Material Safety Data Sheet

Transcription

1 02 Section 1 Product Identification Material Safety Data Sheet he Sherwin-Williams Co. mergency telephone number (216) Prospect Ave. N.W. Information telephone number (216) Cleveland, OH Date of preparation January 21, , he Sherwin-Williams Co. Reducers - 1 V M & P Mineral xempt Secondary Diacetone Reducer 132 Naphtha Spirits Xylol Butanol Alcohol R1K3 R1K4 R4K11 R6K19 R6K24 R7K132 SOL/1 Section 2 ACGIH OSHA LD50 LC50 Vapor CAS No. Hazardous Ingredients LV PL Units (Rat-Oral) (Rat) Pressure (percent by weight) <SL> <SL> mg/kg /4hr. mm V. M. & P. Naphtha. 300 <400> NAv NAv Mineral Spirits NAv NAv Medium Aromatic Hydrocarbons. NAv NAv NAv NAv Propanol <500> <500> 5045 NAv Butanol NAv Diacetone Alcohol NAv Butoxyethanol (skin) 470 NAv Cyclohexanone (skin) % B Y W I G H Methoxy-2-Propanol Acetate NAv NAv 8500 NAv Weight per Gallon (lbs.) VOC (Volatile Organic Compounds) - lbs./gal Photochemically Reactive No No No No Yes No Flash Point ( F) DOL Storage Category 1B 2 1B 1C 2 2 Flammability Classification (Flammable - Combustible) Flam. Comb. Flam. Flam. Comb. Comb. HMIS (NFPA) Rating (health - flammability - reactivity) Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR C MSDS ext Page Follows 1

2 Reducers - 1 Section 3 Hazards Identification ROUS OF XPOSUR - xposure may be by INHALAION and/or SKIN or Y contact, depending on conditions of use. Alcohols and acetates can be absorbed through the skin. Follow recommendations for proper use, ventilation, and personal protective equipment to minimize exposure. FFCS OF OVRXPOSUR - Irritation of eyes, skin and respiratory system. May cause nervous system depression. xtreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPOMS OF OVRXPOSUR - Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MDICAL CONDIIONS AGGRAVAD BY XPOSUR - None generally recognized. CANCR INFORMAION - For complete discussion of toxicology data refer to Section 11. Section 4 First Aid Measures If INHALD: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in YS: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWD: Do not induce vomiting. Get medical attention immediately. Section 5 Fire Fighting Measures FLAMMABILIY CLASSIFICAION - See ABL FLASH POIN - See ABL LL 0.8 UL 13.1 XINGUISHING MDIA - Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIR AND XPLOSION HAZARDS - Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPCIAL FIR FIGHING PROCDURS - Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 Accidental Release Measures SPS O B AKN IN CAS MARIAL IS RLASD OR SPILLD - Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 Handling and Storage DOL SORAG CAGORY - See ABL PRCAUIONS O B AKN IN HANDLING AND SORING - Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - xtinguish all flames, pilot lights, and heaters - urn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. ransfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 xposure Controls/Personal Protection PRCAUIONS O B AKN IN US - Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. VNILAION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , RSPIRAORY PROCION - If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROCIV GLOVS - Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Y PROCION - Wear safety spectacles with unperforated sideshields. OHR PRCAUIONS - Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SOL/1 Section 9 Physical and Chemical Properties PRODUC WIGH See ABL VAPORAION RA Slower than ether SPCIFIC GRAVIY VAPOR DNSIY Heavier than air BOILING POIN F MLING POIN Not Available VOLAIL VOLUM 100 % SOLUBILIY IN WAR Not Available Section 10 Stability and Reactivity SABILIY - Stable CONDIIONS O AVOID - None known. INCOMPAIBILIY - None known. HAZARDOUS DCOMPOSIION PRODUCS - By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMRIZAION - Will not occur Section 11 oxicological Information CHRONIC Health Hazards - No ingredient in these products is an IARC, NP or OSHA listed carcinogen. Prolonged overexposure to solvent ingredients in the following products may cause adverse effects to organ systems: V M & P Naphtha & Mineral Spirits liver, urinary Reducer 132 liver, urinary, blood forming xempt Xylol liver, urinary, blood forming, reproductive Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Section 12 cological Information Section 13 Disposal Considerations WAS DISPOSAL MHOD - Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable PA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 ransport Information Section 15 Regulatory Information CALIFORNIA PROPOSIION 65 - WARNING: V M & P Naphtha and xempt Xylol contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SCA CRIFICAION - All chemicals in these products are listed, or are exempt from listing, on the SCA Inventory. Section 16 Other Information hese products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. he above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. 1

