinogen by NTP, IARC or OSHA. SECTION 12: ECOLOGICAL INFORMATION Ethylene Glycol: LC50 Goldfish: 5,000 mg/l/24 hr. at 20 C static conditions. Toxicity threshold (cell multiplication inhibition test): Bacterial (Pseudomonas putida): 10,000 mg/l Protozoa (Entosiphon sulcatum and Uronema parduczi Chatton-Lwoff): >10,000 mg/l Algae (Microcystis aeruginosa): 2,000 mg/l Green algae (Scenedesmus quandricauda): >10,000 mg/l SECTION 13: DISPOSAL INFORMATION Dispose of product in accordance with all local, state/provincial and federal regulations. SECTION 14: TRANSPORT INFORMATION U.S. DOT HAZARD CLASSIFICATION 6

155 PROPER SHIPPING NAME: None UN NUMBER: None LABELS REQUIRED: None PRESTONE ANTIFREEZE/COOLANT MSDSP149 DOT MARINE POLLUTANTS: This product does not contains Marine Pollutants as defined in 49 CFR IMDG CODE SHIPPING CLASSIFICATION DESCRIPTION: Not Regulated Note: IF A BULK SHIPMENT IS INVOLVED, THE FOLLOWING INFORMATION APPLIES: U.S. DOT HAZARD CLASSIFICATION PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, N.O.S. (Ethylene glycol) UN NUMBER: UN3082 LABELS REQUIRED: Class 9, UN3082 SECTION 15: REGULATORY INFORMATION EPA SARA 311/312 HAZARD CLASSIFICATION: Acute health, chronic health EPA SARA 313: This Product Contains the Following Chemicals Subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): Ethylene Glycol % PROTECTION OF STRATOSPHERIC OZONE: This product is not known to contain or to have been manufactured with ozone depleting substances as defined in 40 CFR Part 82, Appendix A to Subpart A. CERCLA SECTION 103: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for this product, based on the RQ for Ethylene Glycol (96% maximum) of 5,000 lbs, is 5,208 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. CALIFORNIA PROPOSITION 65 - This product may contain the following substances known to the State of California to cause Cancer and/or Reproductive Harm: 1,4-Dioxane (trace amount). EPA TSCA INVENTORY: All of the components of this material are listed on the Toxic Substances Control Act (TSCA) Chemical Substances Inventory. CANADIAN ENVIRONMENTAL PROTECTION ACT: All of the ingredients are listed on the Canadian Domestic Substances List. 7

156 PRESTONE ANTIFREEZE/COOLANT MSDSP149 CANADIAN WHMIS CLASSIFICATION: Class D - Division 2 - Subdivision B - (A toxic material causing other chronic effects) EUROPEAN INVENTORY OF EISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS): All of the ingredients are listed on the EINECS inventory. AUSTRALIA: All of the ingredients of this product are listed on the Australian Inventory of Chemical Substances. SECTION 16: OTHER INFORMATION NFPA RATING (NFPA 704) - FIRE: 1 HEALTH: 2 REACTIVITY: 0 REVISION SUMMARY: Section 4: Notes to Physican Section 9: Specific Gravity Section 16: Contact Name and Address This MSDS is directed to professional users and bulk handlers of the product. Consumer products are labeled in accordance with Federal Hazardous Substances Act regulations. While Prestone Products Corporation believes that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of tests conducted, the data are not to be taken as a warranty or representation for which Prestone Products Corporation assumes legal responsibility. They are offered for your consideration, investigation and verification. Any use of these data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. If more information is needed, please contact: Stan Prusakowski Prestone Products Corporation 55 Federal Road Danbury, CT (203)

157 M A T E R I A L S A F E T Y D A T A S H E E T PAGE #: 1 OF 4 PRODUCT NAME: BEAR PEPPER MACE (AEROSOL) MSDS NUMBER: PRODUCT CODE: 80346, MSDS DATE: 02/24/2010 KEY NUMBER: EMERGENCY PHONE #'s: CHEMTREC: / IDENTIFICATION Mace Personal Defense, Inc. 160 Benmont Avenue - Ste. 1 Bennington, VT Chemical Name: OC Spray Chemical Family: Irritant Agent CAS #: CAS Name: Synonyms / Common Name: OC Spray DOT Information: HEALTH FIRE REACTIVITY 2 Hazardous 3 Flash Point: Below 100 F, 38 C 0 Stable SPECIFIC See Addendum: Ref. PAGE: Chemical Formula: Molecular Weight: 2. PHYSICAL DATA Appearance: Color: State: Odor Characteristics: ph: Viscosity: Specific Gravity (Water = 1): Vapor Density (Air = 1): Vapor Pressure: See Addendum: Ref. PAGE: Red/orange liquid Red/orange Melting Point: Boiling Point: Not known 370F Liquid Flash Point: < 100F Pungent Freezing Point: Not known Not known Percent Volatility: Near complete Not known Evaporation Rate (BAc = 1): Not known 68F Solubility in Water: Insoluble Not known Solubility in Oil: Not known F Solubility in Acetone: Not known 3. INGREDIENTS See Addendum: Ref. PAGE: Material / Components CAS #: CAS Name TLV Units Approx. % Oleoresin Capsicum Oleoresin Capsaicin None established Remaining - Trade Secret - 29 CFR (i). 4. FIRE AND EPLOSION HAZARD DATA See Addendum: Flash Point: < 100F Flammable Limits in Air % by volume: Lower Upper None None Extinguishing Media: Dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Ref. PAGE: Special Fire Fighting Procedures: Use air-supplied, NIOSH-approved respirator to protect against gases and fumes. Unusual Fire & Explosion Hazards: Containers may explode in the heat of a fire. Resulting smoke and fumes would be irritating to eyes and mucous membranes.

158 Mace Personal Defense, Inc. MATERIAL SAFETY DATA SHEET PAGE #: 2 PRODUCT NAME: BEAR PEPPER MACE (AEROSOL) 160 Benmont Avenue - Ste. 1 Bennington, VT MSDS NUMBER: MSDS DATE: PRODUCT CODE: KEY NUMBER: /24/ , OF 4 5. HEALTH HAZARD DATA See Addendum: PAGE #: Threshold Limit Value: Not known Effects of Overexposure: Inhalation: May cause gagging and coughing with irritation to the lungs. Skin Contact: May cause skin irritation to sensitive parts upon direct contact. Eye Contact: May cause eye irritation upon direct contact. Ingestion: May cause irritation to mouth, throat and stomach upon direct contact. Delayed Effects: Not known Medical Conditions Aggravated by Exposure Not known 6. FIRST AID MEASURES See Addendum: PAGE #: Inhalation: Skin Contact: Eye Contact: Ingestion: NOTES TO PHYSICIAN: Remove the victim from immediate source of exposure and assure that the victim is breathing. If breathing is difficult, administer oxygen. If the victim is not breathing, adminster CPR. Seek immediate medical attention. Promptly flush skin with water until all chemical is removed. If there is evidence of frostbite, bathe (do not rub) with lukewarm water. If water is not available, cover with a clean, soft cloth or similar covering. Seek medical attention. Immediately flush eyes with large amounts of water for at least 15 minutes. In case of frostbite, water should be lukewarm, lifting eyelids occasionally to facilitate irrigation. Seek medical attention if symptoms persist. Ingestion is unlikely because of the physical properties and is not expected to be hazardous. DO NOT induce vomiting unless instructed to do so by a physician. Contact the Poison Control Center at REACTIVITY DATA See Addendum: PAGE #: Stability: Incompatibility: (materials to avoid) Presents no significant reactivity hazard. Not known. Hazardous Combustion or Decomposition Products Thermal decomposition may produce phosgene, hydrogen fluoride and irritating fumes. Hazardous Polymerization: May occur. Conditions to Avoid: Contents may discharge at elevated temperature. 8. SPILL OR LEAK PROCEDURES Actions to take for Leaks & Spills See Addendum: Individual pressurized containers pose no significant risk. PAGE #: Waste Disposal Method: Dispose of in accordance with current laws and regulations.

159 Mace Personal Defense, Inc. MATERIAL SAFETY DATA SHEET PAGE #: 3 PRODUCT NAME: BEAR PEPPER MACE (AEROSOL) 160 Benmont Avenue - Ste. 1 Bennington, VT MSDS NUMBER: MSDS DATE: PRODUCT CODE: KEY NUMBER: /24/ , OF 4 9. SPECIAL PROTECTION INFORMATION Respiratory Protection: See Addendum: Ref. PAGE: Respiratory protection is normally not required in well-ventilated areas, however, NIOSH approved respiratory protection may be required when the material is used in a confined area. Eye Protection: Skin Protection: Other Clothing: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear chemical safety goggles. Skin contact with refrigerant may cause frostbite. General work clothing and gloves (leather) should provide adequate protection. Where contact with liquid is likely, such as in a spill or leak, impervious boots and clothing should be worn. Other Equipment: Engineering Controls: Provide ventilation if working in confined area. 10. HANDLING AND STORAGE Special Precautions: See Addendum: Ref. PAGE: Avoid breathing vapors and liquid contact with eyes, skin or clothing. Do not puncture or drop cylinders, expose to open flame or excessive heat. Use with adequate ventilation. Other Precautions: 11. REGULATORY INFORMATION Workplace Classification: See Addendum: Ref. PAGE: 12. TOICOLOGICAL INFORMATION Acute Data: See Addendum: Ref. PAGE: 4 Reproductive / Teratology Data 13. ECOLOGICAL INFORMATION See Addendum: Fate in the Environment: This product has not been tested for environmental effects. Ref. PAGE: 14. DISPOSAL CONDITIONS See Addendum: Procedures: Dispose of in accordance with applicable environmental laws and regulations. Ref. PAGE: 15. TRANSPORTATION INFORMATION See Addendum: Ref. PAGE: 4 DOT Classification: Warning Labels:

160 Mace Personal Defense, Inc. MATERIAL SAFETY DATA SHEET PAGE #: 4 OF PRODUCT NAME: BEAR PEPPER MACE (AEROSOL) 160 Benmont Avenue - Ste. 1 Bennington, VT MSDS NUMBER: MSDS DATE: PRODUCT CODE: KEY NUMBER: /24/ , OTHER INFORMATION The information contained herein is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. Various governmental agencies may have specific regulations concerning the transportation, handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance. 12. TOICOLOGICAL INFORMATION - Ref. Pg. 3 Toxicity: Strong skin and eye irritant. Exposure to capsaicin pepper spray results in temporary blindness, lacrimation (tear production), burning sensation, pain, and redness of the skin, nasal irritation, coughing, bronchoconstriction, and dyspnea. The following LD values were obtained from the "Capsaicin Technical Fact Sheet" of the National Pesticide Information Center, Acute oral LD50 values were determined to be 97.4 mg/kg and mg/kg in female and male mice, respectively, and mg/kg and mg/kg in female and male rats, respectively. Additional LD50 values for male mice were and 190 mg/kg depending on the carrier solution when the capsaicin was administered within the stomach. Studies using mice have reported LD50 values ranging from 47.2 mg/kg to 2500 mg/kg. The LD50 in humans has been estimated at g/kg. Primary routes of entry: Inhalation, skin and ingestion. High inhaled amounts may cause dizziness, unconsciousness and asphyxia. Skin contact may cause local irritation and a general allergic reaction in sensitive individuals. 15. TRANSPORTATION INFORMATION - Ref. Pg. 3 GROUND (USA) 49 CFR, Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Shipper must be trained and certified. Refer to CFR 49 AIR (USA), IATA Proper Shipping Name: Consumer Commodity Hazard Class or Division: 9 UN/ID: ID 8000 Shipper must be trained and certified. Refer to IATA Dangerous Goods Regulations.

