Material Safety Data Sheet

Transcription

1 Number : W525A090525A Revision : 1.00 Date : 25/06/2003 Replace : / / F+ - Extremely flammable Xi - Irritant N - Dangerous for the environment 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Type of product and use: Synthetic lubricant. Company identification: WYNN'S BELGIUM N.V. Industriepark West 46 B-9100 Sint-Niklaas tel: INT fax: INT Emergency phone Nr.: BIG 32.(0)14/ COMPOSITION/INFORMATION ON INGREDIENTS Composition: Hazardous component(s): Solution of silicone and perfume in petroleumdistillates. naphtha (petroleum), hydrotreated light (CAS / EINECS ) wt%: >50 Symb: F/Xn/N R: 11,38,51/53,65,67 butane (CAS / EINECS ) wt%: Symb: F+ R: 12 propane (CAS / EINECS ) wt%: Symb: F+ R: HAZARDS IDENTIFICATION Important hazards-fire: Important hazards-toxicity: Important hazards-chemical reactions: Environmental hazards: Extremely flammable. In use, may form flammable/explosive vapour-air mixture. Pressurized container. Aerosol may explode under the effect of heat. Irritating to skin. Vapours may cause drowsiness and dizziness. No data available. May cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Using proper respiratory protection, immediately remove the affected victim from exposure. Remove to fresh air. In case of loss of consciousness, give artificial respiration. Remove contaminated clothing. Wash thoroughly with soap and water. In case of burns immediately cool affected skin as long as possible with cold water. If inflammation or irritation persists, seek medical advice. Continue rinsing for at least 10 minutes. Publication Date : Number : W525A090525A Page : 1 / 5 Pollux6

2 Ingestion: If inflammation or irritation persists, seek medical advice. If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. Seek medical advice. 5. FIRE-FIGHTING MEASURES Extinguishing media: - Suitable: Carbon dioxide, dry chemicals, foam (AFFF/ATC), water spray (fog). - Not to be used: Water jet. Special exposure hazards: Fumes, smoke, carbon dioxide (CO2), carbon monoxide (CO) (Toxic). Heating will cause pressure rise, severe risk of bursting and explosion. Bursting aerosols can be forcibly projected from a fire. Special protective equipment for fire Full protective clothing and self-containing breathing apparatus. fighters: 6. ACCIDENTAL RELEASE MEASURES Personal precautions: In case of insufficient ventilation, use face mask with breathing filter, type: A (ABEK) Ensure good ventilation. Methods for cleaning up: - On soil: Remove sources of ignition. Keep public away. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Absorb small spills on dry chemical absorbent. - On water: Remove sources of ignition. Obtain expert chemical advice. 7. HANDLING AND STORAGE Handling: Do not breathe vapour. Avoid contact with skin and eyes. Do not smoke. Ensure good ventilation. DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Do not spray on a naked flame or any incandescent material. Storage: Avoid contact with strong acids and oxidizers. Store at temperatures below 50 C Store in dry, cool, well ventilated area. Packaging: - General: Do not pierce or burn, even after use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Recommended engineering controls: The use of local exhaust ventilation is recommended to control process emissions near the source. Provide mechanical ventilation of confined spaces. Arrange for eye wash possibility. Publication Date : Number : W525A090525A Page : 2 / 5

3 Occupational Threshold limit values (TLV): recommendations total hydrocarbons based on compostition: 100 ppm Personal protection: - Respiratory protection: Ensure good ventilation. - Skin and hand protection: Handle in accordance with good industrial hygiene and safety procedures. Appropriate protective clothing and gloves Nitrile, Neoprene, - Not to be used: Natural rubber, - Eye protection: Safety goggles/visor. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and chemical properties of the active product without gas. These are indicative values only. Please refer also to the product specification sheet. Appearance: Liquid. Odour: naphtha Characteristic. ph : Not applicable. Boiling point: C Melting point: <-20 C Flash point: -18 C Vapour pressure at 20 C: 4.20 hpa Density at 20 C: 729 kg/m³ Solubility in water: Negligible. Oxidising properties: Partition coefficient (P o/w): Pour point: 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Stable in normal conditions of use. Store away from direct sunlight. Store at temperatures below 50 C Avoid contact with strong acids and oxidizers. Carbon monoxyde vapors emitted in due case of incomplete combustion of the product. 11. TOXICOLOGICAL INFORMATION (Based on test with similar products). (Refers to active component). No toxicological information available. Oral LD50 (rat): Dermal LD50 (Rabbit): Inhalation LC50 (Rat/4h): Skin contact: Eye contact: Moderately irritating. Moderately irritating. Publication Date : Number : W525A090525A Page : 3 / 5

