1. Substance/preparation and manufacturer/supplier identification

Transcription

1 Safety data sheet Page: 1/12 1. Substance/preparation and manufacturer/supplier identification Efka FA 4663 (old Texaphor 963) Use: dispersing agent Manufacturer/supplier: PT BASF Indonesia Plaza GRI, 10th & 11th Floor Jl. H.R. Rasuna Said Blok X-2 No.1 Jakarta Selatan 12950, P.O. Box 2431 Gbr., Jakarta 10024, INDONESIA Telephone: / Telefax number: / Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Flammable liquid: Cat. 4 Skin corrosion/irritation: Cat. 2 Skin sensitization: Cat. 1B Specific target organ toxicity single exposure: Cat. 3 (Vapours may cause drowsiness and dizziness.) Specific target organ toxicity repeated exposure (Digestive system, Liver, Immune system): Cat. 2 Hazardous to the aquatic environment - acute: Cat. 1 Hazardous to the aquatic environment - chronic: Cat. 1 Label elements and precautionary statement: Pictogram:

2 Page: 2/12 Signal Word: Warning Hazard Statement: Combustible liquid. Causes skin irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. May cause damage to organs (Digestive system, Liver, Immune system) through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): Wear protective gloves and eye/face protection. Avoid release to the environment. Use only outdoors or in a well-ventilated area. Do not breathe dust/gas/mist/vapours. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Contaminated work clothing should not be allowed out of the workplace. Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (on hair): Wash with plenty of soap and water. Collect spillage. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use (...) for extinction. Precautionary Statements (Storage): Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Preparation based on: amine salt, hydrocarbon solvent Hazardous ingredients naphthalene Content (W/W): >= 0 % - < 1 % CAS Number: Acute Tox.: Cat. 4 (oral) Carc.: Cat. 2 Aquatic Acute: Cat. 1 Aquatic Chronic: Cat. 2 M-factor acute: 1 M-factor chronic: 1 1,2,4-trimethylbenzene

3 Page: 3/12 Content (W/W): >= 0.3 % - < 3 % CAS Number: Flam. Liq.: Cat. 3 Acute Tox.: Cat. 4 (Inhalation - vapour) Acute Tox.: Cat. 5 (oral) Skin Corr./Irrit.: Cat. 2 Eye Dam./Irrit.: Cat. 2A STOT SE: Cat. 3 (irr. to respiratory syst.) Aquatic Acute: Cat. 2 Aquatic Chronic: Cat. 2 Fatty acids, C18-unsatd., dimers, compds. with coco alkylamines Content (W/W): >= 50 % - < 75 % Skin Corr./Irrit.: Cat. 2 CAS Number: Skin Sens.: Cat. 1B STOT RE (Digestive system, Liver, Immune system): Cat. 2 (oral) Aquatic Acute: Cat. 1 Aquatic Chronic: Cat. 1 Solvent naphtha (petroleum), heavy arom. Content (W/W): >= 25 % - < 50 % CAS Number: Asp. Tox.: Cat. 1 STOT SE: Cat. 3 (drowsiness and dizziness) Aquatic Acute: Cat. 2 Aquatic Chronic: Cat First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Rinse mouth immediately and then drink plenty of water, seek medical attention. Note to physician: Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

4 Page: 4/12 5. Fire-Fighting Measures Suitable extinguishing media: water spray, dry powder, foam Unsuitable extinguishing media for safety reasons: water jet Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Breathing protection required. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling No special measures necessary provided product is used correctly. Protection against fire and explosion: Take precautionary measures against static discharges. Storage Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Protect from temperatures below: 5 C Protect from temperatures above: 35 C

5 Page: 5/12 8. Exposure controls and personal protection Components with occupational exposure limits naphthalene, ; TWA value 10 ppm (ACGIHTLV) STEL value 15 ppm (ACGIHTLV) Skin Designation (ACGIHTLV) The substance can be absorbed through the skin. STEL value 15 ppm (OEL (ID)) TWA value 10 ppm (OEL (ID)) 1,2,4-trimethylbenzene, ; TWA value 25 ppm (ACGIHTLV) TWA value 123 mg/m3 ; 25 ppm (OEL (ID)) Personal protective equipment Respiratory protection: Respiratory protection in case of vapour/aerosol release. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): fluoroelastomer (FKM) mm coating thickness Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