161 341 Christian Street, Oxford, CT USA Tel: (203) Fax: (203) MATERIAL SAFETY DATA SHEET BENTONITE CLAY MSDS 1. PRODUCT NAME AND COMPANY IDENTIFICATION Product Name: BENTONITE CLAY, SODIUM TYPE Product Use: Personal Care Formulations Company Name: Natural Sourcing Company Address: 341 Christian Street, Oxford, CT 06478, USA Date Issued: 6/1/2008 Emergency Telephone Number: Chemtrec Tel: (800) COMPOSITION/INGREDIENT INFORMATION Ingredients: Preservatives & Solvents: Other Gases & Liquids: 100% natural mineral, raw material, montmorillonite. Naturally occurring hydrated aluminosilicate of sodium, calcium, magnesium, and iron. None None Other Solids: Respirable crystalline silica (CAS #s and ). Estimated quantity less than 2%. CAS #: HAZARDS IDENTIFICATION Eyes: Skin: Ingestion: Inhalation: Mechanical irritant Possible drying resulting in dermatitis Not expected to be a hazard Short term exposure to dust levels exceeding the PEL may cause irritation of respiratory tract resulting in a dry cough. Chronic exposure to free silica contain in airborne bentonite dust where levels are higher than TLVs may lead to development of silicosis or other respiratory problems. Persistent dry cough and labored breathing upon exertion are symptomatic. Risk of Slips/Falls: To use in complete safety, respect exposure limits. Dampening the floor while cleaning a clay storage site may render it extremely slippery. Dry cleaning is recommended if people are required to continue working on the site. 4. FIRST AID MEASURES Eyes: Skin: Flush with plenty of water or eye wash solution for 15 minutes. Get medical attention if irritation persists. Due to its use in cosmetics, no adverse effects are expected. May dry mucous and skin. Wash with soap and water. Page 1 of 4

162 Ingestion: Inhalation: Medical Conditions Generally Aggravated by Exposure: No information Remove to fresh air. If symptoms of irritation persist, seek medical advice. Inhalation may aggravate respiratory illness. Individuals with pulmonary and/or respiratory disease, including but not limited to asthma and bronchitis should be precluded from exposure to dust. 5. FIRE FIGHTING MEASURES Extinguishing Media: Special Firefighting Procedures: Unusual Fire & Explosion Hazards: Note: N/A N/A N/A Will not burn 6. ACCIDENTAL RELEASE MEASURES (STEPS FOR SPILLS) Precautions: Methods for Cleaning Up: Avoid dust formation. In the event of a high level exposure to volatile dust, wear a protective mask and safety goggles. Sweep up or vacuum small spills carefully. For large spills, use water sprays or ventilated evacuation systems to prevent dust prevention. Use caution when using water - very slippery when wet. Dispose of according to local regulations. 7. HANDLING AND STORAGE Handling Safe Handling: Avoid dust formation. Provide appropriate ventilation where dust forms. In the event where there is insufficient ventilation wear suitable breathing equipment. Storage Requirements for Storage Areas and Containers: Store in closed containers below 30 C in well ventilated areas. Very slippery when wet. 8. EPOSURE CONTROL/PERSONAL PROTECTION Exposure Value Limits: Eye: Skin/Body: Respiratory: Ventilation: Other: Work/Hygiene Practice: Respect the regulatory provisions for dust (inhalable and breathable) and crystalline silica. Safety glasses should be worn. Gloves should be worn. Use NIOSH/MSHA approved respirators for silica bearing dust. Provide appropriate ventilation and filters in places where dust may be generated. Evaluate need based on application. Slip proof shoes may be worn where spills may occur. Normal work and hygiene practices 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: Grey Odor: Characteristic Solubility in Water: Insoluble Vapor Density: >1 Page 2 of 4

163 Specific Gravity: STABILITY AND REACTIVITY Stability: Incompatibility (Materials to Avoid): Hazardous Decomposition or Byproducts: Conditions to Avoid: Stable N/A N/A N/A 11. TOICOLOGICAL INFORMATION Exposure Limits: OSHA 8 hr. TWA) Signs & Symptoms of Exposure: Carcinogenicity: 15 mg/m3 (total dust) 5 mg/m3 (respirable dust) Reparable crystalline silica : 0.1 mg/m3 Prolonged or high exposure to respirable dust may cause shortness of breath and other respiratory effects. The international agency for research on cancer has determined that crystalline silica inhaled in the form of quartz or crystobalite in conjunction with the use of these materials from occupational sources is carcinogenic to humans. (Group 1 carcinogenic to humans) (Refer to IARC monograph 68, Silica, some silicates and organic fibers published June 1997). The National Toxicology Program classifies respirable crystalline silica as reasonable anticipated to be a carcinogen. For further information, see: Adverse Effects of Crystalline Silica Exposure published by the American Thoracic Society, medical section of the American Lung Association, American Journal of Respiratory and Critical Care Medicine, Volume 155, pages , The small quantities of crystalline silica (quartz) found in this material are, under normal conditions, naturally coated with an unremovable layer of amorphous silica and/or clay. IARC (Vol 68, 1997, pp ) states that crystalline silica (quartz) can differ in toxicity depending on the minerals with which it is combined, citing studies in IARC (Vol 42, 1987, p 86) which states that the toxic effect of crystalline silica (quartz) is reduced by the protective effect. Due mainly to clay minerals ECOLOGICAL INFORMATION Ecotoxicity: No known ecological hazards are associated with this product. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Dispose of according to local, state and federal regulations, and in a manner that does not pose a risk due to emission of breathable dust. 14. TRANSPORT INFORMATION DOT Classification: Not classified Page 3 of 4

164 15. REGULATORY INFORMATION No Information 16. ADDITIONAL INFORMATION This information is provided for documentation purposes only. The complete range of conditions or methods of use are beyond our control therefore we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate however, all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and local regulations remains the responsibility of the user. This safety sheet cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary. All health and safety information contained in this bulletin should be provided to your employees or customers. Page 4 of 4

165 WPC Brands, Inc. P.O. Box 4406 Bridgeton, MO Material Safety Data Sheet Hazardous Material Identification System (HMIS) HEALTH 2 REACTIVITY 0 Complies with OSHA s Hazard Communication Standard, 29 CFR FLAMMABILITY 2 PERSONAL None I Trade Name: Repel 100 Insect Repellent Product Type: Insect Repellent Product Item Number: Formula Code Number: EPA Registration Number Manufacturer Emergency Telephone Numbers II Hazards Ingredient/Identity Information Chemsico Division of United Industries Corporation 8494 Chapin Industrial Drive St. Louis, MO For Chemical Emergency: For Information: Prepared by: Date Prepared: III Physical and Chemical Characteristics Chemical % OSHA PEL ACGIH TLV Appearance & Odor: Clear liquid, slight odor DEET (N,N-diethyl-m NA NA Boiling Point: 160 C toluamide) Vapor Pressure: 1.67 x 10-3 CAS# Specific Gravity: Vapor Density: 6.7 % Volatile (by vol.): 100% Solubility in Water: NA Evaporation Rate: Approximately 1 (Butyl Acetate = 1) C. A. Duckworth March 12, 2009 IV Fire and Explosive Hazards Data V Reactivity Data Flash Point: 311 F(pmcc) Stability: Stable Flame Extension: NA Polymerization: Will not occur Autoignition Temperature: N/A Conditions to Avoid: None Fire Extinguishing Media: Carbon dioxide, Foam, Dry chemical Incompatible Materials: May soften or damage some synthetics Decomposition Temperature: NA such as rayon. May damage leather. Special Fire-Fighting Procedures: For Small Fires: Use Carbon dioxide or Hazardous Decomposition dry chemical extinguisher. For Large Fires: Use copious amounts of water. or Byproducts: None Unusual Fire and Explosion Hazards: Also see Section VII VI Health Hazard Data VII Precautions for Safe Handling and Use Ingestion (Swallowing): Harmful if swallowed. First Aid: Call a Poison Control Center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a Poison Control Center or doctor. Do not give anything by mouth to an unconscious person. Eye Contact: Causes substantial but temporary eye injury. First Aid: Hold eyelids open and flush slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Special Notes: Probable mucosal damage may contradict the use of gastric lavage. Use of this product may cause skin reactions in rare cases. If you suspect a reaction to this product, discontinue use. Take off contaminated clothing. Rinse immediately with plenty of water for minutes. Contact a Poison Control Center or doctor. Have the product container with you when calling or going for treatment. Health conditions Aggravated by Exposure: None known Ingredients listed by NTP, OSHA, or IARC as Carcinogens or Potential Carcinogens: None VIII Control Measures Steps to be Taken in Case Material is Released or Spilled: Soak up with absorbent material. Wash small quantities away with soapy water. Waste Disposal: Do not puncture or incinerate. If empty: Place in trash or offer for recycling. If partially filled: Call your local solid waste disposal agency or CLEANUP for disposal instructions. Never place unused product down an indoor or outdoor drain. Handling & Storage Precautions: Keep away from heat, sparks, or open flame. Exposure to temperatures higher than F may cause bursting. I Transportation Data Read and follow label directions. They are your best guide to using this product effectively, and give necessary safety precautions to protect your health. DOT Shipping Name: Not regulated by DOT DOT Hazard Class: NONE The information and statements herein are believed to be reliable but are not to be construed as warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE.

