Risalah Data Keselamatan Safety data sheet

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1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/18 1. Pengenalan bahan kimia dan pembekal Cutina GMS V Nama bahan kimia: Glycerides, mono- and di- Kegunaan: bahan tambah khusus untuk industri kimia, kandungan kosmetik, Cosmetic preparation Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Tidak memerlukan pengelasan menurut kriteria GHS untuk produk ini. Unsur label dan pernyataan berjaga-jaga: Produk tidak memerlukan label amaran bahaya menurut kriteria GHS. Bahaya lain yang tidak menyebabkan pengelasan: Debu halus boleh membentuk campuran mudah terbakar bersama udara

2 Mukasurat (Page): 2/18 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Glycerides, C14-18 mono- and di- Nombor CAS: Langkah-Langkah Pertolongan Cemas Nasihat am: Jika kesan-kesan kesihatan yang buruk berkembang dapatkan rawatan perubatan. Jika tersedut: tidak berkenaan. Apabila terkena kulit: Jika terkena kulit, segera basuh dengan air yang banyak. Apabila terkena mata: Jika terkena mata, segera basuh selama sekurang-kurangnya 15 minit dengan air yang banyak. Dapatkan perhatian perubatan jika perlu. Apabila tertelan: Segera basuh mulut dan kemudian minum ml air. Nota kepada doktor: Gejala: Tiada gejala yang ketara dijangka oleh kerana pengelasan tidak diperlukan untuk produk ini. Nota kepada doktor: Bahaya: Tiada bahaya dijangka dengan penggunaan yang disyorkan dan pengendalian yang sesuai. Rawatan: Rawat mengukit gejala. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: semburan air, serbuk kering, busa Alat memadam yang tidak sesuai untuk tujuan keselamatan: karbon dioksida Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap.

3 Mukasurat (Page): 3/18 Maklumat lanjut: Lupuskan sisa kebakaran dan air pemadam api yang tercemar menurut peraturan rasmi. 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Gunakan pakaian pelindung diri. Elakkan pembentukan debu. Langkah berjaga-jaga untuk alam sekitar: Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah kecil: Kutip dengan alat yang sesuai dan lupuskan. Bagi sejumlah besar: Bendung dengan bahan pengikat debu dan lupuskan. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Perlindungan terhadap kebakaran dan letupan: Elakkan pembentukan debu. Ambil langkah berjaga-jaga terhadap luahan statik. Jauhkan dari semua sumber pencucuhan: haba, percikan api, nyalaan terbuka. Penyimpanan Bahan yang sesuai untuk bekas: Polietilena ketumpatan tinggi (HDPE) Maklumat lanjut tentang keadaan penyimpanan: Pastikan bekas tertutup rapat dan kering; simpan di tempat yang dingin. Sila rujuk risalah data khusus produk untuk maklumat lanjut. Kestabilan penyimpanan: Suhu penyimpanan: <= 30 C Lindungi daripada lembapan. Lindungi daripada suhu melebihi : 40 C Produk akan lebur apabila melebihi had suhu yang dinyatakan. 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja Tiada had pendedahan pekerjaan yang diketahui.

4 Mukasurat (Page): 4/18 Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan jika debu terbentuk. Perlindungan tangan: Sarung tangan pelindung yang sesuai dengan spesifikasi berikut. Cadangan tersebut adalah sah untuk keadaan makmal, keadaan tempat kerja yang khusus perlu diambil kira secara berasingan Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374): getah nitril (NBR) mm ketebalan salutan Perlindungan mata: Kaca mata keselamatan dengan pelindung sisi (gogal berbingkai) (contohnya EN 166) Perlindungan badan: Perlindungan badan mesti dipilih bergantung kepada aktiviti dan pendedahan, contohnya apron, kasut perlindungan, pakaian perlindungan bahan kimia (Berdasarkan DIN-EN 465) Langkah kebersihan dan keselamatan am: Jangan makan, minum, merokok atau menggunakan tembakau di tempat kerja. Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: nilai ph: serbuk, Jenis berlilin kekuningan tidak berbau Tidak boleh digunakan Tidak boleh digunakan julat lebur: C takat didih: tidak ditentukan Takat kilat: C (DIN ISO 2592) Tahap penyejatan: Produk ini adalah pepejal tidak meruap Kemudahbakaran (pepejal/gas): tidak mencucuh Had letupan bawah: Tidak berkaitan untuk pengelasan dan pelabelan bagi pepejal. Had letupan atas: Tidak berkaitan untuk pengelasan dan pelabelan bagi pepejal. Suhu pencucuhan: tidak ditentukan