6 Page: 6/12 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: ph value: Freezing point: Boiling point: liquid brownish solvent-like Not determined due to potential health hazard by inhalation. Flash point: 68 C Evaporation rate: Flammability (solid/gas): not highly flammable Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Self ignition: Temperature: > 430 C not self-igniting Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: < 1.00 mbar (23.0 C) Density: approx g/cm3 (20 C) Relative density: (20 C) Relative vapour density (air): (ISO ) Solubility in water: insoluble (20 C) Hygroscopy: Non-hygroscopic Solubility (qualitative) solvent(s): organic solvents insoluble, soluble

7 Page: 7/12 Partitioning coefficient n-octanol/water (log Pow): not applicable for mixtures Surface tension: Viscosity, dynamic: 1,200-1,500 mpa*s (20 C) (DIN 53019) 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: None known during use and storage if used according to instructions. Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity LD50 rat (oral): > 2,000 mg/kg LC50 rat (by inhalation): 4 h LD50 rat (dermal): > 5,000 mg/kg LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 423) LD50 rat (dermal): > 5,000 mg/kg (OECD Guideline 402)

8 Page: 8/12 Irritation Skin corrosion/irritation rabbit: Irritant. Serious eye damage/irritation rabbit: non-irritant Skin corrosion/irritation In vitro assay: Irritant. (OECD Guideline 431) Serious eye damage/irritation In vitro assay: non-irritant (OECD Guideline 437) Respiratory/Skin sensitization Mouse Local Lymph Node Assay (LLNA) mouse: skin sensitizing mouse: skin sensitizing (OECD Guideline 442B) Germ cell mutagenicity Assessment of mutagenicity: No data available concerning mutagenic effects. Carcinogenicity Assessment of carcinogenicity: Reproductive toxicity Assessment of reproduction toxicity: Developmental toxicity Assessment of teratogenicity: Specific target organ toxicity (single exposure):

9 Page: 9/12 Remarks: Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product may cause damage to the immune system after repeated oral/dermal/inhalative uptake. The substance may cause damage to the liver after repeated ingestion. Damages the gastrointestinal tract. The product has not been tested. The statement has been derived from the properties of the rat oral unspecified (OECD Guideline 407) NOAEL: 12.5 mg/kg Aspiration hazard No aspiration hazard expected. Other relevant toxicity information Assessment indicates this product through repeated exposure may cause skin dryness or cracking 12. Ecological Information Ecotoxicity Toxicity to fish: LC50 (96 h) > mg/l, Fish Aquatic invertebrates: LC50 (48 h) < 1 mg/l, daphnia Aquatic plants: EC50 < 1 mg/l Microorganisms/Effect on activated sludge: EC50 (0.5 h), bacteria Chronic toxicity to fish: Chronic toxicity to aquatic invertebrates:

10 Page: 10/12 Toxicity to fish: LC50 (96 h) 55 mg/l, Fish (OECD 203; ISO 7346; 84/449/EEC, C.1) Aquatic invertebrates: EC50 (48 h) < 1 mg/l, daphnia (OECD Guideline 202, part 1) Aquatic plants: EC50 (72 h) 0.39 mg/l, algae (OECD Guideline 201) Microorganisms/Effect on activated sludge: EC10 (30 min) 1,800 mg/l, bacteria (DIN Part 27 (draft)) EC10 (30 min) 1,000 mg/l, bacteria (DIN Part 27 (draft)) Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity. Mobility Assessment transport between environmental compartments: Persistence and degradability Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria). The product has not been tested. The statement has been derived from the properties of the Bioaccumulation potential Assessment bioaccumulation potential: The product has not been tested. Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations.

11 Page: 11/12 Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA) Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: Proper shipping name: YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: Proper shipping name: 9, EHSM ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains SOLVENT NAPHTHA) 15. Regulatory Information Regulations of the European union (Labelling) Directive 1999/45/EC ('Preparation Directive'): Hazard symbol(s) N Xn Dangerous for the environment. Harmful. R-phrase(s)

12 Page: 12/12 R38 Irritating to skin. R43 May cause sensitization by skin contact. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. R67 Vapours may cause drowsiness and dizziness. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S23.3 Do not breathe vapour/spray. S24 Avoid contact with skin. S37 Wear suitable gloves. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Hazard determining component(s) for labelling: Fatty acids, C18-unsatd., dimers, compds. with coco alkylamines, Solvent naphtha (petroleum), heavy arom. Other regulations 16. Other Information Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.