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169 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No US GHS Synonyms: Ultra Low Sulfur Diesel; Low Sulfur Diesel; No. 2 Diesel; Motor Vehicle Diesel Fuel; Non- Road Diesel Fuel; Locomotive/Marine Diesel Fuel * * * Section 1 - Product and Company Identification * * * Manufacturer Information Hess Corporation Phone: Corporate EHS 1 Hess Plaza Emergency # CHEMTREC Woodbridge, NJ (Environment, Health, Safety Internet Website) * * * Section 2 - Hazards Identification * * * GHS Classification: Flammable Liquids - Category 3 Skin Corrosion/Irritation Category 2 Germ Cell Mutagenicity Category 2 Carcinogenicity - Category 2 Specific Target Organ Toxicity (Single Exposure) - Category 3 (respiratory irritation, narcosis) Aspiration Hazard Category 1 Hazardous to the Aquatic Environment, Acute Hazard Category 3 GHS LABEL ELEMENTS Symbol(s) Signal Word DANGER Hazard Statements Flammable liquid and vapor. Causes skin irritation. Suspected of causing genetic defects. Suspected of causing cancer. May cause respiratory irritation. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Harmful to aquatic life. Precautionary Statements Prevention Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep container tightly closed. Ground/bond container and receiving equipment. Page 1 of 10 Revision Date 8/30/12

170 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Wash hands and forearms thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing fume/mist/vapours/spray. Response In case of fire: Use water spray, fog or foam to extinguish. IF ON SKIN (or hair): Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting. IF exposed or concerned: Get medical advice/attention. Storage Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. * * * Section 3 - Composition / Information on Ingredients * * * CAS # Component Percent Fuels, diesel, no Naphthalene <0.1 A complex mixture of h ydrocarbons with carbon numbers in the range C9 and higher. * * * Section 4 - First Aid Measures * * * First Aid: Eyes In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention. First Aid: Skin Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or with waterless hand cleanser. Obtain medical attention if irritation or redness develops. Thermal burns require immediate medical attention depending on the severity and the area of the body burned. First Aid: Ingestion DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated. Page 2 of 10 Revision Date 8/30/12

171 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No First Aid: Inhalation Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately. * * * Section 5 - Fire Fighting Measures * * * General Fire Hazards See Section 9 for Flammability Properties. Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard. Hazardous Combustion Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Extinguishing Media SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, and other gaseous agents. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers. Unsuitable Extinguishing Media None Fire Fighting Equipment/Instructions Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other fire fighting equipment. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand selfcontained breathing apparatus with full facepiece and full protective clothing. Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam. * * * Section 6 - Accidental Release Measures * * * Recovery and Neutralization Carefully contain and stop the source of the spill, if safe to do so. Materials and Methods for Clean-Up Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal. Caution, flammable vapors may accumulate in closed containers. Emergency Measures Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact. Page 3 of 10 Revision Date 8/30/12

172 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Personal Precautions and Protective Equipment Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8). Environmental Precautions Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection. Prevention of Secondary Hazards None * * * Section 7 - Handling and Storage * * * Handling Procedures Handle as a combustible liquid. Keep away from heat, sparks, excessive temperatures and open flame! No smoking or open flame in storage, use or handling areas. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion. Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents." Storage Procedures Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition. Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks." Incompatibilities Keep away from strong oxidizers. * * * Section 8 - Exposure Controls / Personal Protection * * * Component Exposure Limits Fuels, diesel, no. 2 ( ) ACGIH: 100 mg/m3 TWA (inhalable fraction and vapor, as total hydrocarbons, listed under Diesel fuel) Skin - potential significant contribution to overall exposure by the cutaneous route (listed under Diesel fuel) Page 4 of 10 Revision Date 8/30/12

173 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Naphthalene ( ) ACGIH: 10 ppm TWA 15 ppm STEL Skin - potential significant contribution to overall exposure by the cutaneous route OSHA: 10 ppm TWA; 50 mg/m3 TWA NIOSH: 10 ppm TWA; 50 mg/m3 TWA 15 ppm STEL; 75 mg/m3 STEL Engineering Measures Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Personal Protective Equipment: Respiratory A NIOSH/MSHA-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection. Personal Protective Equipment: Hands Gloves constructed of nitrile, neoprene, or PVC are recommended. Personal Protective Equipment: Eyes Safety glasses or goggles are recommended where there is a possibility of splashing or spraying. Personal Protective Equipment: Skin and Body Chemical protective clothing such as of E.I. DuPont TyChem, Saranex or equivalent recommended based on degree of exposure. Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Clear, straw-yellow. Odor: Mild, petroleum distillate odor Physical State: Liquid ph: ND Vapor Pressure: F (21 C) Vapor Density: >1.0 Boiling Point: 320 to 690 F (160 to 366 C) Melting Point: ND Solubility (H2O): Negligible Specific Gravity: 60 F (16 C) Evaporation Rate: Slow; varies with conditions VOC: ND Percent Volatile: 100% Octanol/H2O Coeff.: ND Flash Point: >125 F (>52 C) minimum Flash Point Method: PMCC Upper Flammability Limit 7.5 Lower Flammability Limit 0.6 (UFL): (LFL): Burning Rate: ND Auto Ignition: 494 F (257 C) * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability This is a stable material. Hazardous Reaction Potential Will not occur. Page 5 of 10 Revision Date 8/30/12

174 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Conditions to Avoid Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources. Incompatible Products Keep away from strong oxidizers. Hazardous Decomposition Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). * * * Section 11 - Toxicological Information * * * Acute Toxicity A: General Product Information Harmful if swallowed. B: Component Analysis - LD50/LC50 Naphthalene ( ) Inhalation LC50 Rat >340 mg/m3 1 h; Oral LD50 Rat 490 mg/kg; Dermal LD50 Rat >2500 mg/kg; Dermal LD50 Rabbit >20 g/kg Potential Health Effects: Skin Corrosion Property/Stimulativeness Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are repeatedly exposed. Potential Health Effects: Eye Critical Damage/ Stimulativeness Contact with eyes may cause mild irritation. Potential Health Effects: Ingestion Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur. Potential Health Effects: Inhalation Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death. WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death. Respiratory Organs Sensitization/Skin Sensitization This product is not reported to have any skin sensitization effects. Generative Cell Mutagenicity This material has been positive in a mutagenicity study. Carcinogenicity A: General Product Information Suspected of causing cancer. Page 6 of 10 Revision Date 8/30/12

175 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Studies have shown that similar products produce skin tumors in laboratory animals following repeated applications without washing or removal. The significance of this finding to human exposure has not been determined. Other studies with active skin carcinogens have shown that washing the animal s skin with soap and water between applications reduced tumor formation. B: Component Carcinogenicity Fuels, diesel, no. 2 ( ) ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed under Diesel fuel) Naphthalene ( ) ACGIH: A4 - Not Classifiable as a Human Carcinogen NTP: Reasonably Anticipated To Be A Human Carcinogen (Possible Select Carcinogen) IARC: Monograph 82 [2002] (Group 2B (possibly carcinogenic to humans)) Reproductive Toxicity This product is not reported to have any reproductive toxicity effects. Specified Target Organ General Toxicity: Single Exposure This product is not reported to have any specific target organ general toxicity single exposure effects. Specified Target Organ General Toxicity: Repeated Exposure This product is not reported to have any specific target organ general toxicity repeat exposure effects. Aspiration Respiratory Organs Hazard The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death. * * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and State regulations. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Fuels, diesel, no. 2 ( ) Test & Species Conditions 96 Hr LC50 Pimephales promelas 35 mg/l [flowthrough] Naphthalene ( ) Test & Species 96 Hr LC50 Pimephales promelas mg/l [flow-through] 96 Hr LC50 Oncorhynchus mykiss 1.6 mg/l [flowthrough] 96 Hr LC50 Oncorhynchus mykiss mg/l [static] 96 Hr LC50 Pimephales promelas 1.99 mg/l [static] Conditions Page 7 of 10 Revision Date 8/30/12

176 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Hr LC50 Lepomis macrochirus mg/l [static] 72 Hr EC50 Skeletonema costatum 0.4 mg/l 48 Hr LC50 Daphnia magna 2.16 mg/l 48 Hr EC50 Daphnia magna 1.96 mg/l [Flow through] 48 Hr EC50 Daphnia magna mg/l [Static] Persistence/Degradability No information available. Bioaccumulation No information available. Mobility in Soil No information available. * * * Section 13 - Disposal Considerations * * * Waste Disposal Instructions See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations. Disposal of Contaminated Containers or Packaging Dispose of contents/container in accordance with local/regional/national/international regulations. * * * Section 14 - Transportation Information * * * DOT Information Shipping Name: Diesel Fuel NA #: 1993 Hazard Class: 3 Packing Group: III Placard: Regulatory Information * * * Section 15 - Regulatory Information * * * Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR ) and/or CERCLA (40 CFR 302.4). Naphthalene ( ) CERCLA: 100 lb final RQ; 45.4 kg final RQ SARA Section 311/312 Hazard Classes Acute Health Chronic Health Fire Sudden Release of Pressure Reactive Page 8 of 10 Revision Date 8/30/12

177 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No SARA SECTION SUPPLIER NOTIFICATION This product may contain listed chemicals below the de minimis levels which therefore are not subject to the supplier notification requirements of Section 313 of the Emergency Planning and Community Right- To-Know Act (EPCRA) of 1986 and of 40 CFR 372. If you may be required to report releases of chemicals listed in 40 CFR , you may contact Hess Corporate Safety if you require additional information regarding this product. State Regulations Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI Fuels, diesel, no No No No Yes No No Naphthalene Yes Yes Yes Yes Yes No The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. Component Analysis - WHMIS IDL No components are listed in the WHMIS IDL. Additional Regulatory Information Component Analysis - Inventory Component CAS # TSCA CAN EEC Fuels, diesel, no Yes DSL EINECS Naphthalene Yes DSL EINECS * * * Section 16 - Other Information * * * NFPA Hazard Rating Health 1 Fire 2 Reactivity HMIS Hazard Rating Health 1* Slight Fire 2 Moderate Physical 0 Minimal *Chronic 1 Page 9 of 10 Revision Date 8/30/12

178 Safety Data Sheet Material Name: Diesel Fuel, All Types SDS No Key/Legend ACGIH = American Conference of Governmental Industrial Hygienists; ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail; ADR/RID = European Agreement of Dangerous Goods by Road/Rail; AS = Standards Australia; DFG = Deutsche Forschungsgemeinschaft; DOT = Department of Transportation; DSL = Domestic Substances List; EEC = European Economic Community; EINECS = European Inventory of Existing Commercial Chemical Substances; ELINCS = European List of Notified Chemical Substances; EU = European Union; HMIS = Hazardous Materials Identification System; IARC = International Agency for Research on Cancer; IMO = International Maritime Organization; IATA = International Air Transport Association; MAK = Maximum Concentration Value in the Workplace; NDSL = Non-Domestic Substances List; NFPA = National Fire Protection Association; NOHSC = National Occupational Health & Safety Commission; NTP = National Toxicology Program; STEL = Short-term Exposure Limit; TDG = Transportation of Dangerous Goods; TLV = Threshold Limit Value; TSCA = Toxic Substances Control Act; TWA = Time Weighted Average Literature References None Other Information Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material. End of Sheet Page 10 of 10 Revision Date 8/30/12

179 MATERIAL SAFETY DATA SHEET Identity: Eye Wash / Wound Irrigation Sterile, Buffered, Isotonic, Saline Aaxis Pacific Address: Section 1 Telephone: Fax: Forge St Blacktown, N.S.W. Date Prepared: 15/02/ , Australia Prepared by: Sher Soa Section II Material Identification Information Components (Chemical Names & Common Name) Hazardous Component 1% or greater, Carcinogens 0.1% or greater. CAS No. % Sodium Chloride OSHA PEL ACGIH TLV OTHER LIMITS Potassium Dihydrogen Phosphate Sodium Hydroxide Section III Physical/Chemical Characteristics Physical State: LIQUID Specific Gravity (H2O = 1) 1 Boiling Point: 100 C Melting Point: N/A Vapour Pressure (mm Hg); N/A Evaporation Rate (Water =1) 1 Vapour Density (Air =1) Unknown Water Reactive: None Solubility in Water; Good Percent Volatile: N/A ph: Appearance and Odour: Clear, Colourless Liquid, Odourless Section IV Fire and Explosion Data Flash Point Non-Flammable Flammability Limits in Air % by Volume: N/A Extinguisher Media: Carbon Dioxide, Water, Foam Special Fire Fighting Procedure: None Auto Ignition Temperature N/A Unusual Fire and Explosion Hazards: None LEL: N/A UEL: N/A Stability Incompatibility (Materials to Avoid): Hazardous Decomposition Products: Section V Reactivity Data Unstable; No Conditions to Avoid: Stable: N/A N/A Yes None Hazardous Polymerization May May Occur No Conditions to Avoid: None Occur: May Not Occur: Yes Section VI Health Hazard Data Potential Acute Health Effects Eye Contact: PRODUCT IS INTENDED FOR USE IN OCULAR AREA Skin Contact Inhalation: Ingestion PRODUCT HAS NO EFFECT PRODUCT HAS NO EEFECT MAY CAUSE STOMACH DISCOMFORT IF LARGE AMOUNT INGESTED

