SAFETY DATA SHEET E-MOX PRO BROAD SPECTRUM WORMER FOR HORSES. Bayer Australia Ltd 875 Pacific Highway Pymble NSW Page 1 of 9
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1 Page 1 of 9 SAFETY DATA SHEET A18236/01/AUS E-MOX PRO BROAD SPECTRUM WORMER FOR HORSES SECTION 1 IDENTIFICATION Bayer Australia Ltd 875 Pacific Highway Pymble NSW 2073 Product Name Emergency Telephone Number hour Emergency Service Australia Wide, Toll Free Contact Point (for non-emergency calls) Animal Health Division (02) E-MOX PRO BROAD SPECTRUM WORMER FOR HORSES Product Use Other Names FOR ANIMAL TREATMENT ONLY For the broad-spectrum treatment and control of roundworms, tapeworms and bots in horses. Moxidectin, Oxfendazole, Praziquantel Creation Date 25 November 2015 Revision Date New SDS
2 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 2 of 9 SECTION 2 HAZARD IDENTIFICATION Hazard Classification HAZARDOUS SUBSTANCE NOT CLASSIFIED AS DANGEROUS GOODS when transported by road or rail within Australia under Special Provision AU01 of the Australian Dangerous Goods Code, 7th Edition. CLASSIFIED AS DANGEROUS GOODS when transported by sea or air. GHS-Classification Signal Word Hazard Statements Precautionary statements Acute toxicity, Oral, Category 4 (H302) Acute toxicity, Inhalation, Category 4 (H332) Eye irritation, Category 2 (H319) Hazardous to the aquatic environment, Category 1 (H400) Hazardous to the aquatic environment, Category 1 (H410) WARNING H302 + H332 Harmful if swallowed or if inhaled H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects. Prevention: P202 Do not handle until all safety precautions have been read and understood. P273 Avoid release to the environment. P281 Use personal protective equipment as required. Response: P312 Call Poisons Information or doctor/ physician if you feel unwell. P337 + P313 If eye irritation persists: Get medical advice/ attention. P391 Collect spillage.
3 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 3 of 9 SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Components Moxidectin Concentration [Weight percent] >= < 2.5 CAS-No.: CAS name: Milbemycin B, 5-O-demethyl-28-deoxy-25-[(1E)-1,3- dimethyl-1-butenyl]-6,28-epoxy-23-(methoxyimino)-,6r,23e,25s)- GHS Classification: Acute Tox. 3 H301 Acute Tox. 4 H332 Repr. 2 H361 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Also contains Benzyl alcohol Concentration [Weight percent] >= 2 - <= 10 CAS-No.: CAS name: Benzenemethanol GHS Classification: Acute Tox. 4 H332 Acute Tox. 4 H302 Sodium metabisulphite Concentration [Weight percent] >= <= 0.5 CAS No.: CAS name: Pyrosulfurous acid, disodium salt GHS Classification: Acute Oral Toxicity - Category 4 Eye Damage - Category 1
4 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 4 of 9 SECTION 4 FIRST AID MEASURES First Aid Statement Poisons Schedule Schedule 5 If poisoning occurs, contact a doctor or Poisons Information Centre. Phone Australia Inhalation Skin contact Eye contact Ingestion Advice to doctor Inhalation of fumes is unlikely with this paste formulation. If coughing, dizziness or shortness of breath develops, move individual to fresh air. Seek medical attention. Remove contaminated clothing and clean before reuse. Wash all exposed areas of skin with plenty of soap and water. Seek medical attention if irritation develops. Hold eyelids open and flush with a steady, gentle stream of water for 15 minutes. Seek medical advice if irritation persists. Do not induce vomiting. Give a glass of water to drink. Seek medical attention. Harmful if swallowed. May cause abdominal pain and discomfort, anorexia, headache, dizziness, fever, nausea, vomiting and diarrhoea. Extremely large oral doses may cause intestinal cramps, loss of appetite, lethargy, lung bleeding, oedema, liver and epicardial bleeding. Other symptoms including giddiness, ringing in the ears, sleeplessness, anxiety, confusion, convulsions, hallucinations, drowsiness, insomnia and skin rashes have also been reported. SECTION 5 FIRE FIGHTING MEASURES Flammability Non-flammable. Extinguishing Media Fire and Explosion Hazards Hazardous Combustion Products Fire Fighting Carbon dioxide, extinguishing powder, foam. Not known. May produce carbon monoxide, nitrogen oxides and sulphur oxides when heated to decomposition. Wear self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes.
