The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
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1 The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 14 Refrigerant 2007FR Revised 7-JAN-1997 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification "FREON" is a registered trademark of DuPont. Corporate MSDS Number Formula : DU : CF4 Company Identification MANUFACTURER/DISTRIBUTOR DuPont Fluoroproducts 1007 Market Street Wilmington, DE PHONE NUMBERS Product Information : (outside the U.S ) Transport Emergency : CHEMTREC (outside U.S ) Medical Emergency : (outside the U.S ) COMPOSITION/INFORMATION ON INGREDIENTS Components Material CAS Number % TETRAFLUOROMETHANE ("FREON" 14 REFRIGERANT) 100 HAZARDS IDENTIFICATION Potential Health Effects Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness, or death. Intentional misuse can be fatal. Vapor reduces oxygen available for breathing and is heavier than air. Liquid contact causes frostbite. HUMAN HEALTH EFFECTS Overexposure by inhalation may include temporary central nervous system depression with such effects as dizziness, headache, confusion, incoordination, and loss of consciousness; or with gross overexposure (>20%), temporary
2 2007FR DuPont Page 2 (HAZARDS IDENTIFICATION - Continued) alteration of the heart s electrical activity with irregular pulse, palpitations or inadequate circulation. Eye or skin contact with the liquid may cause frostbite. Individuals with preexisting diseases of the central nervous or cardiovascular systems may have increased susceptibility to the toxicity of excessive exposures. Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. FIRST AID MEASURES First Aid INHALATION Immediately remove to fresh air. Keep persons calm. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT Treat for frostbite. Seek medical assistance. EYE CONTACT Immediately flush eyes with plenty of water. Call a physician. Notes to Physicians Because of possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution only in situations of emergency life support. FIRE FIGHTING MEASURES Flammable Properties Flash Point : Will not burn Flammable limits in Air, % by Volume LEL : Not applicable UEL : Not applicable Autoignition : >1100 C (>2012 F)
3 2007FR DuPont Page 3 Fire and Explosion Hazards: (FIRE FIGHTING MEASURES - Continued) Cylinders are equipped with pressure and temperature relief devices but may still rupture under fire conditions. Extinguishing Media As appropriate for combustibles in the area. Fire Fighting Instructions Use water spray or fog to cool container. Self-contained breathing apparatus (SCBA) is required if cylinders rupture or release under fire conditions. ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Accidental Release Measures Ventilate area - especially low places where heavy vapors might collect. Remove open flames. For large releases, wear self-contained breathing apparatus (SCBA). HANDLING AND STORAGE Handling (Personnel) Avoid breathing vapors and contact with eyes and skin. Use with sufficient ventilation to keep employee exposure below recommended limits. Storage Store in clean, dry area. Do not heat above 52 C (125 F). EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should be used when large amounts are released. Mechanical ventilation should be used in low places.
4 2007FR DuPont Page 4 (EXPOSURE CONTROLS/PERSONAL PROTECTION - Continued) Personal Protective Equipment Lined neoprene gloves should be used when transferring gas. Under normal manufacturing conditions no respiratory protection is required when using this product. Self-contained breathing apparatus (SCBA) is required if a large release occurs. Exposure Guidelines Exposure Limits "FREON" 14 Refrigerant PEL (OSHA) : None Established TLV (ACGIH) : None Established PHYSICAL AND CHEMICAL PROPERTIES Physical Data Boiling Point : C ( F) Vapor Pressure : C (-50.1 F) Critical Temperature (-50 degf) Critical Temp Vapor Density : 3.03 (Air=1.0) % Volatiles : 100 WT% Solubility in Water : C (77 F) Odor : None Form : Compressed gas Color : Clear, colorless Liquid Density : C (-112 F) STABILITY AND REACTIVITY Chemical Stability Material is stable. However, avoid open flames and high temperatures. Incompatibility with Other Materials Incompatible with alkali or alkaline earth metals - powdered A1, Zn, Be, etc. Decomposition "FREON" 14 Refrigerant decomposes at high temperatures (open flames, glowing metal surface, etc.) forming hydrofluoric acid. Polymerization Polymerization will not occur.
5 2007FR DuPont Page 5 TOXICOLOGICAL INFORMATION Animal Data Inhalation 15 minute ALC: 895,000 ppm in rats. Effects observed in animals from exposure by inhalation to concentrations of >89%, v/v include central nervous system depression and death. Exposure by inhalation at concentrations as high as 22.4% resulted in no observed adverse effects. No animal test reports are available to define carcinogenic, mutagenic, embryotoxic, or reproductive hazards. DISPOSAL CONSIDERATIONS Waste Disposal Comply with Federal, State, and Local regulations. Reclaim by distillation or remove to permitted waste disposal facility. TRANSPORTATION INFORMATION # Shipping Information DOT/IMO/IATA Proper Shipping Name : TETRAFLUOROMETHANE, COMPRESSED Hazard Class : 2.2 UN No. : 1982 Shipping Label : Nonflammable Gas Shipping Containers: Cylinders REGULATORY INFORMATION U.S. Federal Regulations TSCA Inventory Status : Reported/Included. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute : Yes Chronic : No Fire : No Reactivity : No Pressure : Yes
6 2007FR DuPont Page 6 (REGULATORY INFORMATION - Continued) LISTS: Extremely Hazardous Substance - No CERCLA Hazardous Substance - No Toxic Chemicals - No OTHER INFORMATION NFPA, NPCA-HMIS NPCA-HMIS Rating Health : 1 Flammability : 0 Reactivity : 1 Personal Protection rating to be supplied by user depending on use conditions. The data in this relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS : MSDS Coordinator > : DuPont Fluoroproducts Address : Wilmington, DE Telephone : (800) # Indicates updated section. This information is based upon technical information believed to be reliable. It is subject to revision as additional knowledge and experience is gained. End of MSDS
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 14 Refrigerant 2007FR Revised
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 500 Refrigerant 2012FR Revised
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 114 3038FR Revised 7-JAN-1997
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 12 2022FR Revised 7-OCT-1996
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 FE-13 3017FR Revised 6-APR-2004 CHEMICAL
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 12 2022FR Revised 19-APR-2004
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "DYMEL" 152a Aerosol Propellant/Isobutane
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 12/"FREON" 114 Fluorocarbon
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 23 2025FR Revised 4-NOV-2002
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 FE-25 3016FR Revised 25-JUN-2002 CHEMICAL
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FORMACEL" Z-2 BLOWING AGENT 3024FR
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "DYMEL" A Aerosol Propellant/Isobutane
Du Pont Material Safety Data Sheet
Page 1 "SUVA" 95 CEFS0095 Revised 9-Mar-11 Printed 03/09/2011 Substance ID :130000000550 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification Corporate MSDS Number : DU008080 Product Use Refrigerant
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "DYMEL" A Aerosol Propellant/A-46 Blend
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 500 Refrigerant 2012FR Revised
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 22 2008FR Revised 5-OCT-1996
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 502 Refrigerant 2075FR Revised
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The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
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Material Safety Data Sheet Revised: 04/22/08
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The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "SUVA" 134a AUTO 2188FR Revised 18-APR-2007
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries.
The MSDS format adheres to the standards and regulatory requirements of the United States and may not meet regulatory requirements in other countries. DuPont Page 1 "FREON" 11 2090FR Revised 27-JUN-2005
The MSDS format adheres to the standards and regulatory requirements of Canada and may not meet regulatory requirements in other countries.
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4. FIRST AID MEASURES
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