3 02 Section 1 Product Identification Material Safety Data Sheet he Sherwin-Williams Co. mergency telephone number (216) Prospect Ave. N.W. Information telephone number (216) Cleveland, OH Date of preparation January 21, 2002 Reducers , he Sherwin-Williams Co. SOL/2 oluene Xylene High Flash High Flash Acrylic namel No. 104 No. 145 (oluol) (Xylol) Naphtha 100 Naphtha 150 Standard Warm Weather R2K1 R2K4 R2K5 R7K100 R2K7 R4K35 R4K36 R7K104 R7K145 Section 2 ACGIH OSHA LD50 LC50 Vapor CAS No. Hazardous Ingredients LV PL Units (Rat-Oral) (Rat) Pressure (percent by weight) <SL> <SL> mg/kg /4hr. mm Lt. Aliphatic Hydrocarbon Solvent NAv NAv oluene. 50 <150> (skin) thylbenzene <125> <125> Xylene. <150> <150> NAv Light Aromatic Hydrocarbons. NAv NAv NAv NAv Cumene NAv ,3,5-rimethylbenzene NAv NAv ,2,4-rimethylbenzene NAv NAv Medium Aromatic Hydrocarbons. NAv NAv NAv NAv Naphthalene <15> <15> NAv NAv Butanol C 50 C 50 (skin) Methoxy-2-propanol <150> <150> NAv Butoxyethanol (skin) 470 NAv Acetone. 500 <750> NAv Methyl thyl Ketone. <300> <300> 2740 NAv Methyl n-amyl Ketone NAv Butoxyethyl Acetate. NAv NAv 2400 NAv P R C N B Y W I G H Weight per Gallon (lbs.) VOC (Volatile Organic Compounds) mitted - lbs./gal VOC Less Water & Federally xempt Solvents - lbs./gal Photochemically Reactive Yes Yes Yes Yes Yes Yes Yes Yes Flash Point ( F) / DOL Storage Category 40 / 1B 80 / 1C 105 / / 3A 10 / 1B 10 / 1B 105 / 2 80 / 1C Flammability Classification (Flammable - Combustible) Flam. Flam. Comb. Comb. Flam. Flam. Comb. Flam. HMIS (NFPA) Rating (health - flammability - reactivity) * * * * * * Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR C 2

4 Reducers - 2 Section 3 Hazards Identification ROUS OF XPOSUR - xposure may be by INHALAION and/or SKIN or Y contact, depending on conditions of use. Alcohols and acetates can be absorbed through the skin. Follow recommendations for proper use, ventilation, and personal protective equipment to minimize exposure. FFCS OF OVRXPOSUR - Irritation of eyes, skin and respiratory system. May cause nervous system depression. xtreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPOMS OF OVRXPOSUR - Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MDICAL CONDIIONS AGGRAVAD BY XPOSUR - None generally recognized. CANCR INFORMAION - For complete discussion of toxicology data refer to Section 11. Section 4 First Aid Measures If INHALD: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in YS: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWD: Do not induce vomiting. Get medical attention immediately. Section 5 Fire Fighting Measures FLAMMABILIY CLASSIFICAION - See ABL FLASH POIN - See ABL LL 0.5 UL 12.8 XINGUISHING MDIA - Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIR AND XPLOSION HAZARDS - Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPCIAL FIR FIGHING PROCDURS - Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 Accidental Release Measures SPS O B AKN IN CAS MARIAL IS RLASD OR SPILLD - Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 Handling and Storage DOL SORAG CAGORY - See ABL PRCAUIONS O B AKN IN HANDLING AND SORING - Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - xtinguish all flames, pilot lights, and heaters - urn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. ransfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 xposure Controls/Personal Protection PRCAUIONS O B AKN IN US - Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. VNILAION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , RSPIRAORY PROCION - If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROCIV GLOVS - Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Y PROCION - Wear safety spectacles with unperforated sideshields. OHR PRCAUIONS - Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SOL/2 Section 9 Physical and Chemical Properties PRODUC WIGH See ABL VAPORAION RA Slower than ether SPCIFIC GRAVIY VAPOR DNSIY Heavier than air BOILING POIN F MLING POIN Not Available VOLAIL VOLUM % SOLUBILIY IN WAR Not Available Section 10 Stability and Reactivity SABILIY - Stable CONDIIONS O AVOID - None known. INCOMPAIBILIY - None known. HAZARDOUS DCOMPOSIION PRODUCS - By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMRIZAION - Will not occur Section 11 oxicological Information CHRONIC Health Hazards - thylbenzene is classified by IARC as possibly carcinogenic to humans(2b) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. hese effects were not observed in animals exposed to lower concentrations. here is no evidence that ethylbenzene causes cancer in humans. Methyl thyl Ketone may increase the nervous system effects of other solvents. Prolonged overexposure to solvent ingredients in the following products may cause adverse effects to organ systems: High Flash Naphtha 100, High Flash Naphtha 150 liver, urinary, reproductive Reducer 104, Reducer 145, Xylene liver, urinary, reproductive oluol liver, urinary, cardiovascular, reproductive Acrylic namel (Standard & Warm Weather) liver, urinary, blood forming, cardiovascular, reproductive Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Section 12 cological Information Section 13 Disposal Considerations WAS DISPOSAL MHOD - Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable PA hazardous waste numbers. Waste from products containing Methyl thyl Ketone may also require extractability testing. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 ransport Information Section 15 Regulatory Information CALIFORNIA PROPOSIION 65 - WARNING: hese products, except for High Flash Naphtha 150, contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. High Flash Naphtha 150 contains a chemical known to the State of California to cause birth defects or other reproductive harm. SCA CRIFICAION - All chemicals in these products are listed, or are exempt from listing, on the SCA Inventory. Section 16 Other Information hese products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. he above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. 2