180 Identity: Emergency First Aid Procedure Eye Contact; Skin Contact; Inhalation; Ingestion; Eye Wash Sterile, Buffered, Isotonic, Saline (Blue Label) Section VII Health Hazard Data SEEK MEDICAL ASSISTANCE FOR FURTHER TREATMENT, OBSERVATION AND SUPPORT AS NECESSARY NONE REQUIRED NONE REQUIRED NONE REQUIRED CALL A PHYSICIAN, IF STOMACH DISCOMFORT OCCURS. Section VIII Control and Protective Measures Respiratory protection (Specify NONE Type): Protection Gloves: NONE Eye Protection NONE Ventilation to be Used: Local Exhaust N/A Special: N/A Mechanical (General) N/A Other: N/A Other protective Clothing and Equipment: NOT REQUIRED Hygienic Work Practices: KEEP CONTAINER CLOSED WHEN NOT IN USE. ALWAYS READ LABEL BEFORE USE. Section I precaution for Safety Handling and Use Leak Procedure Steps to be taken if Material is Spilled or Released: Waste Disposal Methods: Precaution to be taken in handling and Storage: Other Precaution and/or Special Hazards: HMIS Rating: Health: 0 Flammability : MOP UP OR FLUSH DOWN SANITARY SEWER. IN ACCORDANCE WITH MUNICIPAL, PROVINCIAL AND FEDERAL REGULATION KEEP AT ROOM TEMPERATURE (15-30 C) KEEP FROM FREEZING READ LABEL BEFORE USING. 0 Reactivity 0 Personal 0 Protection NFPA Rating: Health: 0 Flammability 0 Reactivity 0 Personal Protection 0

181 I - Product Identification Product Identifier: { Fire Extinguisher ABC Multipurpose Dry Chemical { Fire Extinguisher Powder ABC Multipurpose Chemical Name: ABC Dry Chemical (Mono-Ammonium Phosphate) Chemical Family: Mixture Formula: (NH 4) H2PO4 Product Use: Used in the application of extinguishing fires. Manufacturer's Name and Telephone Number: Flag Fire Equipment Hwy #2 & Patillo Road, RR#1 Tecumseh, Ontario N8N 2L9 Emergency Telephone: Technical Information: II - Hazardous Ingredients Name Silica Gel % 0.12 Cas # LD 50 >4500 mg/kg/rat Other Ingredients Name Cas # Mono Ammonium Phosphate Tricalcium Phosphate Methyl Hydrogen Polysiloxane LC 50 >2 mg/hr/rat Fire Extinguishers contain compressed air to ensure a high velocity discharge of product. WHMIS Class A. III - Physical Data Physical State Odour and Appearance Odour Threshold (ppm) Vapour Pressure (mm Hg) Evaporation Rate Boiling Point ( o C) Freezing Point ( o C) ph Specific Gravity Solubility in Water IV - Fire and Explosion Data Flashpoint ( o C) and Method: Means of Extinction Upper Flammable Point Lower Flammable Point Auto Ignition Temperature ( o C) Hazardous Combustion Products Explosion Data Sensitivity to Impact Sensitivity to Static Discharge Solid Yellow Crystal and odourless Not Applicable Not Applicable None Not Applicable Not Applicable 4.5 of 1% solution Not Applicable 38 grams / 100 ml H 2O Non-flammable None required Not Applicable Not Applicable Not Applicable None Known Not Applicable Not Applicable V - Reactivity Data Yes Chemical Stability Yes Incompatibility with other substances Conditions to avoid: Do not mix with strong Alkalies Hazardous Decomposition Products Decomposes if heated above 121 o C o C Ammonia, Carbon Monoxide and Oxides of Nitrogen are produced. MATERIAL SAFETY DATA SHEET VI - Toxicological Properties Route of Entry Skin Contact Eye Contact Inhalation z Skin Absorption Ingestion Effects of Overexposure: At high dust concentrations, irritation of eyes, skin and mucus membranes by chemical or mechanical action may occur. Exposure Limits Not Available Irritancy of Product Not Available Sensitization to Product Not Available Carcinogenicity None. Product is considered a nusisance dust. Silica Gel is a Synthetic Amorphous Silica which is considered a nuisance dust and no medical conditions are abnormally aggravated by this product. Teratogenicity None Reproductive Toxicity None Mutagenicity None Synergistic Products Not Available VII - Preventative Measures Gloves None Required Respirator If in high dust concentration, wear a properly fitted NIOSH-approved dust respirator Footwear None Required Clothing None Specified Eyewear None Required Engineering Controls Adequate ventilation should be available to maintain dust levels below applicable standards on respirable and total nuisance dust. (at recharge stations only) Leak and Spill Procedure Ensure clean-up is performed by trained personnel only. Shovel or sweep up dry material for recycling or disposal. Flush residue with water. Waste Disposal Review federal, provincial/state, and local government requirements prior to disposal. Disposal by secure landfill may be acceptable. Handling Procedures Avoid container damage Storage Requirements Cool dry areas Special shipping information Fire Extinguisher Class 2.2 UN # 1044 VIII - First Aid Measures Inhalation: Ingestion: Eye Contact: Skin Contact: If breathing difficulty occurs because of dust inhalation, remove to fresh air. If person is conscious, give large amounts of water. If eye irritation occurs, flush with copious amounts of water. Get medical attention if irritation persists. Wash with mild soap and water. I - Preparation Date of MSDS Prepared by Department: Health and Safety Date: 01/01/2002 Fire Extinguisher ABC Multipurpose Dry Chemical "Information contained herein is provided without any warranty. Flag Fire Equipment Ltd. will not be liable for any damage which may result from the use or reliance on any information contained herein." Before any product is used, the label should be carefully read. MSDS Control # MS Updated MSDS forms may also be obtained on the internet at

182 Conforms to ANSI Z Standard Product name Synonym Trade name Code Material uses In case of emergency Material Safety Data Sheet Fogtech D Instant Anti-Fog 1. Product and company identification Supplier/Manufacturer : MSDS authored by 2. Hazards identification Potential acute health effects Inhalation Ingestion Skin Eyes : : : : : : : Fogtech D Instant Anti-Fog Moistened towelette wipe in sealed packet Fogtech D Instant Anti-Fog FTPKD001 Significantly improves vision through polycarbonate lenses, shields or windows by preventing fogging or misting. MotoSolutions 966 Coral Drive Rodeo, California, Tel : Fax : gene@motosolutions.com KMK Regulatory Services Inc. (510) Emergency overview Physical state : Moistened towelette. Color : Water clear. Signal word : WARNING! Hazard statements : BEFORE APPLICATION: FLAMMABLE SOLID. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Precautionary measures OSHA/HCS status : : : : AFTER APPLICATION AND EVAPORATION OF ALCOHOL CARRIER: NO SIGNIFICANT EFFECTS. : Keep away from heat, sparks and flame. Avoid contact with eyes. Keep container tightly closed and sealed until ready for use. : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). No known significant effects or critical hazards. No known significant effects or critical hazards. Moderately irritating to the skin with prolonged contact. Temporarily Irritating to eyes. Potential chronic health effects Chronic effects : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Target organs : Contains material which may cause damage to the following organs: blood, the nervous system, the reproductive system, liver, upper respiratory tract, skin, eyes, central nervous system (CNS). Over-exposure signs/symptoms KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 1/7

183 2. Hazards identification Inhalation Ingestion Skin Eyes : No specific data. : No specific data. : Adverse symptoms may include the following with prolonged contact: irritation redness : Adverse symptoms may include the following: pain or irritation watering redness Fogtech D Instant Anti-Fog Medical conditions aggravated by overexposure : None known. See toxicological information (Section 11) 3. Composition/information on ingredients United States Name CAS number % Ethyl Alcohol Canada Name CAS number % Ethyl Alcohol There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Skin contact Inhalation Ingestion Notes to physician : 5. Fire-fighting measures Flammability of the product Extinguishing media : : : : Suitable : Not suitable : Special exposure hazards : Hazardous decomposition products Special protective equipment for fire-fighters : : Immediately flush eyes with plenty of water for at least 20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptoms occur. If symptoms occur, immediately flush skin with plenty of water for at least 20 minutes. Get medical attention if symptoms occur. None known. Get medical attention if symptoms occur. Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur. No specific treatment. Treat symptomatically. Flammable. Use dry chemical, CO2, water spray (fog) or foam. Do not use water jet. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. : Decomposition products may include the following materials: carbon dioxide carbon monoxide Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 2/7

184 Fogtech D Instant Anti-Fog 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up : None known. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Small spill : Large spill : 7. Handling and storage Handling Storage : : Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosionproof equipment. Dispose via a licensed waste disposal contractor. Place spilled material in an appropriate container for disposal. Avoid contact with eyes. Keep away from heat, sparks and flame. Wash thoroughly after handling. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). 8. Exposure controls/personal protection United States Ingredient Exposure limits Ethyl Alcohol ACGIH TLV (United States, 2/2010). STEL: 1000 ppm 15 minute(s). NIOSH REL (United States, 6/2009). TWA: 1900 mg/m³ 10 hour(s). TWA: 1000 ppm 10 hour(s). OSHA PEL (United States, 6/2010). TWA: 1900 mg/m³ 8 hour(s). TWA: 1000 ppm 8 hour(s). Canada Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations Ethyl Alcohol US ACGIH 2/ AB 4/ BC 9/ ON 7/ QC 6/ Consult local authorities for acceptable exposure limits. Recommended monitoring procedures Engineering measures Hygiene measures Personal protection Respiratory Hands : Eyes : Skin : Environmental exposure controls : None known. : None known. : Ensure that eyewash stations and safety showers are close to the workstation location. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. : Not required under normal conditions of use. Not required under normal conditions of use. Not required under normal conditions of use. Not required under normal conditions of use. : Not required. KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 3/7

185 9. Physical and chemical properties Physical state Flash point Color Molecular formula Solubility : Moistened towelette. : Closed cup: -18 to 23 C (-0.4 to 73.4 F) [Pensky-Martens.] : Water clear. : Not applicable. : Soluble in water. 10. Stability and reactivity Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological information Acute toxicity : : : : Fogtech D Instant Anti-Fog The product is stable. Avoid all possible sources of ignition (spark or flame). Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis. Decomposition products may include the following materials: carbon dioxide carbon monoxide : Under normal conditions of storage and use, hazardous reactions will not occur. Product/ingredient name Result Species Dose Exposure Ethyl Alcohol LC50 Inhalation Vapor Rat mg/m3 4 hours LD50 Oral Rat 7 g/kg - Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Ethyl Alcohol Eyes - Moderate irritant Rabbit μl - Skin - Moderate irritant Rabbit - 24 hours 20 mg - IDLH Synergistic products : Not available. : Not available. 12. Ecological information Ecotoxicity Aquatic ecotoxicity Product/ingredient name : No known significant effects or critical hazards. Result Species Exposure Ethyl Alcohol Acute EC mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC ug/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC ug/l Marine water Crustaceans - Artemia franchiscana - 48 hours Larvae Acute LC ug/l Fresh water Fish - Oncorhynchus mykiss 4 days Chronic NOEC ul/l Fresh water Fish - Gambusia holbrooki - Larvae - 3 days 12 weeks 13. Disposal considerations Waste disposal : The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 4/7

