SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions EVA-POX Cold Cure Bonder #41 Part B None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name CHASE CORPORATION - ZETA CCP Address 201 Zeta Drive Pittsburgh, PA United States Telephone Emergency phone number Chemtrec, US (+1) Chemtrec, outside of US 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Skin corrosion/irritation Serious eye damage/eye irritation Sensitization, respiratory Sensitization, skin Category 1 Category 1 Category 1 Category 1 Signal word Hazard statement Precautionary statement Prevention Response Danger Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Do not breathe mist or vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Specific treatment (see this label). If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. 1 / 8

2 Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 2,2'-iminodi(ethylamine) Other components below reportable levels < *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Remove contaminated clothing immediately and wash skin with soap and water. Take off immediately all contaminated clothing. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Burning pain and severe corrosive skin damage. Difficulty in breathing. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 2 / 8

3 Methods and materials for containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components 2,2'-iminodi(ethylamine) (CAS ) Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 1 ppm Value 2,2'-iminodi(ethylamine) (CAS ) Biological limit values Exposure guidelines US - California OELs: Skin designation TWA US - Minnesota Haz Subs: Skin designation applies US ACGIH Threshold Limit Values: Skin designation 4 mg/m3 1 ppm No biological exposure limits noted for the ingredient(s). Can be absorbed through the skin. Skin designation applies. Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Appropriate engineering controls Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. Chemical respirator with organic vapor cartridge and full facepiece. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 3 / 8

4 Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Liquid. Liquid. Grey. Ammoniacal F (-39 C) estimated F (207 C) estimated > F (> C) Tag Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Density Specific gravity 0.31 hpa estimated F (398.9 C) estimated 0.96 g/cm3 estimated 0.96 estimated 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong acids. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Causes digestive tract burns. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Prolonged inhalation may be harmful. May cause irritation to the respiratory system. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes severe skin burns. May cause an allergic skin reaction. Causes serious eye damage. Burning pain and severe corrosive skin damage. Difficulty in breathing. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. 4 / 8

5 Information on toxicological effects Acute toxicity May cause an allergic skin reaction. Product Species EVA-POX Cold Cure Bonder #41 Part B (CAS Mixture) Acute Oral LD50 Rat Other LD50 Guinea pig Mouse Rabbit Rat Components Species Acute Oral LD50 Rat Other LD50 Guinea pig Mouse Rabbit Rat Test Results mg/kg estimated mg/kg estimated mg/kg estimated mg/kg estimated mg/kg estimated Test Results 1080 mg/kg 162 mg/kg 71 mg/kg 1090 mg/kg 74 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Causes severe skin burns and eye damage. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Product This product is not expected to cause reproductive or developmental effects. Prolonged inhalation may be harmful. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Species EVA-POX Cold Cure Bonder #41 Part B (CAS Mixture) Aquatic Fish LC50 Fish Test Results mg/l, 96 hours estimated 5 / 8

6 Components Aquatic Fish LC50 Species Guppy (Poecilia reticulata) Test Results 1014 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging No data is available on the degradability of this product. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards ERG Code Special precautions for user Other information Passenger and cargo aircraft Cargo aircraft only IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk UN2079 Diethylenetriamine, solution (2,2'-iminodi(ethylamine)) 8-8 II Read safety instructions, SDS and emergency procedures before handling. B2, IB2, T7, TP UN2079 Diethylenetriamine solution (2,2'-iminodi(ethylamine)) 8 - II No. 8L Read safety instructions, SDS and emergency procedures before handling. Allowed. Allowed. UN2079 DIETHYLENETRIAMINE SOLUTION (2,2'-iminodi(ethylamine)) 8-6 / 8

7 Packing group II Environmental hazards Marine pollutant No. EmS F-A, S-B Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Transport in bulk according to This substance/mixture is not intended to be transported in bulk. Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations No Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 7 / 8

8 Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 HMIS ratings Health: 3* Flammability: 0 Physical hazard: 0 NFPA ratings Health: 3 Flammability: 0 Instability: 0 Disclaimer The information offered in this data sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication, however, no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. This material is intended for industrial use only. No warranty, expressed or implied is made. No No 8 / 8