IMPORTANT: THIS DOCUMENT CONTAINS MSDS FOR THE RESIN AND THE HARDENER. FOR HARDENER MSDS SCROLL THROUGH THE DOCUMENT TO PAGE (4) ONWARDS.

Transcription

1 Easy Composites MSDS Epoxy Tooling Gel Coat Revision 3 Revision date 10 June 2013 Page 1 of 6 IMPORTANT: THIS DOCUMENT CONTAINS MSDS FOR THE RESIN AND THE HARDENER. FOR HARDENER MSDS SCROLL THROUGH THE DOCUMENT TO PAGE (4) ONWARDS. SAFETY DATA SHEET Epoxy Tooling Gel Coat 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company Epoxy Tooling Gel Coat Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke on Trent ST3 5XA United Kingdom sales@easycomposites.co.uk Telephone +44 (0) HAZARDS IDENTIFICATION Main hazards Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients Concentration CAS EINECS CAS Symbols/Risk phrases Bisphenol F epichlorohydrin resin, 1 25% Xi; R36/38 43 N; R51/53 mw < 700 Glycidyl ether 1 30% Xi; R36/38 43 N; R51/53 Bisphenol A (epichlorhydrin) (reaction product) 20 60% Xi; R36/37/38 R43 N; R51/53 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion 5. FIRE FIGHTING MEASURES Extinguishing media Fire hazards Protective equipment 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Irritating to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. Carbon oxides. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. Ensure adequate ventilation of the working area. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe.

2 Easy Composites MSDS Epoxy Tooling Gel Coat Revision 3 Revision date 10 June 2013 Page 2 of 6 precautions Clean up methods Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. 7. HANDLING AND STORAGE Handling Storage Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Measures Respiratory protection Hand protection Eye protection Protective equipment Ensure adequate ventilation of the working area. Wear: Suitable respiratory equipment. Chemical resistant gloves (PVC) Approved safety goggles. Wear chemical protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Description Paste. Colour Green. Odour Odourless. Relative density 1.65 Viscosity mpa.s (25 C) 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION Toxicological information Bisphenol A (epichlorhydrin) (reaction product) 12. ECOLOGICAL INFORMATION Ecotoxicity Bisphenol A (epichlorhydrin) (reaction product) Oral Rat LD50 = mg/kg Dermal Rabbit LD50 = > 2000 mg/kg Toxic to aquatic organisms, may cause long term adverse effects in the aquatic Green algae EC50/96h = 220 mg/l Rainbow trout LC50/96h = mg/l 13. DISPOSAL CONSIDERATIONS General information Dispose of in compliance with all local and national regulations. 14. TRANSPORT INFORMATION Proper Shipping Name ADR/RID ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S,. UN 3082 Packing group III Class 9 Hazard ID 90 IMDG

3 Easy Composites MSDS Epoxy Tooling Gel Coat Revision 3 Revision date 10 June 2013 Page 3 of 6 UN 3082 Packing group III Class 9 Marine pollutant:. EmS Code F A S F IATA UN 3082 Packing group III Class 9 Subsidiary risk Packing Instruction (Cargo) 914 Maximum quantity: 450L Packing Instruction (Passenger) 914 Maximum quantity: 450L 15. REGULATORY INFORMATION Labelling Symbols The product is classified in accordance with 67/548/EEC. Xi Irritant; N Dangerous for the environment Risk phrases Safety phrases R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic S24 Avoid contact with skin. S29 Do not empty into drains. S37 Wear suitable gloves. 16. OTHER INFORMATION Text of risk phrases in Section 3. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. This document differs from the previous version in the following areas: 2 hazardous ingredients.

