White to light tan crystalline solid.

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1 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Synonyms: furoic acid, 2-furan carboxylic acid QO 2-furoic acid Manufacturer s Name and Address: Penn A Kem 3324 Chelsea Avenue Memphis, TN Emergency Number, if inside US: Emergency Number, if outside US: (901) (877) SECTION 2: Composition/Information on Ingredients CAS NO.: EINECS/ELINCS: Chemical Name: 2-furoic acid Molecular Weight: 112. Chemical Formula: C 5 H 4 O 3 Percent: % Note: SECTION 3: Hazards Identification Emergency Overview: Potential Health Effects: Eye: Ingestion: Inhalation: Chronic: Target Organs: White to light tan crystalline solid. May cause eye irritation. May cause skin irritation. May cause irritation of the digestive tract. May cause respiratory tract irritation. No information found. No information found. Note: May cause eye and skin irritation. May cause respiratory and digestive tract irritation. The toxicological properties of this material have not been fully investigated. SECTION 4: First Aid Measures Eyes: Ingestion: Inhalation: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Note to Physician: Treat symptomatically and supportively. Page 1 of 5

2 SECTION 5: Fire Fighting Measures General Information: Extinguishing Media: As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Flash Point: >140F Auto ignition Temperature: Explosion limits, Lower: Upper: NFPA Rating: (estimated) Health: 1; Flammability: 1; Instability: 1 SECTION 6: Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Pick up spill and place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. SECTION 7: Handling and Storage Handling: Storage: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. SECTION 8: Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits: Chemical name: ACGIH: NIOSH: OSHA Final PELS Page 2 of 5

3 SECTION 8: Exposure Controls, Personal Protection Cont d Personal Protective Equipment: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Clothing: Respirators: Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. A respiratory protection program that meets OSHA's 29 CFR and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. SECTION 9: Physical and Chemical Properties Physical State: Solid, crystals Appearance: White to tan to light brown color. Odor: No odor. Dust can irritate mucous membrane of the nose. ph: Not available for the solid. Dissolved in water, ph is approximately 2. Vapor Pressure: Vapor Density: 4. Evaporation Rate: Viscosity: Boiling Point: 231 C, material can sublime Freezing/Melting Point: 133 C.. Decomposition Temperature: Solubility: Water, ethanol, acetone, tetrahydrofuran. Specific Gravity/Density: Variable. Molecular Formula: C 5 H 4 O 3 Molecular Weight: 112. SECTION 10: Stability and Reactivity Chemical Stability: Conditions to Avoid: Incompatibilities with other Materials: Hazardous Decomposition Products: Hazardous Polymeration: Stable under normal temperatures and pressures. At high temperatures can produce furan and carbon dioxide. Incompatible materials, excess heat, strong oxidants, bases. When dissolved in water, the solution is corrosive. None known. Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Can produce furan at high temperatures. Will not occur. SECTION 11: Toxicological Information RTECS#: CAS#: LD50/LC50: Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65. Page 3 of 5

4 Epidemiology: SECTION 11: Toxicological Information Cont d Teratogenicity: Reproductive Effects: Mutagenicity: Neurotoxicity: Other Studies: SECTION 12: Ecological Information SECTION 13: Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: RCRA U-Series:.. SECTION 14: Transport Information Shipping Name: Hazard Class: UN Number: Packing Group: Nonhazardous US DOT Shipping Name: Hazard Class: UN Number: Packing Group: International Nonhazardous for international shipment SECTION 15: Regulatory Information TSCA (Toxic Substance Control Act): Listed on the TSCA inventory. TSCA Significant New Use Rule: US FEDERAL: None of the chemicals in this product have SNUR under TSCA. Section 12b: None of the chemicals in this product are listed under TSCA Section 12b. CERLA Hazardous Substances and Corresponding RQs: None of the chemicals in this product have an RQ. SARA Section 302 (Superfund Amendments and Reauthorizations Act): None of the chemicals in this product have a TPQ. Page 4 of 5

5 313 Reportable Ingredients: None of the chemicals are reportable under Section 313. Health & Safety Reporting List: Chemical Test Rules: None of the chemicals are on the Health & Safety Reporting List. None of the chemicals are under a Chemical Test Rule. Clean Act: Clean Water Act: OSHA: US FEDERAL CONT D: This material does not contain any hazardous air pollutants, Class 1 Ozone depletors, or Class 2 Ozone depletors. None of the chemicals in this product are listed as Hazardous Substances, Priority Pollutants, or Toxic Pollutants under the CWA. OSHA considers none of the chemicals in this product highly hazardous. STATE: CAS # is not present on state lists CA, PA, MN, MA, FL, or NJ. California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives: Hazard Symbols: Not Available. Risk Phrases: Safety Phrases: S 24/25, Avoid contact with skin and eyes. S 37, Wear suitable gloves. S 45, In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 28A, In case of skin contact, wash immediately with plenty of water. WGK (Water Danger/Protection): CAS # : Canada DSL/NDSL: This chemical is listed on the DSL list. Canada WHMIS: Canadian Ingredient Disclosure List: None. SECTION 16: Additional Information MSDS Creation Date: 01/10/2011 Revision # 0 Date: The data contained herein is based on information currently available to Penn A Kem, and believed to be factual and the opinions expressed to be those of qualified experts; however, this data is not be taken as a warranty or representation for which Penn A Kem assumes legal responsibility. Page 5 of 5

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