186 Fogtech D Instant Anti-Fog 14. Transport information International transport regulations Regulatory information UN number Proper shipping name Classes PG* Label Additional information DOT Classification Not regulated Remarks Special Provision 47 TDG Classification - Not regulated United States Postal Service Not regulated Remarks PCSC Ruling March 15, 2011 IMDG Class Not regulated Remarks Special Provision 216 IATA-DGR Class Not regulated Remarks Special Provision A46 PG* : Packing group Exemption to the above classification may apply. AERG : Not applicable. Packaging: In sealed packets containing 1.4 grams/2,5 ml of liquid fully absorbed into folded towelette. 15. Regulatory information United States HCS Classification U.S. Federal regulations : : Flammable solid Irritating material TSCA 8(a) PAIR: Octamethylcyclotetrasiloxane; Decamethylcyclopentasiloxane TSCA 8(a) IUR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. TSCA 8(d) H and S data reporting: Decamethylcyclopentasiloxane SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: Ethyl Alcohol SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Ethyl Alcohol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Class I Substances Clean Air Act Section 602 Class II Substances DEA List I Chemicals (Precursor Chemicals) DEA List II Chemicals (Essential Chemicals) State regulations Massachusetts New York New Jersey Pennsylvania California Prop. 65 No products were found. : Not listed : Not listed : Not listed : Not listed : Not listed : The following components are listed: Ethyl Alcohol : None of the components are listed. : The following components are listed: Ethyl Alcohol : The following components are listed: Ethyl Alcohol KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 5/7

187 Fogtech D Instant Anti-Fog 15. Regulatory information Canada WHMIS (Canada) : Class B-4: Flammable solid. Class D-2B: Material causing other toxic effects (Toxic). Canadian lists Canadian NPRI : The following components are listed: Ethyl Alcohol CEPA Toxic substances : None of the components are listed. Canada inventory : Not determined. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. International regulations International lists : Australia inventory (AICS): Not determined. China inventory (IECSC): Not determined. Japan inventory: Not determined. Korea inventory: Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. 16. Other information Label requirements : BEFORE APPLICATION: FLAMMABLE SOLID. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. Hazardous Material Information System (U.S.A.) : AFTER APPLICATION AND EVAPORATION OF ALCOHOL CARRIER: NO SIGNIFICANT EFFECTS. Health : 1 Flammability : 2 Physical hazards : 0 Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR , the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) : Health : 1 Flammability : 2 Instability : 0 Reprinted with permission from NFPA , Identification of the Hazards of Materials for Emergency Response Copyright 1997, National Fire Protection Association, Quincy, MA This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright 2001, National Fire Protection Association, Quincy, MA This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Canada WHMIS (Canada) : History Date of issue mm/dd/yyyy : Date of previous issue : Version : 04/01/ /15/ KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 6/7

188 16. Other information Fogtech D Instant Anti-Fog Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. KMK Regulatory Services Inc. Tel : GHS-7769 ( )/ GHS-7767 ( ); Services Réglementaires KMK Inc. 7/7

189 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No EMERGENCY OVERVIEW DANGER! ETREMELY FLAMMABLE - EYE AND MUCOUS MEMBRANE IRRITANT - EFFECTS CENTRAL NERVOUS SYSTEM - HARMFUL OR FATAL IF SWALLOWED - ASPIRATION HAZARD NFPA 704 (Section 16) High fire hazard. Keep away from heat, spark, open flame, and other ignition sources. If ingested, do NOT induce vomiting, as this may cause chemical pneumonia (fluid in the lungs). Contact may cause eye, skin and mucous membrane irritation. Harmful if absorbed through the skin. Avoid prolonged breathing of vapors or mists. Inhalation may cause irritation, anesthetic effects (dizziness, nausea, headache, intoxication), and respiratory system effects. Long-term exposure may cause effects to specific organs, such as to the liver, kidneys, blood, nervous system, and skin. Contains benzene, which can cause blood disease, including anemia and leukemia. 1. CHEMICAL PRODUCT and COMPANY INFORMATION Hess Corporation 1 Hess Plaza Woodbridge, NJ EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800) COMPANY CONTACT (business hours): Corporate Safety (732) MSDS (Environment, Health, Safety) Internet Website SYNONYMS: Hess Conventional (Oxygenated and Non-oxygenated) Gasoline; Reformulated Gasoline (RFG); Reformulated Gasoline Blendstock for Oxygenate Blending (RBOB); Unleaded Motor or Automotive Gasoline See Section 16 for abbreviations and acronyms. 2. COMPOSITION and INFORMATION ON INGREDIENTS * INGREDIENT NAME (CAS No.) CONCENTRATION PERCENT BY WEIGHT Gasoline ( ) 100 Benzene ( ) ( reformulated gasoline) n-butane ( ) < 10 Ethyl Alcohol (Ethanol) ( ) 0-10 Ethyl benzene ( ) < 3 n-hexane ( ) 0.5 to 4 Methyl-tertiary butyl ether (MTBE) ( ) 0 to 15.0 Tertiary-amyl methyl ether (TAME) ( ) 0 to 17.2 Toluene ( ) ,2,4- Trimethylbenzene ( ) < 6 ylene, mixed isomers ( ) 1-15 A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic hydrocarbons. May contain antioxidant and multifunctional additives. Non-oxygenated Conventional Gasoline and RBOB do not have oxygenates (Ethanol or MTBE and/or TAME). Revision Date: 09/25/2007 Page 1 of 9

190 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No Oxygenated Conventional and Reformulated Gasoline will have oxygenates for octane enhancement or as legally required. 3. HAZARDS IDENTIFICATION EYES Moderate irritant. Contact with liquid or vapor may cause irritation. SKIN Practically non-toxic if absorbed following acute (single) exposure. May cause skin irritation with prolonged or repeated contact. Liquid may be absorbed through the skin in toxic amounts if large areas of skin are exposed repeatedly. INGESTION The major health threat of ingestion occurs from the danger of aspiration (breathing) of liquid drops into the lungs, particularly from vomiting. Aspiration may result in chemical pneumonia (fluid in the lungs), severe lung damage, respiratory failure and even death. Ingestion may cause gastrointestinal disturbances, including irritation, nausea, vomiting and diarrhea, and central nervous system (brain) effects similar to alcohol intoxication. In severe cases, tremors, convulsions, loss of consciousness, coma, respiratory arrest, and death may occur. INHALATION Excessive exposure may cause irritations to the nose, throat, lungs and respiratory tract. Central nervous system (brain) effects may include headache, dizziness, loss of balance and coordination, unconsciousness, coma, respiratory failure, and death. WARNING: the burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death. CHRONIC EFFECTS and CARCINOGENICITY Contains benzene, a regulated human carcinogen. Benzene has the potential to cause anemia and other blood diseases, including leukemia, after repeated and prolonged exposure. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with systemic toxicity. See also Section 11 - Toxicological Information. MEDICAL CONDITIONS AGGRAVATED BY EPOSURE Irritation from skin exposure may aggravate existing open wounds, skin disorders, and dermatitis (rash). Chronic respiratory disease, liver or kidney dysfunction, or pre-existing central nervous system disorders may be aggravated by exposure. 4. FIRST AID MEASURES EYES In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention. SKIN Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or waterless hand cleanser. Obtain medical attention if irritation or redness develops. INGESTION Revision Date: 09/25/2007 Page 2 of 9

191 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated. INHALATION Remove person to fresh air. If person is not breathing, ensure an open airway and provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: FLASH POINT: -45 o F (-43 o C) AUTOIGNITION TEMPERATURE: highly variable; > 530 o F (>280 o C) OSHA/NFPA FLAMMABILITY CLASS: 1A (flammable liquid) LOWER EPLOSIVE LIMIT (%): 1.4% UPPER EPLOSIVE LIMIT (%): 7.6% FIRE AND EPLOSION HAZARDS Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. Flowing product may be ignited by self-generated static electricity. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces. Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard. ETINGUISHING MEDIA SMALL FIRES: Any extinguisher suitable for Class B fires, dry chemical, CO2, water spray, fire fighting foam, or Halon. LARGE FIRES: Water spray, fog or fire fighting foam. Water may be ineffective for fighting the fire, but may be used to cool fire-exposed containers. During certain times of the year and/or in certain geographical locations, gasoline may contain MTBE and/or TAME. Firefighting foam suitable for polar solvents is recommended for fuel with greater than 10% oxygenate concentration - refer to NFPA 11 Low Expansion Foam Edition. FIRE FIGHTING INSTRUCTIONS Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire extinguishers and other fire fighting equipment. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing. Isolate area around container involved in fire. Cool tanks, shells, and containers exposed to fire and excessive heat with water. For massive fires the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Major fires may require withdrawal, allowing the tank to burn. Large storage tank fires typically require specially trained personnel and equipment to extinguish the fire, often including the need for properly applied fire fighting foam. See Section 16 for the NFPA 704 Hazard Rating. Revision Date: 09/25/2007 Page 3 of 9

192 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No ACCIDENTAL RELEASE MEASURES ACTIVATE FACILITY SPILL CONTINGENCY or EMERGENCY PLAN. Evacuate nonessential personnel and remove or secure all ignition sources. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to confirm spill areas. Spills may infiltrate subsurface soil and groundwater; professional assistance may be necessary to determine the extent of subsurface impact. Carefully contain and stop the source of the spill, if safe to do so. Protect bodies of water by diking, absorbents, or absorbent boom, if possible. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material. The use of fire fighting foam may be useful in certain situations to reduce vapors. The proper use of water spray may effectively disperse product vapors or the liquid itself, preventing contact with ignition sources or areas/equipment that require protection. Take up with sand or other oil absorbing materials. Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal - caution, flammable vapors may accumulate in closed containers. Response and clean-up crews must be properly trained and must utilize proper protective equipment (see Section 8). 7. HANDLING and STORAGE HANDLING PRECAUTIONS ******USE ONLY AS A MOTOR FUEL****** ******DO NOT SIPHON BY MOUTH****** Handle as a flammable liquid. Keep away from heat, sparks, and open flame! Electrical equipment should be approved for classified area. Bond and ground containers during product transfer to reduce the possibility of static-initiated fire or explosion. Special slow load procedures for "switch loading" must be followed to avoid the static ignition hazard that can exist when higher flash point material (such as fuel oil) is loaded into tanks previously containing low flash point products (such as this product) - see API Publication 2003, "Protection Against Ignitions Arising Out Of Static, Lightning and Stray Currents. STORAGE PRECAUTIONS Keep away from flame, sparks, excessive temperatures and open flame. Use approved vented containers. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition. Store in a well-ventilated area. This storage area should comply with NFPA 30 "Flammable and Combustible Liquid Code". Avoid storage near incompatible materials. The cleaning of tanks previously containing this product should follow API Recommended Practice (RP) 2013 "Cleaning Mobile Tanks In Flammable and Combustible Liquid Service" and API RP 2015 "Cleaning Petroleum Storage Tanks". WORK/HYGIENIC PRACTICES Emergency eye wash capability should be available in the near proximity to operations presenting a potential splash exposure. Use good personal hygiene practices. Avoid repeated and/or prolonged skin exposure. Wash hands before eating, drinking, smoking, or using toilet facilities. Do not use as a cleaning solvent on the skin. Do not use solvents or harsh abrasive skin cleaners for washing this product from exposed skin areas. Waterless hand cleaners are effective. Promptly remove contaminated clothing and launder before reuse. Use care when laundering to prevent the formation of flammable vapors which could ignite via washer or dryer. Consider the need to discard contaminated leather shoes and gloves. Revision Date: 09/25/2007 Page 4 of 9