5 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 5 of 9 SECTION 6 ACCIDENTAL RELEASE MEASURES Accidental Release Emergency Procedures: None applicable. Product is supplied as a paste in discrete dosage syringes. Method of Containment and Clean up Procedures Wear protective equipment to prevent skin and eye contamination. Immediately remove spills with a binding material (e.g. sand, sawdust or diatomaceous earth). Treat spill area with plenty of water. Dispose of waste by burying or incineration in compliance with local waste disposal regulations. Dispose of empty container and syringe by wrapping with paper and putting in garbage. Do not contaminate streams, rivers or waterways. SECTION 7 HANDLING AND STORAGE Safe Handling Limit all unnecessary personal contact. Use only as directed. Harmful if swallowed. May irritate the eyes and skin. Avoid contact with eyes and skin. Do not smoke, eat or drink while handling or using the product. Observe good personal hygiene by washing hands before and after use. Wear rubber gloves when opening the container and using the product. Wash hands after use. Always handle product according to label to ensure product integrity. Storage Store below 30 C (Room temperature) in a dry and well-ventilated place, and away from incompatible materials and direct sunlight. Keep out of reach of children. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Limits Ventilation Eye Protection Skin Protection Respirator There are no exposure limits established for this formulation. Natural ventilation should be adequate under normal operating conditions. Eye protection such as protective glasses or goggles is recommended when this product is being used. Avoid prolonged skin contact. Wash hands or other exposed areas after handling and use. Under normal conditions of use with sufficient ventilation no respiratory protection is required.
6 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 6 of 9 SECTION 9 PHYSICAL & CHEMICAL PROPERTIES Physical State Appearance Odour Vapour pressure Boiling point Paste Off-white to pale pink colour A characteristic apple odour No statements available No statements available Viscosity 20 C ph 20 C Apparent density Flash point C. Non flammable SECTION 10 STABILITY & REACTIVITY Chemical Stability Stable under normal ambient and anticipated storage conditions of temperature and pressure. Conditions to Avoid Incompatible Materials Hazardous Decomposition Hazardous Reactions Keep away from extreme heat. Oxidising agents. May produce carbon monoxide, nitrogen oxides and sulphur oxides when heated to decomposition. Polymerisation will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Acute Toxicity Acute oral toxicity: Moxidectin LD50 (mouse): 42mg/kg Praziquantel LD50 (rat): 1050mg/kg Oxfendazole LD50 (rat, mouse): 6400mg/kg Benzyl alcohol LD50 (rabbit): 1040mg/kg Acute dermal toxicity: No evidence of dermal toxicity for any of the ingredients. Acute inhalational toxicity: Moxidectin LC50 (rat, dust/mist): 3.28mg/L Skin irritation Eye irritation Sensitisation Reproductive Effects Mutagenicity Carcinogenic Effects Contact may cause mild skin irritation and discomfort. Contact may cause moderate discomfort to eyes, and mild redness. The mixture is considered to be sensitising, because at least one of the ingredients present at >0.1% is sensitising. Moxidectin treatment studies in horses did not show an effect on the outcome of pregnancy. No ingredients present at a concentration >0.1% is considered to be a mutagen. No ingredients present at a concentration >0.1% is considered to be a mutagen.