5 02 Section 1 Product Identification Material Safety Data Sheet he Sherwin-Williams Co. mergency telephone number (216) Prospect Ave. N.W. Information telephone number (216) Cleveland, OH Date of preparation January 17, , he Sherwin-Williams Co. Reducers - 3 Acetone Methyl thyl HAPS Complying Butyl Reducer 54 Reducer 58 Ketone Dye Stain Cellosolve R6K9 R6K10 R6K21 R6K25 R7K54 R7K58 SOL/3 Section 2 ACGIH OSHA LD50 LC50 Vapor CAS No. Hazardous Ingredients LV PL Units (Rat-Oral) (Rat) Pressure (percent by weight) <SL> <SL> mg/kg /4hr. mm thylbenzene <125> <125> Xylene. <150> <150> NAv thanol NAv Propanol <500> <500> 5045 NAv Butoxyethanol (skin) 470 NAv Acetone. 500 <750> NAv Methyl thyl Ketone. <300> <300> 2740 NAv Methyl n-amyl Ketone NAv n-propyl Acetate <250> <250> 9370 NAv Methyl Isobutyl Ketone. 50 <75> 50 <75> 2080 NAv Methoxy-2-Propanol Acetate NAv NAv 8500 NAv P R C N B Y W I G H Weight per Gallon (lbs.) VOC (Volatile Organic Compounds) - lbs./gal Photochemically Reactive No No No No Yes Yes Flash Point ( F) DOL Storage Category 1B 1B 1B 3A 1B 1C Flammability Classification (Flammable - Combustible) Flam. Flam. Flam. Comb. Flam. Flam. HMIS (NFPA) Rating (health - flammability - reactivity) * * Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR C Butyl Cellosolve is a trademark of Union Carbide MSDS ext Page Follows 3

