Page 1/6. Material Safety Data Sheet acc. to ISO/DIS 11014

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1 Page 1/6 1 Identification of substance: Product details: Application of the substance / the preparation Additive i.e. for OPV and printing inks/ For industrial use only! Manufacturer/Supplier: Indulor Group info@indulor.de Schulstraße 3 D Ankum Germany Phone: Fax: Emergency information: 24 h Medical Emergency Phone: (800) (USA and Canada) or (International) In the event of emergency spill, fire or exposure call Chemtrec: (800) or international: Composition/Data on components: CAS Wt % Components Water Proprietary 40.0 Styrene-Acrylic Resin (non-hazardous) Ammonia, calculated on 100% (substance is nearly fully reacted to form the polymer ammonium salt) 3 Hazards identification Effects of acute exposure: Eye: May cause eye irritation. Skin: Prolonged or repeated contact may cause mild skin irritation. Inhalation: Inhalation of the vapours of the heated product may cause irritation of mucuous membranes, headache, nausea, dizziness drowsiness. Ingestion: May cause nausea or abdominal discomfort. Information pertaining to particular dangers for man and environment According to current European laws and regulations the product is not dangerous or toxic material (based on the available data). NFPA ratings (scale 0-4) Health = 1 0= Insignificant Fire = 0 Reactivity = 0 1= Slight 2= Moderate 3= High 4= Very High 4 First aid measures General information Immediately remove any clothing soiled by the product. (Contd. on page 2)

2 Page 2/6 (Contd. of page 1) After inhalation In case of complaints which may be caused by vapours supply fresh air. If breathing is affected, consult a doctor. After skin contact Remove soiled clothes and shoes. Clean effected skin thoroughly with water and a mild cleansing agent. No residues shall remain on the skin. If irritation develops, consult a doctor. After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing Rinse out mouth and then drink plenty of water. Seek medical treatment. Information for doctor The following symptoms may occur: After inhalation of the vapours: Irritation of mucuous membranes, headache, nausea, dizziness, drowsiness. 5 Fire fighting measures Flashpoint: not applicable Flammable Limits: not applicable Autoignition: not applicable Suitable extinguishing agents CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire fighting measures that suit the environment. Special hazards caused by the material, its products of combustion or resulting gases: Dangerous decomposition products see chapter 10: stability and reactivity. Protective equipment: Wear self-contained respiratory protective device. Do not inhale combustion vapours. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Collect contaminated fire fighting water separately. It must not enter the sewage system. 6 Accidental release measures Person-related safety precautions: Ensure adequate ventilation. Use respiratory protective device against the effects of fumes/vapours/aerosol. Keep unprotected persons away. Measures for environmental protection: Do not allow product to reach sewage system or any water course. Do not allow to penetrate the ground/soil. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Send for recovery or disposal in suitable receptacles. Dispose contaminated material as waste according to item 13. (Contd. on page 3)

3 Page 3/6 (Contd. of page 2) 7 Handling and storage Handling Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Avoid contact with eyes and skin. Avoid inhalation of vapours. Information about protection against explosions and fires: No special measures required. Storage Requirements to be met by storerooms and receptacles: Store at temperatures over 5 C and below 30 C, keep in closed containers. Information about storage in one common storage facility: Store away from foodstuffs and feed. Further information about storage conditions: None. 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: Ammonia: The OSHA PEL for ammonia is 50 ppm, 8-hour TWA; the ACGIH TLV is 25 ppm, 8-hour TWA with a STEL of 35 ppm. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment General protective and hygienic measures The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Do not eat or drink while working. All protective equipment used shall be according to 29 CFR.1910 Subpart I Personal Protective Equipment Breathing equipment: Necessary if OEL-values (see above) are reached. Protection of hands: Protective gloves. To avoid skin problems reduce the wearing of gloves to the required minimum. Check protective gloves prior to each use for their proper condition. The glove material has to be impermeable and resistant to the product. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation After use of gloves apply skin-cleaning agents and skin cosmetics. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 4)

4 Page 4/6 Eye protection: Chemical safety goggles with side shields Body protection: Protective work clothing. Apron 9 Physical and chemical properties: General Information (Contd. of page 3) Form: Liquid Color: Yellowish Odor: Characteristic Value/Range Unit Method Change in condition Melting point/melting range: undetermined Boiling point/boiling range: undetermined Flash point: Not applicable Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Vapor pressure: at 20 C 23.0 hpa Density: at 20 C appr g/cm³ Solubility in / Miscibility with Water: Miscible ph-value: at 20 C ~ 7.9 Viscosity: dynamic: at 25 C ~ 1400 mpas Haake Rotovisco RV 20 MS: MV-DIN Additional information VOC content: < 0.4 % 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. Materials to be avoided: Acids Oxidants Reducing agents Dangerous reactions No dangerous reactions known Dangerous products of decomposition: In the case of fire or at high temperatures the formation of the following decomposition products is possible: Irritant gases/vapours Corrosive gases/vapours (Contd. on page 5)

5 Page 5/6 (Contd. of page 4) 11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification: LD 50 (oral, rat): > 5000 mg/kg (analogy) LD 50 (dermal, rat): > 5000 mg/kg (analogy) Primary irritant effect: on the skin: Prolonged or repeated contact may cause mild skin irritation. on the eye: May cause eye irritation. Sensitization: No sensitizing effects known. Experience with humans: If used according to instructions no negative effects have been reported due to many years of experience. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. 12 Ecological information: Ecotoxical effects: Acquatic toxicity: Presently there are no ecotoxicological values available. General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Danger to drinking water is possible if large quantities leak into the ground or into water course. 13 Disposal considerations Product: Recommendation Disposal according to instructions of local authorities. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information DOT regulations: Hazard class: - regulations Land transport ADR/RID (cross-border) ADR/RID class: - regulations Maritime transport IMDG: IMDG Class: - regulations Marine pollutant: No (Contd. on page 6)

6 Page 6/6 (Contd. of page 5) Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - regulation 15 Regulations Markings according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. National regulations Water hazard class Germany) Water hazard class 1 (Self-assessment): slightly hazardous for water. Regulation or reporting requirements USA TSCA: All components of this material are included or are exempted from listing on the TSCA Inventory of Chemical Substances. This product contains a polymer for which qualification under the 1995 TSCA polymer exemption has been documented. SARA section 355: This product is not subject to the reporting requirements under SARA 355. SARA section 313: Ammonia is subject to the reporting requirements, but as ammonia salt only 10% are reportable. Prop. 65 Cancer: Product ingredients are not listed. Prop Repr. tox.: Product ingredients are not listed. 16 Other information: This information is based on our present knowledge. However, this shall not constitute a warranty, express or implied, for any specific product features and shall not establish a legally valid contractual relationship. Statements herein should not be construed as representations or warranties. Users are responsible to evaluate all available information when using product for any particular use and to comply with all applicable laws and regulations. Department issuing MSDS: Quality assurance Dr. Oberschmidt Contact: refer to section 1