SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 1.4 Revision Date: 05/12/2016 SS4267. Product identifier: SS4267
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1 SAFETY DATA SHEET 1. Identification Product identifier: SS4267 Other means of identification Synonyms: Recommended use and restriction on use Recommended use: Mixture Restrictions on use: Not known. SILOXANE RESIN/FLUID Manufacturer/Importer/Distr ibutor Information : Momentive Performance Materials LLC 260 Hudson River Road Waterford NY Contact person : commercial.services@momentive.com Telephone : General information Emergency telephone number Supplier : CHEMTREC Hazard(s) identification Hazard Classification Not classified Label Elements Hazard Symbol: Signal Word: Hazard Statement: Target Organs No symbol none not applicable Precautionary Statement Prevention: not applicable SDS_US 1/11
2 Response: Storage: Disposal: Other hazards which do not result in GHS classification: not applicable not applicable not applicable None. 3. Composition/information on ingredients Mixtures Composition Comments: The components are not hazardous or are below required disclosure limits. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: If swallowed, do NOT induce vomiting. Give a glass of water. Do not give victim anything to drink if he is unconscious. Get medical attention if any discomfort continues. None known. Wash area with soap and water. Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention if symptoms occur. Most important symptoms/effects, acute and delayed Symptoms: Hazards: Treatment is symptomatic and supportive. Indication of immediate medical attention and special treatment needed Treatment: 5. Fire-fighting measures General Fire Hazards: Suitable (and unsuitable) extinguishing media Suitable extinguishing media: All standard extinguishing agents are suitable. SDS_US 2/11
3 Unsuitable extinguishing media: Specific hazards arising from the chemical: Special protective equipment and precautions for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: Firefighters must wear NIOSH/MSHA approved positive pressure selfcontained breathing apparatus with full face mask and full protective clothing. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Avoid contact with skin and eyes. Keep out of reach of children. Attention: Not for injection into humans. Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as specified in the protective equipment section. 7. Handling and storage Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Sensitivity to static discharge is not expected. Store at room temperature in the original container. Keep container closed. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source None of the components have assigned exposure limits. Appropriate Engineering Controls Provide eyewash station and safety shower. Local exhaust is recommended. SDS_US 3/11
4 Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Safety glasses with side shields Chemical resistant gloves Wear suitable protective clothing and eye/face protection. None known. 9. Physical and chemical properties Appearance Physical state: liquid Form: liquid Color: Colorless, /, Pale yellow Odor: Odorless Odor threshold: ph: Melting point/freezing point: Initial boiling point and boiling range: Flash Point: ca. 201 C Evaporation rate: Flammability (solid, gas): Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Density: 1.03 g/cm3 Relative density: ca. 1 Solubility(ies) Solubility in water: Insoluble Solubility (other): Partition coefficient (n-octanol/water) Log Pow: Auto-ignition temperature: SDS_US 4/11
5 Decomposition temperature: SADT: Viscosity, dynamic: Viscosity, kinematic: 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Material is stable under normal conditions. Hazardous polymerisation does not occur. None known. None known. In case of fire, gives off (emits): Carbon dioxide Silicon dioxide. Measurements at temperatures above 150 C in presence of air (oxygen) have shown that small amounts of formaldehyde are formed due to oxidative degradation. 11. Toxicological information Information on likely routes of exposure Ingestion: Inhalation: Skin Contact: Eye contact: Symptoms related to the physical, chemical and toxicological characteristics Ingestion: Inhalation: Skin Contact: Eye contact: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral LD 50 (Rat): 5,000 mg/kg SDS_US 5/11
6 Dermal Inhalation Not classified for acute toxicity based on available data. LC50 (Rat): 535 mg/l Repeated dose toxicity Skin Corrosion/Irritation (Rabbit, 4 h): No skin irritation Serious Eye Damage/Eye Irritation (Rabbit): No eye irritation Respiratory or Skin Sensitization Carcinogenicity IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: No carcinogenic components identified US. National Toxicology Program (NTP) Report on Carcinogens: No carcinogenic components identified US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure SDS_US 6/11
7 Specific Target Organ Toxicity - Repeated Exposure Target Organs Aspiration Hazard Other effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Aquatic Invertebrates Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative Potential Bioconcentration Factor (BCF) SDS_US 7/11
8 Partition Coefficient n-octanol / water (log Kow) Mobility in Soil: Known or predicted distribution to environmental compartments SILOXANES AND SILICONES, DI-ME Silicic acid, trimethylsilyl ester Other Adverse Effects: 13. Disposal considerations General information: Disposal instructions: Contaminated Packaging: Dispose of waste and residues in accordance with local authority requirements. Disposal should be made in accordance with federal, state and local regulations. Dispose of as unused product. 14. Transport information DOT Not regulated. IMDG Not regulated. IATA Not regulated. 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. SDS_US 8/11
9 US. OSHA Specifically Regulated Substances (29 CFR ) Chemical Identity SILOXANES AND SILICONES, DI-ME Decamethylcyclopentasil oxane Cyclohexasiloxane Dodecamethyl- Toluene Octamethylcyclotetrasilox ane OSHA hazard(s) No OSHA Hazards Causes mild skin irritation.; Respiratory hazard. No OSHA Hazards Causes mild skin irritation.; Systemic effects Systemic effects CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Toluene Reportable quantity 1,000 lbs. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories No SARA Hazards Fire Hazard SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Toluene 1,000 lbs. SARA 311/312 Hazardous Chemical None present or none present in regulated quantities. SARA 313 (TRI Reporting) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) Chemical Identity Reportable quantity Toluene Reportable quantity: 1,000 lbs. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ): None present or none present in regulated quantities. US State Regulations US. California Proposition 65 This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. SDS_US 9/11
10 Toluene Developmental toxin. US. New Jersey Worker and Community Right-to-Know Act No ingredient regulated by NJ Right-to-Know Law present. US. Massachusetts RTK - Substance List No ingredient regulated by MA Right-to-Know Law present. US. Pennsylvania RTK - Hazardous Substances No ingredient regulated by PA Right-to-Know Law present. US. Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. Inventory Status: Australia AICS: y (positive listing) Remarks: None. EU EINECS List: y (positive listing) Remarks: None. Japan (ENCS) List: y (positive listing) Remarks: None. China Inventory of Existing y (positive listing) Remarks: None. Chemical Substances: Korea Existing Chemicals Inv. y (positive listing) Remarks: None. (KECI): Canada DSL Inventory List: y (positive listing) Remarks: None. Canada NDSL Inventory: n (Negative listing) Remarks: None. Philippines PICCS: y (positive listing) Remarks: None. US TSCA Inventory: y (positive listing) Remarks: On TSCA Inventory Taiwan. Taiwan inventory (CSNN): y (positive listing) Remarks: None. 16.Other information, including date of preparation or last revision HMIS Hazard ID Health 0 Flammability 1 Physical Hazards 0 PERSONAL PROTECTION Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; RNP - Rating not possible; *Chronic health effect Issue Date: 05/12/2016 Revision Date: Version #: 1.4 SDS_US 10/11
11 Further Information: Disclaimer: Notice to reader Unless otherwise specified in section 1, Momentive products are intended for use in the manufacture and/or formulation of products and are not intended for direct consumer use. These products are not intended for long-lasting (> 30 days) implantation, injection or direct ingestion into the human body, nor for use in the manufacture of multiple use contraceptives. Keep out of the reach of children. Further Information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.,*, and TM indicate trademarks owned by or licensed to Momentive. SDS_US 11/11
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