6 Reducers - 3 Section 3 Hazards Identification ROUS OF XPOSUR - xposure may be by INHALAION and/or SKIN or Y contact, depending on conditions of use. o minimize exposure, follow recommendations for proper use, ventilation, and personal protective equipment. FFCS OF OVRXPOSUR - Irritation of eyes, skin and respiratory system. May cause nervous system depression. xtreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPOMS OF OVRXPOSUR - Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MDICAL CONDIIONS AGGRAVAD BY XPOSUR - None generally recognized. CANCR INFORMAION - For complete discussion of toxicology data refer to Section 11. Section 4 First Aid Measures If INHALD: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in YS: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWD: Do not induce vomiting. Get medical attention immediately. Section 5 Fire Fighting Measures FLAMMABILIY CLASSIFICAION - See ABL FLASH POIN - See ABL LL 1.0 UL 19.0 XINGUISHING MDIA - Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIR AND XPLOSION HAZARDS - Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPCIAL FIR FIGHING PROCDURS - Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 Accidental Release Measures SPS O B AKN IN CAS MARIAL IS RLASD OR SPILLD - Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 Handling and Storage DOL SORAG CAGORY - See ABL PRCAUIONS O B AKN IN HANDLING AND SORING - Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - xtinguish all flames, pilot lights, and heaters - urn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. ransfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 xposure Controls/Personal Protection PRCAUIONS O B AKN IN US - Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. VNILAION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , RSPIRAORY PROCION - If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROCIV GLOVS - Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Y PROCION - Wear safety spectacles with unperforated sideshields. OHR PRCAUIONS - Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SOL/3 Section 9 Physical and Chemical Properties PRODUC WIGH See ABL VAPORAION RA Slower than ether SPCIFIC GRAVIY VAPOR DNSIY Heavier than air BOILING POIN F MLING POIN Not Available VOLAIL VOLUM 100 % SOLUBILIY IN WAR Not Available Section 10 Stability and Reactivity SABILIY - Stable CONDIIONS O AVOID - None known. INCOMPAIBILIY - None known. HAZARDOUS DCOMPOSIION PRODUCS - By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMRIZAION - Will not occur Section 11 oxicological Information CHRONIC Health Hazards - thylbenzene is classified by IARC as possibly carcinogenic to humans(2b) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. hese effects were not observed in animals exposed to lower concentrations. here is no evidence that ethylbenzene causes cancer in humans. Methyl thyl Ketone may increase the nervous system effects of other solvents. Prolonged overexposure to solvent ingredients in the following products may cause adverse effects to organ systems: HAPS Complying Dye Stain liver Methyl thyl Ketone reproductive Reducer 54 liver, urinary, reproductive Butyl Cellosolve liver, urinary, blood forming Reducer 58 liver, urinary, blood forming, reproductive Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Section 12 cological Information Section 13 Disposal Considerations WAS DISPOSAL MHOD - Waste from Butyl Cellosolve is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste from other products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable PA hazardous waste numbers. Waste from products containing Methyl thyl Ketone may also require extractability testing. Incinerate all products in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 ransport Information Section 15 Regulatory Information CALIFORNIA PROPOSIION 65 - WARNING: Acetone, Reducer 54 and Reducer 58 contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SCA CRIFICAION - All chemicals in these products are listed, or are exempt from listing, on the SCA Inventory. Section 16 Other Information hese products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. he above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. 3

7 02 Section 1 Product Identification Reducers - 4 Material Safety Data Sheet he Sherwin-Williams Co. mergency telephone number (216) Prospect Ave. N.W. Information telephone number (216) Cleveland, OH Date of preparation January 22, , he Sherwin-Williams Co. SOL/4 Section 2 ACGIH OSHA LD50 LC50 Vapor CAS No. Hazardous Ingredients LV PL Units (Rat-Oral) (Rat) Pressure (percent by weight) <SL> <SL> mg/kg /4hr. mm (2-Butoxyethoxy)-ethanol NAv NAv 5660 NAv Butyl Carbitol XANOL ster Alcohol R6K28 R6K33 No ingredients in this product are hazardous as defined by the Department of Labor Weight per Gallon (lbs.) PRCN BY WIGH VOC (Volatile Organic Compounds) - lbs./gal Photochemically Reactive No No Flash Point ( F) DOL Storage Category 3B 3B Flammability Classification (Flammable - Combustible - Not Applicable) Not Applicable Not Applicable HMIS (NFPA) Rating (health - flammability - reactivity) Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR C Butyl Carbitol is a trademark of Union Carbide. XANOL is a trademark of astman Chemical. MSDS ext Page Follows 4