193 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No EPOSURE CONTROLS and PERSONAL PROTECTION EPOSURE LIMITS Component (CAS No.) Exposure Limits Source TWA (ppm) STEL (ppm) Gasoline ( ) ACGIH A3 Benzene ( ) OSHA 1 5 Carcinogen ACGIH A1, skin USCG 1 5 n-butane ( ) ACGIH Aliphatic Hydrocarbon Gases Alkane (C1-C4) Ethyl Alcohol (ethanol) ( ) OSHA ACGIH A4 Ethyl benzene ( ) OSHA ACGIH A3 n-hexane ( ) OSHA ACGIH Skin Methyl-tertiary butyl ether [MTBE] ( ) ACGIH 50 A3 Tertiary-amyl methyl ether [TAME] ( ) None established Toluene ( ) OSHA ACGIH Ceiling: 300 ppm; Peak: 500 ppm (10 min.) A4 1,2,4- Trimethylbenzene ( ) ACGIH ylene, mixed isomers ( ) OSHA ACGIH A4 ENGINEERING CONTROLS Use adequate ventilation to keep vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. EYE/FACE PROTECTION Safety glasses or goggles are recommended where there is a possibility of splashing or spraying. SKIN PROTECTION Gloves constructed of nitrile or neoprene are recommended. Chemical protective clothing such as that made of of E.I. DuPont Tychem, products or equivalent is recommended based on degree of exposure. Note: The resistance of specific material may vary from product to product as well as with degree of exposure. Consult manufacturer specifications for further information. RESPIRATORY PROTECTION A NIOSH-approved air-purifying respirator with organic vapor cartridges or canister may be permissible under certain circumstances where airborne concentrations are or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying respirators is limited. Refer to OSHA 29 CFR , NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection and limitations. Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection. 9. PHYSICAL and CHEMICAL PROPERTIES APPEARANCE A translucent, straw-colored or light yellow liquid Note Revision Date: 09/25/2007 Page 5 of 9

194 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No ODOR A strong, characteristic aromatic hydrocarbon odor. Oxygenated gasoline with MTBE and/or TAME may have a sweet, ether-like odor and is detectable at a lower concentration than non-oxygenated gasoline. ODOR THRESHOLD Odor Detection Odor Recognition Non-oxygenated gasoline: ppm ppm Gasoline with 15% MTBE: ppm ppm Gasoline with 15% TAME: 0.1 ppm 0.2 ppm BASIC PHYSICAL PROPERTIES BOILING RANGE: 85 to 437 o F (39 to 200 o C) VAPOR PRESSURE: o F (38 o C) ( mm 68 o F (20 o C) VAPOR DENSITY (air = 1): AP 3 to 4 SPECIFIC GRAVITY (H 2 O = 1): EVAPORATION RATE: (n-butyl acetate = 1) PERCENT VOLATILES: 100 % SOLUBILITY (H 2 O): Non-oxygenated gasoline - negligible (< 77 o F). Gasoline with 15% MTBE - slight 77 o F); ethanol is readily soluble in water 10. STABILITY and REACTIVITY ) STABILITY: Stable. Hazardous polymerization will not occur. CONDITIONS TO AVOID Avoid high temperatures, open flames, sparks, welding, smoking and other ignition sources INCOMPATIBLE MATERIALS Keep away from strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke). Contact with nitric and sulfuric acids will form nitrocresols that can decompose violently. 11. TOICOLOGICAL PROPERTIES ACUTE TOICITY Acute Dermal LD50 (rabbits): > 5 ml/kg Acute Oral LD50 (rat): ml/kg Primary dermal irritation (rabbits): slightly irritating Draize eye irritation (rabbits): non-irritating Guinea pig sensitization: negative CHRONIC EFFECTS AND CARCINOGENICITY Carcinogenicity: OSHA: NO IARC: YES - 2B NTP: NO ACGIH: YES (A3) IARC has determined that gasoline and gasoline exhaust are possibly carcinogenic in humans. Inhalation exposure to completely vaporized unleaded gasoline caused kidney cancers in male rats and liver tumors in female mice. The U.S. EPA has determined that the male kidney tumors are species-specific and are irrelevant for human health risk assessment. The significance of the tumors seen in female mice is not known. Exposure to light hydrocarbons in the same boiling range as this product has been associated in animal studies with effects to the central and peripheral nervous systems, liver, and kidneys. The significance of these animal models to predict similar human response to gasoline is uncertain. This product contains benzene. Human health studies indicate that prolonged and/or repeated overexposure to benzene may cause damage to the blood-forming system (particularly bone marrow), and serious blood disorders such as aplastic anemia and leukemia. Benzene is listed as a human carcinogen by the NTP, IARC, OSHA and ACGIH. Revision Date: 09/25/2007 Page 6 of 9

195 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No This product may contain methyl tertiary butyl ether (MTBE ): animal and human health effects studies indicate that MTBE may cause eye, skin, and respiratory tract irritation, central nervous system depression and neurotoxicity. MTBE is classified as an animal carcinogen (A3) by the ACGIH. 12. ECOLOGICAL INFORMATION Keep out of sewers, drainage areas and waterways. Report spills and releases, as applicable, under Federal and State regulations. If released, oxygenates such as ethers and alcohols will be expected to exhibit fairly high mobility in soil, and therefore may leach into groundwater. The API ( provides a number of useful references addressing petroleum and oxygenate contamination of groundwater. 13. DISPOSAL CONSIDERATIONS Consult federal, state and local waste regulations to determine appropriate disposal options. 14. TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME: Gasoline DOT HAZARD CLASS and PACKING GROUP: 3, PG II DOT IDENTIFICATION NUMBER: UN 1203 DOT SHIPPING LABEL: FLAMMABLE LIQUID PLACARD: 15. REGULATORY INFORMATION U.S. FEDERAL, STATE, and LOCAL REGULATORY INFORMATION This product and its constituents listed herein are on the EPA TSCA Inventory. Any spill or uncontrolled release of this product, including any substantial threat of release, may be subject to federal, state and/or local reporting requirements. This product and/or its constituents may also be subject to other federal, state, or local regulations; consult those regulations applicable to your facility/operation. CLEAN WATER ACT (OIL SPILLS) Any spill or release of this product to "navigable waters" (essentially any surface water, including certain wetlands) or adjoining shorelines sufficient to cause a visible sheen or deposit of a sludge or emulsion must be reported immediately to the National Response Center ( ) as required by U.S. Federal Law. Also contact appropriate state and local regulatory agencies as required. CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIRONMENT) The CERCLA definition of hazardous substances contains a petroleum exclusion clause which exempts crude oil, refined, and unrefined petroleum products and any indigenous components of such. However, other federal reporting requirements (e.g., SARA Section 304 as well as the Clean Water Act if the spill occurs on navigable waters) may still apply. SARA SECTION 311/312 - HAZARD CLASSES ACUTE HEALTH CHRONIC HEALTH FIRE SUDDEN RELEASE OF PRESSURE REACTIVE SARA SECTION SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372: INGREDIENT NAME (CAS NUMBER) Benzene ( ) Ethyl benzene ( ) < 3 CONCENTRATION WT. PERCENT 0.1 to 4.9 (0.1 to 1.3 for reformulated gasoline) Revision Date: 09/25/2007 Page 7 of 9

196 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No n-hexane ( ) 0.5 to 4 Methyl-tertiary butyl ether (MTBE) ( ) 0 to 15.0 Toluene ( ) 1 to 15 1,2,4- Trimethylbenzene ( ) < 6 ylene, mixed isomers ( ) 1 to 15 US EPA guidance documents ( for reporting Persistent Bioaccumulating Toxics (PBTs) indicate this product may contain the following deminimis levels of toxic chemicals subject to Section 313 reporting: INGREDIENT NAME (CAS NUMBER) Polycyclic aromatic compounds (PACs) Benzo (g,h,i) perylene ( ) Lead ( ) CONCENTRATION - Parts per million (ppm) by weight CALIFORNIA PROPOSITION 65 LIST OF CHEMICALS This product contains the following chemicals that are included on the Proposition 65 List of Chemicals required by the California Safe Drinking Water and Toxic Enforcement Act of 1986: INGREDIENT NAME (CAS NUMBER) Date Listed Benzene 2/27/1987 Ethyl benzene 6/11/2004 Toluene 1/1/1991 CANADIAN REGULATORY INFORMATION (WHMIS) Class B, Division 2 (Flammable Liquid) Class D, Division 2A (Very toxic by other means) and Class D, Division 2B (Toxic by other means) 16. OTHER INFORMATION NFPA HAZARD RATING HEALTH: 1 Slight FIRE: 3 Serious REACTIVITY: 0 Minimal HMIS HAZARD RATING HEALTH: 1 * Slight FIRE: 3 Serious PHYSICAL: 0 Minimal * CHRONIC SUPERSEDES MSDS DATED: 07/01/06 ABBREVIATIONS: AP = Approximately < = Less than > = Greater than N/A = Not Applicable N/D = Not Determined ppm = parts per million ACRONYMS: ACGIH American Conference of Governmental Industrial Hygienists CERCLA Comprehensive Emergency Response, Compensation, and Liability Act AIHA American Industrial Hygiene Association DOT U.S. Department of Transportation ANSI American National Standards Institute [General Info: (800) ] (212) EPA U.S. Environmental Protection Agency API American Petroleum Institute (202) HMIS Hazardous Materials Information System Revision Date: 09/25/2007 Page 8 of 9

197 MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No IARC International Agency For Research On Cancer MSHA Mine Safety and Health Administration NFPA National Fire Protection Association (617) NIOSH National Institute of Occupational Safety and Health NOIC Notice of Intended Change (proposed change to ACGIH TLV) NTP National Toxicology Program OPA Oil Pollution Act of 1990 OSHA U.S. Occupational Safety & Health Administration PEL Permissible Exposure Limit (OSHA) RCRA Resource Conservation and Recovery Act REL Recommended Exposure Limit (NIOSH) SARA Superfund Amendments and Reauthorization Act of 1986 Title III SCBA Self-Contained Breathing Apparatus SPCC Spill Prevention, Control, and Countermeasures STEL Short-Term Exposure Limit (generally 15 minutes) TLV Threshold Limit Value (ACGIH) TSCA Toxic Substances Control Act TWA Time Weighted Average (8 hr.) WEEL Workplace Environmental Exposure Level (AIHA) WHMIS Workplace Hazardous Materials Information System (Canada) DISCLAIMER OF EPRESSED AND IMPLIED WARRANTIES Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our written contract of sale or acknowledgment. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material. Revision Date: 09/25/2007 Page 9 of 9

