SAFETY DATA SHEET Premisan Plus+

Transcription

1 Revision Date 19/07/2013 Revision 3 Supersedes date 18/06/2013 SAFETY DATA SHEET Premisan Plus+ SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Premisan Plus+ Product No Relevant identified uses of the substance or mixture and uses advised against Identified uses Washroom Cleaner Ready to Use - Disinfectant 1.3. Details of the supplier of the safety data sheet Supplier Premiere Products Oakley Gardens, Bouncers Lane, Cheltenham, GLOS GL52 5JD Fax laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Xi;R36/38. R31. Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Labelling Irritant Risk Phrases Safety Phrases R31 Contact with acids liberates toxic gas. R36/38 Irritating to eyes and skin. S1/2 Keep locked up and out of the reach of children. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice Other hazards This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 7

2 SODIUM HYDROXIDE 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Corr. 1A - H314 Classification (67/548/EEC) C;R35 SODIUM HYPOCHLORITE SOLUTION,... % Cl ACTIVE 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) EUH031 Skin Corr. 1B - H314 Aquatic Acute 1 - H400 Classification (67/548/EEC) C;R34 R31 N;R50 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention. Ingestion Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Get medical attention immediately! Skin contact Promptly wash contaminated skin with water. Promptly remove clothing if soaked through and wash the skin with water. Get medical attention if any discomfort continues. Eye contact Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation May cause respiratory irritation Ingestion May cause stomach pain or vomiting. Skin contact Reddened skin if chemical is not removed by washing. Later, white and wrinkled skin without pain, often with delayed skin burns. Eye contact May cause blurred vision and serious eye damage Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Water. Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters 2 / 7

3 Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground. Collect and dispose of spillage as indicated in section Methods and material for containment and cleaning up Absorb with inert, damp, non-combustible material, then flush area with water Reference to other sections For personal protection, see section 8. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Store at moderate temperatures in dry, well ventilated area. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes SODIUM HYDROXIDE WEL 2 mg/m3 WEL = Workplace Exposure Limit. Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Respiratory equipment None noted. Hand protection Use protective gloves. Eye protection Wear approved safety goggles. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 3 / 7

4 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Initial boiling point and boiling range ( C) Melting point ( C) Clear liquid. Water-white. Chlorine. Soluble in water. Relative density Bulk Density Vapour density (air=1) Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution 13.0 ph-value, Diluted Solution Viscosity Solubility Value (G/100G H2O@20 C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Other Flammability Oxidising properties 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY Premisan Plus Reactivity Generates toxic gas in contact with acid Chemical stability Avoid Contact with acids. 4 / 7

5 10.3. Possibility of hazardous reactions Conditions to avoid Generates toxic gas in contact with acid Incompatible materials Materials To Avoid Strong acids Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Skin Corrosion/Irritation: Extreme ph Respiratory or skin sensitisation: Respiratory sensitisation Skin sensitisation Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: STOT - Single exposure Specific target organ toxicity - repeated exposure: STOT - Repeated exposure Aspiration hazard: 5 / 7

6 Viscosity Inhalation Irritating to respiratory system. Ingestion May cause stomach pain or vomiting. May cause internal injury. Skin contact Strongly irritating. Prolonged contact may cause burns. Eye contact May cause severe irritation to eyes. May cause chemical eye burns. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name 6 / 7

7 14.3. Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health. EU Legislation System of specific information relating to Dangerous Preparations. 2001/58/EC. Dangerous Preparations Directive 1999/45/EC. REGULATION (EU) No 528/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 22 May 2012 concerning the making available on the market and use of biocidal products Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By Revision Date 19/07/2013 Revision 3 Supersedes date 18/06/2013 SDS No. 4 Date 18/6/2013 Risk Phrases In Full R34 R35 R31 R36/38 R50 Hazard Statements In Full H319 H314 H315 EUH031 H400 Causes burns. Health & Safety Officer Causes severe burns. Contact with acids liberates toxic gas. Irritating to eyes and skin. Very toxic to aquatic organisms. Causes serious eye irritation. Causes severe skin burns and eye damage. Causes skin irritation. Contact with acids liberates toxic gas. Very toxic to aquatic life. 7 / 7