8 Reducers - 4 Section 3 Hazards Identification ROUS OF XPOSUR - xposure may be by INHALAION and/or SKIN or Y contact, depending on conditions of use. Alcohols and acetates can be absorbed through the skin. Follow recommendations for proper use, ventilation, and personal protective equipment to minimize exposure. FFCS OF OVRXPOSUR - Irritation of eyes, skin and upper respiratory system. In a confined area vapors in high concentration may cause headache, nausea or dizziness. SIGNS AND SYMPOMS OF OVRXPOSUR - Redness and itching or burning sensation may indicate eye or excessive skin exposure. MDICAL CONDIIONS AGGRAVAD BY XPOSUR - None generally recognized. CANCR INFORMAION - For complete discussion of toxicology data refer to Section 11. Section 4 First Aid Measures If INHALD: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in YS: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWD: Do not induce vomiting. Get medical attention immediately. Section 5 Fire Fighting Measures FLAMMABILIY CLASSIFICAION - See ABL FLASH POIN - See ABL LL 0.8 UL 13.1 XINGUISHING MDIA - Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIR AND XPLOSION HAZARDS - Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat. SPCIAL FIR FIGHING PROCDURS - Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 Accidental Release Measures SPS O B AKN IN CAS MARIAL IS RLASD OR SPILLD - Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 Handling and Storage DOL SORAG CAGORY - See ABL PRCAUIONS O B AKN IN HANDLING AND SORING - Keep container closed when not in use. ransfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 xposure Controls/Personal Protection PRCAUIONS O B AKN IN US - Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. VNILAION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , RSPIRAORY PROCION - If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROCIV GLOVS - Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Y PROCION - Wear safety spectacles with unperforated sideshields. Section 9 Physical and Chemical Properties PRODUC WIGH See ABL VAPORAION RA Slower than ether SPCIFIC GRAVIY 0.95 VAPOR DNSIY Heavier than air BOILING POIN F MLING POIN Not Available VOLAIL VOLUM 100 % SOLUBILIY IN WAR Not Available Section 10 Stability and Reactivity SABILIY - Stable CONDIIONS O AVOID - None known. INCOMPAIBILIY - None known. HAZARDOUS DCOMPOSIION PRODUCS - By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMRIZAION - Will not occur Section 11 oxicological Information CHRONIC Health Hazards - No ingredient in these products is an IARC, NP or OSHA listed carcinogen. Section 12 cological Information Section 13 Disposal Considerations SOL/4 WAS DISPOSAL MHOD - Waste from these products is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 ransport Information Section 15 Regulatory Information SCA CRIFICAION - All chemicals in these products are listed, or are exempt from listing, on the SCA Inventory. Section 16 Other Information hese products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. he above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. 4

9 02 Section 1 Product Identification Lacquer Reducers Material Safety Data Sheet he Sherwin-Williams Co. mergency telephone number (216) Prospect Ave. N.W. Information telephone number (216) Cleveland, OH Date of preparation January 23, , he Sherwin-Williams Co. Butyl Lacquer Retarder tching K119 hinner K120 hinner Acetate hinner hinner hinner R6K18 R7K22 R7K27 R7K53 R7K119 R7K120 SOL-LAC Section 2 ACGIH OSHA LD50 LC50 Vapor CAS No. Hazardous Ingredients LV PL Units (Rat-Oral) (Rat) Pressure (percent by weight) <SL> <SL> mg/kg /4hr. mm V. M. & P. Naphtha <400> NAv NAv Mineral Spirits NAv NAv oluene. 50 <150> thylbenzene <125> <125> Xylene. <150> <150> Methanol 200 <250> 200 <250> (skin) (skin) NAv Propanol <500> <500> 5045 NAv Methyl-1-propanol NAv Butoxyethanol (skin) 470 NAv Acetone. 500 <750> NAv Methyl thyl Ketone. <300> <300> 2740 NAv Methyl Isobutyl Ketone. <75> <75> 2080 NAv Methyl n-amyl Ketone NAv n-butyl Acetate > <200> Lt. Aliphatic Hydrocarbon Solvent NAv NAv P R C N B Y W I G H Isobutyl Acetate NAv Butoxyethyl Acetate. NAv NAv 2400 NAv Weight per Gallon (lbs.) Percent Water VOC (Volatile Organic Compounds) mitted - lbs./gal VOC Less Water & Federally xempt Solvents - lbs./gal Photochemically Reactive No No No Yes Yes No Flash Point ( F) / DOL Storage Category 81 / 1C 32 / 1B 47 / 1B 25 / 1B 1 / 1B 3 / 1B HMIS (NFPA) Rating (health - flammability - reactivity) * * * * * Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR C 5