4 Inhalation: Ingestion: Skin sensitization test: Mutagenicity and Carcinogenicity: May cause loss of consciousness or other central nervous system effects. Irritating to eyes and respiratory system. May cause nausea, dizziness. Minimal toxicity. Data not available. 12. ECOLOGICAL INFORMATION Mobility: This substance is highly volatile and will rapidly evaporate to the air if released into the environment. Degradability: Based upon data for a similar substance or estimated data. This substance is expected to biodegrade rapidly. This substance is expected to be removed in a wastewater treatment facility. Ecotoxicity and bioaccumulation: Expected to be toxic to aquatic organisms. WGK class (Germany): DISPOSAL CONSIDERATIONS Disposal of product: Disposal of packaging: This product is not suitable for disposal by either landfill or via municipal sewers, drains, natural streams or rivers. Dispose of in a safe manner, in accordance with local regulations. Dispose of in a safe manner, in accordance with local regulations. 14. TRANSPORT INFORMATION UN 1950 Proper shipping name: Aerosol --ADR/RID: LQ2 Class: 2, 5F Label: MARITIME TRANSPORT (IMO-IMDG): LQ=1L Klasse: 2.1 EMS: F-D, S-U Marine Pollutant: / --AIR TRANSPORT (CAO/IATA): Class: 2.1 Packing instructions: REGULATORY INFORMATION EEC labelling information: Classification and labelling according to the directives 67/548/EEG and 1999/45/EG. Directive 2001/59/EG: Substances classified as harmful on the basis of an aspiration hazard need not be labelled as harmful with R65 when placed on the market in aerosol containers or in containers fitted with a sealed spray attachment. - Symbol(s): Extremely flammable: F+. Irritant: Xi. Dangerous for the environment: N Publication Date : Number : W525A090525A Page : 4 / 5

5 - R Phrase(s): R 12: Extremely flammable. R 38: Irritating to skin. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 67: Vapours may cause drowsiness and dizziness. - S Phrase(s): Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. Without adequate ventilation formation of explosive mixtures may be posssible. S 23.2: Do not breathe vapour. S 23.4: Do not breathe spray. S 24: Avoid contact with skin. S 51: Use only in well-ventilated areas. S 57: Use appropriate containment to avoid environmental contamination. 16. OTHER INFORMATION Sources of key data used: Raw material suppliers'data sheets were used as key data sources in the preparation of this safety data sheet. Nature of revision: Correction in Section: 2,7,8,9,11,15,16 Text of R phrases mentioned in Section 2 R 11: Highly flammable. R 12: Extremely flammable. R 38: Irritating to skin. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 65: Harmful, may cause lung damage if swallowed. R 67: Vapours may cause drowsiness and dizziness. This safety data sheet has been made in accordance with the directives 91/155/EEG, 93/112/EEG and 2001/58/EG. It completes the technical directions for use, but does not replace it. The data mentioned on these documents are to our knowledge correct on the date of publication and are provided on the assumption that the product will be used as indicated by the manufacturer/supplier. The indication of these safety data, without being considered as complete, helps the user to fulfil his obligations with regard to dangerous substances. The user is obliged to evaluate the product and use it in a safe way in compliance with the effective laws and stipulations. The user has to make sure that all regulations as to human and environmental protection during handling, storage and use of the products are observed. Publication Date : Number : W525A090525A Page : 5 / 5