4 Easy Composites MSDS Epoxy Tooling Gel Coat Revision 3 Revision date 10 June 2013 Page 4 of 6 SAFETY DATA SHEET Epoxy Tooling Gel Coat Hardener 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company Epoxy Tooling Gel Coat Hardener Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke on Trent ST3 5XA United Kingdom sales@easycomposites.co.uk Telephone +44 (0) HAZARDS IDENTIFICATION Main hazards Causes burns. May cause sensitisation by skin contact. Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic Possible risk of impaired fertility. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients Concentration CAS EINECS CAS Symbols/Risk phrases 3,6,9,12 Tetraazatetradecamethylenediamine % C; R34 R43 N; R50/53 2,2' Iminodiethylamine 1 30% Xn; R21/22 C; R34 R43 (2,2' Iminodi(ethylamine)) 4,4' Isopropylidenediphenol 1 30% Repr Cat 3; R62 Xi; R37 41 R43 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion 5. FIRE FIGHTING MEASURES Extinguishing media Fire hazards Protective equipment 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean up methods Causes burns. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Causes burns. Causes severe inflammation and may damage the cornea. Seek medical attention. Inhalation of vapour may cause shortness of breath. Move the exposed person to fresh air. Seek medical attention. Ingestion causes burns to the respiratory tract. DO NOT INDUCE VOMITING. If swallowed, seek medical advice immediately and show this container or label. Use as appropriate: carbon dioxide (CO2), dry chemical, foam. Corrosive. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Wear suitable protective equipment Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Transfer to suitable, labelled containers for

5 Easy Composites MSDS Epoxy Tooling Gel Coat Revision 3 Revision date 10 June 2013 Page 5 of 6 disposal. Clean spillage area thoroughly with plenty of water. 7. HANDLING AND STORAGE Handling Storage Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits 2,2' Iminodiethylamine WEL 8 hr limit ppm: 1 WEL 8 hr limit mg/m3: 4.3 (2,2' Iminodi(ethylamine)) WEL 15 min limit ppm: WEL 15 min limit mg/m3: Engineering Measures Ensure adequate ventilation of the working area. Respiratory protection Wear: Self contained breathing apparatus. Hand protection Chemical resistant gloves (PVC) Eye protection Approved safety goggles. Protective equipment Wear chemical protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Description Liquid. Colour Clear Odour Ammoniacal. Relative density 1.02 Viscosity 350 mpa.s (25 C) 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION Toxicological information 3,6,9,12 Tetra azatetradecamethylenediamine Corrosivity Oral Rat LD50 = 1600 mg/kg Causes burns. 12. ECOLOGICAL INFORMATION Ecotoxicity 3,6,9,12 Tetra azatetradecamethylenediamine Daphnia EC50/48h = 18 mg/l g/l 13. DISPOSAL CONSIDERATIONS General information Dispose of in compliance with all local and national regulations. 14. TRANSPORT INFORMATION Proper Shipping Name AMINES, LIQUID, CORROSIVE N.O.S,. ADR/RID UN 2735 Packing group III Class 8 Hazard ID 80 IMDG UN 2735 Packing group III Class 8 Marine pollutant:.

6 Easy Composites MSDS Epoxy Tooling Gel Coat Revision 3 Revision date 10 June 2013 Page 6 of 6 EmS Code F A S B IATA UN 2735 Packing group III Class 8 Subsidiary risk Packing Instruction (Cargo) 820 Maximum quantity: 60L Packing Instruction (Passenger) 818 Maximum quantity: 5L 15. REGULATORY INFORMATION Labelling Symbols The product is classified in accordance with 67/548/EEC. C Corrosive; N Dangerous for the environment Risk phrases Safety phrases R34 Causes burns. R50/53 Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic R62 Possible risk of impaired fertility. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. S29 Do not empty into drains. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 16. OTHER INFORMATION Text of risk phrases in Section 3. R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R37 Irritating to respiratory system. R41 Risk of serious damage to eyes. R50/53 Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic R62 Possible risk of impaired fertility. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. This document differs from the previous version in the following areas: 15 symbols. 16 text of risk phrases in Section 2.