Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Number: Issue date: 11/21/ PRODUCT AND COMPANY IDENTIFICATION Product type: Epoxy Hardener Item number: EB4212 Region: United States Company address: Contact information: Henkel Electronic Materials LLC Jamboree Road Irvine, CA Telephone: HENKEL ( ) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *2 Color: Tan FLAMMABILITY: 1 Odor: Ammoniacal PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Causes respiratory tract irritation. Contains crystalline silica (quartz), which is classified as a possible carcinogen. However, the crystalline silica present in this product is encapsulated in the liquid and will only be liberated if the product is sanded or abraded, and even then what is liberated will not be pure crystalline silica. Appropriate precautions, however, should be taken if the product is sanded or abraded to prevent personnel from breathing the dust. Moderate skin irritation. May cause allergic skin reaction. Moderate eye irritation. May cause gastrointestinal tract irritation if swallowed. Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Wollastonite (Ca(SiO3)) Talc Tetraethylene pentamine Limestone Page 1 of 5

2 4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: C ( F) Closed cup Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon, oxides of nitrogen, irritating organic vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. 7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Avoid all ignition sources in storing and handling this material. Keep cool in accordance with label instructions. Wear protective equipment when handling. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 5

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Wollastonite (Ca(SiO3)) 20 MPPCF TWA 2.4 MPPCF TWA Talc 2 mg/m3 TWA 0.1 mg/m3 TWA 0.3 mg/m3 TWA 50 ppm Tetraethylene pentamine Limestone 10 mg/m3 TWA mg/m3 TWA 5 mg/m3 TWA 15 mg/m3 TWA 2.4 MPPCF TWA 0.1 mg/m3 TWA 0.3 mg/m3 TWA 1 ppm (5 mg/m3) TWA Aerosol. (SKIN) Aerosol. (Skin sensitizer.) Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Use local exhaust ventilation if the potential for airborne exposure exists. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Tan Odor: Ammoniacal Odor threshold: ph: Alkaline Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: 1.45 Vapor density: Flash point: C ( F) Closed cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partially miscible Partition coefficient (n-octanol/water): VOC content: 0 %; 0 g/l Estimated Page 3 of 5

4 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable at normal conditions. under normal processing. Oxides of carbon. Oxides of nitrogen. Ammonia. Nitric acid. Nitrosamines. Strong oxidizing agents. Acids. Peroxides. CAUTION! N-nitrosamines (many of which are known to be potent carcinogens) may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations. Store away from incompatible materials. Keep away from open flames, hot surfaces and sources of ignition. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) No No No Wollastonite (Ca(SiO3)) No No No Talc No No No Tetraethylene pentamine No No No Limestone No No No Known To Be Human Carcinogen. Group 1 No Hazardous components Wollastonite (Ca(SiO3)) Talc Tetraethylene pentamine Limestone Health Effects/Target Organs No Records Lung Irritant, Lung, Some evidence of carcinogenicity Irritant, Mutagen, Allergen Nuisance dust Immune system, Lung, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. U.S. Department of Transportation Ground (49 CFR) Not regulated Hazard class or division: Identification number: 14. TRANSPORT INFORMATION Page 4 of 5

5 International Air Transportation (ICAO/IATA) Environmentally hazardous substance, liquid, n.o.s. (Fatty acids, tall-oil, reaction products with ) Hazard class or division: 9 Identification number: UN 3082 III Water Transportation (IMO/IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fatty acids, tall-oil, reaction products with ) Hazard class or division: 9 Identification number: UN 3082 III Marine pollutant: United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimus Immediate Health, Delayed Health above reporting de minimus This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Tricia Voghell, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5