IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers

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1 PROFENOFOS 500 EC MATERIAL SAFETY DATA SHEET IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name : Profenofos 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Acute toxicity, Inhalation (Category 4) Acute toxicity, Dermal (Category 4) Acute toxicity, Oral (Category 4) Classification according to EU Directives 67/548/EEC or 1999/45/EC Harmful by inhalation, in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H302 H312 H332 H410 Warning Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 P280 P501 Supplemental Hazard Statements Avoid release to the environment. Wear protective gloves/ protective clothing. Dispose of contents/ container to an approved waste disposal plant. none According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R20/21/22 R50/53 S-phrase(s) S36/37 S60 S61 Caution - substance not yet tested completely. Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Harmful by inhalation, in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/ Safety data sheets.

2 3.1 Substances Formula Molecular Weight Component Profenofos CAS-No. EC-No. Index-No. : : C11H15BrClO3PS 373,63 g/mol Concentration FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides, Sulphur oxides, Oxides of phosphorus, Hydrogen chloride gas, Hydrogen bromide gas Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2-8 C Specific end uses

3 EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form: solid i) Flammability (solid, gas) j) k) Upper/lower flammability or explosive limits Vapour pressure l) Vapour density m) Relative density n) o) p) q) r) s) Water solubility Partition coefficient: n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties t) Oxidizing properties 9.2 Other safety information

4 STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products - TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat mg/kg LC50 Inhalation - rat - 4 h mg/m3 LD50 Dermal - rabbit mg/kg Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Cytogenetic analysis Sister chromatid exchange sperm Micronucleus test Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Reproductive toxicity - mouse - Oral Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count). Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes Additional Information RTECS: TE Harmful if inhaled. May cause respiratory tract irritation. Harmful if swallowed. May be fatal if absorbed through skin. May cause skin irritation. May cause eye irritation.

5 ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Very toxic to aquatic life. DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product TRANSPORT INFORMATION UN number ADR/RID: 2810 IMDG: 2810 IATA: 2810 UN proper shipping name ADR/RID: TOXIC LIQUID, ORGANIC, N.O.S. () IMDG: IATA: TOXIC LIQUID, ORGANIC, N.O.S. () Toxic liquid, organic, n.o.s. () 14.3 Transport hazard class(es) ADR/RID: Packaging group ADR/RID: II Environmental hazards ADR/RID: yes Special precautions for user REGULATORY INFORMATION IMDG: 6.1 IMDG: II IMDG Marine pollutant: yes IATA: 6.1 IATA: II IATA: no This safety datasheet complies with the requirements of Regulation (EC) No. 1907/ Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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