3.1. Substances Not applicable Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification

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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Other means of identification : Zacsil Solution : Grades: 30, 865, 18, Electronics 200, 865 D, Zacsil AG 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Manufacturing 1.3. Details of the supplier of the safety data sheet Zaclon LLC 2981 Independence Road Cleveland, OH T or Emergency telephone number Emergency number : Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Acute Tox. 4 (Oral) H Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H302 - Harmful if swallowed : P264 - Wash thoroughly after handling P270 - Do not eat, drink or smoke when using this product P301+P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell P330 - If swallowed, rinse mouth P501 - Dispose of contents/container in accordance with local/regional/national/international regulations Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification Water (CAS No) Not classified Potassium silicate (CAS No) Acute Tox. 4 (Oral), H302 02/06/2014 EN (English) Page 1

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Move person to non-contaminated air. If the affected person is not breathing, apply artificial respiration. : Flush skin with water. Remove contaminated clothing and wash before reuse and discard shoes. : Flush with plenty of water for at least 15 minutes. Seek medical advice if irritation develops or persists. : Do not induce vomiting. Immediately give two glasses of water or activated charcoal slurry. Call a physician. Never give anything by mouth to an unconscious person. : May cause respiratory tract irritation. : Prolonged or repeated contact may cause skin irritation. : May cause severe eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Not considered a likely route of exposure under normal product use conditions. May cause gastrointestinal irritation if ingested. : Use appropriate extinguishing media for surrounding fire. : None Special hazards arising from the substance or mixture Fire hazard Explosion hazard 5.3. Advice for firefighters Protection during firefighting : None SECTION 6: Accidental release measures : None known. : Firefighters should wear full protective gear Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Stop the flow of material, if this is without risk. Methods for cleaning up : Spill area will be slippery; use care to avoid falling. Confine spill and soak up with absorbent. Place in an approved container and dispose in accordance with local, state and federal regulations Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions : Store between 40 F /4 C and 110 F /43 C. Keep from freezing. Keep drums tightly closed to avoid evaporation Specific end use(s) Manufacturing 02/06/2014 EN (English) 2/5

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection : General (mechanical) room ventilation is expected to be satisfactory for normal handling. : Use rubber gloves. : Use chemical splash goggles. : Wear suitable work clothes to minimize skin contact : None needed under normal product use conditions. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Colour : Colorless. Odour : Odorless. Odour threshold ph : Relative evaporation rate (butylacetate=1) : < 1 Melting point Freezing point : 0 C (32 F) Boiling point : 100 C (212 F) at 760 mm Hg Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Specific gravity : Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability The product is stable at normal handling and storage conditions Possibility of hazardous reactions Will not occur Conditions to avoid None Incompatible materials Strong acids 02/06/2014 EN (English) 3/5

4 10.6. Hazardous decomposition products Not Determined SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Zacsil Solution ATE (oral) LD50 oral rat ATE (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) : Harmful if swallowed mg/kg bodyweight 1300 mg/kg mg/kg bodyweight Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity LC50 fishes 1 LC50 fish mg/l (Exposure time: 96 h - Species: Lepomis macrochirus) 3185 mg/l (Exposure time: 96 h - Species: Brachydanio rerio [semi-static]) Persistence and degradability Bioaccumulative potential BCF fish 1 (no bioaccumulation expected) Mobility in soil Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose of contents/container in accordance with local/regional/national/international regulations. SECTION 14: Transport information In accordance with DOT Not a dangerous good in sense of transport regulations SECTION 15: Regulatory information US Federal regulations Water ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory 02/06/2014 EN (English) 4/5

5 Listed on the United States TSCA (Toxic Substances Control Act) inventory US State regulations SECTION 16: Other information Full text of H-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category H302 Harmful if swallowed This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 02/06/2014 EN (English) 5/5

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