5 Mukasurat (Page): 5/18 Penguraian terma: pencucuhan sendiri: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Tidak boleh digunakan Bahaya letupan: tidak mudah meletup Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: Tidak boleh digunakan Kepekatan: g/cm3 (60 C) Ketumpatan pukal: dianggarkan kg/m3 Ketumpatan wap relatif (udara): Tidak boleh digunakan Keterlarutan dalam air: tidak terlarut Keterlarutan (kualitatif) pelarut: tiada tidak terlarut Pekali petakan n-oktanol/air (log Pow): tidak ditentukan Kelikatan, dinamik: Kelikatan, kinematik: tidak boleh digunakan, produk adalah pepejal tidak boleh digunakan, produk adalah pepejal Maklumat lain: Jika perlu, maklumat tentang parameter fizikal and kimia ada dinyatakan didalam bahagian ini. Tiada maklumat lain didapati. 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Lihat MSDS bahagian 7 - Pengendalian dan Penyimpanan. Penguraian terma: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Bahan yang perlu dielakkan: Tiada bahan yang diketahui perlu dielakkan. Tindak balas berbahaya: Produk mungkin mengandungi debu halus boleh meletup atau debu tersebut mungkin dihasilkan melalui geseran semasa diangkut atau dipindah.

6 Mukasurat (Page): 6/18 Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. 11. Maklumat Toksikologi Ketoksikan akut Penilaian ketoksikan akut: Tidak toksik selepas sekali terkena kulit Tidak toksik selepas sekali ditelan. Data eksperimen/dikira: LD50 tikus (melalui mulut): > 2,000 mg/kg (Garispanduan OECD 401) LD50 tikus (dermal): > 2,000 mg/kg Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kerengsaan Penilaian kesan merengsa: Tidak merengsakan mata. Tidak merengsakan kulit. Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: merengsa sedikit (Garispanduan OECD 404) Kerosakkan/kerengsaan mata yang serius arnab: (Garispanduan OECD 405) Pemekaan pernafasan/kulit Penilaian pemekaan: Tiada kesan pemekaan Data eksperimen/dikira: marmut: Tidak memeka Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kemutagenan sel germa Penilaian kemutagenan: Tiada kesan mutagen didapati dalam pelbagai ujian dengan mikroorganisma Data eksperimen/dikira: Ujian Ames negatif Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Cerakin mikronukleus

7 Mukasurat (Page): 7/18 mencit: negatif Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Kekarsinogenan Penilaian kekarsinogenan: Semua maklumat yang boleh didapati tidak menyediakan petunjuk kepada kesan karsinogen. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Maklumat yang ada tentang produk tidak menunjukkan ketoksikan pembiakan. Ketoksikan perkembangan Penilaian keteratogenan: Dalam kajian haiwan, bahan ini tidak menyebabkan malformasi.. Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Berdasarkan maklumat yang ada, ketoksikan organ sasaran yang khusus adalah tidak dijangka selepas sekali pendedahan. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Maklumat yang ada tentang produk tidak memberi petunjuk tentang ketoksikan kepada organ sasaran selepas pendedahan secara berulang-ulang. Bahaya penyedutan Tiada bahaya penyedutan dijangka. 12. Maklumat Ekologi Keekotoksikan Ketoksikan kepada ikan: LC50 > 100 mg/l, Brachydanio rerio Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Invertebrat air: EC50 > 100 mg/l, Daphnia magna Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama.

8 Mukasurat (Page): 8/18 Tumbuhan akuatik: EC50 > 100 mg/l, Scenedesmus subspicatus Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC0 > 100 mg/l, Pseudomonas putida Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Ketoksikan kronik kepada invertebrata akuatik: Tiada kesan kepekatan yang diperhatikan (21 hari), > 0.01 mg/l, Daphnia magna (Garispanduan OECD 202, Bahagian 2, semistatik) Tiada kesan toksik dalam julat keterlarutan. Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Bahan tidak akan menyejat ke atmosfera daripada permukaan air Penjerapan kepada fasa tanah pejal dijangka Keterusan dan boleh keterdegradasikan Penilaian biodegradasi dan penyingkiran (H2O): Mudah terbiodegradasikan (menurut kriteria OECD) Potensi Biotumpukan Penilaian potensi bioakumilasi: Tidak dijangka terakumulasi dalam organisma. 13. Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. Pembungkusan tercemar: Bungkusan yang tidak tercemar boleh diguna semula. Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya. 14. Maklumat Pengangkutan Pengangkutan domestik: Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan laut IMDG

9 Mukasurat (Page): 9/18 Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan udara IATA/ICAO Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan Peraturan lain Jika maklumat peraturan lain yang berkenaan tidak dinyatakan dibahagian lain didalam risalah data keselamatan ini, ianya akan dinyatakan bahagian ini. 16. Maklumat lain Maklumat bagi penggunaan yang dirancang: Produk ini adalah berkualiti untuk industri dan sekiranya tidak dinyatakan atau dipersetujui harus digunakan semata-mata untuk kegunaan industri. Ini termasuk penggunaan yang dinyatakan dan disyorkan. Sebarang tujuan penggunaan lain hendaklah dibincangkan dengan pengeluar. Secara khususnya, ini berkaitan dengan penggunaan bagi produk yang menjadi objek piawai dan peraturan khas Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

10 Mukasurat (Page): 10/18 1. Identification of the chemical and of the supplier Cutina GMS V Chemical name: Glyceride, mono- and di- Use: Cosmetic preparation Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: No need for classification according to GHS criteria for this product. Label elements and precautionary statement: The product does not require a hazard warning label in accordance with GHS criteria. Other hazards which do not result in classification: Fine dust can form an inflammable mixture together with air. 3. Composition/information on ingredients Chemical nature Glycerides, C14-18 mono- and di- CAS Number: First-Aid Measures General advice: If adverse health effects develop seek medical attention.

