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1 SDS Date: 2/23/2015 Crabgrass Killer Concentrate EPA Reg SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION CAS #: Product Use: Manufacturer: Liquid Mixture Herbicide Concentrate Chemsico St. Louis, MO SECTION 2 - HAZARDS IDENTIFICATION This product is classified according to the Globally Harmonized System (GHS). ROUTES OF EXPOSURE Page 1 Potential short term health effects: Eyes, Ingestion Eyes: Skin: Inhalation: Ingestion: Target organs: Chronic effects: Signs and symptoms: Composition comments: Causes moderate eye irritation. expected reaction. expected reaction. Harmful if swallowed Eyes, Digestive system SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, edema, drying, defatting and cracking of the skin. This product is considered not hazardous under 29 CFR (Hazard Communication). NOTE: reportable quantities of hazardous ingredients are present per OSHA 29 CFR toxic chemical(s) subject to reporting requirements of Section 313 of Title III and 40 CFR 372 are present. ACTIVE COMPONENT CAS# PERCENTAGE 2,4-D, dimethylamine salt Quinclorac Dicamba, dimethylamine salt Sulfentrazone OTHER COMPONENT CAS# PERCENTAGE Other N/A 93.82

2 te: Ingredients not identified are not hazardous. SECTION 4 - FIRST AID MEASURES FIRST AID PROCEDURES Eye contact: Skin contact: Inhalation: Ingestion: te to Physician: General advice: Hold eye open and rinse slowly and gently with water for minutes. Remove contacts, if present, after the first 5 minutes, then continue rinsing eye. Call a Poison Control Center or doctor for treatment advice. ne required ne required Call a Poison Control Center or doctor immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a doctor. Do not give anything by mouth to an unconscious person. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Keep out of reach of children. SECTION 5 - FIRE FIGHTING MEASURES Flammable properties: SUITABLE EXTINGUISHING MEDIA Extinguishing media: Unsuitable extinguishing media: t flammable by OSHA criteria. Water Fog, Foam, CO 2, Dry Chemical SPECIFIC HAZARDS ARISING FROM THE CHEMICAL Protection of firefighters: Protective equipment for firefighters: Hazardous combustion products: SENSITIVITY TO MECHANICAL IMPACT Explosion data: Sensitivity to static discharge: Personal precautions: Firefighters should wear full protective clothing including self-contained breathing apparatus. ne known Keep unnecessary personnel away. Do not touch or walk through spilled material. HMIS Ratings Health Hazard 1 Fire Hazard 0 Reactivity 0 Page 2

3 SECTION 6 - ACCIDENTAL RELEASE MEASURES Methods for containment: Methods for cleaning up: Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with earth, sand or absorbent material swept up and placed in suitable, covered, and labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. SECTION 7 - HANDLING AND STORAGE Handling: Storage: Use good industrial hygiene practices in handling this material. Keep out of reach of children. Store in a closed container away from incompatible materials. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: EYE / FACE PROTECTION Personal protective equipment: Hand protection: Skin and body protection: Respiratory protection: General hygiene considerations: General ventilation normally adequate. ne required ne required ne required ne required Handle in accordance with good industrial hygiene and safety practice. When using, do not eat or drink. Wash hands before breaks and immediately after handling the product. SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Appearance: Clear Color: Tan to dark brown Form: Liquid Odor: Amine odor Odor threshold: Physical state: Liquid ph: 6.5 Freezing point: 32 F Page 3

4 Boiling point: 212 F Flash point: Evaporation rate: Flammability limits in air, lower, % by volume: Flammability limits in air, upper, % by volume: Vapor pressure: Vapor density: >200 0 F Specific gravity: 1.03 Octanol/water coefficient: Auto-ignition temperature: Chemical stability: Conditions to avoid: Incompatible materials: Estimated slower than water SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION Stable under recommended storage conditions. Do not mix with other chemicals. Avoid strong oxidizers. Hazardous decomposition products: ne known Possibility of hazardous reactions: SECTION 11 - TOXICOLOGICAL INFORMATION Hazardous polymerization does not occur. EFFECTS OF ACUTE EXPOSURE Eye: Skin: Inhalation: Ingestion: Sensitization: Chronic effects/ Carcinogenicity: Mutagenicity: Reproductive effects: Teratogenicity: Ecotoxicity: Causes eye irritation. May cause irritation. Dermal LD 50 > 5000 mg/kg LC 50 > 2mg/L (EPA Tox category IV) LD 50 > 3000 mg/kg t a skin sensitizer. SECTION 12 - ECOLOGICAL INFORMATION Environmental effects: Aquatic toxicity: Persistence / degradability: Page 4

5 Bioaccumulation / accumulation: Partition coefficient: Mobility in environmental media: Chemical fate information: SECTION 13 - DISPOSAL CONSIDERATIONS Waste codes: Disposal instructions: Waste from residues / unused products: Contaminated packaging: Dispose in accordance with all applicable regulations. SECTION 14 - TRANSPORTATION INFORMATION U.S. Department of Transportation (DOT): U.S. Federal regulations: IATA: IMDG: t regulated as dangerous goods. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. t Regulated t Regulated SECTION 15 - REGULATORY INFORMATION 29 CFR hazardous chemical Occupational Safety and Health Administration (OSHA): CERCLA (Superfund) reportable quantity: HAZARD CATEGORIES Superfund Amendments and Reauthorization Act of 1986 (SARA): Immediate Hazard Delayed Hazard Fire Hazard Pressure Hazard Reactivity Hazard Section 302 extremely hazardous Substance: Section 311 hazardous chemical: Clean Air Act (CAA): Page 5

6 Clean Water Act (CWA): State regulations: INVENTORY STATUS Inventory Country(s) or region name on inventory (yes/no)*: Disclaimer: N/A, Regulated by EPA Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. SECTION 16 - OTHER INFORMATION Issue date: 02/23/15 Prepared by: United Industries Corp. (800) Page 6

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