Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA PPE Issued Date 07-Feb-2007 Revision Date 18-Nov PRODUCT AND COMPANY IDENTIFICATION Revision Number: 6 UPI 630 Freedom Business Center Suite 402 King of Prussia,PA Emergency Telephone Number Chemtrec: (800) (24hrs) or (703) Medical: Rocky Mountain Poison Control Center (866) (24hrs) UPI Company Information Contact Information Customer Service R&D Technical Service Phone Number Available Hrs 8:00 am to 5:00 pm EST 8:00 am - 5:00 pm (EST) Product Name TOPSIN M 70% WP EPA Reg # Recommended Use fungicide Product Code Page 1 / 8

2 2. HAZARDS IDENTIFICATION Emergency Overview Harmful by inhalation, in contact with skin and if swallowed May cause thyroid and liver damage based on animal data. May cause allergic skin reaction Irritating to eyes CAUTION Appearance Light brown. Physical State Powder. Odor Slight. Rotten egg-like. Potential Health Effects - Inhalation - Skin contact Eyes Skin Inhalation Ingestion Irritating to eyes. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Slightly toxic if inhaled. May be harmful if swallowed. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Name Chemical Name CAS-No Weight % OSHA PEL Thiophanate-methyl N/A 4. FIRST AID MEASURES Eye Contact Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin Contact Inhalation Ingestion Notes to Physician Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call poison control center or doctor for treatment advice. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artifical respiration. Call a poison control center or doctor for further treatment advice. Call a physician or Poison Control Center immediately Have person sip a glass of water if able to swallow Do not induce vomiting unless told to do so by a poison control center or doctor Never give anything by mouth to an unconscious person No information available Page 2 / 8

3 5. FIRE-FIGHTING MEASURES Flammable Explosive Properties Flash Point Autoignition Temperature Flammability Limits in Air Extnguishing Media Fire/Explosion Hazard Hazardous Combustion Products Use: Water spray, Carbon dioxide (CO2), Foam Dry chemical. Firefighters and others who may be exposed to products of combustion should wear full fire fighting turn out gear and selfcontained breathing apparatus. Fire fighting equipment should be thoroughly decontaminated after use. No information available. NFPA Health 1 Flammability 0 Instability 0 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods for Clean-up Avoid contact with skin, eyes and clothing. Use personal protective equipment. Consult a regulatory specialist to determine appropriate state or local reporting requirements, for assistance in waste characterization and/or hazardous waste disposal and other requirements listed in pertinenet environmental permits.. Do not flush into surface water or sanitary sewer system. Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Handling Storage Avoid breathing dust. Keep out of reach of children. Wash thoroughly after handling.. Do not eat, drink or smoke when using this product. Keep containers tightly closed in a dry, cool and well-ventilated place. Page 3 / 8

4 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Engineering Controls Personal Protective Equipment Eye/face Protection Skin Protection Respiratory Protection This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Investigate engineering techniques to reduce exposures. Local mechanical exhaust ventilation is preferred. Consult ACGIH ventilation manual or NFPA Standard 91 for design of exhaust systems.. Avoid contact with eyes. Goggles. Rubber gloves. Wear protective gloves/clothing. Where airborne exposure is likely, use NIOSH approved respiratory protection equipment appropriate to the material and/or its components. Full facepiece equipment is recommended and, if used, replaces need for face shield and/or chemical goggles. If exposures cannot be kept at a minimum with engineering controls, consult respirator manufacturer to determine appropriate type equipment for given application. Observe respirator use limitations specified by NIOSH or the manufacturer. For emergency and other conditions where there may be a potential for significant exposure, use an approved full face positive-pressure, self-contained breathing apparatus. Respiratory protection programs must comply with 29 CFR General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Light brown Odor Slight Rotten egg-like Physical State Powder ph No data available Boiling Point/Range Melting Point/Range Specific Gravity Solubility Insoluble Evaporation Rate Vapor Pressure 7.12 X 10-8 mmhg(tech) Vapor Density VOC Content Viscosity Molecular Weight No data available Bulk Density No data available Percent Solids Percent Volatiles 10. STABILITY AND REACTIVITY Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Possibility of Hazardous Polymerization Stable under recommended storage conditions No information available. Strong oxidizing agents. No information available. Hazardous polymerisation does not occur 11. TOXICOLOGICAL INFORMATION Acute Toxicity Page 4 / 8