7 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 7 of 9 SECTION 12 ECOLOGICAL INFORMATION Ecotoxicology Assessment Toxicity This substance is considered extremely toxic in the aquatic environment, toxic towards terrestrial invertebrates and harmful in the soil environment and towards terrestrial vertebrates. Toxicity to fish: Moxidectin Acute Fish toxicity: LC50 0,16 μg/l Test species: Oncorhynchus mykiss (rainbow trout) LC50 0,62 μg/l Test species: Lepomis macrochirus (Bluegill) Acute Fish toxicity: LC50 10 mg/l Test species: Lepomis macrochirus (Bluegill) Duration of test: 96 h Toxicity to daphnia and other aquatic invertebrates: Moxidectin EC50 30,2 ng/l Test species: Daphnia magna (Water flea) EC50 55 mg/l Test species: Daphnia magna (Water flea) Duration of test: 24 h Toxicity to algae: Moxidectin EC50 > 86,9 μg/l IC50 > 100 mg/l Duration of test: 72 h Toxicity to bacteria: EC mg/l Test species: Photobacterium phosphoreum Duration of test: 0.5 h Toxicity to fish (Chronic toxicity): No statements available. Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): No statements available. Persistence and degradability Biodegradability: %, 28 d rapidly biodegradable Method: OECD Test Guideline 301C Biochemical Oxygen Demand (BOD): No statements available. Chemical Oxygen Demand (COD): No statements available.
8 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 8 of 9 SECTION 13 DISPOSAL CONSIDERATIONS Spills and disposal Immediately remove spills with liquid binding material (e.g. sand, sawdust or diatomaceous earth). Treat spill area with plenty of water. Place product in container and dispose of waste in compliance with local waste disposal regulations. Do not allow product to contaminate waterways or sewage disposal areas. Dispose of empty container by wrapping with paper and putting in garbage. SECTION 14 TRANSPORT INFORMATION UN No 3082 UN Proper Shipping Name Class & Subsidiary Risk Packaging Group Hazchem Code Environmentally Hazardous Substance, Liquid, NOS (Moxidectin) 9 III 3Z NOT CLASSIFIED AS DANGEROUS GOODS when transported by road or rail within Australia under Special Provision AU01 of the Australian Dangerous Goods Code, 7th Edition. CLASSIFIED AS DANGEROUS GOODS when transported by sea or air. SECTION 15 REGULATORY INFORMATION Poisons Schedule Schedule S5 APVMA Registration The product is registered by the APVMA. Registration Number Labelling All necessary directions, precautions and warnings for normal use of the product are included on the product label.
9 A18236/01/AUS ULTRAMOX ORAL PASTE FOR HORSES Page 9 of 9 SECTION 16 OTHER INFORMATION Summary of Changes Acronyms Disclaimer New SDS. ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail APVMA Australian Pesticides and Veterinary Medicines Authority CAS Chemical Abstracts Service Registry Number GHS Globally Harmonized System of Classification and Labelling of Chemicals HDPE High density polyethylene LDPE Low density polyethylene OECD Organisation for Economic Co-operation and Development STOT Specific Target Organ Toxicity SUSDP Standard for the Uniform Scheduling of Drugs and Poisons TWA Time Weighted Average average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week. UN Number United Nations number This Safety Data Sheet has been developed according to the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Third revised edition. United Nations, The data, information and recommendations herein ("information") are represented in good faith and believed to be correct as of the date hereof. The purpose of this Safety Data Sheet is to describe product in terms of their safety requirements. Bayer Australia Limited makes no representation of merchantability, fitness for a particular purpose or application, or of any other nature with respect to the information or the product to which the information refers ("the product"). The information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use of the product. The physical data shown herein are typical values based on material tested. These values should not be construed as a guaranteed analysis of any specific lot or as guaranteed specification for the product or specific lots thereof. Due care should be taken to make sure that the use or disposal of this product and / or its packaging is in compliance with relevant Federal, State and Local Government regulations. END OF SDS
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