198 MSDS Material Safety Data Sheet International Chemical Industries, Inc Km. 32 Bo. Tuktukan, Guiguinto, Bulacan Philippines 24 Hour Emergency Telephone: All non-emergency calls should be directed to Customer Service ( x501) Hydrochloric Acid Section 1 Product Identification Synonyms: Muriatic acid; hydrogen chloride, aqueous CAS No.: Molecular Weight: Chemical Formula: HCl Section 2 Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Hydrogen Chloride % Yes Water % No Section 3 Hazards Identification Emergency Overview POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE, MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG DAMAGE Health Rating: 3 Severe (Poison) Flammability Rating: 0 None Reactivity Rating: 2 Moderate Contact Rating: Extreme (Corrosive) Potential Health Effects Inhalation: Corrosive! Irritating to respiratory tract; inhalation of vapors can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, pulmonary edema, circulatory failure, and death. Ingestion: Corrosive! Swallowing hydrochloric acid can cause immediate pain and burns of the mouth, throat, esophagus and gastrointestinal tract. May cause nausea, vomiting, and diarrhea. Swallowing may be fatal. International Chemical Industries, Inc. Km. 32 Bo. Tuktukan, Guiguinto, Bulacan 3015 Philippines Phone Number: (6344) to 45 FA Number: (6344) Toll Free No

199 Skin Contact: Corrosive! Can cause redness, pain, and severe skin burns unless the hydrochloric acid is washed off immediately. Skin may dry or crack due to astringent nature of material. Repeated skin contact may lead to development of dermatitis. Concentrated solutions cause deep ulcers and discolor skin. Eye Contact: Corrosive! Eye contact results in severe irritation and painful burns of the eyes and eyelids. If material is not removed by copious irrigation with water at room temperature, visual Impairment or total loss of vision could result. Chronic Exposure: Prolonged exposure to low-level concentrations of hydrochloric acid vapor may cause discoloration and erosion of teeth, bleeding of nose and gums, and ulcers of the nasal mucosa. Asthma, bronchitis, emphysema, bronchial hyperactivity, skin allergies, and eczema may all be aggravated by exposure to hydrochloric acid vapor. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye disease may be more susceptible to the effects of this substance. The discomfort caused by hydrochloric acid vapor is usually sufficient to induce a person to leave areas of excessive concentrations; vapor can be fatal to those sprayed with acid or trapped in enclosed areas. Section 4 First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water, avoiding hot water or hard scrubbing, for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally to ensure thorough rinsing; delay can result to permanent injury. Get medical attention immediately. Section 5 Fire Fighting Measures Fire: Extreme heat or contact with metals can release flammable hydrogen gas. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: If involved in fire, use water spray. Neutralize with soda ash or slaked lime. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or positive pressure mode. Structural firefighter s protective clothing is ineffective for fires involving hydrochloric acid. Stay away from ends of tanks. Cool tanks with water spray until well after fire is out. International Chemical Industries, Inc. Km. 32 Bo. Tuktukan, Guiguinto, Bulacan 3015 Philippines Phone Number: (6344) to 45 FA Number: (6344) Toll Free No

200 Section 6 Accidental Release Measures Review safety precautions before proceeding with cleanup. Use appropriate personal protection equipment. Evacuate area and stay upwind. Attempts to stop or reduce leak should be made only by trained personnel, when there is at most a minimal risk of injury. Large spills should be contained with dikes and pumped into tanks suitable for acid storage. Full acid-resistant suits and self-contained breathing apparatus should be worn. Use a water fog or spray to control vapors. Neutralize spill with lime (calcium hydroxide), limestone (calcium carbonate), or soda ash (sodium carbonate). CAUTION: limestone and soda ash will evolve CO2; ventilation should be provided in closed areas. Dike area around spill to prevent spreading, and use of absorbent material to pick up spill. Section 7 Handling and Storage Storage tanks and piping for HCl should be constructed of materials recommended for corrosive products. FRP, PVC, HDPE, and/or rubber are the materials of choice for piping and storage tank. Metering pumps and other equipment that comes in contact with concentrated solutions of HCl must also be constructed of acid resistant materials such as PVC, rubber, Teflon, ceramic and Hastalloy C. No wetted parts shall contain metals such as carbon steel, stainless steel, brass or aluminum. Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. When diluting, the acid should always be added to water slowly and in small amounts. Never use hot water and never add water to the acid. Water added to acid can cause uncontrolled boiling and splashing. When opening metal containers, use non-sparking tools because of the possibility of hydrogen gas being present. Observe all warnings and precautions listed for the product. Section 8 Exposure Controls/Personal Protection Airborne Exposure Limits: For Hydrochloric acid: OSHA Permissible Exposure Limit (PEL): 5 ppm (ceiling) ACGIH Threshold Limit Value (TLV): 2 ppm (Ceiling), A4 not classifiable as a human carcinogen Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. International Chemical Industries, Inc. Km. 32 Bo. Tuktukan, Guiguinto, Bulacan 3015 Philippines Phone Number: (6344) to 45 FA Number: (6344) Toll Free No

201 Skin Protection: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. Section 9 Physical and Chemical Properties Appearance: Colorless, fuming liquid Odor: Pungent odor of hydrogen chloride. Solubility: Infinite in water with slight evolution of heat. Density: 1.15 Boiling Point: 53C (127F) Azeotrope (20.2%) boils at 109C (228F) Melting Point: -74C (-101F) Vapor Density (Air=1): No information found Vapor Pressure (mm Hg): 25C (77F) Evaporation Rate: No information found. Section 10 Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Containers may burst when heated. Hazardous Decomposition Products: When heated to decomposition, emits toxic hydrogen chloride fumes and will react with water or steam to produce heat and toxic and corrosive fumes. Thermal oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas. Incompatibilities: A strong mineral acid, concentrated hydrochloric acid is incompatible with many substances and highly reactive with strong bases, metals, metal oxides, hydroxides, amines, carbonates and other alkaline materials. Incompatible with materials such as cyanides, sulfides, sulfites, and formaldehyde. Conditions to Avoid: Heat, direct sunlight. Section 11 Toxicological Information Inhalation rat LC50: 3124 ppm/1h; oral rabbit LD50: 900 mg/kg (Hydrochloric acid concentrated); investigated as a tumorigen, mutagen, reproductive effector. Carcinogenicity: None of the components of this material are listed as a carcinogen by IARC, NTP, OSHA or ACGIH. Section 12 - Ecological Information Environmental Fate: When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater. Environmental Toxicity: This material is expected to be toxic to aquatic life. International Chemical Industries, Inc. Km. 32 Bo. Tuktukan, Guiguinto, Bulacan 3015 Philippines Phone Number: (6344) to 45 FA Number: (6344) Toll Free No

202 Section 13 - Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to an approved waste facility. Processing, use or contamination of this product may change the waste management options. Dispose of waste in accordance with applicable federal, state and local requirements. Section 14 Transport Information Domestic (Land, D.O.T) Proper Shipping Name: HYDROCHLORIC ACID Hazard Class: 8 UN/NA: UN1789 DOT Labels: Corrosive DOT Placards: Corrosive Packing Group: II International (Water, I.M.O.) Proper Shipping Name: HYDROCHLORIC ACID Hazard Class: 8 UN/NA: UN1789 IMO Label: Corrosive Packing Group: II Shipping Containers: Rubber-lined steel tank cars/trucks; polyethylene drums, bottles Storage Conditions: Keep containers closed Section 15 Regulatory Information TSCA: CAS No is listed on the TSCA Chemical Substance Inventory Section 16 Other Information NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0 Label Hazard Warning: POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG DAMAGE. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. Use only with adequate ventilation. Wash thoroughly after handling. Store in a tightly closed container. Remove and wash contaminated clothing promptly. International Chemical Industries, Inc. Km. 32 Bo. Tuktukan, Guiguinto, Bulacan 3015 Philippines Phone Number: (6344) to 45 FA Number: (6344) Toll Free No

203 Label First Aid In case of contact, immediately flush eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases get medical attention immediately. Disclaimer: ************************************************************************ International Chemical Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. INTERNATIONAL CHEMICAL INDUSTRIES, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY< INTERNATIONAL CHEMICAL INDUSTRIES, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OR RELIANCE UPON THIS INFORMATION. ************************************************************************ International Chemical Industries, Inc. Km. 32 Bo. Tuktukan, Guiguinto, Bulacan 3015 Philippines Phone Number: (6344) to 45 FA Number: (6344) Toll Free No

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216 Material Safety Data Sheet Revision Issued: 1/28/2011 Supercedes: 10/05/2005 First Issued: 12/01/1985 Section I - Chemical Product And Company Identification Product Name: Nitric Acid Synonyms/Common Names: Aqua Fortis; Hydrogen Nitrate; HNO 3 CAS Number: HBCC MSDS No. CN No. Main Street, Orange, California Telephone No: Outside Calif: Chemtrec: Section II - Composition/Information On Ingredients Exposure Limits (TWAs) in Air Chemical Name CAS Number % ACGIH TLV OSHA PEL STEL Nitric Acid ppm 2 ppm 4 ppm Section III - Hazard Identification Routes of Exposure: Nitric acid can affect the body if it is inhaled or swallowed, or if it comes in contact with the eyes or skin. Summary of Acute Health Hazards Ingestion: Can cause irritation and severe corrosive burns to mouth, throat, and stomach, and may be fatal if swallowed. Inhalation: Gases or acid mist can cause severe irritation or corrosive burns to the upper respiratory system, including nose, mouth, and throat. Lung irritation, nitrogen oxide poisoning, and pulmonary edema can also occur. May cause severe breathing difficulties which may be delayed in onset. Skin: Can cause severe corrosive burns or irritation. May stain the skin bright yellow. Eyes: Can cause irritation, corneal burns, conjunctivitis, and may cause blindness. Contact lenses should not be worn when working with this material. Summary of Chronic Health Hazards: Long-term exposure to concentrated vapors may cause erosion of teeth and lung damage. Long-term exposures seldom occur due to the corrosive properties of the acid. Effects of Overexposure: Possible acute pulmonary edema, chronic obstructive pulmonary disease, or chronic bronchitis from inhalation. The vapor and mist may erode the exposed teeth. On the skin or through ingestion, the liquid may cause pain and severe and penetrating burns. In contact with the eyes, the liquid produces severe burns which may lead to visual impairment or blindness. Medical Conditions Generally Aggravated by Exposure: Skin disorders and respiratory (asthma-like) disorders. Note to Physicians: Nitric Acid vapors contain nitrogen oxides. Acute overexposure Product Name: Nitric Acid 1 of 5

