SAFETY DATA SHEET ULTIMEG #

Transcription

1 Revision Date 31/01/2012 Revision 17 Supersedes date 21/09/2011 SAFETY DATA SHEET ULTIMEG # According to Regulation (EC) No 1907/2006 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name ULTIMEG # Product No. U372# 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer AEV LIMITED MARION STREET BIRKENHEAD MERSEYSIDE CH41 6LT Tel. +44(0) Fax. +44(0) Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical and Chemical Hazards Flam. Liq. 3 - H226 Human health Environment Classification (1999/45/EEC) Xn;R20/21. Xi;R38. R10. Acute Tox. 4 - H312;Acute Tox. 4 - H332;Skin Irrit. 2 - H315 Not classified. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements Contains XYLENE Label In Accordance With (EC) No. 1272/2008 Signal Word Warning Hazard Statements H226 H312 H315 H332 Precautionary Statements P271 P280 P501 Supplementary Precautionary Statements P210 P233 P240 P241 P242 P243 P261 P264 Flammable liquid and vapour. Harmful in contact with skin. Causes skin irritation. Harmful if inhaled. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Dispose of contents/container to Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ /equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. 1 / 6

2 2.3. Other hazards ULTIMEG # P IF ON SKIN: Wash with plenty of soap and water. P IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 P322 Specific treatment (see on this label). Specific measures (see on this label). P If skin irritation occurs: Get medical advice/attention. P362 P363 Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. P In case of fire: Use for extinction. P Store in a well-ventilated place. Keep cool. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures XYLENE 50-70% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Classification (67/548/EEC) R10 Xn;R20/21 Xi;R38 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Inhalation Move the exposed person to fresh air at once. For breathing difficulties oxygen may be necessary. If breathing stops, provide artificial respiration. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion DO NOT INDUCE VOMITING! Remove victim immediately from source of exposure. Rinse mouth thoroughly. Provide rest, warmth and fresh air. Get medical attention immediately! Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Contact physician if irritation persists Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Fire can be extinguished using: Foam. Dry chemicals, sand, dolomite etc Special hazards arising from the substance or mixture Specific hazards Fire creates: Toxic gases/vapours/fumes of: Carbon. Carbon dioxide (CO2). Carbon monoxide (CO). Nitrous gases (NOx). Hydrocarbons Advice for firefighters 2 / 6

3 Special Fire Fighting Procedures ULTIMEG # Avoid breathing fire vapours. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or liquid contact protection. Absorb in vermiculite, dry sand or earth and place into containers Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Use explosion proof electric equipment Conditions for safe storage, including any incompatibilities Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Flammable liquid storage Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes XYLENE WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits WEL 50 ppm(sk) mg/m3(sk) ppm(sk) 441 mg/m3(sk) 8.2. Exposure controls Protective equipment Engineering measures Well-ventilated area. Respiratory equipment Respiratory protection must be used if air contamination exceeds acceptable level. Hand protection Use protective gloves. Eye protection Use approved safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 3 / 6

4 ULTIMEG # 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Light brown. Odour Organic solvents. Solubility Insoluble in water Initial boiling point and boiling range mm Hg Relative density Vapour density (air=1) 3.7 Vapour pressure 0.93 kpa 20 Viscosity 4.7 Ps 25 Flash point 27 CC (Closed cup). Auto Ignition Temperature ( C) 490 Flammability Limit - Lower(%) 1 Flammability Limit - Upper(%) Other information SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Conditions to avoid Avoid heat. Avoid contact with oxidisers or reducing agents Incompatible materials Hazardous decomposition products Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation Harmful by inhalation. Vapours may cause headache, fatigue, dizziness and nausea. Ingestion Harmful if swallowed. May cause internal injury. Skin contact May cause sensitisation by skin contact. May be absorbed through the skin. Product has a defatting effect on skin. Eye contact Irritation of eyes and mucous membranes. Health Warnings INHALATION. Gas or vapour is harmful on prolonged exposure or in high concentrations. SKIN CONTACT. Irritating to skin. Acts as a defatting agent on skin. May cause cracking of skin, and eczema. EYE CONTACT. Irritating to eyes. INGESTION. May cause stomach pain or vomiting. Route of entry Inhalation. Skin absorption. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Dangerous for the environment if discharged into watercourses Toxicity 4 / 6

5 ULTIMEG # Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 1263 UN No. (IMDG) 1263 UN No. (ICAO) UN proper shipping name Proper Shipping Name PAINT Transport hazard class(es) ADR/RID/ADN Class Class 3: Flammable liquids. IMDG Class 3 ICAO Class/Division 3 Transport Labels FLAMMABLE LIQUID Packing group IMDG Packing group ICAO Packing group III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS Tunnel Restriction Code F-E, S-E (D/E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 5 / 6

6 ULTIMEG # Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References Petroleum (Consolidation) Act, as amended 1984 SI Highly Flammable Liquid Regulations Environmental Listing Control of Pollution (Special Waste Regulations) Act Control of Pollution Act Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health. Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). EU Legislation System of specific information relating to Dangerous Preparations. 2001/58/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment SECTION 16: OTHER INFORMATION Revision Date 31/01/2012 Revision 17 Supersedes date 21/09/2011 SDS No. 1 Risk Phrases In Full R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. Hazard Statements In Full H315 Causes skin irritation. H226 Flammable liquid and vapour. H332 Harmful if inhaled. H312 Harmful in contact with skin. 6 / 6