10 Lacquer Reducers Section 3 Hazards Identification ROUS OF XPOSUR - xposure may be by INHALAION and/or SKIN or Y contact, depending on conditions of use. Alcohols and acetates can be absorbed through the skin. Follow recommendations for proper use, ventilation, and personal protective equipment to minimize exposure. FFCS OF OVRXPOSUR - Irritation of eyes, skin and respiratory system. May cause nervous system depression. xtreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPOMS OF OVRXPOSUR - Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MDICAL CONDIIONS AGGRAVAD BY XPOSUR - None generally recognized. CANCR INFORMAION - For complete discussion of toxicology data refer to Section 11. Section 4 First Aid Measures If INHALD: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in YS: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWD: Do not induce vomiting. Get medical attention immediately. Section 5 Fire Fighting Measures FLAMMABILIY CLASSIFICAION - RD LABL -- Flammable, Flash below 100 F FLASH POIN - See ABL LL 0.5 UL 36.5 XINGUISHING MDIA - Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIR AND XPLOSION HAZARDS - Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPCIAL FIR FIGHING PROCDURS - Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 Accidental Release Measures SPS O B AKN IN CAS MARIAL IS RLASD OR SPILLD - Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 Handling and Storage DOL SORAG CAGORY - See ABL PRCAUIONS O B AKN IN HANDLING AND SORING - Contents are FLAMMABL. Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - xtinguish all flames, pilot lights, and heaters - urn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. ransfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 xposure Controls/Personal Protection PRCAUIONS O B AKN IN US - Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. VNILAION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , RSPIRAORY PROCION - If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROCIV GLOVS - Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Y PROCION - Wear safety spectacles with unperforated sideshields. OHR PRCAUIONS - Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SOL-LAC Section 9 Physical and Chemical Properties PRODUC WIGH See ABL VAPORAION RA Slower than ether SPCIFIC GRAVIY VAPOR DNSIY Heavier than air BOILING POIN F MLING POIN Not Available VOLAIL VOLUM % SOLUBILIY IN WAR Not Available Section 10 Stability and Reactivity SABILIY - Stable CONDIIONS O AVOID - None known. INCOMPAIBILIY - None known. HAZARDOUS DCOMPOSIION PRODUCS - By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMRIZAION - Will not occur Section 11 oxicological Information CHRONIC Health Hazards - thylbenzene is classified by IARC as possibly carcinogenic to humans(2b) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. hese effects were not observed in animals exposed to lower concentrations. here is no evidence that ethylbenzene causes cancer in humans. Methyl thyl Ketone may increase the nervous system effects of other solvents. Prolonged overexposure to solvent ingredients in the following products may cause adverse effects to organ systems: Butyl Acetate blood forming K119 hinner, K120 hinner liver, urinary, blood forming, cardiovascular, reproductive tching, Lacquer and Retarder hinners liver, urinary, blood forming, cardiovascular, reproductive Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Section 12 cological Information Section 13 Disposal Considerations WAS DISPOSAL MHOD - Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable PA hazardous waste numbers. Waste from products containing Methyl thyl Ketone may also require extractability testing. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 ransport Information Section 15 Regulatory Information CALIFORNIA PROPOSIION 65 - WARNING: hese products, except for Butyl Acetate, contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SCA CRIFICAION - All chemicals in these products are listed, or are exempt from listing, on the SCA Inventory. Section 16 Other Information hese products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. he above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. 5

11 02 Section 1 Product Identification Material Safety Data Sheet he Sherwin-Williams Co. mergency telephone number (216) Prospect Ave. N.W. Information telephone number (216) Cleveland, OH Date of preparation January 21, , he Sherwin-Williams Co. POLAN Reducers SOL-POL MAK Cyclo- K69 K84 K94 Retarder Reducer Reducer hexanone hinner hinner hinner R6K30 R6K32 R7K69 R7K84 R7K94 R7K216 R7KB29 R7KB50 Section 2 ACGIH OSHA LD50 LC50 Vapor CAS No. Hazardous Ingredients LV PL Units (Rat-Oral) (Rat) Pressure (percent by weight) <SL> <SL> mg/kg /4hr. mm oluene. 50 <150> (skin) thylbenzene <125> <125> Xylene. <150> <150> NAv Methyl thyl Ketone. <300> <300> 2740 NAv Methyl Isobutyl Ketone. <75> <75> 2080 NAv Methyl n-amyl Ketone NAv Cyclohexanone (skin) Isopropyl Acetate. n-butyl Acetate. 250 <310> 250 <310> <200> <200> NAv Weight per Gallon (lbs.) % B Y W I G H VOC (Volatile Organic Compounds) - lbs./gal Photochemically Reactive No Yes Yes No No No No No Flash Point ( F) DOL Storage Category 2 2 1B 1B 1B 1C 1B 1B Flammability Classification (Flammable - Combustible) Comb. Comb. Flam. Flam. Flam. Flam. Flam. Flam. HMIS (NFPA) Rating (health - flammability - reactivity) * * * Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR C MSDS ext Page Follows 6

