1. Identification of the substance/preparation and the company/undertaking

Transcription

1 MSDS number Revision Date Apr Identification of the substance/preparation and the company/undertaking EcoVAE 1608 Manufacturer or supplier's details Celanese (Shanghai) International Trading Co., Ltd. Room 239, Xinmao Building South Taizhong Road Waigaoqiao Free Trade Zone Shanghai, China Celanese Pte Ltd 138 Robinson Road #17-00 Singapore (068906) Product Information Emergency telephone number In China Emergency Phone Number: (NRCC) End Use: Industrial use 2. Hazards identification Signal Word Statements of Hazard No labeling requirement under GHS. Not a dangerous product according to GHS 3. Composition/Information on ingredients Chemical characterization Water-borne polymer emulsion. Basis: Vinyl acetate Ethylene plasticizer-free Remarks For the full text of the R-phrases mentioned in this Section, see Section First aid measures 1 of 6

2 4. First aid measures General Information Remove contaminated, soaked clothing immediately and dispose of safely. Skin Wash off with soap and water. If symptoms persist, call a physician. Eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately. Inhalation Move to fresh air. If symptoms persist, call a physician. Ingestion If swallowed, seek medical advice immediately and show this container or label. If conscious, drink plenty of water. Do not induce vomiting without medical advice. 5. Fire-fighting measures Suitable extinguishing media Foam, Dry powder, Carbon dioxide (CO2), Water spray Extinguishing media which must not be used for safety reasons Do not use a solid water stream as it may scatter and spread fire. Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases Under conditions giving incomplete combustion, hazardous gases produced may consist of carbon monoxide carbon dioxide (CO2) Combustion gases of organic materials must in principle be graded as inhalation poisons Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Environmental precautions Dike and collect water used to fight fire. Other Information This is a water-based product and presents no particular fire or explosion hazard 6. Accidental release measures Personal precautions Contaminated surfaces will be extremely slippery. Avoid contact with the skin and the eyes. Environmental precautions Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system. 2 of 6

3 Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Contaminated equipment (brushes, rags) must be cleaned immediately with water. Dispose of in accordance with local regulations. Additional information Consult trained personnel. Consider the information for "Personal Protection" in chapter 8 of this Safety Data Sheet. 7. Handling and storage Handling Storage Hygiene measures Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use. Advice on safe handling Product may contain hazardous volatile ingredients which could accumulate in the unvented headspace of drums or containers. Open containers in ventilated area. Do not breathe vapor. During longer storage small amounts of carbon monoxide may form. To the best of our knowledge, no OEL (occupational exposure limit) is exceeded during the intended use.. Containers/tanks may only be entered after thoroughly executed ventilation while considering national regulations and international standards for inspection of containers/tanks. In any case of doubt a measurement of the CO concentration is necessary. Incompatible products No special restrictions on storage with other products Protection - fire and explosion: No special protective measures against fire required. Material storage Protect from frost. To maintain product quality, do not store in heat or direct sunlight. Keep at temperatures between 5 and 35 C (40 and 95 F). Incompatible products No special restrictions on storage with other products Technical measures/storage conditions Keep tightly closed in a dry and cool place. No special technical protective measures required. German storage class 12: Non-combustible liquids 8. Exposure controls / personal protection ACGIH Exposure Limits No exposure limits established. 3 of 6

4 MSDS number Revision Date Apr Exposure controls Engineering measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Personal protective equipment General advice Hygiene measures Eye protection Hand protection Avoid contact with skin and eyes. Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash contaminated clothing before re-use. safety glasses Chemicals resistant gloves Suitable material nitrile rubber Type Nitril (Company KCL) or comparable article; or refer to glove manufacturer's recommendation Evaluation according to EN 374: level 6 Material thickness approx. 0.1 / 0.4 mm Break through time > 480 min Environmental exposure controls Do not discharge into the drains/surface waters/groundwater Environmental Precautions Should not be released into the environment 9. Physical and chemical properties Appearance Form Color Odor liquid milky white sweet ph Method ISO 976 Viscosity C Method Brookfield Visc. RVT Sp. 4 / 20 r.p.m. Vapor pressure C Water solubility miscible Remarks The product was not tested for properties not listed on the MSDS Stability and reactivity Reactivity Stable under recommended storage conditions 4 of 6

5 Chemical Stability Possibility of hazardous reactions Conditions to avoid Incompatible Materials Hazardous decomposition products No decomposition if stored and applied as directed. No hazards to be especially mentioned. Do not freeze. Materials that react with water No decomposition if stored and applied as directed 11. Toxicological information Toxicological data are not available. Observe the usual hygienic measures for handling chemicals. 12. Ecological information Ecotoxicological data are not available. According to experience, the material has no harmful effect on the environment. 13. Disposal considerations Product information Disposal required in compliance with all waste management related state and local regulations. The choice of the appropriate method of disposal depends on the product composition by the time of disposal as well as the local statutes and possibilities for disposal Diluted solution may be introduced into a biological purification plant, with permission of the responsible authorities Uncleaned empty packaging Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse Regulations concerning reuse or disposal of used packaging materials must be observed. 14. Transport information US Department of Transportation Not regulated ADR/RID ADN Not regulated Not regulated ICAO/IATA IMDG Not restricted Not regulated 5 of 6

6 15. Regulatory information 16. Other information Prepared By Product Stewardship Department Celanese For further information, see: For more information, consult the Technical Data Sheet ( Other Information: Traces of residual monomers can be found in the product:. Vinyl acetate. Changes against the previous version are marked by *** Sources of key data used to compile the datasheet Information contained in this safety data sheet is based on Celanese owned data and public sources deemed valid or acceptable. The absence of data elements required by ANSI or 1907/2006/EC indicates that no data meeting these requirements is available. Further information This information is based on our present state of knowledge. It shall describe our products regarding safety requirements and shall not be construed as a guarantee or statement of condition and/or quality 6 of 6