11 Mukasurat (Page): 11/18 If inhaled: not relevant. On skin contact: After contact with skin, wash immediately with plenty of water. On contact with eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Seek medical attention if necessary. On ingestion: Rinse mouth and then drink ml of water. Note to physician: Symptoms: No significant symptoms are expected due to the non-classification of the product. Note to physician: Hazards: No hazard is expected under intended use and appropriate handling. Treatment: Treat symptomatically. 5. Fire-Fighting Measures Suitable extinguishing media: water spray, dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Avoid dust formation. Environmental precautions: Do not discharge into drains/surface waters/groundwater.

12 Mukasurat (Page): 12/18 Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling Handle in accordance with good industrial hygiene and safety practice. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges. Avoid all sources of ignition: heat, sparks, open flame. Storage Suitable materials for containers: High density polyethylene (HDPE) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Please refer to the product specific data sheet for further information. Storage stability: Storage temperature: <= 30 C Protect against moisture. Protect from temperatures above: 40 C The product melts above the declared temperature limit. 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known. Personal protective equipment Respiratory protection: Breathing protection if dusts are formed. Hand protection: Suitable are protective gloves with the following specification. The recommendation is valid for laboratory conditions, specific workplace conditions must be taken into consideration separately. Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): nitrile rubber (NBR) mm coating thickness

13 Mukasurat (Page): 13/18 Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: No eating, drinking, smoking or tobacco use at the place of work. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: ph value: powder, waxy type yellowish odourless not applicable not applicable melting range: C Boiling point: not determined Flash point: C (DIN ISO 2592) Evaporation rate: The product is a non-volatile solid. Flammability (solid/gas): not flammable Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: not determined Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Self ignition: not applicable Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: not applicable

14 Mukasurat (Page): 14/18 Density: g/cm3 (60 C) Bulk density: approx kg/m3 Relative vapour density (air): not applicable Solubility in water: insoluble Solubility (qualitative) solvent(s): none insoluble Partitioning coefficient n-octanol/water (log Pow): not determined Viscosity, dynamic: Viscosity, kinematic: not applicable, the product is a solid not applicable, the product is a solid Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. No further information available. 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: No substances known that should be avoided. Hazardous reactions: The product may contain explosive fine dust or such dust may be produced by abrasion during transport or product transfer. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single skin contact. Virtually nontoxic after a single ingestion. Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401)

15 Mukasurat (Page): 15/18 LD50 rat (dermal): > 2,000 mg/kg The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Irritation Assessment of irritating effects: Not irritating to the eyes. Not irritating to the skin. Experimental/calculated data: Skin corrosion/irritation rabbit: Slightly irritating. (OECD Guideline 404) Serious eye damage/irritation rabbit: (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: No sensitizing effect. Experimental/calculated data: guinea pig: Non-sensitizing. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Germ cell mutagenicity Assessment of mutagenicity: No mutagenic effect was found in various tests with microorganisms and mammals. Experimental/calculated data: Ames-test negative The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Micronucleus assay mouse: negative The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: The whole of the information assessable provides no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The information available on the product provides no indication of reproductive toxicity. Developmental toxicity Assessment of teratogenicity:

16 Mukasurat (Page): 16/18 In animal studies the substance did not cause malformations. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. The information available on the product provides no indication of toxicity on target organs after repeated exposure. Aspiration hazard No aspiration hazard expected. 12. Ecological Information Ecotoxicity Toxicity to fish: LC50 > 100 mg/l, Brachydanio rerio The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aquatic invertebrates: EC50 > 100 mg/l, Daphnia magna The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aquatic plants: EC50 > 100 mg/l, Scenedesmus subspicatus The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Microorganisms/Effect on activated sludge: EC0 > 100 mg/l, Pseudomonas putida The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Chronic toxicity to aquatic invertebrates: No observed effect concentration (21 d), > 0.01 mg/l, Daphnia magna (OECD Guideline 202, part 2, semistatic) No toxic effects occur within the range of solubility.

17 Mukasurat (Page): 17/18 Mobility Assessment transport between environmental compartments: The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected. Persistence and degradability Assessment biodegradation and elimination (H2O): Readily biodegradable (according to OECD criteria). Bioaccumulation potential Assessment bioaccumulation potential: Accumulation in organisms is not to be expected. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated

18 Mukasurat (Page): 18/ Regulatory Information Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. 16. Other Information Information on intended use: This product is of industrial quality and unless otherwise specified or agreed intended exclusively for industrial use. This includes the mentioned and recommended usage. Any other intended applications should be discussed with the manufacturer. In particular this concerns the application for products that are the object of special standards and regulations. Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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