12 POLAN Reducers Section 3 Hazards Identification ROUS OF XPOSUR - xposure may be by INHALAION and/or SKIN or Y contact, depending on conditions of use. o minimize exposure, follow recommendations for proper use, ventilation, and personal protective equipment. FFCS OF OVRXPOSUR - Irritation of eyes, skin and respiratory system. May cause nervous system depression. xtreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPOMS OF OVRXPOSUR - Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. MDICAL CONDIIONS AGGRAVAD BY XPOSUR - None generally recognized. CANCR INFORMAION - For complete discussion of toxicology data refer to Section 11. Section 4 First Aid Measures If INHALD: If affected, remove from exposure. Restore breathing. Keep warm and quiet. If on SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. If in YS: Flush eyes with large amounts of water for 15 minutes. Get medical attention. If SWALLOWD: Do not induce vomiting. Get medical attention immediately. Section 5 Fire Fighting Measures FLAMMABILIY CLASSIFICAION - See ABL FLASH POIN - See ABL LL 1.0 UL 10.0 XINGUISHING MDIA - Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIR AND XPLOSION HAZARDS - Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPCIAL FIR FIGHING PROCDURS - Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 Accidental Release Measures SPS O B AKN IN CAS MARIAL IS RLASD OR SPILLD - Remove all sources of ignition. Ventilate and remove with inert absorbent. Section 7 Handling and Storage DOL SORAG CAGORY - See ABL PRCAUIONS O B AKN IN HANDLING AND SORING - Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - xtinguish all flames, pilot lights, and heaters - urn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. ransfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 xposure Controls/Personal Protection PRCAUIONS O B AKN IN US - Use only with adequate ventilation. Avoid breathing vapor and spray mist. Avoid contact with skin and eyes. Wash hands after using. VNILAION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , , RSPIRAORY PROCION - If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. PROCIV GLOVS - Wear gloves which are recommended by glove supplier for protection against materials in Section 2. Y PROCION - Wear safety spectacles with unperforated sideshields. OHR PRCAUIONS - Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. SOL-POL Section 9 Physical and Chemical Properties PRODUC WIGH See ABL VAPORAION RA Slower than ether SPCIFIC GRAVIY VAPOR DNSIY Heavier than air BOILING POIN F MLING POIN Not Available VOLAIL VOLUM 100 % SOLUBILIY IN WAR Not Available Section 10 Stability and Reactivity SABILIY - Stable CONDIIONS O AVOID - None known. INCOMPAIBILIY - None known. HAZARDOUS DCOMPOSIION PRODUCS - By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMRIZAION - Will not occur Section 11 oxicological Information CHRONIC Health Hazards - thylbenzene is classified by IARC as possibly carcinogenic to humans(2b) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. hese effects were not observed in animals exposed to lower concentrations. here is no evidence that ethylbenzene causes cancer in humans. Methyl thyl Ketone may increase the nervous system effects of other solvents. Prolonged overexposure to solvent ingredients in the following products may cause adverse effects to organ systems: Cyclohexanone, Methyl Amyl Ketone liver, urinary K69 hinner liver, urinary, cardiovascular, reproductive R7KB50, R7K216 liver, urinary, blood forming, reproductive K84 hinner, K94 hinner, R7KB29 liver, urinary, blood forming, cardiovascular, reproductive Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Section 12 cological Information Section 13 Disposal Considerations WAS DISPOSAL MHOD - Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable PA hazardous waste numbers. Waste from products containing Methyl thyl Ketone may also require extractability testing. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Section 14 ransport Information Section 15 Regulatory Information CALIFORNIA PROPOSIION 65 - WARNING: hese products, except for Cyclohexanone, Methyl Amyl Ketone and R7KB50, contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SCA CRIFICAION - All chemicals in these products are listed, or are exempt from listing, on the SCA Inventory. Section 16 Other Information hese products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. he above information pertains to these products as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to these products may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information. 6