217 by inhalation can result in delayed pulmonary edema. Observe affected patients for delayed effects up to 48 hours after exposure. Screen patients with chest x-ray, arterial blood gas, methemoglobinemia level, and pulmonary function tests. Bronchiolitis obliterans may develop weeks after exposure. Section IV - First Aid Measures Ingestion: DO NOT INDUCE VOMITING. Drink large amounts of water to dilute acid. GET PROMPT MEDICAL ATTENTION. Inhalation: If inhaled, will cause difficult breathing or loss of consciousness. Move to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen. GET PROMPT MEDICAL ATTENTION. Skin: Promptly flush with plenty of soap and water for at least 15 minutes. Remove contaminated clothing. Wash clothing before reuse. GET PROMPT MEDICAL ATTENTION. Eyes: Wash eyes immediately with large amounts of water, for at least 30 minutes, lifting the lower and upper lids. Contact lenses should not be worn when working with this material. Do not allow victim to rub or keep eyes closed. GET PROMPT MEDICAL ATTENTION. Flash Point: Not Flammable Lower Explosive Limit: N/A Section V - Fire Fighting Measures Autoignition Temperature: N/A Upper Explosive Limit: N/A Unusual Fire and Explosion Hazards: Will accelerate the burning of combustible materials and can cause ignition by contact with combustible materials. Contact with common materials may generate hydrogen gas, which can form flammable mixtures with air. Extinguishing Media: Use water in flooding quantities as fog on adjacent fires. Special Firefighting Procedures: Water spray may be useful in minimizing or dispersing vapors and cooling equipment exposed to heat and flame. In danger area, wear bunker gear and self-contained breathing apparatus for fires beyond the incipient range (29CFR ) Section VI - Accidental Release Measures Spills may need to be reported to the National Response Center (800/ ) DOT Reportable Quantity (RQ) is 1000 pounds Adequate ventilation is required to eliminate any nitrogen oxides released and, if soda ash or limestone is used, CO 2. Stay upwind and away from spill. Keep all ignition sources and hot metal surfaces away from spill/release. Keep material out of water sources and sewers. Build dikes using inert material (i.e. dry sand or earth) to contain flow as necessary. Dilute spills or leaks with plenty of water. Neutralize residue with sodium bicarbonate, then place into a chemical waste container. A vapor suppressing foam may be used to reduce vapors. Section VII - Handling and Storage Avoid inhalation of vapors or mists and all bodily contact. Keep away from incompatible substances. Store in a cool, well-ventilated, properly drained area out of the sun. Avoid storage on wood floors or near wooden walls, etc. Diking of storage tanks if recommended. When diluting, the acid should always be added slowly to water and in small amounts. Never use hot water and never add water to the acid. Water added to acid can cause uncontrolled boiling and splashing. Protect from physical damage. Keep containers tightly closed. Do not get in eyes, on skin, or on clothing. Remove contaminated clothing and wash before reuse. Product Name: Nitric Acid 2 of 5

218 Section VIII - Exposure Controls/Personal Protection Respiratory Protection: Only respirators approved by MSHA or NIOSH are permissible. Only non-oxidizable sorbents are allowed. A chemical cartridge respirator is not recommended due to the potential for exposure limits being exceeded prior to odor breakthrough. See SUPPLEMENTAL INFORMATION section. Respirator Selection 100 ppm or less (250 mg/m³ or less): GMOVS/SAF/SCBAF/SA:PD,PP,CF 100 ppm or greater (250 mg/m³ or greater), or entry and escape from unknown concentrations: GMS/SCBA Ventilation: Ventilation sufficient to reduce mists and nitrogen oxide concentrations below permissible TLV levels. Mechanical exhaust systems or closed ventilated systems may be required. Always keep the nitric acid vapor concentration levels below 2 ppm (5 mg/m³). Protective Clothing: Impervious clothing should be used to prevent any possibility of physical contact with liquid nitric acid. Clothing may include a rubber acid suit, hood, boots and gloves, and an air mask and chemical goggles. Eye Protection: Splash-proof safety goggles should be used if the possibility of liquid nitric acid contacting the eyes exists. Do not wear contact lenses. Eight-inch minimum face shields should be used. Other Protective Clothing or Equipment: N/A Work/Hygienic Practices: Facilities for quick drenching of the body, in addition to an eye-wash fountain, should be provided within the immediate work area for emergency use. Employees who handle nitric acid should wash their hands before eating, smoking, or using toilet facilities. Do NOT place food, coffee or other drinks in the area where dusting or splashing of solutions is possible. Section I - Physical and Chemical Properties Physical State: Liquid ph: 1-2 % Acid in Solution: Melting Point/Range: -42 C@68% -44 F 31 F Appearance/Color/Odor: Watery liquid, colorless, yellow, or red fuming liquid with a suffocating, acrid odor. Solubility in Water: 100% % Acid in Solution Vapor Pressure(mmHg) 5-10 <3@70 F 2.9@68 F Molecular Weight: 63 (solute) % Acid in Solution Specific Gravity(Water=1) % Acid in Solution Vapor Density(Air=1) > 1 < % Acid in Solution Weight/Gallon (Lbs.) Product Name: Nitric Acid 3 of 5

219 Evaporation Rate (N-Butyl Acetate=1): < 1 Boiling Point/Range: % % Volatiles: 100% (by volume) How to detect this compound : N/A Stability: Stable Section - Stability and Reactivity Hazardous Polymerization: N/A Conditions to Avoid: Avoid exposure to direct sunlight. Materials to Avoid: Most metals, metallic powders, alcohol, charcoal, turpentine, hydrogen sulfide, wood excelsior, paper, cotton and similar organic materials. Alkalies, carbon, carbonates, cyanides, diborane organic chemicals, fluorine, phosphine, sulfides, thiocyanates. Nitric Acid is corrosive or incompatible with many common materials including mild steel, PVC, Viton, and rubber. Viton is a registered trademark of DuPont Dow Elastomers. Hazardous Decomposition Products: When heated to decomposition, emits toxic nitrogen oxides fumes and hydrogen nitrate. Will react with water or steam to produce heat and toxic and corrosive fumes. Section I - Toxicological Information Nitric acid vapor or mist is an irritant of the eyes, mucous membranes, and skin. When nitric acid is exposed to air or comes in contact with organic matter, it decomposes to yield a mixture of toxic oxides of nitrogen, including nitric oxide and nitrogen dioxide. Exposure to high concentrations of nitric acid vapor or mist causes pneumonitis and pulmonary edema which may be fatal; onset of symptoms may be delayed for 4 to 30 hours. In contact with the eyes, the liquid produces severe burns which may result in permanent damage and visual impairment. On the skin, the liquid or concentrated vapor produces immediate, severe and penetrating burns; concentrated solutions cause deep ulcers and stain the skin a bright yellow or yellowish brown color. The vapor and mist may erode the exposed teeth. Ingestion of the liquid will cause immediate pain and burns of the mouth, esophagus, and gastrointestinal tract. N/A Section II - Ecological Information Section III - Disposal Considerations Nitric acid may be disposed of by neutralizing with water and alkaline material (such as soda ash, lime, etc.) and disposing in a secured sanitary landfill. Disposal of nitric acid may be subject to federal, state, and local regulations. Users of this product should review their operations in terms of applicable federal, state, and local laws and regulations, then consult with the appropriate regulatory agencies before discharging or disposing of waste material. Section IV - Transport Information DOT Proper Shipping Name: NITRIC ACID DOT Hazard Class/ I.D. No.: 8, UN2031, II Less than 65 percent nitric acid: 8, UN2031, PGII At least 65 percent, but not more than 70 percent nitric acid: 8, (5.1), UN2031, PGII More than 70 percent nitric acid: 8, (51), UN 2031, PG I Product Name: Nitric Acid 4 of 5

220 Section V - Regulatory Information This product contains the following toxic chemical(s) subject to the reporting requirements of SARA TITLE III of the Emergency Planning and Community Right-To Know Act (EPCRA) of 1986 and of 40 CFR 372: Section 302 Extremely Hazardous Substance (EHS): CAS # Lbs. (454 Kilograms) (85 Gals.) Threshold Planning Quantity (TPQ) Section 304 Extremely Hazardous Substance (EHS): CAS # Lbs. (454 Kilograms) (85 Gals.) Reportable Quantity (RQ) CERCLA Hazardous Substance: CAS # Lbs. (454 Kilograms) (85 Gals.) Reportable Quantity (RQ) Section 313 Supplier Notification: CAS # , % by Weight: 30-71% NFPA Rating: Health - 3; Flammability - 0; Instability - 0; Other - (Oxidizer) 0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme Carcinogenicity Lists: National Toxicology Program (NTP): No International Agency for Research on Cancer (IARC) Monograph: No Occupational Safety & Health Administration (OSHA) Regulated: Yes Section VI - Other Information Synonyms/Common Names: Aqua Fortis; Hydrogen Nitrate; HNO 3 Chemical Family/Type: Inorganic acid Sections changed since last revision: III, VII,, IV IMPORTANT! Read this MSDS before use or disposal of this product. Pass along the information to employees and any other persons who could be exposed to the product to be sure that they are aware of the information before use or other exposure. This MSDS has been prepared according to the OSHA Hazard Communication Standard [29 CFR ]. The MSDS information is based on sources believed to be reliable. However, since data, safety standards, and government regulations are subject to change and the conditions of handling and use, or misuse are beyond our control, Hill Brothers Chemical Company makes no warranty, either expressed or implied, with respect to the completeness or continuing accuracy of the information contained herein and disclaims all liability for reliance thereon. Also, additional information may be necessary or helpful for specific conditions and circumstances of use. It is the user's responsibility to determine the suitability of this product and to evaluate risks prior to use, and then to exercise appropriate precautions for protection of employees and others. Product Name: Nitric Acid 5 of 5

221 Product name Supplier Product use MSDS # Date of Preparation/Revision In case of emergency Material Safety Data Sheet Section 1. Chemical product and company identification Synonym Emergency overview : : : Propane AIRGAS INC., on behalf of its subsidiaries 259 North Radnor-Chester Road Suite 100 Radnor, PA Synthetic/Analytical chemistry. : n-propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. : : : 4/26/2011. Propane Section 2. Hazards identification Physical state Target organs Routes of entry Potential acute health effects Eyes Skin Inhalation Ingestion Medical conditions aggravated by overexposure Inhalation See toxicological information (Section 11) : : Gas. [COLORLESS LIQUEFIED COMPRESSED GAS; ODORLESS BUT MAY HAVE SKUNK ODOR ADDED.] WARNING! FLAMMABLE GAS. MAY CAUSE FLASH FIRE. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CONTENTS UNDER PRESSURE. Keep away from heat, sparks and flame. Do not puncture or incinerate container. May cause target organ damage, based on animal data. Use only with adequate ventilation. Keep container closed. Contact with rapidly expanding gases can cause frostbite. : May cause damage to the following organs: the nervous system, heart, central nervous system (CNS). : : : : : : Contact with rapidly expanding gas may cause burns or frostbite. Contact with rapidly expanding gas may cause burns or frostbite. Acts as a simple asphyxiant. Ingestion is not a normal route of exposure for gases Potential chronic health effects Chronic effects : May cause target organ damage, based on animal data. Target organs : May cause damage to the following organs: the nervous system, heart, central nervous system (CNS). Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Build 1.1 Page: 1/7