5 Product Information Single exposure studies indicate: Oral: Practically non-toxic to rats (LD50 >5,000 mg/kg) Dermal: No more than slightly toxic to rabbits (LD50 >2,000 mg/kg) Inhalation: SLightly toxic to rats (4 hr LC mg/l) Skin Irritation: Non-irritating to rabbits Eye Irritation: Non-irritating to rabbits Skin allergy was observed in guinea pigs following repeated exposure. Repeated or long-term oral administration produced effects on the thyroid, liver or kidneys in rats, mice and dogs. An increased incidence of liver tumors was observed in mice and thyroid tumors were observed in male rats following long-term oral exposure. No effects were seen on the ability of male or female rats to reproduce when exposed orally for 2 successive generations. No birth defects were observed in the offspring of rats exposed orally during pregnancy. In rabbits, developmental effects were noted only at maternally toxic doses. No genetic changes were observed in tests using animal cells. Chronic Toxicity Carcinogenicity There are no known carcinogenic chemicals in this product 12. ECOLOGICAL INFORMATION Ecotoxicity This material is practically non-toxic to carp(95 hr LC50 >100 mg/l), and fiddler crab (96 hr LC50 >560 mg/l). It is slightly toxic to bluegill (96 hr LC mg/l), Daphnid (48 hr EC mg/l) and shrimp (96 hr LC mg/l). It is moderately toxic to trout (96 hr LC mg/l) and oysters (96 hr LC mg/l) and oysters (96 hr LC ppm) and highly toxic to catfish.. Chem Fate:. No information available. 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Contaminated Packaging Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide or rinsate is a violation of Federal law. If the wastes cannot be disposed of by use or according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.. Dispose of contents/container in accordance with local regulation. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION DOT When shipped in packages greater than 15 lbs the following descriptions applies: Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. (Thiophanate methyl) Hazard Class 9 UN-No UN3077 Packing Group PG III Reportable Quantity (RQ): 10 Lbs (Thiophanate methyl) ICAO Not regulated Page 5 / 8

6 14. TRANSPORT INFORMATION IATA UN-No 3077 Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. (Thiophanate methyl) Hazard Class 9 Packing Group PG III ERG Code 9L IMDG/IMO Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. (Thiophanate-methyl) Hazard Class 9 UN-No 3077 Packing Group PG III 15. REGULATORY INFORMATION International Inventories Thiophanate-methyl DSL EINECS/ELINCS CHINA KECL USA Listed Listed Listed Listed Federal Regulations SARA 313 Y Chemical Name CAS-No Weight % Thiophanate-methyl SARA 311/312 Hazardous Categorization Chronic Health Hazard Acute Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes No No No Clean Water Act Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any HAPs. CERCLA Chemical Name Thiophanate-methyl RQ Page 6 / 8

7 RCRA Chemical Name RCRA - D Series Wastes RCRA - P Series Wastes RCRA - U Series Wastes Thiophanate-methyl U409 Pesticide Information State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name CAS-No Category California Prop. 65 Thiophanate-methyl Listed: May 18, 1999 Female reproductive toxin. Listed: May 18, 1999 Male reproductive toxin. 600 ug/day Oral State Right-to-Know Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Thiophanate-methyl Substance no Substance no Substance no Substance no International Regulations Mexico - Grade Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class Not determined 16. OTHER INFORMATION Revision Date 18-Nov-2009 Revision Summary Update section 14 Page 7 / 8

8 UPI, Inc. believes that the information and recommendations container herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be valid where such product is used in combination with other materials or in any process. Further, since the conditions and methods of use are beyond the control of UPI, Inc. UPI, Inc. expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information. End of MSDS Page 8 / 8