Material Safety Data Sheet Sodium metasilicate pentahydrate MSDS# Section 1 - Chemical Product and Company Identification MSDS Name: Sodium

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1 Material Safety Data Sheet Sodium metasilicate pentahydrate MSDS# Section 1 - Chemical Product and Company Identification MSDS Name: Sodium metasilicate pentahydrate Catalog Numbers: S/5360/60, S/5360/63, S/6400/60 Synonyms: Disodium metasilicate pentahydrate; Disodium trioxosilicate pentahydrate. Company Identification:Fisher Scientific UK Bishop Meadow Road, Loughborough Leics. LE11 5RG For information in Europe, call:(01509) Emergency Number, Europe: Section 2 - Composition, Information on Ingredients CAS#: Chemical Name: Sodium metasilicate pentahydrate %: 100 EINECS#: unlisted Hazard Symbols: Text for R-phrases: see Section 16 Hazard Symbols: C Section 3 - Hazards Identification EMERGENCY OVERVIEW Harmful if swallowed. Causes burns. Irritating to respiratory system. Potential Health Effects Eye: Contact with eyes may cause severe irritation, and possible eye burns. Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May be harmful if swallowed. Inhalation: May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. Chronic: Chronic inhalation may cause effects similar to those of acute inhalation. Section 4 - First Aid Measures Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately. In case of contact, immediately flush skin with plenty of water for

2 at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# : CAS# : Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if

3 irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Solid Color: white Odor: ph: 12.6 (1% soln) Vapor Pressure: Viscosity: Boiling Point: Freezing/Melting Point: 72 deg C ( F) Autoignition Temperature: Not applicable Flash Point: Not applicable. Explosion Limits: Lower: Explosion Limits: Upper: Decomposition Temperature: Solubility in water: Very soluble in water Specific Gravity/Density: 1.75 Molecular Formula: Na2SiO3.5H2O Molecular Weight: Section 10 - Stability and Reactivity Chemical Stability: Stable. Conditions to Avoid: Dust generation. Incompatibilities with Other Materials Acids, fluorine, Flammable hydrogen gas may be produced on prolonged contact with materials such as aluminum, tin, lead, and zinc.. Hazardous Decomposition Products Toxic fumes of sodium oxide. Hazardous Polymerization Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# : VV CAS# : VV LD50/LC50: CAS# : Draize test, rabbit, skin: 250 mg/24h Severe; Oral, mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 1153 mg/kg;. CAS# : Oral, rat: LD50 = 847 mg/kg;. Carcinogenicity: Sodium metasilicate anhydrous - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Sodium metasilicate pentahydrate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Other: See actual entry in RTECS for complete information. Section 12 - Ecological Information Section 13 - Disposal Considerations Products considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local authority or advice. Empty containers must be decontaminated before returning for recycling.

4 Section 14 - Transport Information IATA IMO RID/ADR Section 15 - Regulatory Information European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C R 22 Harmful if swallowed. R 34 Causes burns. R 37 Irritating to respiratory system. Safety Phrases: S 13 Keep away from food, drink and animal feeding stuffs. S 24/25 Avoid contact with skin and eyes. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# : 1 CAS# : 1 Canada CAS# is listed on Canada's DSL List US Federal TSCA CAS# is listed on the TSCA Inventory. CAS# is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form in on the Section 16 - Other Information Text for R-phrases from Section 2 MSDS Creation Date: 12/12/1997 Revision #6 Date 3/23/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims,

5 losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages