Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Date: 05/09/2007 Issue date: 05/09/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite(r) 3873(TM) Adhesive Item No. : Product type: Anaerobic Adhesive Region: United States Company address: Henkel Corporation 1001 Trout Brook Crossing Rocky Hill, Connecticut Contact Information: Telephone: Emergency telephone: Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER mg/m 3 TWA particulate matter containing no asbestos and <1% crystalline silica mg/m³ Total Dust (as Al) 15 mg/m³ TWA total dust 5 mg/m³ TWA respirable fraction 15 mg/m³ Total Dust (as Al) 5 mg/m³ Respirable Dust (as Al) ppm TWA; 3 ppm STEL ppm (ceiling) fiber/cm3 TWA respirable fibers: length > 5 µm, aspect ratio equal to or greater than 3:1, as determined by the membrane filter method at X magnification (4-mm objective), using phase-contrast illumination. 5 mg/m³ TWA inhalable fraction 3. HAZARDS IDENTIFICATION 0.1 mg/m 3 TWA EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 2* Color: Grey FLAMMABILITY: 1 Odor: Mild PHYSICAL HAZARD: 1 Personal Protection: See Section 8 WARNING: Item No. : Product name: Loctite(r) 3873(TM) Adhesive 1 of 5

2 COMBUSTIBLE LIQUID CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause irritation to nose and throat. Irritating to skin. May cause allergic skin reaction. Contact with eyes will cause irritation. May be harmful if swallowed. May cause kidney, liver, lung, or gastrointestinal abnormalities. Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. If symptoms develop and persist, get medical attention. Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if symptoms occur. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Do not induce vomiting. Keep individual calm. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: 73 C (163 F) Pensky Martens closed cup Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Irritating organic vapors. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Ensure adequate ventilation. Soak up with inert absorbent. Store in a partly filled, closed container until disposal. Item No. : of 5 Product name: Loctite(r) 3873(TM) Adhesive

3 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Do not breathe mist or vapors. For safe storage, store at or below 38 C (100 F). Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Incompatible products: Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves. Safety goggles or safety glasses with side shields. See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Grey Odor: Mild Vapor pressure: Less than 5 mm Hg ph: Not applicable Boiling point/range: Greater than 149ºC (300ºF) Melting point/range: Specific gravity: Vapor density: Evaporation rate: Solubility in water: Slight Partition coefficient (n-octanol/water): VOC content: 17.78%; 364 grams/liter (EPA Method 24) 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Stable. Will not occur. Oxides of carbon. Irritating organic vapors. Reducing agents. Free radical initiators. Amines. Peroxides. Heavy metals. Oxidizing agents (strong) Oxygen scavengers. Alkalis. Other polymerization initiators. Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10). 11. TOXICOLOGICAL INFORMATION Carcinogen Status Item No. : of 5 Product name: Loctite(r) 3873(TM) Adhesive

4 Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Suspect Carcinogen Group 2B Yes Literature Referenced Target Organ & Other Health Effects Hazardous components Health Effects/Target Organs Corrosive, Irritant, Nuisance dust Irritant, Lung, Respiratory Allergen, Respiratory 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR): Hazard class or division: International Air Transportation (ICAO/IATA): Hazard class or division: WaterTransportation (IMO/IMDG): Item No. : of 5 Product name: Loctite(r) 3873(TM) Adhesive

5 Hazard class or division: Marine pollutant: 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.. CERCLA/SARA Section 302 EHS: above reporting de minimus. CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). (CAS# ). California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. B.3, D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 2, 11, 15 Prepared by: Kyra Kozak Woods, Manager, Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : of 5 Product name: Loctite(r) 3873(TM) Adhesive

6 Material Safety Data Sheet Revision Date: 05/09/2007 Issue date: 05/09/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: 3873 Adhesive Thermally Conductive Item No. : Product type: Anaerobic Adhesive Region: United States Company address: Henkel Corporation 1001 Trout Brook Crossing Rocky Hill, Connecticut Contact Information: Telephone: Emergency telephone: Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER mg/m 3 TWA particulate matter containing no asbestos and <1% crystalline silica mg/m³ Total Dust (as Al) 15 mg/m³ TWA total dust 5 mg/m³ TWA respirable fraction 15 mg/m³ Total Dust (as Al) 5 mg/m³ Respirable Dust (as Al) ppm TWA; 3 ppm STEL ppm (ceiling) fiber/cm3 TWA respirable fibers: length > 5 µm, aspect ratio equal to or greater than 3:1, as determined by the membrane filter method at X magnification (4-mm objective), using phase-contrast illumination. 5 mg/m³ TWA inhalable fraction 3. HAZARDS IDENTIFICATION 0.1 mg/m 3 TWA EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 2* Color: Grey FLAMMABILITY: 1 Odor: Mild PHYSICAL HAZARD: 1 Personal Protection: See Section 8 WARNING: Item No. : Product name: 3873 Adhesive Thermally Conductive 1 of 5

7 COMBUSTIBLE LIQUID CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause irritation to nose and throat. Irritating to skin. May cause allergic skin reaction. Contact with eyes will cause irritation. May be harmful if swallowed. May cause kidney, liver, lung, or gastrointestinal abnormalities. Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. If symptoms develop and persist, get medical attention. Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if symptoms occur. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Do not induce vomiting. Keep individual calm. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: 73 C (163 F) Pensky Martens closed cup Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Irritating organic vapors. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Ensure adequate ventilation. Soak up with inert absorbent. Store in a partly filled, closed container until disposal. Item No. : of 5 Product name: 3873 Adhesive Thermally Conductive

8 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Do not breathe mist or vapors. For safe storage, store at or below 38 C (100 F). Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Incompatible products: Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves. Safety goggles or safety glasses with side shields. See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Grey Odor: Mild Vapor pressure: Less than 5 mm Hg ph: Not applicable Boiling point/range: Greater than 149ºC (300ºF) Melting point/range: Specific gravity: Vapor density: Evaporation rate: Solubility in water: Slight Partition coefficient (n-octanol/water): VOC content: 17.78%; 364 grams/liter (EPA Method 24) 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Stable. Will not occur. Oxides of carbon. Irritating organic vapors. Reducing agents. Free radical initiators. Amines. Peroxides. Heavy metals. Oxidizing agents (strong) Oxygen scavengers. Alkalis. Other polymerization initiators. Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10). 11. TOXICOLOGICAL INFORMATION Carcinogen Status Item No. : of 5 Product name: 3873 Adhesive Thermally Conductive

9 Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Suspect Carcinogen Group 2B Yes Literature Referenced Target Organ & Other Health Effects Hazardous components Health Effects/Target Organs Corrosive, Irritant, Nuisance dust Irritant, Lung, Respiratory Allergen, Respiratory 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR): Hazard class or division: International Air Transportation (ICAO/IATA): Hazard class or division: WaterTransportation (IMO/IMDG): Item No. : of 5 Product name: 3873 Adhesive Thermally Conductive

10 Hazard class or division: Marine pollutant: 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.. CERCLA/SARA Section 302 EHS: above reporting de minimus. CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). (CAS# ). California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. B.3, D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 2, 11, 15 Prepared by: Kyra Kozak Woods, Manager, Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : of 5 Product name: 3873 Adhesive Thermally Conductive